Phototransferred thermoluminescence of α-Al2O3: C: experimental results and empirical models
- Chithambo, Makaiko L, Seneza, Cleophace, Kalita, Jitumani M
- Authors: Chithambo, Makaiko L , Seneza, Cleophace , Kalita, Jitumani M
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115681 , vital:34215 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: The thermoluminescence glow curve of α-Al2O3:C consists of a prominent apparently-single peak and a number of weaker intensity secondary peaks. Phototransferred thermoluminescence (PTTL) from secondary glow peaks in α-Al2O3:C is reported. For completeness and to aid discussion, complementary results for the main peak are included. The problem studied is one of phototransferred thermoluminescence for a system of multiple acceptors and multiple donors. A TL glow curve recorded at 5 °C/s following irradiation to 0.5 Gy shows the main peak (labelled II) at 240 °C and two secondary peaks at 86 °C (peak I) and 360 °C (peak III). Peak I is reproduced under phototransfer after any preheating between 100 and 500 °C. Peak II is also reproduced as a PTTL peak after preheating to any temperature up to 800 °C. For the latter, the duration of preheating matters because if the sample is preheated at 800 °C for say, 6 min, PTTL is obtained but not when this is extended to say, 15 min. No PTTL was observed from peak III at all. A study of the time dependence of the PTTL intensity from peak III, following preheating that removes peaks I and II, shows that its electron trap acts as an acceptor when the duration of illumination to stimulate electrons from deep traps is brief but that when the illumination time is extended, the electron trap for peak III loses some of its trapped electrons to the shallower traps thus acting as a donor trap.
- Full Text: false
- Date Issued: 2017
- Authors: Chithambo, Makaiko L , Seneza, Cleophace , Kalita, Jitumani M
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/115681 , vital:34215 , https://doi.org/10.1016/j.radmeas.2017.08.009
- Description: The thermoluminescence glow curve of α-Al2O3:C consists of a prominent apparently-single peak and a number of weaker intensity secondary peaks. Phototransferred thermoluminescence (PTTL) from secondary glow peaks in α-Al2O3:C is reported. For completeness and to aid discussion, complementary results for the main peak are included. The problem studied is one of phototransferred thermoluminescence for a system of multiple acceptors and multiple donors. A TL glow curve recorded at 5 °C/s following irradiation to 0.5 Gy shows the main peak (labelled II) at 240 °C and two secondary peaks at 86 °C (peak I) and 360 °C (peak III). Peak I is reproduced under phototransfer after any preheating between 100 and 500 °C. Peak II is also reproduced as a PTTL peak after preheating to any temperature up to 800 °C. For the latter, the duration of preheating matters because if the sample is preheated at 800 °C for say, 6 min, PTTL is obtained but not when this is extended to say, 15 min. No PTTL was observed from peak III at all. A study of the time dependence of the PTTL intensity from peak III, following preheating that removes peaks I and II, shows that its electron trap acts as an acceptor when the duration of illumination to stimulate electrons from deep traps is brief but that when the illumination time is extended, the electron trap for peak III loses some of its trapped electrons to the shallower traps thus acting as a donor trap.
- Full Text: false
- Date Issued: 2017
A case study on the health risks related to flood disasters in South Africa
- Tandlich, Roman, Ncube, Mbonisi, Khamanga, Sandile M, Zuma, Bongumusa M
- Authors: Tandlich, Roman , Ncube, Mbonisi , Khamanga, Sandile M , Zuma, Bongumusa M
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/75917 , vital:30482 , DOI: 10.20965/jdr.2016.p0732
- Description: Floods occurred in the Ndlambe Local Municipality in South Africa in October 2012. During various stages of the post-disaster recovery, bacterial concentrations were measured in water and soil samples from the flood zone. All drinking water concentrations of E. coli were below 1–3 colony forming units per 100 millilitres (CFUs/100 mL). The flood waters contained between 46500 to more than 100000 CFUs/100 mL of E. coli. {The concentrations of Salmonella spp. in the flood waters varied from 5000 to 250000 CFUs/100 mL. The presumptive Vibrio spp. concentrations in flood waters ranged from 1000 to over 150000 CFUs/100 mL. {The soil concentrations for E. coli ranged from 1 to above 330 colony-forming units per 1 g of soil dry weight (CFUs/g). The soil concentrations of Salmonella spp. varied from below 1 to 22 CFUs/g. The estimated airborne fungal concentrations ranged from 16820 to 28540 colony-forming units per 1 cubic meter. An outbreak of an infectious disease was recorded among the volunteers who assisted with the post-disaster recovery. The likely bacterial causative agents included strains of Aeromonas spp. and Vibrio cholerae. Any human contact with either the contaminated flood waters or of flooded dwellings should only occur, if the individuals in questions are equipped with the full-body personal protective gear. Non-governmental stakeholders performed majority of the post-disaster recovery operations, as the local government could only cover 11% of the required costs. Applying sanitation funds to disaster recovery and increased use of the low-cost flood defence products in high risk areas could provide a solution for the future.
