Infrared evidence for the transmission of electronic effects through a metal atom in a series of new cadmium complexes

Title: Infrared evidence for the transmission of electronic effects through a metal atom in a series of new cadmium complexes
Creator: Haigh, John M
Creator: Van Dam, M A
Creator: Thornton, D A
Date Issued: 1967
Date: 1967
Type: text
Type: Article
Identifier: vital:6371
Identifier: http://hdl.handle.net/10962/d1006073
Description: A series of novel cadmium complexes has been synthesized from the reaction of cadmium chloride, bromide and iodide with primary aromatic amines. The complexes are either mononuclear or polynuclear according to the nature of the halide and amine employed. A possible mechanism for their formation is proposed. The N - H stretching and bending frequencies are linearly related to the electronegativity of the co-ordinated halogen, indicating that the electron withdrawing capacity of the halogen is transmitted through the cadmium atom.
Format: 10 pages
Format: pdf
Language: English
Relation: Haigh, J.M. and van Dam, M.A. and Thornton, D.A. (1967) Infrared evidence for the transmission of electronic effects through a metal atom in a series of new cadmium complexes. Zietschrift fur anorganische und allgemeine Chemie, 355 . pp. 94-103.

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RU Department of Pharmacy

Haigh, JM (Prof)

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