- Title
- Synthesis and singlet oxygen production by a phthalocyanine when embedded in asymmetric polymer membranes
- Creator
- Mafukidze, Donovan M
- Creator
- Mashazi, Philani N
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2016
- Date
- 2016
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/188563
- Identifier
- vital:44765
- Identifier
- xlink:href="https://doi.org/10.1016/j.polymer.2016.10.032"
- Description
- 2(3), 9(10), 16(17), 23(24)-Tetrakis-(4-aminophenoxy) phthalocyaninato indium (III) chloride (ClInTAPPc, 3) was first conjugated to two different polymers: polystyrene (PS) and polyacrylonitrile (PAN) to form 3-PS and 3-PAN. The conjugates were cast into the corresponding polymers to form membranes represented as 3-PS-membrane and 3-PAN-membrane, respectively. The prepared membranes were characterized using various techniques including scanning electron microscopy and solid state UV/Vis spectroscopy. Singlet oxygen quantum yields were higher for the 3-PS-membrane at 0.51 compared to 3-PAN-membrane at 0.35. The larger singlet oxygen also applies to 3-PS (0.63) compared to 3-PAN (0.38) when in solution.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (11 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Polymer
- Relation
- Mafukidze, D.M., Mashazi, P. and Nyokong, T., 2016. Synthesis and singlet oxygen production by a phthalocyanine when embedded in asymmetric polymer membranes. Polymer, 105, pp.203-213
- Relation
- Polymer volume 105 p. 203 2016 0032-3861
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Mashazi, Philani N (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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| View Details Download | SOURCE1 | Synthesis and singlet oxygen production by a phthalocyanine.pdf | 731 KB | Adobe Acrobat PDF | View Details Download |