- Title
- Comparative electrocatalytic behavior of self-assembled monolayer of thiol derivatised Co (II) phthalocyanines on gold disk, ultramicro cylinder and fiber electrodes
- Creator
- Nombona, Nolwazi
- Creator
- Geraldo, Daniela A
- Creator
- Hakuzimana, Jean
- Creator
- Schwarz, Anne
- Creator
- Westbroek, Philippe
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2009
- Date
- 2009
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/263488
- Identifier
- vital:53632
- Identifier
- xlink:href="https://doi.org/10.1007/s10800-008-9716-y"
- Description
- This paper reports on the use of thiol derivatised cobalt phthalocyanines as self assembled monolayers (SAMs) on gold disk electrode, gold ultramicro-cylinder electrode (UMCE) and on gold coated fiber for the detection of L-cysteine. The complexes are peripherally and non-peripherally substituted with phenylthio substituents. The SAM modified electrodes showed enhancement of catalytic currents and overpotential reduction occurred on the gold modified electrodes with different geometries. Electrocatalytic oxidation of L-cysteine on SAM modified gold coated fiber was reported for the first time. The gold coated fiber and ultramicro cylinder electrode were less stable towards the electrocatalytic oxidation of cysteine compared to its oxidation on the gold disk. The gold disk electrode gave better catalytic performance in terms of stability and reduction of overpotential.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (10 pages)
- Format
- Publisher
- SpringerLink
- Language
- English
- Relation
- Journal of Applied Electrochemistry
- Relation
- Nombona, N., Geraldo, D.A., Hakuzimana, J., Schwarz, A., Westbroek, P. and Nyokong, T., 2009. Comparative electrocatalytic behavior of self-assembled monolayer of thiol derivatised Co (II) phthalocyanines on gold disk, ultramicro cylinder and fiber electrodes. Journal of applied electrochemistry, 39(5), pp.727-736
- Relation
- Journal of Applied Electrochemistry volume 39 number 5 p. 727 2009 1572-8838
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the SpringerLink Terms of Use Statement ( https://link.springer.com/termsandconditions)
- Rights
- Open Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
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| View Details Download | SOURCE1 | Comparative electrocatalytic behavior of self-assembled monolayer.pdf | 642 KB | Adobe Acrobat PDF | View Details Download |