The role of records management in the sustainability of small micro medium enterprises (SMMEs) in the Eastern Cape, South Africa: a study of Alice and Fort Beaufort
- Ajibade, Patrick https://orcid.org/0000-0002-8608-8378
- Authors: Ajibade, Patrick https://orcid.org/0000-0002-8608-8378
- Date: 2014
- Subjects: Knowledge management , Small business
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25259 , vital:64122
- Description: The study sought to investigate the role of records management in the sustainability of the Small Micro, Medium enterprises (SMMEs) in the Eastern Cape Province of South Africa with focus on Alice and Fort Beaufort towns. The objectives of the study were to identify the types of records that are kept by SMMEs; evaluate the infrastructure for the SMMEs records management; determine the compliance of SMMEs with the existing RM legal and regulatory requirements; and identify the challenges related to SMMEs records practices. Twenty three (23) respondents from SMMEs were interviewed. Findings revealed all the respondents could not confirm adoption of any systemic way of records management to support business functions and operations. Majority of the SMMEs due to their inability to maintain records could not identify potential benefit of business RM with an exception of three SMMEs. The respondents were not aware of any compliance and regulatory framework most especially on business records management. The challenges facing SMMEs include; inability to capture/create maintain, preserve business records systematically in its lifecycle. The SMMEs lack needed training especially in records management to allow them the benefit of maintaining business records. It is recommended that SMMEs should acquire skill that would enable them manage their business records that may help improved decision making. There should be legislative and regulatory framework that ensures compliance. And assistance should be rendered to train SMMEs on basic RM skills that could improve their business operations. , Thesis (MLIS) -- Faculty of Social Sciences and Humanities, 2014
- Full Text:
- Date Issued: 2014
- Authors: Ajibade, Patrick https://orcid.org/0000-0002-8608-8378
- Date: 2014
- Subjects: Knowledge management , Small business
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25259 , vital:64122
- Description: The study sought to investigate the role of records management in the sustainability of the Small Micro, Medium enterprises (SMMEs) in the Eastern Cape Province of South Africa with focus on Alice and Fort Beaufort towns. The objectives of the study were to identify the types of records that are kept by SMMEs; evaluate the infrastructure for the SMMEs records management; determine the compliance of SMMEs with the existing RM legal and regulatory requirements; and identify the challenges related to SMMEs records practices. Twenty three (23) respondents from SMMEs were interviewed. Findings revealed all the respondents could not confirm adoption of any systemic way of records management to support business functions and operations. Majority of the SMMEs due to their inability to maintain records could not identify potential benefit of business RM with an exception of three SMMEs. The respondents were not aware of any compliance and regulatory framework most especially on business records management. The challenges facing SMMEs include; inability to capture/create maintain, preserve business records systematically in its lifecycle. The SMMEs lack needed training especially in records management to allow them the benefit of maintaining business records. It is recommended that SMMEs should acquire skill that would enable them manage their business records that may help improved decision making. There should be legislative and regulatory framework that ensures compliance. And assistance should be rendered to train SMMEs on basic RM skills that could improve their business operations. , Thesis (MLIS) -- Faculty of Social Sciences and Humanities, 2014
- Full Text:
- Date Issued: 2014
The Seduction of Ash: " Mia Couto's" The Day Mabata-bata Exploded" and" The Bird-Dreaming Baobab
- Authors: Njovane, Thandokazi
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142702 , vital:38103 , 10.4314/eia.v41i2.2
- Description: Chesca Long-Innes argues that Mia Couto's installation of the fantastic in his short story collection, Voices Made Night, may best be understood "not so much as a product of any 'magical realist' poetics, but as 'naturalised,' or motivated as a function of the collective neurosis of a [Mozambican] society traumatised by its continuing history of poverty and extreme violence". Couto's use of the fantastic, she adds, encompasses both empirical and psychic reality, and both are characterised by instability and elusiveness. The collection, she then maintains, constitutes a reinvention or reimagining of subjective realities constructed and perpetuated by the social trauma underpinning what she terms the "psycho-pathology of post-colonial Mozambique, in which the society as a whole is [. . .] caught in the grip of a profound depression or melancholia".
- Full Text:
- Date Issued: 2014
- Authors: Njovane, Thandokazi
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142702 , vital:38103 , 10.4314/eia.v41i2.2
- Description: Chesca Long-Innes argues that Mia Couto's installation of the fantastic in his short story collection, Voices Made Night, may best be understood "not so much as a product of any 'magical realist' poetics, but as 'naturalised,' or motivated as a function of the collective neurosis of a [Mozambican] society traumatised by its continuing history of poverty and extreme violence". Couto's use of the fantastic, she adds, encompasses both empirical and psychic reality, and both are characterised by instability and elusiveness. The collection, she then maintains, constitutes a reinvention or reimagining of subjective realities constructed and perpetuated by the social trauma underpinning what she terms the "psycho-pathology of post-colonial Mozambique, in which the society as a whole is [. . .] caught in the grip of a profound depression or melancholia".
