Wearing two hats:
- Authors: Vorster, Jo-Anne
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159427 , vital:40296 , https://hdl.handle.net/10520/EJC139349
- Description: In an attempt to find out, I sat in on the weekly meetings of Rhodes University Journalism and Media Studies (JMS) academics who were developing a curriculum for a fourth year course in 2006. My interest as an academic development practitioner is in collaborative development of professional or vocational curricula. What the meeting transcripts and interviews with these and other academics in the journalism school uncover is a complex process that underpins the curriculum development of professional courses - particularly, those professions that are not regulated by a professional board.
- Full Text:
- Date Issued: 2010
- Authors: Vorster, Jo-Anne
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159427 , vital:40296 , https://hdl.handle.net/10520/EJC139349
- Description: In an attempt to find out, I sat in on the weekly meetings of Rhodes University Journalism and Media Studies (JMS) academics who were developing a curriculum for a fourth year course in 2006. My interest as an academic development practitioner is in collaborative development of professional or vocational curricula. What the meeting transcripts and interviews with these and other academics in the journalism school uncover is a complex process that underpins the curriculum development of professional courses - particularly, those professions that are not regulated by a professional board.
- Full Text:
- Date Issued: 2010
What is biocultural diversity?: a theoretical review
- Authors: Cocks, Michelle L
- Date: 2010
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/141475 , vital:37975 , ISBN 9781441957009 , DOI: 10.1007/978-1-4419-5701-6_5
- Description: Over the past decade, scholars from various fields have increasingly emphasized the detrimental effects of global socioeconomic processes on biodiversity. The industrial revolution, the demographic explosion of Homo sapiens, and the rise of the global exchange economy are all implicated as major factors that influence the loss of species diversity. From the late 1980s onward, biosystematics and conservation biology have successfully brought this concern to the attention of the public. Biodiversity is increasingly recognized as an essential resource on which families, communities, and nations depend. Biologists, ecologists, and conservationists have further recognized that solutions to biological problems lie in the mechanisms of social, cultural, and economic systems, which has led to attempts to place a monetary value on species and ecosystems to calculate the cost of using and conserving biodiversity.
- Full Text:
- Date Issued: 2010
- Authors: Cocks, Michelle L
- Date: 2010
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/141475 , vital:37975 , ISBN 9781441957009 , DOI: 10.1007/978-1-4419-5701-6_5
- Description: Over the past decade, scholars from various fields have increasingly emphasized the detrimental effects of global socioeconomic processes on biodiversity. The industrial revolution, the demographic explosion of Homo sapiens, and the rise of the global exchange economy are all implicated as major factors that influence the loss of species diversity. From the late 1980s onward, biosystematics and conservation biology have successfully brought this concern to the attention of the public. Biodiversity is increasingly recognized as an essential resource on which families, communities, and nations depend. Biologists, ecologists, and conservationists have further recognized that solutions to biological problems lie in the mechanisms of social, cultural, and economic systems, which has led to attempts to place a monetary value on species and ecosystems to calculate the cost of using and conserving biodiversity.
- Full Text:
- Date Issued: 2010
When 140 years of small-town meets journalism education newspapering:
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: vital:38358 , http://hdl.handle.net/10520/EJC139344
- Description: By acquiring a 140-year-old newspaper as its site of experiential learning for journalism students in 2003, the Rhodes University School of Journalism and Media Studies set out boldly to enhance both journalism teaching and journalism practice in Grahamstown and South Africa.
- Full Text:
- Date Issued: 2010
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: vital:38358 , http://hdl.handle.net/10520/EJC139344
- Description: By acquiring a 140-year-old newspaper as its site of experiential learning for journalism students in 2003, the Rhodes University School of Journalism and Media Studies set out boldly to enhance both journalism teaching and journalism practice in Grahamstown and South Africa.
- Full Text:
- Date Issued: 2010
When birthing makes the news : the depiction of women as a newsworthy item in Die Burger (Oos-Kaap)
- Authors: Preller, Cindy
- Date: 2010
- Subjects: Mass media and women -- South Africa Childbirth -- South Africa Women -- South Africa Die Burger (Port Elizabeth, South Africa) Journalism -- South Africa -- 21st century Mass media -- Moral and ethical aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3480 , http://hdl.handle.net/10962/d1002935
- Description: The thesis “When birthing makes the news: the depiction of women as a newsworthy item in Die Burger (Oos-Kaap)” analyses a common, yet complex news topic in the South African print media due to the sensitive, often sensationalised, nature of the topic. The private experience of birthing is featured more and more in the public domain of newspapers because of widespread service delivery problems within the South African health department. Focussing on the Eastern Cape, I examine the representation of birthing in Die Burger (Oos-Kaap) in texts printed between 2005 and 2007, and scrutinise the media’s monitorial role of a self-appointed public hero acting on behalf of the women, to expose the poor conditions at government hospitals, specifically in the Nelson Mandela Bay region. How the women and their bodies are reported on, creates a discursive tension between the negative portrayals of the birthing women and the monitorial role of the media. The news values of sensationalism and profit are achieved with visceral representations of the reproductive functions of the birthing women. A poststructuralist feminist theoretical framework reveals discourses that perpetuate race, class and gender inequalities in the apparently socially-concerned sample of texts. A Critical discourse analysis (CDA) provides an approach and method to inform a close textual analysis of both the lexical and visual elements of the texts. The discourses in the sample differed from text to text. Despite these differences, the monitorial role of the media is still achieved. My research argues that acting in the public interest with sensationalist copy is still acting in the public interest. I conclude that it is not easy for newspapers to separate sensationalism from accountability. Media practitioners should be aware of their role in constructing women’s identities and be particularly thoughtful when reporting on birthing. In doing so, this research aims to improve the manner in which women and their bodies are reported on within the news industry.
