Characterization of amine-functionalized single-walled carbon nanotube-low symmetry phthalocyanine conjugates

Title: Characterization of amine-functionalized single-walled carbon nanotube-low symmetry phthalocyanine conjugates
Creator: Chidawanyika, Wadzanai J U
Creator: Nyokong, Tebello
Type: Article
Identifier: vital:7237
Identifier: http://hdl.handle.net/10962/d1019688
Description: Functionalization of single-walled carbon nanotubes (SWCNTs) with amine groups using a previously developed diazonium approach, followed by reaction with a carboxylic acid moiety allows direct attachment by an amide bond. We have developed a new SWCNT-low symmetry phthalocyanine conjugate using this approach, using dicyclohexylcarbodiimide as an activating agent to facilitate formation of an amide bond to give a covalently linked conjugate. A conjugate formed by non-covalent attachment has been used for a comparative investigation by FT-IR, Raman, and UV–Vis spectroscopies, and thermal gravimetric analysis. The fluorescence of the phthalocyanine is quenched in the conjugate.
Description: Original publication is available at http://dx.doi.org/10.1016/j.carbon.2010.04.015
Format: 9 p.
Format: pdf
Publisher: Elsevier
Language: English
Relation: Chidawanyika, W., & Nyokong, T. 2010. Characterization of amine-functionalized single-walled carbon nanotube-low symmetry phthalocyanine conjugates. Carbon, 48(10): 2831-2838. Available: http://dx.doi.org/10.1016/j.carbon.2010.04.015

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Nyokong, Tebello (Distinguished Professor)

RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology

RU Department of Chemistry