- Full Text:
- Date Issued: 2014
The transformers : journalism education
- Authors: Priscilla Boshoff
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70688 , vital:29689
- Description: Universities are strange places. People come in as one kind of being, and leave quite different. They are places of transformation. One way in which they effect this transformation is to challenge our preconceived notions of the world, and our relationship to it. However, at the same time, universities are also places of privilege and so can be conservative – in the sense of conserving and fostering particular interests in their favour.
- Full Text:
- Date Issued: 2014
- Authors: Priscilla Boshoff
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70688 , vital:29689
- Description: Universities are strange places. People come in as one kind of being, and leave quite different. They are places of transformation. One way in which they effect this transformation is to challenge our preconceived notions of the world, and our relationship to it. However, at the same time, universities are also places of privilege and so can be conservative – in the sense of conserving and fostering particular interests in their favour.
- Full Text:
- Date Issued: 2014
The transformers: journalism education
- Authors: Boshoff, Priscilla A
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141911 , vital:38015 , http://journals.co.za/content/rujr/2014/34/EJC159497
- Description: Universities are strange places. People come in as one kind of being, and leave quite different. They are places of transformation. One way in which they effect this transformation is to challenge our preconceived notions of the world, and our relationship to it. However, at the same time, universities are also places of privilege and so can be conservative – in the sense of conserving and fostering particular interests in their favour.
- Full Text:
- Date Issued: 2014
- Authors: Boshoff, Priscilla A
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141911 , vital:38015 , http://journals.co.za/content/rujr/2014/34/EJC159497
- Description: Universities are strange places. People come in as one kind of being, and leave quite different. They are places of transformation. One way in which they effect this transformation is to challenge our preconceived notions of the world, and our relationship to it. However, at the same time, universities are also places of privilege and so can be conservative – in the sense of conserving and fostering particular interests in their favour.
- Full Text:
- Date Issued: 2014
Thinking academic freedom
- Authors: Lange, Lis
- Date: 2014
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/784 , vital:19990
- Description: I have titled this lecture Thinking Academic Freedom, because I would like to make thinking in the Arendtian sense the axis along which to organise this exposition. It was interesting for me that when I sent the title of the lecture I was asked whether I meant thinking or rethinking. It is true that we tend to rethink, revisit and review in the titles of our lectures and papers. This usually means that the accent is not so much on the act of thinking but on the object we are trying to examine. For this occasion, I would like to make the act of thinking itself as important an aspect of the lecture as the issue of academic freedom itself. What interests me is to explore the nature of our work as academics and how this relates to the notion of academic freedom. So, this is my proposed itinerary: I will first stop to flag some of the issues we all know about, current debates on academic freedom which inevitably constitute one layer of the background for these reflections; then I would like to explore with the lens of Hannah Arendt's political thinking the meaning of freedom and thinking in relation to the life of academics. I will then complicate matters further by jumping from Arendt to Pierre Bourdieu's Homo Academicus, after which I hope to land in the not too comfortable terrain of a call to action.
- Full Text:
- Date Issued: 2014
- Authors: Lange, Lis
- Date: 2014
- Subjects: Academic Freedom -- South Africa Universities and colleges -- South Africa Equality Liberty Education and state -- South Africa Education, Higher -- South Africa
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/784 , vital:19990
- Description: I have titled this lecture Thinking Academic Freedom, because I would like to make thinking in the Arendtian sense the axis along which to organise this exposition. It was interesting for me that when I sent the title of the lecture I was asked whether I meant thinking or rethinking. It is true that we tend to rethink, revisit and review in the titles of our lectures and papers. This usually means that the accent is not so much on the act of thinking but on the object we are trying to examine. For this occasion, I would like to make the act of thinking itself as important an aspect of the lecture as the issue of academic freedom itself. What interests me is to explore the nature of our work as academics and how this relates to the notion of academic freedom. So, this is my proposed itinerary: I will first stop to flag some of the issues we all know about, current debates on academic freedom which inevitably constitute one layer of the background for these reflections; then I would like to explore with the lens of Hannah Arendt's political thinking the meaning of freedom and thinking in relation to the life of academics. I will then complicate matters further by jumping from Arendt to Pierre Bourdieu's Homo Academicus, after which I hope to land in the not too comfortable terrain of a call to action.
- Full Text:
- Date Issued: 2014
Thinking Africa Newsletter: (June 2014)
- Authors: Matthews, Sally
- Date: 2014
- Language: English
- Type: text , article
- Identifier: vital:38065 , http://hdl.handle.net/20.500.12137/23
- Description: Thinking Africa Newsletter (June 2014).
- Full Text:
- Date Issued: 2014
- Authors: Matthews, Sally
- Date: 2014
- Language: English
- Type: text , article
- Identifier: vital:38065 , http://hdl.handle.net/20.500.12137/23
- Description: Thinking Africa Newsletter (June 2014).
