- Title
- Electrochemical sensing based on functionalised carbon dots prepared by bottom-up approach
- Creator
- Madikizela, Ziyanda https://orcid.org/0000-0003-0405-8464
- Subject
- Electrochemical analysis
- Subject
- Electrodes, Carbon
- Date Issued
- 2021-02
- Date
- 2021-02
- Type
- Master's theses
- Type
- text
- Identifier
- http://hdl.handle.net/10353/22545
- Identifier
- vital:52424
- Description
- This research was aimed at preparing carbon dots using the microwave method as a bottomup synthetic approach. The prepared carbon dots were them to be used as an electrode modifier in electrochemical detection of metal ion. The structure of the carbon dots prepared were characterized using different techniques including the FTIR, TEM, UV-Vis, PL, XRD and Raman Spectroscopy. It was observed that the nanoparticles consisted of carboxylic acid, amine and alcohol functional groups at their core and surface. UV-Vis and PL revealed that the carbon dots absorb more light in the visible and ultraviolet region, and the sizes of the carbon dots prepared were less than 10 nm. The carbon dots were then utilized for electrochemical sensing of Cd2+ ion, which is considered as one of harmful heavy metal ion when not controlled. Glassy carbon electrode modified with the carbon dots was utilized for the detection of Cd2+ through square wave voltammetry. Effect of different experimental parameters was studied which include electrode preparation, frequency, and amplitude. The electrochemical characterization of the electrode was done using the cyclic voltammetry and electrochemical impedance spectroscopy (EIS), the modified electrode was found conductive with much improved electrochemical performances. The obtained detection limit for Cd2+ sensing was 9.39 ppb, the developed C-dots modified GCE electrode was also tested with tap water Cd2+ spiked solution to demonstrate its implementation in real sample analysis.
- Description
- Thesis (MA) -- Faculty of Science and Agriculture, 2021
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (xiv, 118 pages)
- Format
- Publisher
- University of Fort Hare
- Publisher
- Faculty of Science and Agriculture
- Language
- English
- Rights
- rights holder
- Rights
- All Rights Reserved
- Rights
- Open Access
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Collections
UFH Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | MSc Dissertation for Madikizela Z.pdf | 1 MB | Adobe Acrobat PDF | View Details Download |