Voltammetric characterisation of the self-assembled monolayers (SAMs) of benzyl-and dodecyl-mercapto tetra substituted metallophthalocyanines complexes
- Authors: Agboola, Bolade , Westbroek, Philippe , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281414 , vital:55723 , xlink:href="https://doi.org/10.1016/j.elecom.2006.08.047"
- Description: Voltammetric characterisations of cobalt, iron, manganese, nickel and zinc phthalocyanine complexes tetra substituted with benzyl- and dodecyl-mercapto ring substituents and immobilisation on gold electrodes via the self-assembling technique are presented. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, under potential deposition of copper and solution redox chemistry of [Fe(H2O)6 3+ ]/[Fe(H2O)6 2+ ]. The solution chemistry of [Fe(CN)6]−3/[Fe(CN)6]−4 redox process was used to study the orientation of the CoPcs-SAMs and this revealed a possible deviation from flat orientation of the complexes on the gold electrodes when the SAM formation times were greater than 24 h. For SAM formation time at 24 and 48 h, CoTDMPc-SAM showed more inhibition of the [Fe(CN)6]−3/[Fe(CN)6]−4 redox process than the CoTBMPc-SAM counterpart, indicating more blocking characteristics of the dodecylmercapto ring substituents compared to the benzylmercapto counterpart. To avoid SAM desorption, the potential application should be limited to −0.2 to +0.8 V vs. Ag∣AgCl (NaCl, sat’d) in acidic and neutral pH.
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- Date Issued: 2007
Wi-Fi as a last mile access technology and The Tragedy of the Commons
- Authors: Brandt, Ingrid , Terzoli, Alfredo , Hodgkinson-Williams, Cheryl
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431106 , vital:72744 , https://doi.org/10.1007/978-1-4020-6266-7_33
- Description: With an alarmingly low teledensity in South Africa, just 12%, and not much hope of further wired infrastructure at the local loop level, as the costs incurred are high compared to potential revenue, wireless con-nectivity could be a great asset and service in South Africa. However, the use of unlicensed spectrum in building wireless networks can be comparable to “The Tragedy of the Commons”, the result of selfish be-haviour towards common and limited resources. This paper evaluates the use of 802.11 wireless technologies in building a broadband wire-less network and the effects of high amounts of interference on such a network. The paper concludes that for urban areas 802.11 technologies using unlicensed spectrum is not advisable, unless used in point-to-point links, while its use in rapid rural development (where there is less interference) is very promising.
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- Date Issued: 2007
Written medicines information for South African HIV/AIDS patients: does it enhance understanding of co-trimoxazole therapy?
- Authors: Mansoor, Leila E , Dowse, Roslind
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156860 , vital:40059 , https://0-doi.org.wam.seals.ac.za/10.1093/her/cyl039
- Description: Written information to promote patient education is being increasingly recognized as an integral part of quality health care. The main objective of this study was to evaluate the effect of distributing a patient information leaflet (PIL) on knowledge acquisition and recall. Two different PILs were designed for co-trimoxazole tablets: a simple, shorter PIL that incorporated pictograms and text and a text-only PIL that was longer and more complex. Human immunodeficiency virus-positive participants on chronic co-trimoxazole therapy were enrolled from five local primary health care clinics in Grahamstown, South Africa, and were randomly allocated to a Control Group (no PIL), Group A (text-only PIL) or Group B (simple PIL with pictograms).
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- Date Issued: 2007
Zebra fingerprints: towards a computer-aided identification system for individual zebra
- Authors: Foster, Gregory G , Krijer, Hans , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433482 , vital:72973 , https://doi.org/10.1145/1108590.1108616
- Description: The article presents a study which investigates the development of a computer-aided system for individual zebra identification based on the lateral side stripe pattern. The model proposed for individual animal identification is based on a combination of image processing and fingerprint identification technology. About 20 minutes of zebra footage was filmed at the Amakhala Game Reserve in South Africa. The study indicates that there is sufficient variation in lateral stripe patterns to differentiate individual animals.
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- Date Issued: 2007
Cognitive pharmaceutical services and the community pharmacist: are South African patients receiving them and are they willing to pay?
- Authors: Hill, Peter W , Dowse, Roslind
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156829 , vital:40054 , DOI 10.1211/ijpp.15.2.0007
- Description: The objectives of this study were to ascertain the opinions of randomly selected South African medical aid members regarding the provision by community pharmacists of patient counselling and information; member satisfaction with pharmacist services; their rating of pharmacist accessibility; and if pharmacists should be reimbursed for providing cognitive pharmaceutical services. Setting A South African private healthcare insurance company.
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- Date Issued: 2006
Shakespeare's Victorian Stage: performing history in the theatre of Charles Kean, Richard W. Schoch: book review
- Authors: Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7050 , http://hdl.handle.net/10962/d1007393 , http://hdl.handle.net/10520/EJC48030
- Description: preprint , This book is a primarily a study of Charles Kean’s productions of Shakespeare’s English chronicle plays at the Princess’s Theatre between 1852 and 1859, a period crucial to the development of ideas of English nationalism. Schoch focuses on these particular stagings as more than drama; as performances of nineteenth century theories of history and historical representation. His project operates under the aegis of the so-called ‘linguistic turn’ in cultural theory, and is suspicious of neo-marxian fundamentalism.
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- Date Issued: 2004