- Title
- Spectrophotometric and electrochemical studies of the interaction between iron (II) tetrasulfophthalocyanine and histamine
- Creator
- Oni, Joshua
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2002
- Date
- 2002
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/289629
- Identifier
- vital:56657
- Identifier
- xlink:href="https://doi.org/10.1142/S1088424602000233"
- Description
- The interaction between iron(II) tetrasulfophthalocyanine ([FeIITSPc]4+) and histamine results in the oxidation of the central metal by oxygen in the former, with the formation of a complex denoted as [(His)FeIIITSPc]3− (where His = histamine). The rate constant for the formation of the complex is kf = 2.41 × 10−2dm3.mol−1.s−1 and an equilibrium constant of 6.3 dm3.mol-1 was obtained. The oxidation state of the central metal of [FeIITSPc]4− before and after the coordination of histamine is confirmed by spectroelectrochemistry. Further electrochemical oxidation of this [(His)FeIIITsPc]3− derivative results in a metal-based process proposed to involve an FeIV phthalocyanine species.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (9 pages)
- Format
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Journal of Porphyrins and Phthalocyanines
- Relation
- Oni, J. and Nyokong, T., 2002. Spectrophotometric and electrochemical studies of the interaction between iron (II) tetrasulfophthalocyanine and histamine. Journal of Porphyrins and Phthalocyanines, 6(03), pp.203-210
- Relation
- Journal of Porphyrins and Phthalocyanines volume 6 number 03 p. 203 2002 1099-1409
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the World Scientific Copyright and Permissions Statement (https://0-www.worldscientific.com.wam.seals.ac.za/page/permissions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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