- Full Text: false
- Date Issued: 2016
- Authors: Tandlich, Roman , Ncube, Mbonisi , Khamanga, Sandile M , Zuma, Bongumusa M
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/75917 , vital:30482 , DOI: 10.20965/jdr.2016.p0732
- Description: Floods occurred in the Ndlambe Local Municipality in South Africa in October 2012. During various stages of the post-disaster recovery, bacterial concentrations were measured in water and soil samples from the flood zone. All drinking water concentrations of E. coli were below 1–3 colony forming units per 100 millilitres (CFUs/100 mL). The flood waters contained between 46500 to more than 100000 CFUs/100 mL of E. coli. {The concentrations of Salmonella spp. in the flood waters varied from 5000 to 250000 CFUs/100 mL. The presumptive Vibrio spp. concentrations in flood waters ranged from 1000 to over 150000 CFUs/100 mL. {The soil concentrations for E. coli ranged from 1 to above 330 colony-forming units per 1 g of soil dry weight (CFUs/g). The soil concentrations of Salmonella spp. varied from below 1 to 22 CFUs/g. The estimated airborne fungal concentrations ranged from 16820 to 28540 colony-forming units per 1 cubic meter. An outbreak of an infectious disease was recorded among the volunteers who assisted with the post-disaster recovery. The likely bacterial causative agents included strains of Aeromonas spp. and Vibrio cholerae. Any human contact with either the contaminated flood waters or of flooded dwellings should only occur, if the individuals in questions are equipped with the full-body personal protective gear. Non-governmental stakeholders performed majority of the post-disaster recovery operations, as the local government could only cover 11% of the required costs. Applying sanitation funds to disaster recovery and increased use of the low-cost flood defence products in high risk areas could provide a solution for the future.
- Full Text: false
- Date Issued: 2016
Binding and entry of a non-enveloped T=4 insect RNA virus is triggered by alkaline pH
- Penkler, David L, Jiwaji, Meesbah, Domitrovic, Tatiana, Short, James R, Johnson, John E, Dorrington, Rosemary A
- Authors: Penkler, David L , Jiwaji, Meesbah , Domitrovic, Tatiana , Short, James R , Johnson, John E , Dorrington, Rosemary A
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/65995 , vital:28875 , https://doi.org/10.1016/j.virol.2016.08.028
- Description: publisher version , Tetraviruses are small, non-enveloped, RNA viruses that exclusively infect lepidopteran insects. Their particles comprise 240 copies of a single capsid protein precursor (CP), which undergoes autoproteolytic cleavage during maturation. The molecular mechanisms of capsid assembly and maturation are well understood, but little is known about the viral infectious lifecycle due to a lack of tissue culture cell lines that are susceptible to tetravirus infection. We show here that binding and entry of the alphatetravirus, Helicoverpa armigera stunt virus (HaSV), is triggered by alkaline pH. At pH 9.0, wild-type HaSV virus particles undergo conformational changes that induce membrane-lytic activity and binding to Spodoptera frugiperda Sf9 cells. Binding is followed by entry and infection, with virus replication complexes detected by immunofluorescence microscopy within 2 h post-infection and the CP after 12 h. HaSV particles produced in S. frugiperda Sf9 cells are infectious. Helicoverpa armigera larval virus biofeed assays showed that pre-treatment with the V-ATPase inhibitor, Bafilomycin A1, resulted in a 50% decrease in larval mortality and stunting, while incubation of virus particles at pH 9.0 prior to infection restored infectivity. Together, these data show that HaSV, and likely other tetraviruses, requires the alkaline environment of the lepidopteran larval midgut for binding and entry into host cells.
- Full Text: false
- Date Issued: 2016
- Authors: Penkler, David L , Jiwaji, Meesbah , Domitrovic, Tatiana , Short, James R , Johnson, John E , Dorrington, Rosemary A
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/65995 , vital:28875 , https://doi.org/10.1016/j.virol.2016.08.028
- Description: publisher version , Tetraviruses are small, non-enveloped, RNA viruses that exclusively infect lepidopteran insects. Their particles comprise 240 copies of a single capsid protein precursor (CP), which undergoes autoproteolytic cleavage during maturation. The molecular mechanisms of capsid assembly and maturation are well understood, but little is known about the viral infectious lifecycle due to a lack of tissue culture cell lines that are susceptible to tetravirus infection. We show here that binding and entry of the alphatetravirus, Helicoverpa armigera stunt virus (HaSV), is triggered by alkaline pH. At pH 9.0, wild-type HaSV virus particles undergo conformational changes that induce membrane-lytic activity and binding to Spodoptera frugiperda Sf9 cells. Binding is followed by entry and infection, with virus replication complexes detected by immunofluorescence microscopy within 2 h post-infection and the CP after 12 h. HaSV particles produced in S. frugiperda Sf9 cells are infectious. Helicoverpa armigera larval virus biofeed assays showed that pre-treatment with the V-ATPase inhibitor, Bafilomycin A1, resulted in a 50% decrease in larval mortality and stunting, while incubation of virus particles at pH 9.0 prior to infection restored infectivity. Together, these data show that HaSV, and likely other tetraviruses, requires the alkaline environment of the lepidopteran larval midgut for binding and entry into host cells.
