Improved l-cysteine electrocatalysis through a sequential drop dry technique using multi-walled carbon nanotubes and cobalt tetraaminophthalocyanine conjugates

Nyoni, Stephen; Mugadza, Tawanda; Nyokong, Tebello

Title: Improved l-cysteine electrocatalysis through a sequential drop dry technique using multi-walled carbon nanotubes and cobalt tetraaminophthalocyanine conjugates
Creator: Nyoni, Stephen
Creator: Mugadza, Tawanda
Creator: Nyokong, Tebello
Type: Article
Identifier: vital:7308
Identifier: http://hdl.handle.net/10962/d1020385
Description: Voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy methods are used for characterization of a glassy carbon electrode modified with multi-walled carbon nanotubes (MWCNTs)–cobalt tetraaminophthalocyanine (CoTAPc) mixture or sequential drop dry modification technique whereby the MWCNTs are first placed on to the electrode followed by CoTAPc. The sequential drop dry CoTAPc–MWCNTs modified surface gave better catalytic responses with a catalytic rate constant of 2.2 × 105 M−1 s−1, apparent electron transfer rate constant of 0.073 cm s−1, and a limit of detection of 2.8 × 10−7 M. Scanning electrochemical microscopy (SECM) surface characterization (topography and reactivity) further gave proof the better catalytic perfomance of the sequential drop dry CoTAPc–MWCNTs modified surface.
Description: Original publication is available at http://dx.doi.org/10.1016/j.electacta.2013.10.023
Format: 9 p.
Format: pdf
Publisher: Elsevier
Language: English
Relation: Nyoni, S., Mugadza, T. & Nyokong, T. 2014. Improved l-cysteine electrocatalysis through a sequential drop dry technique using multi-walled carbon nanotubes and cobalt tetraaminophthalocyanine conjugates. Electrochimica Acta, 128:32–40. Available: http://dx.doi.org/10.1016/j.electacta.2013.10.023.

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Nyokong, Tebello (Distinguished Professor)