- Full Text:
- Date Issued: 2010
- Authors: Preller, Cindy
- Date: 2010
- Subjects: Mass media and women -- South Africa Childbirth -- South Africa Women -- South Africa Die Burger (Port Elizabeth, South Africa) Journalism -- South Africa -- 21st century Mass media -- Moral and ethical aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3480 , http://hdl.handle.net/10962/d1002935
- Description: The thesis “When birthing makes the news: the depiction of women as a newsworthy item in Die Burger (Oos-Kaap)” analyses a common, yet complex news topic in the South African print media due to the sensitive, often sensationalised, nature of the topic. The private experience of birthing is featured more and more in the public domain of newspapers because of widespread service delivery problems within the South African health department. Focussing on the Eastern Cape, I examine the representation of birthing in Die Burger (Oos-Kaap) in texts printed between 2005 and 2007, and scrutinise the media’s monitorial role of a self-appointed public hero acting on behalf of the women, to expose the poor conditions at government hospitals, specifically in the Nelson Mandela Bay region. How the women and their bodies are reported on, creates a discursive tension between the negative portrayals of the birthing women and the monitorial role of the media. The news values of sensationalism and profit are achieved with visceral representations of the reproductive functions of the birthing women. A poststructuralist feminist theoretical framework reveals discourses that perpetuate race, class and gender inequalities in the apparently socially-concerned sample of texts. A Critical discourse analysis (CDA) provides an approach and method to inform a close textual analysis of both the lexical and visual elements of the texts. The discourses in the sample differed from text to text. Despite these differences, the monitorial role of the media is still achieved. My research argues that acting in the public interest with sensationalist copy is still acting in the public interest. I conclude that it is not easy for newspapers to separate sensationalism from accountability. Media practitioners should be aware of their role in constructing women’s identities and be particularly thoughtful when reporting on birthing. In doing so, this research aims to improve the manner in which women and their bodies are reported on within the news industry.
- Full Text:
- Date Issued: 2010
White rhinoceros populations in the Eastern Cape: distribution, performance and diet
- Authors: Kraai, Manqhai
- Date: 2010
- Subjects: Rhinoceroses -- South Africa -- Eastern Cape , Rhinoceroses -- Habitat -- South Africa -- Eastern Cape , Rhinoceroses -- Behavior -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10692 , http://hdl.handle.net/10948/1297 , Rhinoceroses -- South Africa -- Eastern Cape , Rhinoceroses -- Habitat -- South Africa -- Eastern Cape , Rhinoceroses -- Behavior -- South Africa -- Eastern Cape
- Description: White rhino populations did not occur historically in the Eastern Cape, South Africa (Skead 2007). They have, however, been introduced into a number of reserves within the Eastern Cape for reasons such as conservation, ecotourism and hunting. Based on the literature on the species, it was hypothesized that white rhinoceros would have been introduced in grass-rich habitats, as they are bulk grazers. White rhinoceros populations were further assessed in terms of population establishment by outlining their distribution and performance since introductions and this was done by extracting intercalving intervals from the literature of native populations and comparing such to the Eastern Cape intercalving intervals, extracted from data obtained from landowners. Finally, the diet of white rhinoceros was quantified, in order to identify plant species potentially at risk from white rhino herbivory using Shamwari Private Game Reserve as a study site. The distribution of white rhino in the Eastern Cape varies in terms of habitat and vegetation types. The majority (62%) of white rhino are located in grass-poor habitats and are primarily there for ecotourism purposes with only a small percentage kept for conservation purposes in the state reserves. Limited data for intercalving intervals of the white rhino in Eastern Cape are comparable to those of populations in the natural range. The ex situ conservation of white rhino in the Eastern Cape proved to be a success as population numbers have increased markedly since the first survey was conducted (Buijs 1999). The diet section of this study showed that white rhino are highly selective grazers even in a grass-limiting habitat which is dominated by browse. Twenty-five principal dietary items were identified in their diet, with only six being preferred in autumn. These are thus the plant species that could be the most vulnerable to white rhino herbivory. Supplementary food provision plays a big part of the feeding scheme of white rhino in Shamwari Private Game Reserve during the winter season, revealing the little confidence that the management has on natural resource availability to the animals at this time. These findings support the value of the Eastern Cape for ex situ conservation of white rhino, and highlight plant species potentially at risk. There is a need for further research on the population performance of these animals, and the plants identified here need to be monitored to assess white rhino impact on the vegetation
- Full Text:
- Date Issued: 2010
