1H NMR-based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative

Lobb, Kevin A; Kaye, Perry T

Title: 1H NMR-based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative
Creator: Lobb, Kevin A
Creator: Kaye, Perry T
Subject: To be catalogued
Date Issued: 2011
Date: 2011
Type: text
Type: article
Identifier: http://hdl.handle.net/10962/448858
Identifier: vital:74766
Identifier: xlink:href="https://doi.org/10.1002/poc.1699"
Description: 1H NMR analysis of the kinetics of skeletal rearrangement of optically pure 3,3-xylyl-2-exo-bornyl tosylate in CDCl3 indicates the operation of tandem autocatalytic and pseudo-first-order transformations, leading sequentially to a pairof isomeric camphene derivatives and involving partial racemization. Changing the solvent system has been shown topermit the chemoselective isolation of either of the isomeric camphenes.
Format: computer
Format: online resource
Format: application/pdf
Format: 1 online resource (7 pages)
Format: pdf
Publisher: Wiley
Language: English
Relation: Journal of Physical Organic Chemistry
Relation: Lobb, K.A. and Kaye, P.T., 2011. 1H NMR-based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative. Journal of Physical Organic Chemistry, 24(1), pp.38-44
Relation: Journal of Physical Organic Chemistry volume 24 number 1 p. 38 2011 1099-1395
Rights: Publisher
Rights: Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
Rights: Closed Access

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Kaye, Perry T (Distinguished Fellow Emeritus Professor)

Lobb, Kevin Allan (Assoc Prof)

RU Department of Chemistry

SDG 03. Good Health and Well-Being

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