31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane

Conibear, Anne C; Lobb, Kevin A; Kaye, Perry T

Title: 31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane
Creator: Conibear, Anne C
Creator: Lobb, Kevin A
Creator: Kaye, Perry T
Subject: To be catalogued
Date Issued: 2010
Date: 2010
Type: text
Type: article
Identifier: http://hdl.handle.net/10962/449304
Identifier: vital:74810
Identifier: xlink:href="https://doi.org/10.1016/j.tet.2010.08.058"
Description: 1H and 31P NMR methods have been used to access rate constants and activation parameters for each of the consecutive second-order silylation reactions involved in the overall transformation (1a→3a→4a), while computational optimisation of the rate constants obtained from the initial, linear phase of each reaction has permitted an excellent fit with the experimental data for the entire course of the reaction.
Format: computer
Format: online resource
Format: application/pdf
Format: 1 online resource (4 pages)
Format: pdf
Publisher: Elsevier
Language: English
Relation: Tetrahedron
Relation: Conibear, A.C., Lobb, K.A. and Kaye, P.T., 2010. 31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane. Tetrahedron, 66(43), pp.8446-8449
Relation: Tetrahedron volume 66 number 43 p. 8446 2010 1464-5416
Rights: Publisher
Rights: Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
Rights: Closed Access

Hits: 119
Visitors: 121
Downloads: 5

Collections

RU Centre for Chemico- and Biomedicinal Research (CCBR)

Lobb, Kevin Allan (Assoc Prof)

Kaye, Perry T (Distinguished Fellow Emeritus Professor)

RU Department of Chemistry

SDG 03. Good Health and Well-Being

		Thumbnail	File	Description	Size	Format
View Details Download			SOURCE1	31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane.pdf	688 KB	Adobe Acrobat PDF	View Details Download