- Authors: Kraai, Manqhai
- Date: 2010
- Subjects: Rhinoceroses -- South Africa -- Eastern Cape , Rhinoceroses -- Habitat -- South Africa -- Eastern Cape , Rhinoceroses -- Behavior -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10692 , http://hdl.handle.net/10948/1297 , Rhinoceroses -- South Africa -- Eastern Cape , Rhinoceroses -- Habitat -- South Africa -- Eastern Cape , Rhinoceroses -- Behavior -- South Africa -- Eastern Cape
- Description: White rhino populations did not occur historically in the Eastern Cape, South Africa (Skead 2007). They have, however, been introduced into a number of reserves within the Eastern Cape for reasons such as conservation, ecotourism and hunting. Based on the literature on the species, it was hypothesized that white rhinoceros would have been introduced in grass-rich habitats, as they are bulk grazers. White rhinoceros populations were further assessed in terms of population establishment by outlining their distribution and performance since introductions and this was done by extracting intercalving intervals from the literature of native populations and comparing such to the Eastern Cape intercalving intervals, extracted from data obtained from landowners. Finally, the diet of white rhinoceros was quantified, in order to identify plant species potentially at risk from white rhino herbivory using Shamwari Private Game Reserve as a study site. The distribution of white rhino in the Eastern Cape varies in terms of habitat and vegetation types. The majority (62%) of white rhino are located in grass-poor habitats and are primarily there for ecotourism purposes with only a small percentage kept for conservation purposes in the state reserves. Limited data for intercalving intervals of the white rhino in Eastern Cape are comparable to those of populations in the natural range. The ex situ conservation of white rhino in the Eastern Cape proved to be a success as population numbers have increased markedly since the first survey was conducted (Buijs 1999). The diet section of this study showed that white rhino are highly selective grazers even in a grass-limiting habitat which is dominated by browse. Twenty-five principal dietary items were identified in their diet, with only six being preferred in autumn. These are thus the plant species that could be the most vulnerable to white rhino herbivory. Supplementary food provision plays a big part of the feeding scheme of white rhino in Shamwari Private Game Reserve during the winter season, revealing the little confidence that the management has on natural resource availability to the animals at this time. These findings support the value of the Eastern Cape for ex situ conservation of white rhino, and highlight plant species potentially at risk. There is a need for further research on the population performance of these animals, and the plants identified here need to be monitored to assess white rhino impact on the vegetation
- Full Text:
- Date Issued: 2010
Women, land rights and HIV/AIDS in Zimbabwe: the case of Zvimba communal area in Mashonaland West Province
- Authors: Arisunta, Caroline
- Date: 2010
- Subjects: Land tenure -- Zimbabwe , AIDS (Disease) in women -- Zimbabwe , Agricultural productivity -- Zimbabwe , Women farmers -- Zimbabwe , Women in agriculture -- Zimbabwe , Widowhood -- Zimbabwe , Inheritance and succession -- Zimbabwe , HIV-positive persons -- Zimbabwe
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11939 , http://hdl.handle.net/10353/233 , Land tenure -- Zimbabwe , AIDS (Disease) in women -- Zimbabwe , Agricultural productivity -- Zimbabwe , Women farmers -- Zimbabwe , Women in agriculture -- Zimbabwe , Widowhood -- Zimbabwe , Inheritance and succession -- Zimbabwe , HIV-positive persons -- Zimbabwe
- Description: This study explores women’s access to land under the customary tenure system. It examines how the changes in land tenure, access and rights to land as a consequence of HIV/AIDS are affecting agricultural productivity, food security and poverty, with a specific focus on women who have lost their husbands to HIV/AIDS in Zvimba. Zvimba is a village community located in Zvimba District in the Mashonaland West Province of Zimbabwe. The study also discusses policy responses designed to cushion the impact of HIV/AIDS on local communities especially women living with HIV/AIDS. The study highlights the vulnerability of widows to land rights violations, mainly inflicted by relatives but sometimes by the wider community. The main form of abuse encountered included the use of abusive language, threats of evictions and at times, beatings. The legal route for seeking redress was rarely used. Fear of witchcraft, low educational levels and fear of causing conflict between children and their paternal relatives also led widows to abandon the fight for their rights. The study further reveals that widows are heavily exposed to dispossession of their land rights. HIV/AIDS has increased the vulnerability of widows and other women to threats and dispossession of their land and other property rights. Dispossession of arable fields was observed in the four wards. The dispossessions and threats to livelihoods were directly related to the HIV positive status of the widows. The findings from this study illustrate the predominant role that male members of the household or family have over land. Thus, culture and traditional practices still affect women in other cases, disadvantaging them in favour of men, as in inheritance of land and property in the household.
