Improved triplet state parameters for indium octacarboxy phthalocyanines when conjugated to quantum dots and magnetite nanoparticles

Title: Improved triplet state parameters for indium octacarboxy phthalocyanines when conjugated to quantum dots and magnetite nanoparticles
Creator: Tshangana, Charmaine
Creator: Nyokong, Tebello
Type: Article
Identifier: vital:7252
Identifier: http://hdl.handle.net/10962/d1020260
Description: Fe3O4 magnetic nanoparticles (MNPs) and glutathione (GSH) capped CdSe@ZnS quantum dots (QDs) were separately coordinated to indium octacarboxy phthalocyanine (InPc(COOH)8) to form ClInPc(COOH)8–MNPs and ClInPc(COOH)8–GSH–CdSe@ZnS, respectively. The photophysical parameters (triplet state and fluorescence quantum yields and lifetimes) were determined for the conjugates. The triplet quantum yields increased from ΦT = 0.49 for InPc(COOH)8 alone to ΦT = 0.61 and 0.56 for InPc(COOH)8 in the conjugates: ClInPc(COOH)8–MNPs and ClInPc(COOH)8–GSH–CdSe@ZnS, respectively. The lifetimes also became longer for the conjugates compared to Pc alone.
Description: Original publication is available at http://dx.doi.org/10.1016/j.molstruc.2015.02.040
Format: 9 p.
Format: pdf
Publisher: Elsevier
Language: English
Relation: Tshangana, C. & Nyokong, T. 2015. Improved triplet state parameters for indium octacarboxy phthalocyanines when conjugated to quantum dots and magnetite nanoparticles. Journal of Molecular Structure, 1089:161–169. Available: http://dx.doi.org/10.1016/j.molstruc.2015.02.040.

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Nyokong, Tebello (Distinguished Professor)