- Title
- Comparative analysis of characteristics of the various sugarcane bagasse types in terms of gasification
- Creator
- Kula, Mpumezo
- Subject
- Bagasse Sugarcane -- Breeding Coal gasification
- Date Issued
- 2016
- Date
- 2016
- Type
- Thesis
- Type
- Masters
- Type
- MSc
- Identifier
- http://hdl.handle.net/10353/13392
- Identifier
- vital:39656
- Description
- The insight that the fossil fuel reserves are limited, together with concerns over security of supply (i.e. the oil crises), initiated the first raise of interest in biomass and all other renewable energy forms. However, the concern grew that global warming and the resulting climate change were enhanced by carbon dioxide (CO2) emissions resulting from fossil fuel consumption. Meanwhile, biomass energy is thought to account for 14–15percent of total world energy consumption. Hence, the exploitation and utilization of biomass energy are effective and necessary for relieving the pressures caused by environmental pollution and fossil fuel shortage (Lv et al., 2010). Recently, extensive research aimed at converting biomass to useful energy have been carried out, especially pyrolysis and gasification, which are particularly suitable for the effective and efficient utilization of biomass. Sugarcane bagasse is the main byproduct of sugarcane mill, ready available at the production site so that it may be a suitable raw material for the production of biofuels, chemicals, and electricity. Among the methods that have been previously studied, is this particular study we explore thermochemical process, gasification. The properties of sugarcane bagasse relevant to gasification are briefly reviewed. The compositions of the bagasse as a fuel are variable, especially with respect to inorganic constituents important to the critical problems of sintering, fouling and slagging. Alkali and alkaline earth metals, in combination with other fuel elements such as silica and sulfur, are responsible for many undesirable reactions in a gasifier system. The three sugarcane bagasse types namely washed, unwashed and the depithed sugarcane bagasse were subjected in different types of characterization to review and compare their characteristics for gasification. Ultimate analysis was used to determine the elemental compositions and this was helpful in estimating the energy input of the materials. Elemental compositions were determined with the CHNS analyzer which gave the percent compositions of each fuel in terms of Carbon, Hydrogen, Nitrogen, Sulphur as well as Oxygen (by difference) and the SEM/EDX which gave the elemental composition of the materials as can be viewed from the EDX. The proximate analysis which is the physical characterization of the materials was carried out to preview the behavior of the sugarcane bagasse when subjected into high temperatures as the gasification process uses very high temperatures. These were determined by the TGA and the volatile matter content; fixed carbon content, moisture content and ash content were extrapolated from the resulting thermogram. SEM images for surface structures of the bagasse and FTIR for the structural functionality and bonding structures. The characterization of the bagasse was conducted to compare their gasification properties.
- Format
- 88 leaves
- Format
- Publisher
- University of Fort Hare
- Publisher
- Faculty of Science and Agriculture
- Language
- English
- Rights
- University of Fort Hare
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UFH Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | MSc (Chemistry) KULA, M.pdf | 1 MB | Adobe Acrobat PDF | View Details Download |