- Full Text:
- Date Issued: 2014
Thinking Africa Newsletter: (March 2014)
- Authors: Matthews, Sally
- Date: 2014
- Language: English
- Type: text , article
- Identifier: vital:38067 , http://hdl.handle.net/20.500.12137/22
- Description: Thinking Africa Newsletter (March 2014).
- Full Text:
- Date Issued: 2014
- Authors: Matthews, Sally
- Date: 2014
- Language: English
- Type: text , article
- Identifier: vital:38067 , http://hdl.handle.net/20.500.12137/22
- Description: Thinking Africa Newsletter (March 2014).
- Full Text:
- Date Issued: 2014
Towards a platform to visualize the state of South Africa's information security
- Swart, Ignus, Irwin, Barry V W, Grobler, Marthie
- Authors: Swart, Ignus , Irwin, Barry V W , Grobler, Marthie
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429688 , vital:72632 , 10.1109/ISSA.2014.6950511
- Description: Attacks via the Internet infrastructure is increasingly becoming a daily occurrence and South Africa is no exception. In response, certain governments have published strategies pertaining to information security on a national level. These policies aim to ensure that critical infrastructure is protected, and that there is a move towards a greater state of information security readiness. This is also the case for South Africa where a variety of policy initiatives have started to gain momentum. While establishing strategy and policy is essential, ensuring its implementation is often difficult and dependent on the availability of resources. This is even more so in the case of information security since virtually all standardized security improvement processes start off with specifying that a proper inventory is required of all hardware, software, people and processes. While this may be possible to achieve at an organizational level, it is far more challenging on a national level. In this paper, the authors examine the possibility of making use of available data sources to achieve inventory of infrastructure on a national level and to visualize the state of a country's information security in at least a partial manner.
- Full Text:
- Date Issued: 2014
- Authors: Swart, Ignus , Irwin, Barry V W , Grobler, Marthie
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429688 , vital:72632 , 10.1109/ISSA.2014.6950511
- Description: Attacks via the Internet infrastructure is increasingly becoming a daily occurrence and South Africa is no exception. In response, certain governments have published strategies pertaining to information security on a national level. These policies aim to ensure that critical infrastructure is protected, and that there is a move towards a greater state of information security readiness. This is also the case for South Africa where a variety of policy initiatives have started to gain momentum. While establishing strategy and policy is essential, ensuring its implementation is often difficult and dependent on the availability of resources. This is even more so in the case of information security since virtually all standardized security improvement processes start off with specifying that a proper inventory is required of all hardware, software, people and processes. While this may be possible to achieve at an organizational level, it is far more challenging on a national level. In this paper, the authors examine the possibility of making use of available data sources to achieve inventory of infrastructure on a national level and to visualize the state of a country's information security in at least a partial manner.
- Full Text:
- Date Issued: 2014
Towards a Sandbox for the Deobfuscation and Dissection of PHP Malware
- Wrench, Peter M, Irwin, Barry V W
- Authors: Wrench, Peter M , Irwin, Barry V W
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429700 , vital:72633 , 10.1109/ISSA.2014.6950504
- Description: The creation and proliferation of PHP-based Remote Access Trojans (or web shells) used in both the compromise and post exploitation of web platforms has fuelled research into automated methods of dissecting and analysing these shells. Current malware tools disguise themselves by making use of obfuscation techniques designed to frustrate any efforts to dissect or reverse engineer the code. Advanced code engineering can even cause malware to behave differently if it detects that it is not running on the system for which it was originally targeted. To combat these defensive techniques, this paper presents a sandbox-based environment that aims to accurately mimic a vulnerable host and is capable of semi-automatic semantic dissection and syntactic deobfuscation of PHP code.
- Full Text:
- Date Issued: 2014
- Authors: Wrench, Peter M , Irwin, Barry V W
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429700 , vital:72633 , 10.1109/ISSA.2014.6950504
- Description: The creation and proliferation of PHP-based Remote Access Trojans (or web shells) used in both the compromise and post exploitation of web platforms has fuelled research into automated methods of dissecting and analysing these shells. Current malware tools disguise themselves by making use of obfuscation techniques designed to frustrate any efforts to dissect or reverse engineer the code. Advanced code engineering can even cause malware to behave differently if it detects that it is not running on the system for which it was originally targeted. To combat these defensive techniques, this paper presents a sandbox-based environment that aims to accurately mimic a vulnerable host and is capable of semi-automatic semantic dissection and syntactic deobfuscation of PHP code.