- Full Text:
- Date Issued: 2010
- Authors: Arisunta, Caroline
- Date: 2010
- Subjects: Land tenure -- Zimbabwe , AIDS (Disease) in women -- Zimbabwe , Agricultural productivity -- Zimbabwe , Women farmers -- Zimbabwe , Women in agriculture -- Zimbabwe , Widowhood -- Zimbabwe , Inheritance and succession -- Zimbabwe , HIV-positive persons -- Zimbabwe
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11939 , http://hdl.handle.net/10353/233 , Land tenure -- Zimbabwe , AIDS (Disease) in women -- Zimbabwe , Agricultural productivity -- Zimbabwe , Women farmers -- Zimbabwe , Women in agriculture -- Zimbabwe , Widowhood -- Zimbabwe , Inheritance and succession -- Zimbabwe , HIV-positive persons -- Zimbabwe
- Description: This study explores women’s access to land under the customary tenure system. It examines how the changes in land tenure, access and rights to land as a consequence of HIV/AIDS are affecting agricultural productivity, food security and poverty, with a specific focus on women who have lost their husbands to HIV/AIDS in Zvimba. Zvimba is a village community located in Zvimba District in the Mashonaland West Province of Zimbabwe. The study also discusses policy responses designed to cushion the impact of HIV/AIDS on local communities especially women living with HIV/AIDS. The study highlights the vulnerability of widows to land rights violations, mainly inflicted by relatives but sometimes by the wider community. The main form of abuse encountered included the use of abusive language, threats of evictions and at times, beatings. The legal route for seeking redress was rarely used. Fear of witchcraft, low educational levels and fear of causing conflict between children and their paternal relatives also led widows to abandon the fight for their rights. The study further reveals that widows are heavily exposed to dispossession of their land rights. HIV/AIDS has increased the vulnerability of widows and other women to threats and dispossession of their land and other property rights. Dispossession of arable fields was observed in the four wards. The dispossessions and threats to livelihoods were directly related to the HIV positive status of the widows. The findings from this study illustrate the predominant role that male members of the household or family have over land. Thus, culture and traditional practices still affect women in other cases, disadvantaging them in favour of men, as in inheritance of land and property in the household.
- Full Text:
- Date Issued: 2010
Wounding and healing as paradox: towards the visual articulation of synthesis
- Authors: De Lange, Bev
- Date: 2010
- Subjects: Psychology
- Language: English
- Type: Thesis , Masters , MTech (Fine Art)
- Identifier: vital:8531 , http://hdl.handle.net/10948/1655 , Psychology
- Description: The very notion of wounding can be argued to imply a process of healing. Indeed some wounds are at the outset designed to be instruments of healing. As ten years of my professional life were spent assisting in the surgical creation of such „wounds‟ in an operating theatre it is from this memory timeframe that I initiated the process of developing visual equivalents that become reflective of both wounding and healing. The operation theatre was also an environment from which I developed increased awareness of mind or psyche as an entity conceptually comprising both conscious and unconscious components. Within this context, it can be argued that the patient‟s state of mind moves between consciousness and forms of unconsciousness induced through anaesthesia. Through research into the writings of the psychoanalyst Carl Jung, I began to develop a greater understanding of the concepts surrounding the conscious and unconscious mind in relation to the development of consciousness as well as to the integration of opposites. It is from this understanding of a dynamic process within the mind itself that I have attempted to develop visual signifiers of paradox in order to give expression to symbols that are reflective of these processes and in so doing indicate the psychological journey towards synthesis and individuation.
- Full Text:
- Date Issued: 2010
- Authors: De Lange, Bev
- Date: 2010
- Subjects: Psychology
- Language: English
- Type: Thesis , Masters , MTech (Fine Art)
- Identifier: vital:8531 , http://hdl.handle.net/10948/1655 , Psychology
- Description: The very notion of wounding can be argued to imply a process of healing. Indeed some wounds are at the outset designed to be instruments of healing. As ten years of my professional life were spent assisting in the surgical creation of such „wounds‟ in an operating theatre it is from this memory timeframe that I initiated the process of developing visual equivalents that become reflective of both wounding and healing. The operation theatre was also an environment from which I developed increased awareness of mind or psyche as an entity conceptually comprising both conscious and unconscious components. Within this context, it can be argued that the patient‟s state of mind moves between consciousness and forms of unconsciousness induced through anaesthesia. Through research into the writings of the psychoanalyst Carl Jung, I began to develop a greater understanding of the concepts surrounding the conscious and unconscious mind in relation to the development of consciousness as well as to the integration of opposites. It is from this understanding of a dynamic process within the mind itself that I have attempted to develop visual signifiers of paradox in order to give expression to symbols that are reflective of these processes and in so doing indicate the psychological journey towards synthesis and individuation.
