Fabrication of a photocatalytic PAN supported C-TiO2-CFA nanocomposite for use in water treatment
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
- Full Text:
- Date Issued: 2020
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
- Full Text:
- Date Issued: 2020
Farmers' perceptions of insect pests in the Eastern Cape maize-based cropping systems and the effects of crop residue management on insect pest populations
- Authors: Kadango, Tendayi Lovemore
- Date: 2018
- Subjects: Cropping systems Crop residue management Corn -- Diseases and pests
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6202 , vital:29507
- Description: Maize (Zea mays L.) is one of the most important crops in South Africa that is cultivated for food, feed and as a cash crop. Maize in the Eastern Cape is typically grown for consumption and the Province is one of the least producers owing to small landholdings, poor production conditions and pests. This study investigated: (i) the different maize cropping systems smallholder farmers practice in the Eastern Cape (EC), (ii) the major maize insect pests within the identified cropping systems, (iii) the perceptions of Eastern Cape smallholder maize farmers on the effects of insect pests, and (iv) the effects of crop residues on insect pests’ population dynamics. Four major cropping systems namely: maize sole cropping without rotations by government sponsored farmers (GCP) (94 percent), maize intercropping without rotations by independent farmers (IF) (79 percent), maize sole cropping without rotations by IF (67 percent) and maize intercropping without rotations by GCP (61 percent) were identified. The choice of a cropping system by the smallholder farmers was significantly influenced by source of sponsorship, the difference in their district localities, tenure system, availability of inputs and farming equipment, percentage of farmland farmers allocate to maize, maize varieties, farming experience, fallow operations and access to irrigation facilities. The major constraints faced by the farmers in maize production are the attack by insect pests, weeds competition, drought, the lack of fencing around the fields and destruction by mammals. The major insect pests identified were stalk borers (Busseola fusca, Chilo partellus), cutworms (Agrotis spp.), aphids (Rhopalosiphum maidis), bollworms (Helicoverpa armigera) and weevils (Sitophylus spp.). The most popular control measures employed were the use of GM maize and pesticides. Results from the field trial showed that field crickets were the major ground dwelling insect pests observed followed by bollworms and cutworms. However, there were no significant influence of residue retention on the insects’ diversity indices, richness, and evenness. Above ground insects sampling revealed the domination by four major insects namely, cutworms, maize stalk borer, bollworms, and spotted stalk borer. Residue management significantly influenced the infestation by spotted stalk borer only on maize plots. However, the general trend was that there was less infestation by the insects in plots where residues were retained than the ones with residue removed. Results from the study indicate that government sponsorship is significantly influencing the maize cropping systems of the smallholder farmers of the Eastern Cape.
- Full Text:
- Date Issued: 2018
- Authors: Kadango, Tendayi Lovemore
- Date: 2018
- Subjects: Cropping systems Crop residue management Corn -- Diseases and pests
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6202 , vital:29507
- Description: Maize (Zea mays L.) is one of the most important crops in South Africa that is cultivated for food, feed and as a cash crop. Maize in the Eastern Cape is typically grown for consumption and the Province is one of the least producers owing to small landholdings, poor production conditions and pests. This study investigated: (i) the different maize cropping systems smallholder farmers practice in the Eastern Cape (EC), (ii) the major maize insect pests within the identified cropping systems, (iii) the perceptions of Eastern Cape smallholder maize farmers on the effects of insect pests, and (iv) the effects of crop residues on insect pests’ population dynamics. Four major cropping systems namely: maize sole cropping without rotations by government sponsored farmers (GCP) (94 percent), maize intercropping without rotations by independent farmers (IF) (79 percent), maize sole cropping without rotations by IF (67 percent) and maize intercropping without rotations by GCP (61 percent) were identified. The choice of a cropping system by the smallholder farmers was significantly influenced by source of sponsorship, the difference in their district localities, tenure system, availability of inputs and farming equipment, percentage of farmland farmers allocate to maize, maize varieties, farming experience, fallow operations and access to irrigation facilities. The major constraints faced by the farmers in maize production are the attack by insect pests, weeds competition, drought, the lack of fencing around the fields and destruction by mammals. The major insect pests identified were stalk borers (Busseola fusca, Chilo partellus), cutworms (Agrotis spp.), aphids (Rhopalosiphum maidis), bollworms (Helicoverpa armigera) and weevils (Sitophylus spp.). The most popular control measures employed were the use of GM maize and pesticides. Results from the field trial showed that field crickets were the major ground dwelling insect pests observed followed by bollworms and cutworms. However, there were no significant influence of residue retention on the insects’ diversity indices, richness, and evenness. Above ground insects sampling revealed the domination by four major insects namely, cutworms, maize stalk borer, bollworms, and spotted stalk borer. Residue management significantly influenced the infestation by spotted stalk borer only on maize plots. However, the general trend was that there was less infestation by the insects in plots where residues were retained than the ones with residue removed. Results from the study indicate that government sponsorship is significantly influencing the maize cropping systems of the smallholder farmers of the Eastern Cape.
