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Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions

  • Authors: Jiang, Yu , Li, Minzhi , Liang, Xu , Mack, John , Wildervanck, Martijn , Nyokong, Tebello , Qin, Mingfeng , Zhu, Weihua
  • Date: 2015-10-07
  • Subjects: Dalton Transactions (2015), 44, 18237-18246, doi:10.1039/c5dt03256c
  • Language: English
  • Type: Article
  • Identifier: vital:7282 , http://hdl.handle.net/10962/d1020322
  • Description: A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions. , Original publication is available at http://dx.doi.org/10.1039/C5DT03256C
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Life orientation sexuality education in South Africa: gendered norms, justice and transformation

  • Authors: Shefer, Tamara , Macleod, Catriona I
  • Date: 2015
  • Language: English
  • Type: Article
  • Identifier: vital:6310 , http://hdl.handle.net/10962/d1018868
  • Description: [From introduction] Research on sexual practices among young South Africans has proliferated in light of the national imperatives to challenge the spread of HIV/AIDS, gender-based violence and unwanted early pregnancies. It has been widely acknowledged that, in order to respond to these social problems, we need to understand the enmeshment of gender, class, age and other forms of social inequality, and how these are played out in ‘normal’ heterosexual relationships. Life Orientation (LO) sexuality education programmes have been viewed as key locations for incorporating education to challenge negative assumptions in respect of HIV/AIDS, gender-based violence and unwanted pregnancy and to promote safer, equitable and non-violent sexual practices. There is a paucity of work that interrogates the LO sexuality education programme in terms of gender norms, gender justice and gender transformation. In the handful of studies conducted on school-based sexuality education in South Africa, researchers have foregrounded a number of challenges, including the dominance of a guiding metaphor of danger and disease in the sexuality education component of LO manuals (Macleod, 2009); educators using a transmission mode of teaching to the exclusion of participation and experiential modes of learning (Rooth, 2005); educators understanding sexuality education as chiefly addressing the provision of information concerning, and prevention of, HIV/AIDS (Francis, 2011); teachers’ preference for abstinence-only education taught by means of a series of moral injunctions (Francis, 2011); and the avoidance of discussions of sexual diversity, and the endorsement of compulsory heterosexuality when same-sex relationships are mentioned (Francis, 2012). Recent research has also highlighted the variation in how teachers approach sexuality education. Francis and DePalma (2014) indicate that, while teachers may promote abstinence as the only appropriate choice for young people, they also recognise the value of teaching relationships and safe sex (aspects associated with comprehensive sexuality education). In their study, Helleve et al. (2009) report that Grades 8 and 9 LO teachers felt confident in teaching HIV and sexuality. This special issue of Perspectives in Education builds on this research by drawing together several papers that examine how LO or Life Skills sexuality programmes challenge and/or reproduce normative constructions of gender and gendered power relations. All the papers use qualitative research to locate these programmes within the complex contexts of their enactment, drawing attention to the multiple possibilities and limitations of such programmes. In the next section, we summarise the key problematics addressed in each of the papers. What curiosities drove the studies conducted by these researchers interested in gender dynamics in schools and LO or Life Skills sexuality education? Why are these curiosities important? We then highlight the key findings that emerged from these curiosities and the nuanced data collected. Finally, and most importantly in terms of the aims of this special issue, we address the ways in which a critical gender lens that facilitates gender transformation and gender justice could possibly be incorporated into LO or Life Skills sexuality programmes.
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  • Date Issued: 2015

Networking English Teachers' Conference

  • Authors: Badat, Saleem
  • Date: 2014-12-04
  • Language: English
  • Type: Text
  • Identifier: vital:7785 , http://hdl.handle.net/10962/d1015940
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Theses on Institutional Planning and Research at Universities

  • Authors: Badat, Saleem
  • Date: 2011-10-11
  • Language: English
  • Type: Text
  • Identifier: vital:7805 , http://hdl.handle.net/10962/d1015998
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  • Date Issued: 2011-10-11

VC's welcome at the Rhodes University House Committees and Sub-Wardens workshop

  • Authors: Badat, Saleem
  • Date: 2011-02-02
  • Language: English
  • Type: Text
  • Identifier: vital:7844 , http://hdl.handle.net/10962/d1016037
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  • Date Issued: 2011-02-02