- Full Text: false
- Date Issued: 2016
Developmental and spatial variations in the diet signatures of hyperbenthic shrimp Nauticaris marionis at the Prince Edward Islands based on stable isotope ratios and fatty acid profiles
- Richoux, Nicole B, Allan, Elizabeth L, Froneman, P William
- Authors: Richoux, Nicole B , Allan, Elizabeth L , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67923 , vital:29169 , https://doi.org/10.1016/j.csr.2016.02.0131
- Description: Publisher version , The caridean shrimp Nauticaris marionis is an ecologically important species in the benthic community around the sub-Antarctic Prince Edward Islands (PEI) as it represents a key prey item for a variety of top predators breeding on the islands. We hypothesized that the diet of N. marionis shifts during its development, and that spatial variability in food availability results in differentiation in the diet signatures of specimens collected from various locations of the shelf waters around the PEI. Specimens were collected from nine stations (depth range 70 to 240 m) around the PEI at inter-island shelf (from west to east: upstream, between and downstream) and nearshore regions during austral autumn 2009. Stable isotope and fatty acid data both revealed spatial and developmental variations in the shrimp diet. Nearshore shrimp were more 13C-enriched than those from the inter-island region, suggesting increased kelp detritus entered the food web in the nearshore regions. The shrimp showed increases in δ13C and δ15N signatures (and trophic position) with an increase in body size, resulting in distinctions between size classes that reflected shifts in their trophic niche through development. The fatty acid profiles similarly indicated distinctions in diet with increased shrimp size (in the deep regions), and spatial variability was evident in relation to region and depth. All shrimp contained large proportions of polyunsaturated and essential fatty acids, indicating that the quality of food consumed was similar between regions despite the diet variability. Our results provide new dietary information about a key species operating near the base of the food web at the highly productive PEI, and show that there were no areas of enhanced nutrition available to the shrimp. As such, there was no nutritional advantage to shrimp inhabiting any specific region around the PEI.
- Full Text: false
- Date Issued: 2016
- Authors: Richoux, Nicole B , Allan, Elizabeth L , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67923 , vital:29169 , https://doi.org/10.1016/j.csr.2016.02.0131
- Description: Publisher version , The caridean shrimp Nauticaris marionis is an ecologically important species in the benthic community around the sub-Antarctic Prince Edward Islands (PEI) as it represents a key prey item for a variety of top predators breeding on the islands. We hypothesized that the diet of N. marionis shifts during its development, and that spatial variability in food availability results in differentiation in the diet signatures of specimens collected from various locations of the shelf waters around the PEI. Specimens were collected from nine stations (depth range 70 to 240 m) around the PEI at inter-island shelf (from west to east: upstream, between and downstream) and nearshore regions during austral autumn 2009. Stable isotope and fatty acid data both revealed spatial and developmental variations in the shrimp diet. Nearshore shrimp were more 13C-enriched than those from the inter-island region, suggesting increased kelp detritus entered the food web in the nearshore regions. The shrimp showed increases in δ13C and δ15N signatures (and trophic position) with an increase in body size, resulting in distinctions between size classes that reflected shifts in their trophic niche through development. The fatty acid profiles similarly indicated distinctions in diet with increased shrimp size (in the deep regions), and spatial variability was evident in relation to region and depth. All shrimp contained large proportions of polyunsaturated and essential fatty acids, indicating that the quality of food consumed was similar between regions despite the diet variability. Our results provide new dietary information about a key species operating near the base of the food web at the highly productive PEI, and show that there were no areas of enhanced nutrition available to the shrimp. As such, there was no nutritional advantage to shrimp inhabiting any specific region around the PEI.
- Full Text: false
- Date Issued: 2016
Indolyl-3-ethanone-α-thioethers: a promising new class of non-toxic antimalarial agents
- Svogie, Archibald L, Isaacs, Michelle, Hoppe, Heinrich C, Khanye, Setshaba D, Veale, Clinton G L
- Authors: Svogie, Archibald L , Isaacs, Michelle , Hoppe, Heinrich C , Khanye, Setshaba D , Veale, Clinton G L
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66233 , vital:28920 , https://doi.org/10.1016/j.ejmech.2016.02.056
- Description: publisher version , The success of chemotherapeutics in easing the burden of malaria is under continuous threat from ever-evolving parasite resistance, including resistance to artemisinin combination therapies. Therefore, the discovery of new classes of antimalarials which inhibit new biological targets is imperative to controlling malaria. Accordingly, we report here the discovery of indolyl-3-ethanone-α-thioethers, a new class of antimalarial compounds with encouraging activity. Synthesis of a focused library of compounds revealed important insight into the SAR of this class of compounds, including critical information regarding the position and chemical nature of substituents on both the thiophenol and indole rings. This investigation ultimately led to the discovery of two hit compounds (16 and 27) which exhibited nano molar in vitro antimalarial activity coupled to no observable toxicity against a HeLa cell line.
- Full Text: false
- Date Issued: 2016
- Authors: Svogie, Archibald L , Isaacs, Michelle , Hoppe, Heinrich C , Khanye, Setshaba D , Veale, Clinton G L
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66233 , vital:28920 , https://doi.org/10.1016/j.ejmech.2016.02.056
- Description: publisher version , The success of chemotherapeutics in easing the burden of malaria is under continuous threat from ever-evolving parasite resistance, including resistance to artemisinin combination therapies. Therefore, the discovery of new classes of antimalarials which inhibit new biological targets is imperative to controlling malaria. Accordingly, we report here the discovery of indolyl-3-ethanone-α-thioethers, a new class of antimalarial compounds with encouraging activity. Synthesis of a focused library of compounds revealed important insight into the SAR of this class of compounds, including critical information regarding the position and chemical nature of substituents on both the thiophenol and indole rings. This investigation ultimately led to the discovery of two hit compounds (16 and 27) which exhibited nano molar in vitro antimalarial activity coupled to no observable toxicity against a HeLa cell line.