- Full Text:
- Date Issued: 2014
Towards building an indigenous knowledge platform to enable culturally-sensitive education underpinned by technological pedagogical and content knowledge (TPACK)
- Ntšekhe, Mathe, Terzoli, Alfredo, Thinyane, Mamello
- Authors: Ntšekhe, Mathe , Terzoli, Alfredo , Thinyane, Mamello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431424 , vital:72773 , http://proceedings.e-skillsconference.org/2014/e-skills275-284Ntsekhe821.pdf
- Description: The everyday use of Information and Communication Technologies (ICTs) is ingrained to the fabric of today’s society. A question open for debate is whether this use is or can be optimized to engender authentic solutions, which are aligned to the natural environment of the people? In this paper, we examine at the question from the vantage point of ed-ucating the rural African child. We engage with the sub-question: can ICTs facilitate education grounded in people's own realities, especially those of the marginalized rural poor? We believe this is possible under specific conditions, which include making Indigenous Knowledge (IK) readily available. We propose building an ICT platform that allows injec-tion of IK into the education process: develop a solution that valorizes IK, but also supports efforts to use ICTs in education driven by Tech-nology, Pedagogy, and Content Knowledge (TPACK) framework. The main goal of this framework is to facilitate effective teaching with tech-nology. TPACK partially embeds IK within pedagogical knowledge and ‘contexts’ of learning; we argue for explicit inclusion of IK within the framework to complement the other knowledges.
- Full Text:
- Date Issued: 2014
- Authors: Ntšekhe, Mathe , Terzoli, Alfredo , Thinyane, Mamello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431424 , vital:72773 , http://proceedings.e-skillsconference.org/2014/e-skills275-284Ntsekhe821.pdf
- Description: The everyday use of Information and Communication Technologies (ICTs) is ingrained to the fabric of today’s society. A question open for debate is whether this use is or can be optimized to engender authentic solutions, which are aligned to the natural environment of the people? In this paper, we examine at the question from the vantage point of ed-ucating the rural African child. We engage with the sub-question: can ICTs facilitate education grounded in people's own realities, especially those of the marginalized rural poor? We believe this is possible under specific conditions, which include making Indigenous Knowledge (IK) readily available. We propose building an ICT platform that allows injec-tion of IK into the education process: develop a solution that valorizes IK, but also supports efforts to use ICTs in education driven by Tech-nology, Pedagogy, and Content Knowledge (TPACK) framework. The main goal of this framework is to facilitate effective teaching with tech-nology. TPACK partially embeds IK within pedagogical knowledge and ‘contexts’ of learning; we argue for explicit inclusion of IK within the framework to complement the other knowledges.
- Full Text:
- Date Issued: 2014
Towards developing a social science research agenda for the South African water sector
- Munnik, Victor, Burt, Jane C
- Authors: Munnik, Victor , Burt, Jane C
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/436797 , vital:73306 , ISBN 978-1-4312-0511-0 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/KV%20325-13.pdf
- Description: The report explores what is meant by social research and introduces a synthetic, interdisciplinary framework for water research that side steps the ‘hard’ and ‘soft’ science debate by demonstrating how different disci-plines help us understand different layers of reality when dealing with complex challenges.
- Full Text:
- Date Issued: 2014
- Authors: Munnik, Victor , Burt, Jane C
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/436797 , vital:73306 , ISBN 978-1-4312-0511-0 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/KV%20325-13.pdf
- Description: The report explores what is meant by social research and introduces a synthetic, interdisciplinary framework for water research that side steps the ‘hard’ and ‘soft’ science debate by demonstrating how different disci-plines help us understand different layers of reality when dealing with complex challenges.
- Full Text:
- Date Issued: 2014
Tracing the ANC’s criticism of South African media: 20 years of democracy
- Authors: Malila, Vanessa
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158661 , vital:40219 , https://hdl.handle.net/10520/EJC159512
- Description: We often forget the strides that have been made in the media industry in South Africa since the end of apartheid and the repressive conditions under which the media industry operated prior to 1994. In the current context of complaints by the ANC about the lack of transformation in the industry and the poor reporting by the mainstream commercial media, the gains in ownership changes and the massive growth of the community media sector in South Africa are sometimes overshadowed. Despite a positive early relationship between the media and the ANC government, things have become progressively more difficult between these two institutions and the criticism from the ANC more vociferous in recent years.
- Full Text:
- Date Issued: 2014
- Authors: Malila, Vanessa
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158661 , vital:40219 , https://hdl.handle.net/10520/EJC159512
- Description: We often forget the strides that have been made in the media industry in South Africa since the end of apartheid and the repressive conditions under which the media industry operated prior to 1994. In the current context of complaints by the ANC about the lack of transformation in the industry and the poor reporting by the mainstream commercial media, the gains in ownership changes and the massive growth of the community media sector in South Africa are sometimes overshadowed. Despite a positive early relationship between the media and the ANC government, things have become progressively more difficult between these two institutions and the criticism from the ANC more vociferous in recent years.