- Full Text:
- Date Issued: 2010
Writing the aerial dancing body a preliminary choreological investigation of the aesthetics and kinetics of the aerial dancing body
- Authors: Acker, Shaun Albert
- Date: 2010
- Subjects: Dance -- 19th century Dance -- 20th century Dance -- 21st century Aerialists Movement, Aesthetics of Feminine beauty (Aesthetics) Movement notation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2129 , http://hdl.handle.net/10962/d1002361
- Description: This mini-thesis investigates some of the nineteenth century socio-cultural ideals that have structured a connection between virtuosic aerial skill and bodily aesthetics. It views the emergence of a style of aerial kineticism that is structured from the gender ideologies of the period. It investigates the continual recurrence of this nineteenth century style amongst contemporary aerial dance works and outlines the possible frictions between this Victorian style of kineticism and contemporary aerial explorations. From this observation, a possible catalyst may be observed with which to relocate and inspire a study of aerial kinetics sans the nineteenth century aesthetic component. This kinesiological catalyst may be viewed in conjunction with the theories of ground-based kinetic theorist, Rudolph Laban’s choreutic study of the body in space. Thus, it may be possible to suggest and introduce a possible practical dance scholarship for aerial dance. This mini-thesis includes an introductory choreological investigation that draws on and integrates the disciplines of kinesiology; choreutic theory; existing aerial kinetic technique; musicology; and the physical sciences.
- Full Text:
- Date Issued: 2010
- Authors: Acker, Shaun Albert
- Date: 2010
- Subjects: Dance -- 19th century Dance -- 20th century Dance -- 21st century Aerialists Movement, Aesthetics of Feminine beauty (Aesthetics) Movement notation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2129 , http://hdl.handle.net/10962/d1002361
- Description: This mini-thesis investigates some of the nineteenth century socio-cultural ideals that have structured a connection between virtuosic aerial skill and bodily aesthetics. It views the emergence of a style of aerial kineticism that is structured from the gender ideologies of the period. It investigates the continual recurrence of this nineteenth century style amongst contemporary aerial dance works and outlines the possible frictions between this Victorian style of kineticism and contemporary aerial explorations. From this observation, a possible catalyst may be observed with which to relocate and inspire a study of aerial kinetics sans the nineteenth century aesthetic component. This kinesiological catalyst may be viewed in conjunction with the theories of ground-based kinetic theorist, Rudolph Laban’s choreutic study of the body in space. Thus, it may be possible to suggest and introduce a possible practical dance scholarship for aerial dance. This mini-thesis includes an introductory choreological investigation that draws on and integrates the disciplines of kinesiology; choreutic theory; existing aerial kinetic technique; musicology; and the physical sciences.
- Full Text:
- Date Issued: 2010
‘We do not cook, we only assist them’
- Ratele, Kopano, Shefer, Tamara, Strebel, Anna, Fouten, Elron
- Authors: Ratele, Kopano , Shefer, Tamara , Strebel, Anna , Fouten, Elron
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/277945 , vital:55334 , xlink:href="https://doi.org/10.1080/14330237.2010.10820414"
- Description: This article discusses how the gendering of activity by boys coincides with, contests or recreates constructions of hegemonic masculinity in the context of South Africa. The study used a qualitative methodology including a series of three focus groups with 14–16 year-old boys across six different schools in the Western Cape, South Africa. A discursive analysis in which particular attention was paid to how participants construct their masculinity in relation to what they may or may not do as boys/men was conducted. The findings foreground how articulations of masculinity by boys are characterised by efforts to gender activity in the process of, amongst other things, counter blushing—meaning not to be regarded as girl-like or a moffie, or other derogatory notions that do not fit with hegemonic masculinity in a particular context. However, resistances and alternative views on what boys/men can and cannot do also emerged, highlighting the contested nature of current constructions of masculinity among young people in South Africa.
- Full Text:
- Date Issued: 2010
- Authors: Ratele, Kopano , Shefer, Tamara , Strebel, Anna , Fouten, Elron
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/277945 , vital:55334 , xlink:href="https://doi.org/10.1080/14330237.2010.10820414"
- Description: This article discusses how the gendering of activity by boys coincides with, contests or recreates constructions of hegemonic masculinity in the context of South Africa. The study used a qualitative methodology including a series of three focus groups with 14–16 year-old boys across six different schools in the Western Cape, South Africa. A discursive analysis in which particular attention was paid to how participants construct their masculinity in relation to what they may or may not do as boys/men was conducted. The findings foreground how articulations of masculinity by boys are characterised by efforts to gender activity in the process of, amongst other things, counter blushing—meaning not to be regarded as girl-like or a moffie, or other derogatory notions that do not fit with hegemonic masculinity in a particular context. However, resistances and alternative views on what boys/men can and cannot do also emerged, highlighting the contested nature of current constructions of masculinity among young people in South Africa.
- Full Text:
- Date Issued: 2010
Irony and transcendence on the Renaissance stage
- Authors: Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7067 , http://hdl.handle.net/10962/d1007455 , https://doi.org/10.1484/M.CURSOR-EB.3.4728
- Description: preprint , This is the concluding essay in a collection entitled 'This Earthly Stage'. The chapter argues that the peculiar task of the stage metaphor - the notion of the theatre as a metaphor for life,which involves complex interactions between rarefied intellectual constructions of life and mundane reality - is to interrogate the tension between an inscrutable cosmic order and the limited viewpoints of ordinary humanity.The piece moves from general considerations of irony and dramatic irony, via an analysis of Kyd's The Spanish Tragedy, to comments on Petrarch, Pico and Vives, culminating in a consideration of irony and transcendence in Shakespeare's last plays.
