- Title
- Enantioselective electrochemical carbon-chloride bond cleavage of hexachlorocyclohexanes (HCHs) catalyzed by Mn (III) Cl-phthalocyanine
- Creator
- Wen, Junxia
- Creator
- Yu, Baoqui
- Creator
- Huang, Tingting
- Creator
- Mack, John
- Creator
- Wildervanck, Martijn
- Creator
- Nyokong, Tebello
- Creator
- Li, Minzhi
- Creator
- Zhu, Weihua
- Creator
- Liang, Xu
- Subject
- To be catalogued
- Date Issued
- 2017
- Date
- 2017
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/189252
- Identifier
- vital:44831
- Identifier
- xlink:href="https://doi.org/10.1016/j.jelechem.2017.09.020"
- Description
- A lipophilic and electron-rich metallophthalocyanine Mn(III)Cl(α,α′-n-OC5H11)8Pc has been synthesized and characterized. A series of electrochemical experiments demonstrate that the Mn(III)Cl(α,α′-n-OC5H11)8Pc complex can be used as a catalyst for highly efficient carbon-chloride bond cleavage of environmental toxic hexachlorocyclohexanes (HCHs) through electrochemical catalysis, and that the increased catalytic efficiency is related to the enantiomeric carbon-chloride σ-bond of HCHs.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (6 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Electroanalytical Chemistry
- Relation
- Wen, J., Yu, B., Huang, T., Mack, J., Wildervanck, M., Nyokong, T., Li, M., Zhu, W. and Liang, X., 2017. Enantioselective electrochemical carbon-chloride bond cleavage of hexachlorocyclohexanes (HCHs) catalyzed by Mn (III) Cl-phthalocyanine. Journal of Electroanalytical Chemistry, 803, pp.111-116
- Relation
- Journal of Electroanalytical Chemistry volume 803 p. 111 2017 1873-2569
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Mack, John (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Enantioselective electrochemical carbon-chloride bond cleavage of hexachlorocyclohexanes.pdf | 700 KB | Adobe Acrobat PDF | View Details Download |