- Title
- The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI)
- Creator
- Haigh, John M
- Creator
- Nassimbeni, Luigi R
- Creator
- Pauptit, Richard A
- Creator
- Rodgers, Allen L
- Creator
- Sheldrick, George M
- Subject
- Aliphatic amine adducts
- Subject
- Uranyl acetylacetonate
- Date Issued
- 1976
- Date
- 1976
- Type
- Article
- Type
- text
- Identifier
- vital:6373
- Identifier
- http://hdl.handle.net/10962/d1006077
- Description
- Crystals of the title compound are monoclinic with a= 8.314 (5), b= 22.723 (9), c= 12.589 (6) A, /3= 123.0 (2t, Z=4, space group P2dc. The structure was determined by Patterson and Fourier methods and refined by full-matrix least squares to a final R of 0.030 for 2043 independent reflexions. The U atom has pentagonal bipyramidal coordination and the N-methylacetylacetoneamine is bonded to U via O. There are two intramolecular N-H. . .0 hydrogen bonds which govern the geometry of the adduct molecule.
- Format
- 4 pages
- Format
- Language
- English
- Relation
- Haigh, J.M. and Nassimbeni, L.R. and Pauptit, R.A. and Rodgers, A.L. and Sheldrick, G.M. (1976) The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI). Acta Crystallographica, B32 . pp. 1398-1401
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