- Full Text:
- Date Issued: 2014
Transformative learning and individual adaptation
- Kronlid, David O, Lotz-Sisitka, Heila
- Authors: Kronlid, David O , Lotz-Sisitka, Heila
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437147 , vital:73347 , ISBN 978-1-137-42804-2 , https://doi.org/10.1057/9781137428042_4
- Description: The first part of this chapter explores learning as a Capability to transformatively engage with the world in a climate change context. It draws on previous work that shows that modern as well as indigenous knowledge systems are being affected by climate change. There is no doubt that for societies to adapt to climate change, there is a need for substantive transformative learning, as people everywhere will need to learn new values, practices, relations, and new ways of being and becoming. Such learning on a societal scale has occurred before—as humans adapted to the emergence of the Industrial Revolu-tion, for example. However, the transformation in the climate change adaptation context in many ways is in response to maladaptations that emerged from previous massive societal transformation processes, making this complex to navigate. It is also well known that climate change is leaving many people insecure and highly vulnerable to climate change impacts; it is affecting us all, but the impacts are uneven (Field et al. 2014), requiring different kinds of transformative learning processes in different places and contexts. In this chapter, we therefore propose that, under climate change conditions, we view learning as a key Capability in climate adaptation contexts.
- Full Text:
- Date Issued: 2014
- Authors: Kronlid, David O , Lotz-Sisitka, Heila
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437147 , vital:73347 , ISBN 978-1-137-42804-2 , https://doi.org/10.1057/9781137428042_4
- Description: The first part of this chapter explores learning as a Capability to transformatively engage with the world in a climate change context. It draws on previous work that shows that modern as well as indigenous knowledge systems are being affected by climate change. There is no doubt that for societies to adapt to climate change, there is a need for substantive transformative learning, as people everywhere will need to learn new values, practices, relations, and new ways of being and becoming. Such learning on a societal scale has occurred before—as humans adapted to the emergence of the Industrial Revolu-tion, for example. However, the transformation in the climate change adaptation context in many ways is in response to maladaptations that emerged from previous massive societal transformation processes, making this complex to navigate. It is also well known that climate change is leaving many people insecure and highly vulnerable to climate change impacts; it is affecting us all, but the impacts are uneven (Field et al. 2014), requiring different kinds of transformative learning processes in different places and contexts. In this chapter, we therefore propose that, under climate change conditions, we view learning as a key Capability in climate adaptation contexts.
- Full Text:
- Date Issued: 2014
Trends in the TD-DFT calculations of porphyrin and phthalocyanine analogs
- Mack, John, Stone, Justin, Nyokong, Tebello
- Authors: Mack, John , Stone, Justin , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193882 , vital:45402 , xlink:href="https://doi.org/10.1142/S108842461450045X"
- Description: In 2005, Kobayashi and coworkers reported trends in the TD-DFT spectra of 17 Zn (II) porphyrinoids [J. Am. Chem. Soc. 2005; 127: 17697] that were analyzed using Michl's perimeter model as part of a study of the anomalous magnetic circular dichroism (MCD) spectroscopy of zinc tetraphenyltetraacenaphthoporphyrin. In recent years, it has become increasingly clear that TD-DFT calculations with the commonly used hybrid B3LYP exchange-correlation functional of the Gaussian software package are problematic in the B-band region of porphyrinoid spectra, since the degree of configurational interaction between the B and higher energy ππ* state appears to be significantly overestimated. The CAM-B3LYP functional is now often preferred for analyzing the optical properties of porphyrinoids, since it includes a long-range correction of the exchange potential, which incorporates an increasing fraction of Hartree–Fock (HF) exchange as the interelectronic separation increases, making it better suited for studying compounds where there is significant charge transfer in the electronic excited states. The trends in the TD-DFT calculations are reexamined with a wider range porphyrinoid compounds including several with pyrazino moieties and are found to provide a closer agreement with the experimental in the B-band region for complexes such as zinc tetraphenylporphyrin and phthalocyanine.
- Full Text:
- Date Issued: 2014
- Authors: Mack, John , Stone, Justin , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193882 , vital:45402 , xlink:href="https://doi.org/10.1142/S108842461450045X"
- Description: In 2005, Kobayashi and coworkers reported trends in the TD-DFT spectra of 17 Zn (II) porphyrinoids [J. Am. Chem. Soc. 2005; 127: 17697] that were analyzed using Michl's perimeter model as part of a study of the anomalous magnetic circular dichroism (MCD) spectroscopy of zinc tetraphenyltetraacenaphthoporphyrin. In recent years, it has become increasingly clear that TD-DFT calculations with the commonly used hybrid B3LYP exchange-correlation functional of the Gaussian software package are problematic in the B-band region of porphyrinoid spectra, since the degree of configurational interaction between the B and higher energy ππ* state appears to be significantly overestimated. The CAM-B3LYP functional is now often preferred for analyzing the optical properties of porphyrinoids, since it includes a long-range correction of the exchange potential, which incorporates an increasing fraction of Hartree–Fock (HF) exchange as the interelectronic separation increases, making it better suited for studying compounds where there is significant charge transfer in the electronic excited states. The trends in the TD-DFT calculations are reexamined with a wider range porphyrinoid compounds including several with pyrazino moieties and are found to provide a closer agreement with the experimental in the B-band region for complexes such as zinc tetraphenylporphyrin and phthalocyanine.