- Full Text:
- Date Issued: 2004
- Authors: Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7067 , http://hdl.handle.net/10962/d1007455 , https://doi.org/10.1484/M.CURSOR-EB.3.4728
- Description: preprint , This is the concluding essay in a collection entitled 'This Earthly Stage'. The chapter argues that the peculiar task of the stage metaphor - the notion of the theatre as a metaphor for life,which involves complex interactions between rarefied intellectual constructions of life and mundane reality - is to interrogate the tension between an inscrutable cosmic order and the limited viewpoints of ordinary humanity.The piece moves from general considerations of irony and dramatic irony, via an analysis of Kyd's The Spanish Tragedy, to comments on Petrarch, Pico and Vives, culminating in a consideration of irony and transcendence in Shakespeare's last plays.
- Full Text:
- Date Issued: 2004
2009/2010 CEO (Celebrating excellence in organisations) Most Influential Women in Business and Government (MIW) in the Education and Teaching Sector
- Authors: Rhodes University
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7178 , http://hdl.handle.net/10962/d1006184 , Nyokong, Tebello
- Description: Professor Tebello Nyokong was awarded the 2009/2010 CEO (Celebrating excellence in organisations) Most Influential Women in Business and Government (MIW) in the Education and Teaching Sector and was named as a runner-up in the Quality of Life category of the Department of Science and Technology's (DST) 2009 Distinguished Woman Scientist Award. Holding a DST/NRF South African Research Chairs Initiative Chair in Medicinal Chemistry and Nanotechnology, she is also the Director of the DST/Mintek Nanotechnology Innovation Centre (NIC) for Sensors. Her pioneering research into photodynamic therapy to harness light for cancer therapy and the early detection of human diseases and environmental clean-up continues to draw attention for more reasons than are immediately apparent.
- Full Text:
- Authors: Rhodes University
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7178 , http://hdl.handle.net/10962/d1006184 , Nyokong, Tebello
- Description: Professor Tebello Nyokong was awarded the 2009/2010 CEO (Celebrating excellence in organisations) Most Influential Women in Business and Government (MIW) in the Education and Teaching Sector and was named as a runner-up in the Quality of Life category of the Department of Science and Technology's (DST) 2009 Distinguished Woman Scientist Award. Holding a DST/NRF South African Research Chairs Initiative Chair in Medicinal Chemistry and Nanotechnology, she is also the Director of the DST/Mintek Nanotechnology Innovation Centre (NIC) for Sensors. Her pioneering research into photodynamic therapy to harness light for cancer therapy and the early detection of human diseases and environmental clean-up continues to draw attention for more reasons than are immediately apparent.
- Full Text:
Characterization of amine-functionalized single-walled carbon nanotube-low symmetry phthalocyanine conjugates
- Chidawanyika, Wadzanai J U, Nyokong, Tebello
- Authors: Chidawanyika, Wadzanai J U , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7237 , http://hdl.handle.net/10962/d1019688
- Description: Functionalization of single-walled carbon nanotubes (SWCNTs) with amine groups using a previously developed diazonium approach, followed by reaction with a carboxylic acid moiety allows direct attachment by an amide bond. We have developed a new SWCNT-low symmetry phthalocyanine conjugate using this approach, using dicyclohexylcarbodiimide as an activating agent to facilitate formation of an amide bond to give a covalently linked conjugate. A conjugate formed by non-covalent attachment has been used for a comparative investigation by FT-IR, Raman, and UV–Vis spectroscopies, and thermal gravimetric analysis. The fluorescence of the phthalocyanine is quenched in the conjugate. , Original publication is available at http://dx.doi.org/10.1016/j.carbon.2010.04.015
- Full Text: false
- Authors: Chidawanyika, Wadzanai J U , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7237 , http://hdl.handle.net/10962/d1019688
- Description: Functionalization of single-walled carbon nanotubes (SWCNTs) with amine groups using a previously developed diazonium approach, followed by reaction with a carboxylic acid moiety allows direct attachment by an amide bond. We have developed a new SWCNT-low symmetry phthalocyanine conjugate using this approach, using dicyclohexylcarbodiimide as an activating agent to facilitate formation of an amide bond to give a covalently linked conjugate. A conjugate formed by non-covalent attachment has been used for a comparative investigation by FT-IR, Raman, and UV–Vis spectroscopies, and thermal gravimetric analysis. The fluorescence of the phthalocyanine is quenched in the conjugate. , Original publication is available at http://dx.doi.org/10.1016/j.carbon.2010.04.015
- Full Text: false
Designing molecular materials and strategies for the electrochemical detection.pdf
- Identifier: http://hdl.handle.net/10962/262592 , vital:53535
- Description: We present an overview of the successes and challenges still faced in the detection of NO, O2˙− and ONOO− in biological media. We provide a full discussion on the electrochemical analyses of each of these species and we summarise the significant research contributions towards the development of sensors for individual and simultaneous detection of these species. We emphasize the importance of understanding the potential interferents in developing such sensors. We show that significant advances have been made with regard to the detection of NO in biological media leading to the development of marketable NO sensors, though there is room for improvement in terms of interferences. A brief outlook into the future perspectives of the use of a multi-electrochemical array sensor for simultaneous detection of NO, O2˙− and ONOO− is presented.
