Activated carbon-decorated polyacrylonitrile fibers and their porphyrin-immobilized composites for removal of methylene blue dye and Ciprofloxacin in water
- Authors: Oyim, James , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2023
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:65077 , xlink:href="https://doi.org/10.1080/10601325.2023.2183868"
- Description: Photocatalyst adsorbents are an appealing group of materials for environmental applications. Herein, we study a new simple, inexpensive, yet very effective adsorbent photocatalyst based on porphyrin immobilized activated carbon-decorated polyacrylonitrile, InP(PAN/AC), for removal of methylene blue dye and Ciprofloxacin in water under Xe-lamp and sunlight irradiation (the latter for Ciprofloxacin only). Our results shed light on developing the most effective and sustainable adsorbent photocatalysts that can easily be industrialized due to the ease of preparation through electrospinning coupled with the readily available preparation materials. After five cycles, the InP(PAN/AC) maintained high methylene dye removal efficiency and structural integrity. Significantly, we propose the coordinated contribution of singlet oxygen and hydroxyl radical in the photodegradation process and highlight the importance of such an integrated system with adsorption and photodegradation capabilities for water treatment.
- Full Text:
- Date Issued: 2023
Integrated photocatalyst adsorbents based on porphyrin anchored to activated carbon granules for water treatment
- Authors: Oyim, James , Amuhaya, Edith K , Matshitse, Refilwe , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300101 , vital:57893 , xlink:href="https://doi.org/10.1016/j.cartre.2022.100191"
- Description: Integration of adsorption and photocatalysis processes can lead to several benefits in water treatment. Integrating well-known adsorbents with photocatalysts ensures that all the interesting components are preserved and helps to overcome the serious downsides of each material and technique when operated independently. In this work, we introduce a new concept of combining both absorption and photodegradation mechanisms using organic photocatalytic adsorbents for water purification. This was achieved by formulating photosensitizing hybrids based on a newly synthesized chloroindium (III) 5,10,15,20-tetrakis(4-acetamidophenyl) porphyrin (InTAAP) compound, anchored on oxygen functionalized coconut shell-based activated carbon granules supports. The fashioned integrated photocatalyst adsorbent hybrid (InTAAP(ACO)) was then studied for their adsorption and photodegradation efficiency using methylene blue dye, where InTAAP(ACO) showed excellent photocatalytic activity compared to ACO and unfunctionalized activated carbon granules (AC), with appreciably high and adsorption properties as AC and ACO.
- Full Text:
- Date Issued: 2022