- Title
- Characterization of 2,(3)-tetra-(4-oxo-benzamide) phthalocyaninato cobalt (II)—single walled carbon nanotube conjugate platforms and their use in electrocatalysis of amitrole
- Creator
- Mugadza, Tawanda
- Creator
- Arslanoğlu, Yasin
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2012
- Date
- 2012
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/244382
- Identifier
- vital:51252
- Identifier
- xlink:href="https://doi.org/10.1016/j.electacta.2012.02.041"
- Description
- In this paper we report on the use of carboxylic acid functionalized single walled carbon nanotubes (SWCNT) in the synthesis of 2,(3)-tetra-(4-oxo-benzamide)phthalocyaninato cobalt (II)–single walled carbon nanotube conjugates (CoTOBPc–SWCNT), their characterization and application in the electrocatalytic oxidation of amitrole. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were used for the detection of amitrole on the modified glassy carbon electrode. The catalytic rate constant was 1.6 × 103 M−1 s−1 and the apparent electron rate transfer constant was 1.5 × 10−5 cm s−1. The linear dynamic range was 1.0 × 10−6–3.0 × 10−5 M, with a sensitivity of ∼1.13 A mol−1 L cm−2.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (8 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Electrochimica acta
- Relation
- Mugadza, T., Arslanoğlu, Y. and Nyokong, T., 2012. Characterization of 2,(3)-tetra-(4-oxo-benzamide) phthalocyaninato cobalt (II)—single walled carbon nanotube conjugate platforms and their use in electrocatalysis of amitrole. Electrochimica acta, 68, pp.44-51
- Relation
- Electrochimica acta volume 68 p. 44 2012 0013-4686
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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- Visitors: 422
- Downloads: 60
Collections
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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