- Full Text:
- Date Issued: 2014
Troubling White Englishness in South Africa: a self-interrogation of privilege, complicity citizenship, and belonging
- Authors: Garman, Anthea
- Date: 2014
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/159746 , vital:40339 , ISBN 978-0739192962
- Description: Unveiling Whiteness in the Twenty-First Century: Global Manifestations, Transdisciplinary Interventions is a tightly interconnected and richly collaborative book that will advance our understanding of why it is so difficult to re-form and reimagine whiteness in the twenty-first century. Composed after the election of the first black U.S. president, post-global financial crisis, more than a decade after 9/11, and concomitant with a rash of xenophobic incidents across the globe, the book distills several key themes associated with a post-millennial global whiteness: the individual and collective emotions of whiteness, the recentering of whiteness through governing and legal strategies, and the retreats from social equity and justice that have characterized the late twentieth and twenty-first century nation state. It also attempts the difficult work of reimagining white identities and cultures for a new era.
- Full Text:
- Date Issued: 2014
- Authors: Garman, Anthea
- Date: 2014
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/159746 , vital:40339 , ISBN 978-0739192962
- Description: Unveiling Whiteness in the Twenty-First Century: Global Manifestations, Transdisciplinary Interventions is a tightly interconnected and richly collaborative book that will advance our understanding of why it is so difficult to re-form and reimagine whiteness in the twenty-first century. Composed after the election of the first black U.S. president, post-global financial crisis, more than a decade after 9/11, and concomitant with a rash of xenophobic incidents across the globe, the book distills several key themes associated with a post-millennial global whiteness: the individual and collective emotions of whiteness, the recentering of whiteness through governing and legal strategies, and the retreats from social equity and justice that have characterized the late twentieth and twenty-first century nation state. It also attempts the difficult work of reimagining white identities and cultures for a new era.
- Full Text:
- Date Issued: 2014
Understanding food security in a perfect storm: an ecosystem services approach
- Poppy, G M, Chiotha, S, Eigenbrod, Felix, Harvey, Celia A, Honza´k, M, Hudson, Malcolm D, Jarvis, A, Madise, Nyovani J, Schreckenberg, Kate, Shackleton, Charlie M, Villa, F, Dawson, Terrence P
- Authors: Poppy, G M , Chiotha, S , Eigenbrod, Felix , Harvey, Celia A , Honza´k, M , Hudson, Malcolm D , Jarvis, A , Madise, Nyovani J , Schreckenberg, Kate , Shackleton, Charlie M , Villa, F , Dawson, Terrence P
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398423 , vital:69410 , xlink:href="https://doi.org/10.1098/rstb.2012.0288"
- Description: Achieving food security in a ‘perfect storm’ scenario is a grand challenge for society. Climate change and an expanding global population act in concert to make global food security even more complex and demanding. As achieving food security and the millennium development goal (MDG) to eradicate hunger influences the attainment of other MDGs, it is imperative that we offer solutions which are complementary and do not oppose one another. Sustainable intensification of agriculture has been proposed as a way to address hunger while also minimizing further environmental impact. However, the desire to raise productivity and yields has historically led to a degraded environment, reduced biodiversity and a reduction in ecosystem services (ES), with the greatest impacts affecting the poor. This paper proposes that the ES framework coupled with a policy response framework, for example Driver-Pressure-State-Impact-Response (DPSIR), can allow food security to be delivered alongside healthy ecosystems, which provide many other valuable services to humankind. Too often, agro-ecosystems have been considered as separate from other natural ecosystems and insufficient attention has been paid to the way in which services can flow to and from the agro-ecosystem to surrounding ecosystems. Highlighting recent research in a large multi-disciplinary project (ASSETS), we illustrate the ES approach to food security using a case study from the Zomba district of Malawi.