Keynote Address by the Vice-Chancellor of Rhodes University at the Graduation, Prize-giving and Induction Ceremony of the Student Sponsorship Programme (Eastern Cape Class of 2010)

  • Authors: Badat, Saleem
  • Date: 2011-01-15
  • Language: English
  • Type: Text
  • Identifier: vital:7835 , http://hdl.handle.net/10962/d1016028
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  • Date Issued: 2011-01-15

Keynote Address by the Vice-Chancellor of Rhodes University at the Graduation, Prize-giving and Induction Ceremony of the Student Sponsorship Programme (Eastern Cape Class of 2010)

  • Authors: Badat, Saleem
  • Date: 2011-01-14
  • Language: English
  • Type: Text
  • Identifier: vital:7834 , http://hdl.handle.net/10962/d1016027
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  • Date Issued: 2011-01-14

Rhodes University 2010 and beyond

  • Authors: Badat, Saleem
  • Date: 2010-02-16
  • Language: English
  • Type: Text
  • Identifier: vital:7783 , http://hdl.handle.net/10962/d1015938
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  • Date Issued: 2010-02-16

Beyond the obsession with skills and towards a discourse of knowledge, skills and attitudes

  • Authors: Badat, Saleem
  • Date: 2009-05-23
  • Language: English
  • Type: Text
  • Identifier: vital:7739 , http://hdl.handle.net/10962/d1015886
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  • Date Issued: 2009-05-23

2008 Rhodes University graduation ceremonies address

  • Authors: Badat, Saleem
  • Date: 2008-03-27
  • Language: English
  • Type: Text
  • Identifier: vital:7669 , http://hdl.handle.net/10962/d1015814
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  • Date Issued: 2008-03-27

Welcome address of the Vice-Chancellor of Rhodes University, Dr Saleem Badat

  • Authors: Badat, Saleem
  • Date: 2008-02-04
  • Subjects: Rhodes University
  • Language: English
  • Type: Text
  • Identifier: vital:7675 , http://hdl.handle.net/10962/d1015820
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  • Date Issued: 2008-02-04

A phenomenological case study of a lecturer's understanding of himself as an assessor

  • Authors: Grant, Rosemary
  • Date: 2008
  • Language: English
  • Type: Article
  • Identifier: vital:6087 , http://hdl.handle.net/10962/d1008582
  • Description: Based on the findings of research conducted as part of a doctoral study aimed at obtaining an understanding of what it means to be an assessor in higher education, this paper outlines the experience of an individual lecturer at a South African university and describes the meaning he makes of his practice as an assessor within the context of a changing understanding of the nature and purpose of higher education. Making a case for personal agency and innovation as critical qualities in the assessment endeavour, the researcher suggests that, in contrast to a view of education increasingly focused on standardization, accountability and outcomes, student assessment is essentially a human encounter in which the humanity and emotions of both lecturer and student need to be acknowledged.
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  • Date Issued: 2008

The assessment and treatment of post-abortion syndrome : a systematic case study from Southern Africa

  • Authors: Boulind, Melissa , Edwards, David J A
  • Date: 2008
  • Language: English
  • Type: Article
  • Identifier: vital:6270 , http://hdl.handle.net/10962/d1008270
  • Description: This article reports a clinical case study of "Grace", a black Zimbabwean woman with post-abortion syndrome (PAS), a form of post-traumatic stress disorder precipitated by aborting an unwanted pregnancy. She was treated by a middle class white South African trainee Clinical Psychologist. The case narrative documents the assessment and the course of treatment which was guided by ongoing case formulation based on current evidence-based models. Factors that made her vulnerable to developing PTSD included active suppression of the memory of the event and lack of social support. An understanding of these factors was used to guide an effective intervention. In spite of the differences in culture and background between client and therapist, there was considerable commonality in their experience as young women and students who each had to balance personal and occupational priorities. The narrative also highlights the commonalities of Grace's experiences with those reported in the literature on post-abortion syndrome, which is mostly from the U. S. A. and Europe.
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  • Date Issued: 2008

Address at the farewell dinner of the 1st Congress of the African Sociology Conference, 18 July 2007.

