- Title
- Redox reactions of an Mo (V) tetrasulfophthalocyanine
- Creator
- Ferraudi, Guillermo
- Creator
- Nyokong, Tebello
- Creator
- Feliz, Mario
- Creator
- Perkovic, Marc
- Creator
- Rillema, D Paul
- Subject
- To be catalogued
- Date Issued
- 1994
- Date
- 1994
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/295530
- Identifier
- vital:57351
- Identifier
- xlink:href="https://doi.org/10.1016/0020-1693(93)03664-V"
- Description
- The preparation of an Mo(V) tetrasulfophthalocyanine and some of its thermal and photochemical reactions have been investigated in this work. Electrochemical processes have been followed by means of the UVVis spectral changes and compared with those observed in flash photolysis. Mo(IV) and Mo(V)-ligand-radical species are common intermediates of the electrochemical and photochemical reactions. In 254 nm irradiations of the Mo(V) tetrasulfophthalocyanine in aqueous solutions of 2-propanol, the macrocycle can be photohydrogenated and the product of the photolysis can be reoxidized with O2 back to the parent complex.
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (6 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganica Chimica Acta
- Relation
- Ferraudi, G., Nyokong, T., Feliz, M., Perkovic, M. and Rillema, D.P., 1994. Redox reactions of an Mo (V) tetrasulfophthalocyanine. Inorganica chimica acta, 215(1-2), pp.27-32
- Relation
- Inorganica Chimica Acta volume 215 number 1-2 p. 27 1994 1873-3255
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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