- Title
- Microstructural evolution of welded creep aged 12% cr martensitic stainless steel
- Creator
- Marx, Genevéve
- Subject
- Stainless steel -- Welding
- Date Issued
- 2019
- Date
- 2019
- Type
- Thesis
- Type
- Doctoral
- Type
- DPhil
- Identifier
- http://hdl.handle.net/10948/30766
- Identifier
- vital:31128
- Description
- Tempered martensite ferritic (TMF) steels with 9-12% Cr additions are used extensively for high-pressure steam pipes in coal-fired power plants. They operate at temperatures above 500ºC and are consequently susceptible to creep damage. Due to economic reasons, welding must be performed on service exposed materials when a component needs to be replaced. Fusion welding results in the formation of different microstructural regions within the weldment. The primary failure mechanism of TMF steel welded components is Type IV cracking that results from accelerated void formation in the fine-grained heat affected zone (FGHAZ) during creep. Short-term creep-tests performed across weldments made on new and service exposed steels have shown that the weldment consistently fails in the FGHAZ of the service exposed material. This observation has not yet been fully explained since not much is known about the microstructural evolution of creep aged material during welding. Thus, further investigation on the microstructure of welded creep aged material is warranted. The main aim of this thesis was to investigate the microstructural evolution when welding upon creep aged 9-12% Cr martensitic steels using advanced electron microscopy techniques. X20CrMoV12-1 (12% Cr) in the virgin and long-term service-exposed state were investigated. GleebleTM weld simulation of the FGHAZ was performed on the materials. Detailed microstructural investigations were conducted on the parent and simulated FGHAZ materials to analyse the voids, dislocation density, micro-grains, and precipitates (M23C6, MX, Laves, Z-phase) in the materials. Light Microscopy (LM) and Scanning Electron Microscopy (SEM) was used to examine the voids. Twin-jet electropolished specimens were prepared for precipitate, micro-grain and substructure analyses using Transmission Kikuchi Diffraction (TKD) combined with Energy Dispersive Spectrometry (EDS), Concentric Backscatter (CBS) imaging, Energy-Filtered Transmission Electron Microscopy (EFTEM), and Annular Dark-Field Scanning Transmission Electron Microscopy (ADF-STEM) combined with EDS. The precipitates were extracted from the iron matrix using Bulk Replication and further investigated using EFTEM and STEM-EDS.
- Format
- xxx, 354 leaves
- Format
- Publisher
- Nelson Mandela University
- Publisher
- Faculty of Science
- Language
- English
- Rights
- Nelson Mandela University
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Collections
NMU School of Computer Science, Mathematics, Physics and Statistics
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | G Marx (210059257) Final Copy of PhD Thesis.pdf | 20 MB | Adobe Acrobat PDF | View Details Download |