- Title
- The effects of point of substitution on the formation of manganese phthalocyanine-based molecular materials
- Creator
- Akinbulu, Isaac Adebayo
- Creator
- Khene, Samson
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2010
- Date
- 2010
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/249103
- Identifier
- vital:51778
- Identifier
- xlink:href="https://doi.org/10.1016/j.tsf.2010.08.145"
- Description
- Molecular films of manganese phthalocyanine (MnPc) complexes, tetra-substituted with 2-diethylaminoethanethio at the peripheral (Mn(OAc)-β-TDEAETPc, 1) and non-peripheral (Mn(OAc)-α-TDEAETPc, 2) positions were formed on glassy carbon electrode by electropolymerization and electrodeposition respectively. Atomic force microscopy images confirmed the presence of the films and revealed significant morphological differences. The films exhibited an electrocatalytic activity towards the oxidation of the insecticide, bendiocarb. Hydrodynamic technique, using rotating disc electrode voltammetry, was used to investigate the kinetics of electro-oxidation of the insecticide. Morphological differences of the films significantly influenced kinetic parameters. Values of Tafel slopes, obtained from Tafel plots, suggested that catalysis of bendiocarb occurred via outer sphere mechanism.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (8 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Thin Solid Films
- Relation
- Akinbulu, I.A., Khene, S. and Nyokong, T., 2010. The effects of point of substitution on the formation of manganese phthalocyanine-based molecular materials: Surface characterization and electrocatalysis. Thin solid films, 519(2), pp.911-918
- Relation
- Thin Solid Films volume 519 number 2 p. 911 2010 0040-6090
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Khene, Samson Mielie (Assoc Prof)
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
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