- Full Text: false
- Date Issued: 2016
SASO and Black Consciousness, and the shift to congress politics
- Authors: Badat, Saleem
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/59755 , vital:27645 , http://witspress.co.za/catalogue/students-must-rise/
- Description: Students Must Rise 98 Chapter 8 SASO and Black Consciousness, and the shift to congress politics I n 1960, demonstrators protesting against pass laws were killed and injured by police at Sharpeville. Soon afterwards, the apartheid government declared a state of emergency. Over 11 000 political activists were detained, and repressive new laws, police raids, arrests, bannings, and torture were used to crush political opposition to apartheid. The African National Congress (ANC) and Pan Africanist Congress (PAC) were banned, and many leaders of the ANC and PAC were arrested and imprisoned , and hundreds fled into exile. For many white South Africans, the rest of the 1960s were a time of economic boom, political calm, prosperity, and rising living standards. Some blacks took the opportunity to accumulate wealth, power, and privilege through the Bantustans that the apartheid government established as part of its separate development programme. For most blacks, it was a period of great economic exploitation, extensive political and social control, fear, and demoralisation. It was difficult to see how there could be any political challenge to white minority rule. Anti-apartheid organisations faced immediate repression. They also had to overcome black people’s fear and demoralisation, which stood in the way of mobilising opposition against apartheid. The emergence of the South African Students’ Organisation and Black Consciousness Despite many problems, the South African Students’ Organisation (SASO) was formed as an exclusively black university and college student organisation in 1968. It escaped immediate state repression, and developed a following among students at the Saleem Badat SASO and Black Consciousness, and the shift to congress politics 99 universities reserved for blacks. Thereafter, the ideology of Black Consciousness (BC) was developed and other BC organisations were formed, resulting in the BC movement. SASO saw its challenge as the ‘assertion, manifestation and development of a sense of awareness politically, socially and economically among the black community’.1 It emphasised black ‘group cohesion and solidarity’ as ‘important facets of Black Consciousness’, the need for ‘the totality of involvement of the oppressed people’, and for BC ‘to be spread to reach all sections of the black community’.2 SASO began community development, literacy, education, media, culture, and sports projects, which aimed to help black communities to determine and realise their own needs. They were seen as a means to win the trust of people and to educate and mobilise them.3 Projects instilled the idea of self-reliance, seen as important for achieving freedom, in members and communities. SASO created a favourable political climate for various organisations to emerge.
- Full Text: false
- Date Issued: 2016
- Authors: Badat, Saleem
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/59755 , vital:27645 , http://witspress.co.za/catalogue/students-must-rise/
- Description: Students Must Rise 98 Chapter 8 SASO and Black Consciousness, and the shift to congress politics I n 1960, demonstrators protesting against pass laws were killed and injured by police at Sharpeville. Soon afterwards, the apartheid government declared a state of emergency. Over 11 000 political activists were detained, and repressive new laws, police raids, arrests, bannings, and torture were used to crush political opposition to apartheid. The African National Congress (ANC) and Pan Africanist Congress (PAC) were banned, and many leaders of the ANC and PAC were arrested and imprisoned , and hundreds fled into exile. For many white South Africans, the rest of the 1960s were a time of economic boom, political calm, prosperity, and rising living standards. Some blacks took the opportunity to accumulate wealth, power, and privilege through the Bantustans that the apartheid government established as part of its separate development programme. For most blacks, it was a period of great economic exploitation, extensive political and social control, fear, and demoralisation. It was difficult to see how there could be any political challenge to white minority rule. Anti-apartheid organisations faced immediate repression. They also had to overcome black people’s fear and demoralisation, which stood in the way of mobilising opposition against apartheid. The emergence of the South African Students’ Organisation and Black Consciousness Despite many problems, the South African Students’ Organisation (SASO) was formed as an exclusively black university and college student organisation in 1968. It escaped immediate state repression, and developed a following among students at the Saleem Badat SASO and Black Consciousness, and the shift to congress politics 99 universities reserved for blacks. Thereafter, the ideology of Black Consciousness (BC) was developed and other BC organisations were formed, resulting in the BC movement. SASO saw its challenge as the ‘assertion, manifestation and development of a sense of awareness politically, socially and economically among the black community’.1 It emphasised black ‘group cohesion and solidarity’ as ‘important facets of Black Consciousness’, the need for ‘the totality of involvement of the oppressed people’, and for BC ‘to be spread to reach all sections of the black community’.2 SASO began community development, literacy, education, media, culture, and sports projects, which aimed to help black communities to determine and realise their own needs. They were seen as a means to win the trust of people and to educate and mobilise them.3 Projects instilled the idea of self-reliance, seen as important for achieving freedom, in members and communities. SASO created a favourable political climate for various organisations to emerge.