- Full Text:
- Date Issued: 2010
- Identifier: http://hdl.handle.net/10962/262592 , vital:53535
- Description: We present an overview of the successes and challenges still faced in the detection of NO, O2˙− and ONOO− in biological media. We provide a full discussion on the electrochemical analyses of each of these species and we summarise the significant research contributions towards the development of sensors for individual and simultaneous detection of these species. We emphasize the importance of understanding the potential interferents in developing such sensors. We show that significant advances have been made with regard to the detection of NO in biological media leading to the development of marketable NO sensors, though there is room for improvement in terms of interferences. A brief outlook into the future perspectives of the use of a multi-electrochemical array sensor for simultaneous detection of NO, O2˙− and ONOO− is presented.
- Full Text:
- Date Issued: 2010
Doctor of Philosophy Degree (honoris causa) – UNISA.
- Authors: Nyokong, Tebello
- Identifier: vital:7224 , http://hdl.handle.net/10962/d1005902
- Description: Doctor of Philosophy Degree (honoris causa) – UNISA.
- Full Text: false
- Authors: Nyokong, Tebello
- Identifier: vital:7224 , http://hdl.handle.net/10962/d1005902
- Description: Doctor of Philosophy Degree (honoris causa) – UNISA.
- Full Text: false
Novel, soluble, FluXoro functional substituted zinc phthalocyanines; synthesis, characterization and photophysicochemical properties
- Erdoğmuş, Ali, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7235 , http://hdl.handle.net/10962/d1019686
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041 , Original publication is available at http://dx.doi.org/10.1016/j.dyepig.2010.01.001
- Full Text: false
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7235 , http://hdl.handle.net/10962/d1019686
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041 , Original publication is available at http://dx.doi.org/10.1016/j.dyepig.2010.01.001
- Full Text: false
Synthesis and electrochemical properties of new cobalt and manganese phthalocyanine complexes tetra-substituted with 3,4-(methylendioxy)-phenoxy
- Erdoğmuş, Ali, Akinbulu, Isaac Adebayo, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Akinbulu, Isaac Adebayo , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7234 , http://hdl.handle.net/10962/d1019672
- Description: The synthesis and electrochemical properties of new cobalt and manganese phthalocyanine complexes, tetra-substituted with 3,4-(methylendioxy)-phenoxy at the peripheral (complexes 3 and 5) and non-peripheral (complexes 4 and 6) positions, are reported. Complexes 3 and 4 showed Q-band absorption, in DMF, at 668 and 686 nm, respectively while Q-band due to complexes 5 and 6 appeared at 732 and 760 nm, respectively in CHCl3. All the complexes showed well resolved redox processes attributed to both metal and ring based processes. Complexes 3 and 4 showed four redox processes, labeled I, II, III and IV. For complex 3, process I (CoIPc−2/CoIPc−3) was observed at −1.45 V, II (CoIIPc−2/CoIPc−2) at −0.38 V, III (CoIIIPc−2/CoIIPc−2) at +0.49 V and IV (CoIIIPc−1/CoIIIPc−2) at +0.97 V versus Ag|AgCl. Similar processes were observed for complex 4 at −1.36 V, −0.27 V, +0.56 V, +1.03 V versus Ag|AgCl, respectively. Complexes 5 and 6 showed two redox processes (I and II). For complex 5, these processes appeared at −0.79 V (MnIIPc−2/MnIIPc−3, I) and −0.07 V versus Ag|AgCl (MnIIIPc−2/MnIIPc−2, II), while for complex 6, they were observed at −0.86 V and −0.04 V versus Ag|AgCl. Spectroelectrochemistry was used to probe and confirm the origin of these processes. , Original publication is availabe at http://dx.doi.org/10.1016/j.poly.2010.05.012
- Full Text: false
- Authors: Erdoğmuş, Ali , Akinbulu, Isaac Adebayo , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7234 , http://hdl.handle.net/10962/d1019672
- Description: The synthesis and electrochemical properties of new cobalt and manganese phthalocyanine complexes, tetra-substituted with 3,4-(methylendioxy)-phenoxy at the peripheral (complexes 3 and 5) and non-peripheral (complexes 4 and 6) positions, are reported. Complexes 3 and 4 showed Q-band absorption, in DMF, at 668 and 686 nm, respectively while Q-band due to complexes 5 and 6 appeared at 732 and 760 nm, respectively in CHCl3. All the complexes showed well resolved redox processes attributed to both metal and ring based processes. Complexes 3 and 4 showed four redox processes, labeled I, II, III and IV. For complex 3, process I (CoIPc−2/CoIPc−3) was observed at −1.45 V, II (CoIIPc−2/CoIPc−2) at −0.38 V, III (CoIIIPc−2/CoIIPc−2) at +0.49 V and IV (CoIIIPc−1/CoIIIPc−2) at +0.97 V versus Ag|AgCl. Similar processes were observed for complex 4 at −1.36 V, −0.27 V, +0.56 V, +1.03 V versus Ag|AgCl, respectively. Complexes 5 and 6 showed two redox processes (I and II). For complex 5, these processes appeared at −0.79 V (MnIIPc−2/MnIIPc−3, I) and −0.07 V versus Ag|AgCl (MnIIIPc−2/MnIIPc−2, II), while for complex 6, they were observed at −0.86 V and −0.04 V versus Ag|AgCl. Spectroelectrochemistry was used to probe and confirm the origin of these processes. , Original publication is availabe at http://dx.doi.org/10.1016/j.poly.2010.05.012