- Full Text:
- Date Issued: 2014
- Authors: Poppy, G M , Chiotha, S , Eigenbrod, Felix , Harvey, Celia A , Honza´k, M , Hudson, Malcolm D , Jarvis, A , Madise, Nyovani J , Schreckenberg, Kate , Shackleton, Charlie M , Villa, F , Dawson, Terrence P
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398423 , vital:69410 , xlink:href="https://doi.org/10.1098/rstb.2012.0288"
- Description: Achieving food security in a ‘perfect storm’ scenario is a grand challenge for society. Climate change and an expanding global population act in concert to make global food security even more complex and demanding. As achieving food security and the millennium development goal (MDG) to eradicate hunger influences the attainment of other MDGs, it is imperative that we offer solutions which are complementary and do not oppose one another. Sustainable intensification of agriculture has been proposed as a way to address hunger while also minimizing further environmental impact. However, the desire to raise productivity and yields has historically led to a degraded environment, reduced biodiversity and a reduction in ecosystem services (ES), with the greatest impacts affecting the poor. This paper proposes that the ES framework coupled with a policy response framework, for example Driver-Pressure-State-Impact-Response (DPSIR), can allow food security to be delivered alongside healthy ecosystems, which provide many other valuable services to humankind. Too often, agro-ecosystems have been considered as separate from other natural ecosystems and insufficient attention has been paid to the way in which services can flow to and from the agro-ecosystem to surrounding ecosystems. Highlighting recent research in a large multi-disciplinary project (ASSETS), we illustrate the ES approach to food security using a case study from the Zomba district of Malawi.
- Full Text:
- Date Issued: 2014
Understanding the replication biology of Providence virus: elucidating the function of non-structural proteins
- Authors: Nakayinga, Ritah
- Date: 2014
- Subjects: Insects Viruses , Viruses Reproduction , Tombusviridae , RNA viruses , RNA polymerases
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/193930 , vital:45408
- Description: Tetraviruses are non-enveloped, small insect RNA viruses with a single stranded positive RNA genome that is either monopartite or bipartite. Providence virus (PrV) is the only member of the three tetravirus families with a viral replicase similar to the replicases of tombusviruses and umbraviruses. The principle aim of this thesis was to study PrV replication, focusing on subcellular localization and potential interactions between PrV replication proteins. The first objective of this study was to generate an anti-p104 antibody that does not cross-react with p40. Expression of the C-terminal portion of p104 in E. coli resulted in no detectable protein. Further expression in an insect cell based expression system resulted in the production of an insoluble protein. Attempts to improve protein solubility with a range of solubilization treatments were unsuccessful. Bioinformatic analysis was used to detect an antigenic region at the C-terminus of p104 and the peptide was used to raise anti-p104 antibodies. These antibodies did not detect native protein by western blot detection however they were used for immunoprecipitation. The establishment of the subcellular localization of PrV required two approaches; immunofluorescence in persistently infected Helicoverpa zea MG8 cells using antip40 and anti-dsRNA antibodies and the expression of EGFP-replicase fusion protein in Spodoptera frugiperda Sf9 cells. Replication of PrV was found to take place in cytosolic punctate structures. Co-immunoprecipitation experiments revealed that p40 self-interacts and interacts with p104. Bioinformatic analysis of PrV p104 suggests that the RdRp is similar to viral RdRps of the carmo-like supergroup II. Potential RNA binding regions are present within p104. A potential p40 interaction domain that shares hydrophilic and surface exposed properties with the TBSV p33 interaction domain is present. A putative arginine-rich region and disordered C-terminal region is present in p130. In conclusion, PrV p104 is the viral replicase. The resemblance of the expression strategy and putative functional domains with tombusviruses and umbraviruses suggest that PrV replication is related to the replication system of the tombusviruses and umbraviruses. This has led to propose that tetravirus replication strategies are diverse and raises questions on the origin and evolution of PrV. , Thesis (PhD) -- Faculty of Science, Biochemistry, Microbiology and Biotechnology, 2014
- Full Text:
- Date Issued: 2014
- Authors: Nakayinga, Ritah
- Date: 2014
- Subjects: Insects Viruses , Viruses Reproduction , Tombusviridae , RNA viruses , RNA polymerases
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/193930 , vital:45408
- Description: Tetraviruses are non-enveloped, small insect RNA viruses with a single stranded positive RNA genome that is either monopartite or bipartite. Providence virus (PrV) is the only member of the three tetravirus families with a viral replicase similar to the replicases of tombusviruses and umbraviruses. The principle aim of this thesis was to study PrV replication, focusing on subcellular localization and potential interactions between PrV replication proteins. The first objective of this study was to generate an anti-p104 antibody that does not cross-react with p40. Expression of the C-terminal portion of p104 in E. coli resulted in no detectable protein. Further expression in an insect cell based expression system resulted in the production of an insoluble protein. Attempts to improve protein solubility with a range of solubilization treatments were unsuccessful. Bioinformatic analysis was used to detect an antigenic region at the C-terminus of p104 and the