Rethinking education for sustainable development as transgressive processes.pdf
- Identifier: http://hdl.handle.net/10962/433196 , vital:72950
- Description: The modernist expansion of Education is examined to explore how the concept of Education for Sustainable Development (ESD) has emerged, is being worked with, and is being assessed in imperatives intended to foster social-ecological change on a global scale. The opening review sketches how education developed as a mediating process in modernity, tracking some recent shifts that are shaping ESD in more and more diverse contexts of education practice. It scopes an ESD terrain where knowledge and ethics-led learning in relation to valued purposes might enable citizens to become engaged in change that secures a sustainable future for generations to come. Within these processes, competence specification is examined as a useful but under-theorised social imaginary for framing learning for future sustainability, primarily in teacher education and curriculum contexts. Here, ESD presents as an open process of situated social learning where emergent competences steer social innovation towards a more sustainable future (SD). The paper attempts to navigate some of the current tensions in relation to knowledge and participation in these processes of learning-to-change. It probes ESD as praxiological processes of dialectical reflexivity that can become situated in contexts of risk and develop as transgressive1 expansions within many conventional learning sequences in curriculum settings. The paper notes that current discourses on ESD and its assessment have often come to stand outside, and in contrast with, conventions of teaching and learning. These discourses also often conflate education and sustainable development in ways that ascribe change to ESD without adequately theorising the expansive and reflexive learning of citizens and how these processes might produce the desired change towards sustainable development (SD) in diverse contexts of learning in and about a changing world.
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- Date Issued: 2014
- Identifier: http://hdl.handle.net/10962/433196 , vital:72950
- Description: The modernist expansion of Education is examined to explore how the concept of Education for Sustainable Development (ESD) has emerged, is being worked with, and is being assessed in imperatives intended to foster social-ecological change on a global scale. The opening review sketches how education developed as a mediating process in modernity, tracking some recent shifts that are shaping ESD in more and more diverse contexts of education practice. It scopes an ESD terrain where knowledge and ethics-led learning in relation to valued purposes might enable citizens to become engaged in change that secures a sustainable future for generations to come. Within these processes, competence specification is examined as a useful but under-theorised social imaginary for framing learning for future sustainability, primarily in teacher education and curriculum contexts. Here, ESD presents as an open process of situated social learning where emergent competences steer social innovation towards a more sustainable future (SD). The paper attempts to navigate some of the current tensions in relation to knowledge and participation in these processes of learning-to-change. It probes ESD as praxiological processes of dialectical reflexivity that can become situated in contexts of risk and develop as transgressive1 expansions within many conventional learning sequences in curriculum settings. The paper notes that current discourses on ESD and its assessment have often come to stand outside, and in contrast with, conventions of teaching and learning. These discourses also often conflate education and sustainable development in ways that ascribe change to ESD without adequately theorising the expansive and reflexive learning of citizens and how these processes might produce the desired change towards sustainable development (SD) in diverse contexts of learning in and about a changing world.
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- Date Issued: 2014
SEK Mqhayi in the 21st Century: Mzantsi youth ideologies within the African renaissance paradigm for sustainable economic and political development
- Authors: Saule, Ncedile
- Subjects: Pan-Africanism , Mqhayi, S E K , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21011 , vital:29427
- Description: I am advancing a celebratory synopsis of Mqhayi, uMzima, uBhomoyi kaCedume at a time when the South African contemporary society is attempting to restructure itself in order to regain lost values before it can successfully and rationally embrace values of other people. In my presentation, I have mindfully taken cognisance of the plight of the so called lost generation, especially among our youth, those who have become strangers in their own land – no language, only misguided and distorted cultural values, no self, distorted history - this of course because of indoctrinations of some psycho-socio-histori-cultural and political imperatives. Strangely enough these are some of the issues that SEK Mqhayi warns us about in his creative works and has made efforts for us to see, but unfortunately no one listened or saw anything. Now that we “have the truth but denied the truth and now that we have the light, but we sit in darkness, Shivering, benighted in the bright noon-day sun,” and now that we are all blind, I think, this evening is the right time to see.