- Full Text: false
Synthesis of zinc phthalocyanine derivatives with improved photophysicochemical properties in aqueous media
- Erdoğmuş, Ali, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7236 , http://hdl.handle.net/10962/d1019687
- Description: The synthesis, photophysical and photochemical properties of new peripherally (β) tetra-substituted thioquinoline Zn(II) (2) and quaternized thioquinoline Zn(II) phthalocyanines (3) and quaternized fluoro functional thiopyridine Zn(II) (5) are described for the first time. These complexes (2, 3 and 5) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Complexes 2, 4 and 6have good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene and are not aggregated in all solvents (except for 2 in DMSO) within a wide concentration range. Complexes 3 and 5 showed very good solubility in water as well as DMSO and DMF. General trends are described for singlet oxygen, photodegradation, fluorescence quantum yields, triplet quantum yields and triplet life times of these complexes in DMSO (2, 4 and 6) and water (3 and 5). Complex 3 gave a very large triplet quantum yield in aqueous media (ΦT = 0.8 in water plus Triton X-100) and a reasonable triplet lifetime of 110 μs. Photophysical and photochemical properties of the phthalocyanines complexes 2–6 are very useful for PDT. , Original publication is available at http://dx.doi.org/10.1016/j.molstruc.2010.04.048
- Full Text: false
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7236 , http://hdl.handle.net/10962/d1019687
- Description: The synthesis, photophysical and photochemical properties of new peripherally (β) tetra-substituted thioquinoline Zn(II) (2) and quaternized thioquinoline Zn(II) phthalocyanines (3) and quaternized fluoro functional thiopyridine Zn(II) (5) are described for the first time. These complexes (2, 3 and 5) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Complexes 2, 4 and 6have good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene and are not aggregated in all solvents (except for 2 in DMSO) within a wide concentration range. Complexes 3 and 5 showed very good solubility in water as well as DMSO and DMF. General trends are described for singlet oxygen, photodegradation, fluorescence quantum yields, triplet quantum yields and triplet life times of these complexes in DMSO (2, 4 and 6) and water (3 and 5). Complex 3 gave a very large triplet quantum yield in aqueous media (ΦT = 0.8 in water plus Triton X-100) and a reasonable triplet lifetime of 110 μs. Photophysical and photochemical properties of the phthalocyanines complexes 2–6 are very useful for PDT. , Original publication is available at http://dx.doi.org/10.1016/j.molstruc.2010.04.048
- Full Text: false
Synthetic pathways to water-soluble phthalocyanines and close analogs
- Dumoulin, Fabienne, Durmus, Mahmut, Ahsen, Vefa, Nyokong, Tebello
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7240 , http://hdl.handle.net/10962/d1019720
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed. , Original publication is available at http://dx.doi.org/10.1016/j.ccr.2010.05.002
- Full Text: false
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7240 , http://hdl.handle.net/10962/d1019720
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed. , Original publication is available at http://dx.doi.org/10.1016/j.ccr.2010.05.002
- Full Text: false
Tuning the physico-electrochemical properties of novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine complex using phenylamine-functionalised SWCNTs
- Agboola, Bolade Oyeyinka, Ozoemena, Kenneth I., Nyokong, Tebello, Fukuda, Takamitsu, Kobayashi, Nagao
- Authors: Agboola, Bolade Oyeyinka , Ozoemena, Kenneth I. , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Language: English
- Type: Article
- Identifier: vital:7238 , http://hdl.handle.net/10962/d1019689
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode. , Original publication is available at http://dx.doi.org/doi:10.1016/j.carbon.2009.10.023
- Full Text: false
- Authors: Agboola, Bolade Oyeyinka , Ozoemena, Kenneth I. , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Language: English
- Type: Article
- Identifier: vital:7238 , http://hdl.handle.net/10962/d1019689
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode. , Original publication is available at http://dx.doi.org/doi:10.1016/j.carbon.2009.10.023
- Full Text: false
Vodacom - Lesotho Hall of Fame, Lifetime Achievement Award
- Authors: Nyokong, Tebello
- Identifier: vital:7225 , http://hdl.handle.net/10962/d1005903
- Description: Vodacom - Lesotho Hall of Fame, Lifetime Achievement Award (Education Category).
- Full Text: false
- Authors: Nyokong, Tebello
- Identifier: vital:7225 , http://hdl.handle.net/10962/d1005903
- Description: Vodacom - Lesotho Hall of Fame, Lifetime Achievement Award (Education Category).
- Full Text: false