peptide was used to raise anti-p104 antibodies. These antibodies did not detect native protein by western blot detection however they were used for immunoprecipitation. The establishment of the subcellular localization of PrV required two approaches; immunofluorescence in persistently infected Helicoverpa zea MG8 cells using antip40 and anti-dsRNA antibodies and the expression of EGFP-replicase fusion protein in Spodoptera frugiperda Sf9 cells. Replication of PrV was found to take place in cytosolic punctate structures. Co-immunoprecipitation experiments revealed that p40 self-interacts and interacts with p104. Bioinformatic analysis of PrV p104 suggests that the RdRp is similar to viral RdRps of the carmo-like supergroup II. Potential RNA binding regions are present within p104. A potential p40 interaction domain that shares hydrophilic and surface exposed properties with the TBSV p33 interaction domain is present. A putative arginine-rich region and disordered C-terminal region is present in p130. In conclusion, PrV p104 is the viral replicase. The resemblance of the expression strategy and putative functional domains with tombusviruses and umbraviruses suggest that PrV replication is related to the replication system of the tombusviruses and umbraviruses. This has led to propose that tetravirus replication strategies are diverse and raises questions on the origin and evolution of PrV. , Thesis (PhD) -- Faculty of Science, Biochemistry, Microbiology and Biotechnology, 2014
- Full Text:
- Date Issued: 2014
Unsymmetrically substituted nickel triazatetra-benzcorrole and phthalocynanine complexes
- Adegoke, Oluwasesan, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189818 , vital:44934 , xlink:href="https://doi.org/10.1007/s10895-013-1317-4"
- Description: We report on the design and application of fluorescent nanoprobes based on the covalent linking of L-glutathione-capped CdSe@ZnS quantum dots (QDs) to newly synthesized unsymmetrically substituted nickel mercaptosuccinic acid triazatetra-benzcorrole (3) and phthalocyanine (4) complexes. Fluorescence quenching of the QDs occurred on conjugation to complexes 3 or 4. The nanoprobes were selectively screened in the presence of different cations and Hg2+ showed excellent affinity in “turning ON” the fluorescence of the nanoprobes. Experimental results showed that the sensitivity of QDs-4 towards Hg2+ was much higher than that of QDs-3 nanoprobe. The mechanism of reaction has been elucidated based on the ability of Hg2+ to coordinate with the sulphur atom of the Ni complex ring and apparently “turn ON” the fluorescence of the linked QDs.
- Full Text:
- Date Issued: 2014
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189818 , vital:44934 , xlink:href="https://doi.org/10.1007/s10895-013-1317-4"
- Description: We report on the design and application of fluorescent nanoprobes based on the covalent linking of L-glutathione-capped CdSe@ZnS quantum dots (QDs) to newly synthesized unsymmetrically substituted nickel mercaptosuccinic acid triazatetra-benzcorrole (3) and phthalocyanine (4) complexes. Fluorescence quenching of the QDs occurred on conjugation to complexes 3 or 4. The nanoprobes were selectively screened in the presence of different cations and Hg2+ showed excellent affinity in “turning ON” the fluorescence of the nanoprobes. Experimental results showed that the sensitivity of QDs-4 towards Hg2+ was much higher than that of QDs-3 nanoprobe. The mechanism of reaction has been elucidated based on the ability of Hg2+ to coordinate with the sulphur atom of the Ni complex ring and apparently “turn ON” the fluorescence of the linked QDs.
- Full Text:
- Date Issued: 2014
Utilizing gesture recognition and Ethernet AVB for distributed surround sound control
- Hedges, Mitchell, Foss, Richard
- Authors: Hedges, Mitchell , Foss, Richard
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426816 , vital:72393 , https://www.aes.org/e-lib/online/browse.cfm?elib=17540
- Description: Gesture recognition has become a preferred approach to the control of various systems. This allows users of the system to interact without having to use any controls or equipment. This paper investigates the use of gesture recognition in order to select and transport audio tracks over an Ethernet AVB network to speaker endpoints. The research uses equipment that is commercially available and relatively cost efficient. The endpoints receive audio samples that are encapsulated within network packets and processes them. The audio tracks are mixed at the endpoints according to gain ratios that will change and be different for each endpoint.
- Full Text:
- Date Issued: 2014
- Authors: Hedges, Mitchell , Foss, Richard
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426816 , vital:72393 , https://www.aes.org/e-lib/online/browse.cfm?elib=17540
- Description: Gesture recognition has become a preferred approach to the control of various systems. This allows users of the system to interact without having to use any controls or equipment. This paper investigates the use of gesture recognition in order to select and transport audio tracks over an Ethernet AVB network to speaker endpoints. The research uses equipment that is commercially available and relatively cost efficient. The endpoints receive audio samples that are encapsulated within network packets and processes them. The audio tracks are mixed at the endpoints according to gain ratios that will change and be different for each endpoint.
- Full Text:
- Date Issued: 2014
Vice-Chancellor's 2014 Address to Graduation Ceremonies
- Authors: Badat, Saleem
- Date: 2014
- Language: English
- Type: text
- Identifier: vital:7868 , http://hdl.handle.net/10962/d1016417
- Full Text:
- Date Issued: 2014
- Authors: Badat, Saleem
- Date: 2014
- Language: English
- Type: text
- Identifier: vital:7868 , http://hdl.handle.net/10962/d1016417
- Full Text:
- Date Issued: 2014