- Title
- Comparative photosensitised transformation of polychlorophenols with different sulphonated metallophthalocyanine complexes in aqueous medium
- Creator
- Ozoemena, Kenneth
- Creator
- Kuznetsova, Nina
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2001
- Date
- 2001
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/291520
- Identifier
- vital:56883
- Identifier
- xlink:href="https://doi.org/10.1016/S1381-1169(01)00243-6"
- Description
- The relative efficiencies for the oxidation of trichlorophenol (TCP) and pentachlorophenol (PCP), sensitised by sulphonated phthalocyanine complexes containing Zn, Al, Sn and Si as central metals, were studied in aqueous solutions. For the first time, sulphonated silicon and tin phthalocyanines were synthesised and their activity towards photosensitisation of singlet oxygen and photo-oxidation of polychlorophenols was examined. The efficiency of the sensitised photo-oxidative degradation of polychlorophenols depends not only on singlet oxygen quantum yield of sensitiser, but also on its stability. The influence of substrate structure and the pH of the solution on the photo-oxidation efficiency, as well as on the sensitiser photodegradation were studied. It was found that the contribution of the Type II (singlet oxygen-mediated) mechanism to the relative efficiency of the photosensitised photo-oxidation of the phenol, decreased from phenol to p-chlorophenol, TCP and PCP, whereas Type I radical pathway increased. The results obtained for PCP give evidence that electron transfer from the excited sensitiser to the substrate in its unionised form is responsible for enhanced sensitiser photodegradation.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (12 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Molecular Catalysis A: Chemical
- Relation
- Ozoemena, K., Kuznetsova, N. and Nyokong, T., 2001. Comparative photosensitised transformation of polychlorophenols with different sulphonated metallophthalocyanine complexes in aqueous medium. Journal of Molecular Catalysis A: Chemical, 176(1-2), pp.29-40
- Relation
- Journal of Molecular Catalysis A: Chemical volume 176 number 1-2 p. 29 2001 1873-314X
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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RU Department of Chemistry
Nyokong, Tebello (Distinguished Professor)
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