- Full Text: false
- Date Issued: 2016
Seeing yourself in a new light: crossing the threshold to “researcher"
- Authors: Clarence, Sherran
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/61390 , vital:28021 , http://www.africansunmedia.co.za/Sun-e-Shop/tabid/78/ProductId/385/Default.aspx , http://dx.doi.org/10.17613/M6WW52
- Description: Writing, and the thinking, reading and analytical process that writers engage with to make writing possible, is transformative, and doctoral students in the social sciences especially tend to write themselves into their new identities as ‘doctors’ and recognised researchers. Much has been written in recent years about doctoral writing, including many advice books on how to write a ‘big-book’ or similar doctoral thesis into being. While some of the journal articles and books are helpful, and provide useful accounts of the complex challenges of writing a doctoral thesis, many of the advice books in particular focus more on the text itself, with the writer oddly under-accounted for. Recent research on, for example, doctoral writing groups and doctoral identity speaks into this gap helpfully, but much of it is written in contexts other than South Africa, and much of it is written for rather than by students going through or having recently completed a PhD process. This chapter contributes to a growing body of research and reflection on the role of writing itself in the process of becoming a ‘doctor’. Building on relevant blog posts and critical reflection through a research journal on my own transformative doctoral writing process at a South African university, this chapter will reflect on how challenging yet also potentially thrilling the writing process can be during a PhD. Readers will hopefully find in this chapter useful insights into their own process of becoming a doctor, and ideas for making their own ‘writing and becoming’ process more engaging and rewarding.
- Full Text: false
- Date Issued: 2016
- Authors: Clarence, Sherran
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/61390 , vital:28021 , http://www.africansunmedia.co.za/Sun-e-Shop/tabid/78/ProductId/385/Default.aspx , http://dx.doi.org/10.17613/M6WW52
- Description: Writing, and the thinking, reading and analytical process that writers engage with to make writing possible, is transformative, and doctoral students in the social sciences especially tend to write themselves into their new identities as ‘doctors’ and recognised researchers. Much has been written in recent years about doctoral writing, including many advice books on how to write a ‘big-book’ or similar doctoral thesis into being. While some of the journal articles and books are helpful, and provide useful accounts of the complex challenges of writing a doctoral thesis, many of the advice books in particular focus more on the text itself, with the writer oddly under-accounted for. Recent research on, for example, doctoral writing groups and doctoral identity speaks into this gap helpfully, but much of it is written in contexts other than South Africa, and much of it is written for rather than by students going through or having recently completed a PhD process. This chapter contributes to a growing body of research and reflection on the role of writing itself in the process of becoming a ‘doctor’. Building on relevant blog posts and critical reflection through a research journal on my own transformative doctoral writing process at a South African university, this chapter will reflect on how challenging yet also potentially thrilling the writing process can be during a PhD. Readers will hopefully find in this chapter useful insights into their own process of becoming a doctor, and ideas for making their own ‘writing and becoming’ process more engaging and rewarding.
- Full Text: false
- Date Issued: 2016
What lies beneath: exploring the deeper purposes of feedback on student writing through considering disciplinary knowledge and knowers
- Van Heerden, Martina, Clarence, Sherran, Bharuthram, Sharita
- Authors: Van Heerden, Martina , Clarence, Sherran , Bharuthram, Sharita
- Date: 2016
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59856 , vital:27669 , https://doi.org/10.1080/02602938.2016.1212985
- Description: Feedback plays an integral role in students’ learning and development, as it is often the only personal communication that students have with tutors or lecturers about their own work. Yet, in spite of its integral role in student learning, there is disagreement between how students and tutors or lecturers perceive the pedagogic purpose of feedback. Central to this disagreement is the role that feedback has to play in ensuring that students produce the ‘right’ kinds of knowledge, and become the ‘right’ kinds of knowers within their disciplines. This paper argues that, in order to find common ground between students and tutors or lecturers on what feedback is for, and how to both give and use it effectively, we need to conceptualise disciplinary knowledge and knowers anew. We offer, as a useful starting point, the Specialisation dimension of Legitimation Code Theory as both practical theory and methodological tool for exploring knowledge and knowers in English Studies and Law as two illustrative cases. The paper concludes that this analysis offers lecturers and tutors a fresh understanding of the disciplinary knowledge and knower structures they work within and, relatedly, a clearer view of the work their feedback needs to do within these.
- Full Text: false
- Date Issued: 2016
- Authors: Van Heerden, Martina , Clarence, Sherran , Bharuthram, Sharita
- Date: 2016
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59856 , vital:27669 , https://doi.org/10.1080/02602938.2016.1212985
- Description: Feedback plays an integral role in students’ learning and development, as it is often the only personal communication that students have with tutors or lecturers about their own work. Yet, in spite of its integral role in student learning, there is disagreement between how students and tutors or lecturers perceive the pedagogic purpose of feedback. Central to this disagreement is the role that feedback has to play in ensuring that students produce the ‘right’ kinds of knowledge, and become the ‘right’ kinds of knowers within their disciplines. This paper argues that, in order to find common ground between students and tutors or lecturers on what feedback is for, and how to both give and use it effectively, we need to conceptualise disciplinary knowledge and knowers anew. We offer, as a useful starting point, the Specialisation dimension of Legitimation Code Theory as both practical theory and methodological tool for exploring knowledge and knowers in English Studies and Law as two illustrative cases. The paper concludes that this analysis offers lecturers and tutors a fresh understanding of the disciplinary knowledge and knower structures they work within and, relatedly, a clearer view of the work their feedback needs to do within these.