- Full Text:
- Authors: Saule, Ncedile
- Subjects: Pan-Africanism , Mqhayi, S E K , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21011 , vital:29427
- Description: I am advancing a celebratory synopsis of Mqhayi, uMzima, uBhomoyi kaCedume at a time when the South African contemporary society is attempting to restructure itself in order to regain lost values before it can successfully and rationally embrace values of other people. In my presentation, I have mindfully taken cognisance of the plight of the so called lost generation, especially among our youth, those who have become strangers in their own land – no language, only misguided and distorted cultural values, no self, distorted history - this of course because of indoctrinations of some psycho-socio-histori-cultural and political imperatives. Strangely enough these are some of the issues that SEK Mqhayi warns us about in his creative works and has made efforts for us to see, but unfortunately no one listened or saw anything. Now that we “have the truth but denied the truth and now that we have the light, but we sit in darkness, Shivering, benighted in the bright noon-day sun,” and now that we are all blind, I think, this evening is the right time to see.
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South African estuaries in the Anthropocene
- Authors: Perissinotto, Renzo
- Subjects: Estuaries -- South Africa , Geology, Stratigraphic -- Anthropocene , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20977 , vital:29424
- Description: In the new geological epoch of total human dominance of the planet, already widely referred to as the “Anthropocene”, estuaries are among the most vulnerable ecosystems to the changes that man’s activities have imposed on the coastal zone. For the non-specialist, an estuary is a “semi-enclosed coastal body of water, which has a permanent or temporary connection with the open sea, and within which sea water is diluted with fresh water from land drainage”.
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- Authors: Perissinotto, Renzo
- Subjects: Estuaries -- South Africa , Geology, Stratigraphic -- Anthropocene , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20977 , vital:29424
- Description: In the new geological epoch of total human dominance of the planet, already widely referred to as the “Anthropocene”, estuaries are among the most vulnerable ecosystems to the changes that man’s activities have imposed on the coastal zone. For the non-specialist, an estuary is a “semi-enclosed coastal body of water, which has a permanent or temporary connection with the open sea, and within which sea water is diluted with fresh water from land drainage”.
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Spectral properties and photophysical behaviour of water soluble cationic Mg(II) and Al(III) phthalocyanines
- Idowu, Mopelola A I, Arslanoglu, Yasin, Nyokong, Tebello
- Authors: Idowu, Mopelola A I , Arslanoglu, Yasin , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7277 , http://hdl.handle.net/10962/d1020292
- Description: Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA). , Original publication is available at http://dx.doi.org/10.2478/s11532-013-0388-z
- Full Text: false
- Authors: Idowu, Mopelola A I , Arslanoglu, Yasin , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7277 , http://hdl.handle.net/10962/d1020292
- Description: Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA). , Original publication is available at http://dx.doi.org/10.2478/s11532-013-0388-z
- Full Text: false
Synthesis and characterization of quantum dots designed for biomedical use
- Kuzyniak, Weronika, Adegoke, Oluwasesan, Sekhosana, Kutloano E, D’Souza, Sarah, Tshangana, Sesethu Charmaine, Hoffmann, Björn, Ermilov, Eugeny A., Nyokong, Tebello, Höpfner, Michael
- Authors: Kuzyniak, Weronika , Adegoke, Oluwasesan , Sekhosana, Kutloano E , D’Souza, Sarah , Tshangana, Sesethu Charmaine , Hoffmann, Björn , Ermilov, Eugeny A. , Nyokong, Tebello , Höpfner, Michael
- Language: English
- Type: Article
- Identifier: vital:7310 , http://hdl.handle.net/10962/d1020387
