- Title
- 31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane
- Creator
- Conibear, Anne C
- Creator
- Lobb, Kevin A
- Creator
- Kaye, Perry T
- Subject
- To be catalogued
- Date Issued
- 2010
- Date
- 2010
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/449304
- Identifier
- vital:74810
- Identifier
- xlink:href="https://doi.org/10.1016/j.tet.2010.08.058"
- Description
- 1H and 31P NMR methods have been used to access rate constants and activation parameters for each of the consecutive second-order silylation reactions involved in the overall transformation (1a→3a→4a), while computational optimisation of the rate constants obtained from the initial, linear phase of each reaction has permitted an excellent fit with the experimental data for the entire course of the reaction.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (4 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Tetrahedron
- Relation
- Conibear, A.C., Lobb, K.A. and Kaye, P.T., 2010. 31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane. Tetrahedron, 66(43), pp.8446-8449
- Relation
- Tetrahedron volume 66 number 43 p. 8446 2010 1464-5416
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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