- Full Text: false
- Date Issued: 2016
Fish predation regimes modify benthic diatom community structures: experimental evidence from an in situ mesocosm study
- Wasserman, Ryan J, Vink, Tim J F, Dalu, Tatenda, Froneman, P William
- Authors: Wasserman, Ryan J , Vink, Tim J F , Dalu, Tatenda , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68052 , vital:29190 , https://doi.org/10.1111/aec.12255
- Description: Publisher version , Diatoms are important primary producers in shallow water environments. Few studies have assessed the importance of biological interactions in structuring these communities. In the present study, benthic diatom community structure in relation to manipulated food webs was assessed using in situ mesocosms, whereby predator-free environments and environments comprising two different fish species were assessed. Zooplankton abundance, settled algal biomass and the diatom community were monitored over a 12‐day period across each of the three trophic scenarios. Differences among treatments over time were observed in zooplankton abundances, particularly copepods. Similarly, the benthic diatom community structure changed significantly over time across the three trophic treatments. However, no differences in total algal biomass were found among treatments. This was likely the result of non‐diatom phytoplankton contributions. We propose that the benthic diatom community structure within the mesocosms was influenced by trophic cascades and potentially through direct consumption by the fish. The study highlights that not only are organisms at the base of the food web affected by predators at the top of the food web, but that predator identity is potentially an important consideration for predator–prey interaction outcomes with consequences for multiple trophic levels.
- Full Text: false
- Date Issued: 2015
- Authors: Wasserman, Ryan J , Vink, Tim J F , Dalu, Tatenda , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68052 , vital:29190 , https://doi.org/10.1111/aec.12255
- Description: Publisher version , Diatoms are important primary producers in shallow water environments. Few studies have assessed the importance of biological interactions in structuring these communities. In the present study, benthic diatom community structure in relation to manipulated food webs was assessed using in situ mesocosms, whereby predator-free environments and environments comprising two different fish species were assessed. Zooplankton abundance, settled algal biomass and the diatom community were monitored over a 12‐day period across each of the three trophic scenarios. Differences among treatments over time were observed in zooplankton abundances, particularly copepods. Similarly, the benthic diatom community structure changed significantly over time across the three trophic treatments. However, no differences in total algal biomass were found among treatments. This was likely the result of non‐diatom phytoplankton contributions. We propose that the benthic diatom community structure within the mesocosms was influenced by trophic cascades and potentially through direct consumption by the fish. The study highlights that not only are organisms at the base of the food web affected by predators at the top of the food web, but that predator identity is potentially an important consideration for predator–prey interaction outcomes with consequences for multiple trophic levels.
- Full Text: false
- Date Issued: 2015
Can δ15N and δ13C stable isotopes and fatty acid signatures indicate changes in phytobenthos composition on an artificial substrate?
- Dalu, Tatenda, Froneman, P William
- Authors: Dalu, Tatenda , Froneman, P William
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68086 , vital:29197 , https://doi.org/10.2989/16085914.2014.974018
- Description: Publisher version , Temporal changes in fatty acid composition and δ15N, δ13C stable isotope values of the phytobenthos growing on artificial clay substrates under natural conditions over a 28-day period at an upstream and a downstream site in the Kowie River near Grahamstown were investigated in 2012. High concentrations of diatom markers 16:1ω7 and 20:5ω3 fatty acids were recorded, especially at the downstream site, reflecting the importance of diatoms in contributing to the phytobenthos communities at that station. After day 7 at the downstream site the average δ15N value of the phytobenthos was lighter, gradually increasing by ∼2‰ and ∼5‰ overall to heavier values on day 28. At the upstream site there were no significant changes (<1‰ increase) in δ15N values of the phytobenthos over time. Stable nitrogen (δ15N) and carbon (δ13C) signatures in the phytobenthos communities were significantly different between sites (one-way ANOVA; p < 0.001). The stable isotope values and fatty acid concentrations of phytobenthos at the downstream site were different to those of the phytobenthos at the upstream site, and they changed concurrently with changes in the phytobenthos community structure. At the downstream site there was a strong correlation of the δ15N of phytobenthos with nitrates (R = 0.56) and time (weeks; R = 0.81). However, the fatty acids were not specific enough to characterise the composition of phytobenthos communities. Other biomarker methods, such as stable isotopes and microscopic examination of the communities, were found to be useful. The results from this relatively small-scale tile experiment indicate the complexity of changes in fatty acid composition and δ15N, δ13C stable isotope values of a phytobenthos community. Stable isotope and fatty acid composition can be successfully used to map changes in phytobenthos composition and carbon and nitrogen flow patterns along a river continuum.