- Description: Semiconductor quantum dots (QDs) have become promising nanoparticles for a wide variety of biomedical applications. However, the major drawback of QDs is their potential toxicity. Here, we determined possible cytotoxic effects of a set of QDs by systematic photophysical evaluation in vitro as well as in vivo. QDs were synthesized by the hydrothermal aqueous route with sizes in the range of 2.0–3.5 nm. Cytotoxic effects of QDs were studied in the human pancreatic carcinoid cell line BON. Cadmium telluride QDs with or without zinc sulfide shell and coated with 3-mercaptopropionic acid (MPA) were highly cytotoxic even at nanomolar concentrations. Capping with l-glutathione (GSH) or thioglycolic acid (TGA) reduced the cytotoxicity of cadmium telluride QDs and cadmium selenide QDs. Determination of the toxicity of QDs revealed IC50 values in the micromolar range. In vivo studies showed good tolerability of CdSe QDs with ZnS shell and GSH capping. We could demonstrate that QDs with ZnS shell and GSH capping exhibit low toxicity and good tolerability in cell models and living organisms. These QDs appear to be promising candidates for biomedical applications such as drug delivery for enhanced chemotherapy or targeted delivery of light sensitive substances for photodynamic therapy. , Original publication is available at http://dx.doi.org/10.1016/j.ijpharm.2014.03.037
- Full Text: false
- Authors: Kuzyniak, Weronika , Adegoke, Oluwasesan , Sekhosana, Kutloano E , D’Souza, Sarah , Tshangana, Sesethu Charmaine , Hoffmann, Björn , Ermilov, Eugeny A. , Nyokong, Tebello , Höpfner, Michael
- Language: English
- Type: Article
- Identifier: vital:7310 , http://hdl.handle.net/10962/d1020387
- Description: Semiconductor quantum dots (QDs) have become promising nanoparticles for a wide variety of biomedical applications. However, the major drawback of QDs is their potential toxicity. Here, we determined possible cytotoxic effects of a set of QDs by systematic photophysical evaluation in vitro as well as in vivo. QDs were synthesized by the hydrothermal aqueous route with sizes in the range of 2.0–3.5 nm. Cytotoxic effects of QDs were studied in the human pancreatic carcinoid cell line BON. Cadmium telluride QDs with or without zinc sulfide shell and coated with 3-mercaptopropionic acid (MPA) were highly cytotoxic even at nanomolar concentrations. Capping with l-glutathione (GSH) or thioglycolic acid (TGA) reduced the cytotoxicity of cadmium telluride QDs and cadmium selenide QDs. Determination of the toxicity of QDs revealed IC50 values in the micromolar range. In vivo studies showed good tolerability of CdSe QDs with ZnS shell and GSH capping. We could demonstrate that QDs with ZnS shell and GSH capping exhibit low toxicity and good tolerability in cell models and living organisms. These QDs appear to be promising candidates for biomedical applications such as drug delivery for enhanced chemotherapy or targeted delivery of light sensitive substances for photodynamic therapy. , Original publication is available at http://dx.doi.org/10.1016/j.ijpharm.2014.03.037
- Full Text: false
Unsymmetrically Substituted Nickel Triazatetra-Benzcorrole and Phthalocynanine Complexes: Conjugation to Quantum Dots and Applications as Fluorescent “Turn ON” Sensors
- Adegoke, Oluwasesan, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7311 , http://hdl.handle.net/10962/d1020403
- Description: We report on the design and application of fluorescent nanoprobes based on the covalent linking of L-glutathione-capped CdSe@ZnS quantum dots (QDs) to newly synthesized unsymmetrically substituted nickel mercaptosuccinic acid triazatetra-benzcorrole (3) and phthalocyanine (4) complexes. Fluorescence quenching of the QDs occurred on conjugation to complexes 3 or 4. The nanoprobes were selectively screened in the presence of different cations and Hg2+ showed excellent affinity in “turning ON” the fluorescence of the nanoprobes. Experimental results showed that the sensitivity of QDs-4 towards Hg2+ was much higher than that of QDs-3 nanoprobe. The mechanism of reaction has been elucidated based on the ability of Hg2+ to coordinate with the sulphur atom of the Ni complex ring and apparently “turn ON” the fluorescence of the linked QDs. , Original publication is available at http://dx.doi.org/10.1007/s10895-013-1317-4
- Full Text: false
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7311 , http://hdl.handle.net/10962/d1020403
- Description: We report on the design and application of fluorescent nanoprobes based on the covalent linking of L-glutathione-capped CdSe@ZnS quantum dots (QDs) to newly synthesized unsymmetrically substituted nickel mercaptosuccinic acid triazatetra-benzcorrole (3) and phthalocyanine (4) complexes. Fluorescence quenching of the QDs occurred on conjugation to complexes 3 or 4. The nanoprobes were selectively screened in the presence of different cations and Hg2+ showed excellent affinity in “turning ON” the fluorescence of the nanoprobes. Experimental results showed that the sensitivity of QDs-4 towards Hg2+ was much higher than that of QDs-3 nanoprobe. The mechanism of reaction has been elucidated based on the ability of Hg2+ to coordinate with the sulphur atom of the Ni complex ring and apparently “turn ON” the fluorescence of the linked QDs. , Original publication is available at http://dx.doi.org/10.1007/s10895-013-1317-4
- Full Text: false