  • Authors: Badat, Saleem
  • Date: 2007-07-18 , 2014-06-13
  • Language: English
  • Type: Text
  • Identifier: vital:7618 , http://hdl.handle.net/10962/d1011830
  • Description: Address at the farewell dinner of the 1st Congress of the African Sociology Conference, 15-18 July 2007.
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  • Date Issued: 2007-07-18

Rhodos, Vol. 9, No. 21

  • Date: 1997-12-10
  • Subjects: Rhodes University -- Rhodos , Grahamstown -- Newspapers
  • Language: English
  • Type: Text
  • Identifier: vital:14937 , http://hdl.handle.net/10962/d1019176
  • Description: The Rhodos newsletter carries news and information about events, awards, projects and developments both on and off campus. Ten editions of Rhodos are printed throughout the academic year for distribution among staff members of the University
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  • Date Issued: 1997-12-10

Rhodos, Vol. 9, No. 18

  • Date: 1997-10-31
  • Subjects: Rhodes University -- Rhodos , Grahamstown -- Newspapers
  • Language: English
  • Type: Text
  • Identifier: vital:14934 , http://hdl.handle.net/10962/d1019173
  • Description: The Rhodos newsletter carries news and information about events, awards, projects and developments both on and off campus. Ten editions of Rhodos are printed throughout the academic year for distribution among staff members of the University
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  • Date Issued: 1997-10-31

Rhodes Newsletter

Rhodos, Vol. 4, No. 17

  • Date: 1992-09-22
  • Subjects: Rhodes University -- Rhodos , Grahamstown -- Newspapers
  • Language: English
  • Type: Text
  • Identifier: vital:14850 , http://hdl.handle.net/10962/d1019089
  • Description: The Rhodos newsletter carries news and information about events, awards, projects and developments both on and off campus. Ten editions of Rhodos are printed throughout the academic year for distribution among staff members of the University
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  • Date Issued: 1992-09-22

Rhodeo: 1986 - September

  • Date: 1986-09
  • Subjects: Grahamstown -- Newspapers , Journalism, Students -- South Africa , Rhodes University -- Activate , Rhodes University -- Students , Student newspapers and periodicals -- South Africa
  • Language: English
  • Type: Text
  • Identifier: vital:14739 , http://hdl.handle.net/10962/d1019611
  • Description: Rhodeo is the Independent Student Newspaper of Rhodes University. Located in Grahamstown, Rhodeo was established in 1947, and renamed in 1994 as Activate. During apartheid Rhodeo became an active part of the struggle for freedom of expression as part of the now defunct South African Student Press Union. Currently Activate is committed to informing Rhodes University students, staff and community members about relevant issues, mainly on campus. These issues range from hard news to more creative journalism. While Activate acts as a news source, one of its main objectives it to be accessible as a training ground for student journalists. The newspaper is run entirely by the students and is published twice a term. Activate is a free newspaper which receives an annual grant from the Rhodes University Student Representative Council, however, majority of its revenue is generated through advertising.
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  • Date Issued: 1986-09

Rhodeo, Vol. 35, No. 4

  • Date: 1981-05
  • Subjects: Grahamstown -- Newspapers , Journalism, Students -- South Africa , Rhodes University -- Activate , Rhodes University -- Students , Student newspapers and periodicals -- South Africa
  • Language: English
  • Type: Text
  • Identifier: vital:14706 , http://hdl.handle.net/10962/d1019578
  • Description: Rhodeo is the Independent Student Newspaper of Rhodes University. Located in Grahamstown, Rhodeo was established in 1947, and renamed in 1994 as Activate. During apartheid Rhodeo became an active part of the struggle for freedom of expression as part of the now defunct South African Student Press Union. Currently Activate is committed to informing Rhodes University students, staff and community members about relevant issues, mainly on campus. These issues range from hard news to more creative journalism. While Activate acts as a news source, one of its main objectives it to be accessible as a training ground for student journalists. The newspaper is run entirely by the students and is published twice a term. Activate is a free newspaper which receives an annual grant from the Rhodes University Student Representative Council, however, majority of its revenue is generated through advertising.
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  • Date Issued: 1981-05
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