- Full Text: false
- Date Issued: 2014
- Authors: Dalu, Tatenda , Froneman, P William
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68086 , vital:29197 , https://doi.org/10.2989/16085914.2014.974018
- Description: Publisher version , Temporal changes in fatty acid composition and δ15N, δ13C stable isotope values of the phytobenthos growing on artificial clay substrates under natural conditions over a 28-day period at an upstream and a downstream site in the Kowie River near Grahamstown were investigated in 2012. High concentrations of diatom markers 16:1ω7 and 20:5ω3 fatty acids were recorded, especially at the downstream site, reflecting the importance of diatoms in contributing to the phytobenthos communities at that station. After day 7 at the downstream site the average δ15N value of the phytobenthos was lighter, gradually increasing by ∼2‰ and ∼5‰ overall to heavier values on day 28. At the upstream site there were no significant changes (<1‰ increase) in δ15N values of the phytobenthos over time. Stable nitrogen (δ15N) and carbon (δ13C) signatures in the phytobenthos communities were significantly different between sites (one-way ANOVA; p < 0.001). The stable isotope values and fatty acid concentrations of phytobenthos at the downstream site were different to those of the phytobenthos at the upstream site, and they changed concurrently with changes in the phytobenthos community structure. At the downstream site there was a strong correlation of the δ15N of phytobenthos with nitrates (R = 0.56) and time (weeks; R = 0.81). However, the fatty acids were not specific enough to characterise the composition of phytobenthos communities. Other biomarker methods, such as stable isotopes and microscopic examination of the communities, were found to be useful. The results from this relatively small-scale tile experiment indicate the complexity of changes in fatty acid composition and δ15N, δ13C stable isotope values of a phytobenthos community. Stable isotope and fatty acid composition can be successfully used to map changes in phytobenthos composition and carbon and nitrogen flow patterns along a river continuum.
- Full Text: false
- Date Issued: 2014
A ring-closing metathesis approach to eight-membered benzannelated scaffolds and subsequent internal alkene isomerizations
- Taher, Abu, Aderibigbe, Blessing A, Morgans, Garreth L, Madeley, Lee G, Khanye, Setshaba D, Van der Westhuizen, Leandi, Fernandes, Manuel A, Smith, Vincent J, Michael, Joseph P, Green, Ivan R, Van Otterlo, Willem A L
- Authors: Taher, Abu , Aderibigbe, Blessing A , Morgans, Garreth L , Madeley, Lee G , Khanye, Setshaba D , Van der Westhuizen, Leandi , Fernandes, Manuel A , Smith, Vincent J , Michael, Joseph P , Green, Ivan R , Van Otterlo, Willem A L
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66252 , vital:28925 , https://doi.org/10.1016/j.tet.2012.12.043
- Description: publisher version , A set of eight-membered benzannelated heterocycles containing two heteroatoms (O,O, NR,NR and O,NR where R=protecting group) was synthesized by ring-closing metathesis from the corresponding ortho-bis-allyl precursors. In this manner, 7-methoxy-2,5-dihydro-1,6-benzodioxocine, 1,2,5,6-tetrahydro-1,6-benzodiazocines, 5,6-dihydro-2H-1,6-benzoxazocines and 5,6,9,10-tetrahydropyrido[2,3-b][1,4]diazocine were synthesized. A number of these compounds were then treated with the catalyst [RuClH(CO)(PPh3)3] to facilitate isomerization of the alkene into conjugation with the heteroatoms in the eight-membered ring. Quite surprisingly, an equal ratio of regioisomers was obtained, even if the heteroatoms were different.
- Full Text: false
- Date Issued: 2013
- Authors: Taher, Abu , Aderibigbe, Blessing A , Morgans, Garreth L , Madeley, Lee G , Khanye, Setshaba D , Van der Westhuizen, Leandi , Fernandes, Manuel A , Smith, Vincent J , Michael, Joseph P , Green, Ivan R , Van Otterlo, Willem A L
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66252 , vital:28925 , https://doi.org/10.1016/j.tet.2012.12.043
- Description: publisher version , A set of eight-membered benzannelated heterocycles containing two heteroatoms (O,O, NR,NR and O,NR where R=protecting group) was synthesized by ring-closing metathesis from the corresponding ortho-bis-allyl precursors. In this manner, 7-methoxy-2,5-dihydro-1,6-benzodioxocine, 1,2,5,6-tetrahydro-1,6-benzodiazocines, 5,6-dihydro-2H-1,6-benzoxazocines and 5,6,9,10-tetrahydropyrido[2,3-b][1,4]diazocine were synthesized. A number of these compounds were then treated with the catalyst [RuClH(CO)(PPh3)3] to facilitate isomerization of the alkene into conjugation with the heteroatoms in the eight-membered ring. Quite surprisingly, an equal ratio of regioisomers was obtained, even if the heteroatoms were different.
