Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone

Title: Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone
Creator: Idahosa, Kenudi C
Creator: Molefe, Duduzile M
Creator: Pakade, Vusumzi E
Creator: Brown, Michael E
Date Issued: 2011
Date: 2011
Type: Article
Identifier: vital:6574
Identifier: http://hdl.handle.net/10962/d1004137
Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
Format: 7 pages
Format: pdf
Language: English
Relation: Idahosa, K.C. and Molefe, D.M. and Pakade, V.E. and Brown, M.E. (2011) Elucidation of the Complex Baylis-Hillman Reaction of 3-Methoxy-2-nitrobenzaldehyde with Methyl Vinyl Ketone. South African Journal of Chemistry, 64 . pp. 144-150.

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Brown, Michael Ewart 1938- (Prof)

RU Department of Chemistry

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