- Title
- Triggering biodegradation of low-density polyethylene films containing biobased additives for ecological applications
- Creator
- Gada, Abongile
- Subject
- Refuse and refuse disposal
- Subject
- Plastics industry and trade -- Waste disposal Polyethylene Polyurethanes
- Date Issued
- 2019
- Date
- 2019
- Type
- Thesis
- Type
- Masters
- Type
- MSc
- Identifier
- http://hdl.handle.net/10948/39796
- Identifier
- vital:35460
- Description
- The aims of the present study are focused on the investigation of low-density polyethylene (LDPE) films that contain biobased pro-oxidizing additives (CSIR1% and CSIR3% (w/w)) for environmental degradation in different abiotic and biotic conditions in comparison to non-biodegradable commercially available Pick n Pay (PnP) PE grocery bags. In this project, a biobased pro-oxidant additive master batch was prepared in a heat kneader mixer. A mixture of biobased radical reaction initiators and natural polymers were melt processed as a master batch. The biobased pro-oxidant additive master batch CSIR1% and CSIR3% and LDPE components were melt-extruded to form biobased pro-oxidant additive LDPE pellets using a twin screw melt extruder. The pelletized biobased pro-oxidant additive LDPE was blown into a 25 -27 μm thick film using a melt blower machine. The LDPE containing biobased pro-oxidant additive CSIR 1% and 3% test samples and the PnP polyethylene carrier bags were submitted to thermal oxidizing test conditions in a 70°C air ventilated oven and direct sunlight (photo oxidation) for a period of six months (180 days). The thermal and photo-oxidized LDPE film test samples were further subjected to biotic degradation tests in aqueous, soil and compost environments for varying periods of 180 days to 263 days in biodegradation evaluation studies. The oxidation degradation rates of the test samples were monitored and determined by evaluating carbonyl index (COi) using FT-IR spectroscopy; molecular weight determination and distribution of the test materials were analyzed by Gel Permeation Chromatography (GPC); compounds analysis was done by GC-MS; percentage crystallinity (Xc%) was quantified by DSC; thermal stability by TGA and morphological surfaces were examined by SEM analytical techniques. Biodegradation tests simulating marine salt water, burial in soil and compost conditioning methods were used to determine the “potential biodegradability” of the thermally and photo-oxidized test samples after the oxidation period. The oxidation extent and rate of LDPE films containing CSIR3% biobased additives was higher than that of LDPE films containing CSIR1% biobased additives. GPC molecular weight determination and distribution results showed a decrease for all the test samples exposed to oxidation. The molecular weight of LDPE films containing CSIR1% biobased additives decreased from 404K Mw to 111K Mw for sunlight oxidized samples and to 16KMw for the thermally oxidized LDPE samples after 200 days of oxidation exposure. Molecular weight of LDPE films containing CSIR3% biobased additives showed the most reduction from 293K Mw to 22K Mw for sunlight oxidized samples and to 2K Mw for thermally oxidized samples after 100 days of oxidation exposure. DSC analysis showed that crystallinity degree decreased after exposure to thermal and photo-oxidation. TGA results showed a reduction of initial degradation temperature by almost half compared to zero-days untreated CSIR3% samples, with higher degree temperatures observed in samples exposed to thermal oxidation than those exposed to photo-oxidation. GC-MS revealed peaks of carbonyls such as alcohols, aldehydes, ketones, carboxylic and anionic acids, and very short chain alkenes and alkanes. The SEM showed heterogeneous morphological modifications in surfaces of samples even though they were not severe. After 172 days the oxidized LDPE samples containing CSIR3% biobased additives, were investigated for potential biodegradation in aqueous, soil and composting environments. Thermally oxidized and photo-oxidized CSIR3% samples showed a mineralization degree of 10.4% and 10.7% respectively, when oxidized in 181 days aqueous biodegradation, 20% and 7.7% respectively, when oxidized in 233 days of soil burial, and 52.6% and 62% respectively, oxidized in 263 days of compost. The obtained results confirmed the abiotic oxidation step as the initiation step for PE degradation, succeeded by assimilation, by action of microorganisms (ultimate biodegradation), of lower weight molecular compounds of oxidized LDPE samples in aqueous medium, soil and composting conditions to final end products of CO2, H2O and new microbial cell biomass.
- Format
- xvii, 116 leaves
- Format
- Publisher
- Nelson Mandela University
- Publisher
- Faculty of Science
- Language
- English
- Rights
- Nelson Mandela University
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NMU School of BioMolecular and Chemical Sciences
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | ABONGILE GADA.pdf | 3 MB | Adobe Acrobat PDF | View Details Download |