- Full Text: false
- Date Issued: 2013
The amaXhosa ukuthwala marriage custom in fact and fiction: a contemporary critique
- Kaschula, Russell H, Huisamen, Tim, Mostert, André M, Nosilela, Bulelwa
- Authors: Kaschula, Russell H , Huisamen, Tim , Mostert, André M , Nosilela, Bulelwa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68344 , vital:29241 , https://doi.org/10.1080/02572117.2013.871454
- Description: publisher version , Ukuthwala is traditionally a marriage custom within the amaXhosa culture in South Africa which permits a ‘legal abduction’ of a bride-to-be. Similar customs of ‘bridal abduction’ exist, most notably in Kyrgyzstan, where it is known as ala kachuu. Research into these customs necessitates a more innovative approach to explore the impact of this social phenomenon. In this article the authors mobilise a fictional narrative to offer a backdrop for a comparative assessment of the impact of bridal ‘legal abduction’ and assess its contemporary status and role within a multicultural society which celebrates the rights of the individual while recognising the value and importance of maintaining cultural identity and traditions. Cultural dissonance has always been characteristic of modern and post-modern societies as they strive for a workable shared ethos. However, when customs such as ‘legal abduction’ (Mtuze, 1993:50) continue under the veil of cultural rights, the wider social sensibilities and perspectives can be at odds with the maintenance of such activities where these activities contradict the rights of the individual as enshrined for example in what can be seen as a liberal South African Constitution.
- Full Text: false
- Date Issued: 2013
- Authors: Kaschula, Russell H , Huisamen, Tim , Mostert, André M , Nosilela, Bulelwa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68344 , vital:29241 , https://doi.org/10.1080/02572117.2013.871454
- Description: publisher version , Ukuthwala is traditionally a marriage custom within the amaXhosa culture in South Africa which permits a ‘legal abduction’ of a bride-to-be. Similar customs of ‘bridal abduction’ exist, most notably in Kyrgyzstan, where it is known as ala kachuu. Research into these customs necessitates a more innovative approach to explore the impact of this social phenomenon. In this article the authors mobilise a fictional narrative to offer a backdrop for a comparative assessment of the impact of bridal ‘legal abduction’ and assess its contemporary status and role within a multicultural society which celebrates the rights of the individual while recognising the value and importance of maintaining cultural identity and traditions. Cultural dissonance has always been characteristic of modern and post-modern societies as they strive for a workable shared ethos. However, when customs such as ‘legal abduction’ (Mtuze, 1993:50) continue under the veil of cultural rights, the wider social sensibilities and perspectives can be at odds with the maintenance of such activities where these activities contradict the rights of the individual as enshrined for example in what can be seen as a liberal South African Constitution.
- Full Text: false
- Date Issued: 2013
Of fences and peace between neighbours
- Authors: Krüger, Rósaan
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68909 , vital:29338 , https://hdl.handle.net/10520/EJC85309
- Description: Publisher version , The speaker in the poem "Mending Wall" by American poet Robert Frost questions the wisdom of the saying that "Good Fences Make Good Neighbo[u]rs" (1914 North of Boston lines 27 and 45). The walls or fences referred to in the poem represent more than just physical barriers separating adjacent premises; the speaker sees them as representing obstacles to communication and friendship between individuals. Seen from the perspective of the speaker, a fence or wall is a "bad" thing. But the speaker is but one of the parties to the neighbourly relationship. For the speaker's neighbour, a wall or a fence is "a protector of privacy" (Watson "Frost's Wall : The View from the Other Side" 1971 44 The New England Quarterly 653 655). Thus there are two views on walls or fences: they can be seen negatively as obstructing good relations, or positively as dividers that secure good relations between neighbours by separating them and protecting their privacy rights.
- Full Text: false
- Date Issued: 2009
- Authors: Krüger, Rósaan
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68909 , vital:29338 , https://hdl.handle.net/10520/EJC85309
- Description: Publisher version , The speaker in the poem "Mending Wall" by American poet Robert Frost questions the wisdom of the saying that "Good Fences Make Good Neighbo[u]rs" (1914 North of Boston lines 27 and 45). The walls or fences referred to in the poem represent more than just physical barriers separating adjacent premises; the speaker sees them as representing obstacles to communication and friendship between individuals. Seen from the perspective of the speaker, a fence or wall is a "bad" thing. But the speaker is but one of the parties to the neighbourly relationship. For the speaker's neighbour, a wall or a fence is "a protector of privacy" (Watson "Frost's Wall : The View from the Other Side" 1971 44 The New England Quarterly 653 655). Thus there are two views on walls or fences: they can be seen negatively as obstructing good relations, or positively as dividers that secure good relations between neighbours by separating them and protecting their privacy rights.
- Full Text: false
- Date Issued: 2009
Aenigmatite stability in silica-undersaturated rocks
- Authors: Marsh, Julian S
- Date: 1975
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/132942 , vital:36911 , https://doi.org/10.1007/BF00373333
- Description: Aenigmatite is common in many trachytes, phonolites and agpaitic nepheline syenites. Petrographic evidence suggests that the aenigmatite in these rocks arises by the reaction of Ti-magnetite with a peralkaline silica-undersaturated liquid, and it is postulated that a no-oxide field, where aenigmatite is stable, exists in alkaline undersaturated magmas.
- Full Text: false
- Date Issued: 1975
- Authors: Marsh, Julian S
- Date: 1975
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/132942 , vital:36911 , https://doi.org/10.1007/BF00373333
- Description: Aenigmatite is common in many trachytes, phonolites and agpaitic nepheline syenites. Petrographic evidence suggests that the aenigmatite in these rocks arises by the reaction of Ti-magnetite with a peralkaline silica-undersaturated liquid, and it is postulated that a no-oxide field, where aenigmatite is stable, exists in alkaline undersaturated magmas.
- Full Text: false
- Date Issued: 1975
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