- Title
- Electrospun fibers functionalized with phthalocyanine-gold nanoparticle conjugates for photocatalytic applications
- Creator
- Tombe, Sekai
- Creator
- Antunes, Edith M
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2013
- Date
- 2013
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/193769
- Identifier
- vital:45394
- Identifier
- xlink:href="https://doi.org/10.1016/j.molcata.2013.01.033"
- Description
- The heterogeneous photocatalytic activity of Zn(II) phthalocyanine-gold nanoparticle conjugates immobilized on electrospun polystyrene fibers was investigated using 4-chlorophenol and Orange G as model pollutants. The phthalocyanine-gold nanoparticle conjugates were synthesized via a ligand exchange reaction and characterized using spectroscopic and microscopic techniques. The interaction between the gold nanoparticles and phthalocyanines did not restrict the formation of excited singlet states, triplet states and hence the formation of singlet oxygen required for photocatalysis. The conjugates showed significantly higher singlet oxygen quantum yields and enhanced photocatalytic activity compared to the phthalocyanines. It was concluded that hybrid electrospun fibers provide great potential as active photocatalysts for oxidizing organic pollutants using singlet oxygen as an oxidant.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (10 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Molecular Catalysis A: Chemical
- Relation
- Tombe, S., Antunes, E. and Nyokong, T., 2013. Electrospun fibers functionalized with phthalocyanine-gold nanoparticle conjugates for photocatalytic applications. Journal of Molecular Catalysis A: Chemical, 371, pp.125-134
- Relation
- Journal of Molecular Catalysis A: Chemical volume 371 p. 125 2013 1873-314X
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Antunes, Edith Martins (Dr)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
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