- Full Text:
- Date Issued: 2018
A sociological analysis of the lives and livelihoods of child support grant caregivers in Queenstown, South Africa
- Authors: Ntantiso, Ziyanda
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/7925 , vital:21325
- Description: The post-apartheid state in South Africa has initiated and implemented a large-scale social assistance programme in the form of social grants, including the child support grant. The grant system is meant to provide recipients, who comprise mainly people from poor black households, with the capacity to reduce levels of poverty in their households. The grant with the largest number of recipients is the child support grant, and it is given to the caregiver of a child eligible to receive the grant. Though the value of the monthly grant is minimal, the prevailing literature suggests that it does contribute in some way to enhancing the welfare of the recipients. This thesis focuses on child support grant recipients in the town of Queenstown in the Eastern Cape, and particularly those recipients for whom the grant is the crucial source of income. The main objective of the thesis is to understand and analyse the lives and livelihoods of child support grant recipients (all women) in Queenstown, South Africa. In this regard, the vast majority of caregivers of grant children are women and they often rely exclusively on the grant in taking care of themselves and the children. The thesis does not seek to determine any direct causal relationship between the child grant and poverty reduction, as much of the existing literature seeks to do. It focuses instead on the lives of the grant recipients, including the many challenges they face, as well as how they use the grant to pursue livelihoods in a manner which may at least inhibit the prospects of entering into deeper levels of poverty. The thesis demonstrates that, despite their deprived conditions of material existence, the female caregivers in Queenstown display significant agency in caring for their grant children.
- Full Text:
- Date Issued: 2017
- Authors: Ntantiso, Ziyanda
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/7925 , vital:21325
- Description: The post-apartheid state in South Africa has initiated and implemented a large-scale social assistance programme in the form of social grants, including the child support grant. The grant system is meant to provide recipients, who comprise mainly people from poor black households, with the capacity to reduce levels of poverty in their households. The grant with the largest number of recipients is the child support grant, and it is given to the caregiver of a child eligible to receive the grant. Though the value of the monthly grant is minimal, the prevailing literature suggests that it does contribute in some way to enhancing the welfare of the recipients. This thesis focuses on child support grant recipients in the town of Queenstown in the Eastern Cape, and particularly those recipients for whom the grant is the crucial source of income. The main objective of the thesis is to understand and analyse the lives and livelihoods of child support grant recipients (all women) in Queenstown, South Africa. In this regard, the vast majority of caregivers of grant children are women and they often rely exclusively on the grant in taking care of themselves and the children. The thesis does not seek to determine any direct causal relationship between the child grant and poverty reduction, as much of the existing literature seeks to do. It focuses instead on the lives of the grant recipients, including the many challenges they face, as well as how they use the grant to pursue livelihoods in a manner which may at least inhibit the prospects of entering into deeper levels of poverty. The thesis demonstrates that, despite their deprived conditions of material existence, the female caregivers in Queenstown display significant agency in caring for their grant children.
- Full Text:
- Date Issued: 2017
Adaptation of the mathematics recovery programme to facilitate progression in the early arithmetic strategies of Grade 2 learners in Zambia
- Authors: Young, Catherine
- Date: 2017
- Subjects: Mathematics -- Study and teaching (Elementary) -- Zambia Arithmetic -- Study and teaching (Elementary) -- Zambia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/4977 , vital:20749
- Description: Research indicates that many children finish primary school in Southern Africa still reliant on inefficient counting strategies. This study extends the research of the South African Numeracy Chair project to early mathematics intervention with Grade 2 learners. It investigated the possible adaptation of the Mathematics Recovery programme to facilitate learner progression in early arithmetic strategies. This study aimed to investigate the possibility of adapting the Mathematics Recovery programme for use in a whole class setting, and to research the effectiveness of such an adapted programme. This study also aimed to investigate the extent of the phenomenon of unit counting and other early arithmetic strategies used in the early years in Zambia. This study was conducted from an emergent perspective. A review of the literature indicated that children who become stuck using unit counting face later mathematical difficulties, and that teacher over-emphasis on unit counting in the early years of schooling may be a contributing factor. This study used a qualitative design research methodology that consisted of a preparation phase, teaching experiment and retrospective analysis. The context of this teaching experiment was a seven week after-school intervention with a class of Grade 2 learners aged seven to eight in a rural Zambian primary school. Data collection and analysis focused on video recordings of a sample of 6 learners. The experimental teaching content focused on the Early Arithmetic Strategies aspect of the Mathematics Recovery programme. Although limited by time and research focus, this study found that all learners made some progress in early arithmetic strategies, and indicates that the Mathematics Recovery programme has potential for adaptation for early intervention in whole class teaching to address the mathematical education challenges in Zambia and beyond. This study also found that unit counting predominated in the sample learners, but that strategies were not yet entrenched, indicating this was a suitable age for early intervention. This study makes methodological contributions to a growing body of research into the adaptation of the Mathematics Recovery in Southern African contexts and suggests avenues for possible further research.
- Full Text:
- Date Issued: 2017
- Authors: Young, Catherine
- Date: 2017
- Subjects: Mathematics -- Study and teaching (Elementary) -- Zambia Arithmetic -- Study and teaching (Elementary) -- Zambia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/4977 , vital:20749
- Description: Research indicates that many children finish primary school in Southern Africa still reliant on inefficient counting strategies. This study extends the research of the South African Numeracy Chair project to early mathematics intervention with Grade 2 learners. It investigated the possible adaptation of the Mathematics Recovery programme to facilitate learner progression in early arithmetic strategies. This study aimed to investigate the possibility of adapting the Mathematics Recovery programme for use in a whole class setting, and to research the effectiveness of such an adapted programme. This study also aimed to investigate the extent of the phenomenon of unit counting and other early arithmetic strategies used in the early years in Zambia. This study was conducted from an emergent perspective. A review of the literature indicated that children who become stuck using unit counting face later mathematical difficulties, and that teacher over-emphasis on unit counting in the early years of schooling may be a contributing factor. This study used a qualitative design research methodology that consisted of a preparation phase, teaching experiment and retrospective analysis. The context of this teaching experiment was a seven week after-school intervention with a class of Grade 2 learners aged seven to eight in a rural Zambian primary school. Data collection and analysis focused on video recordings of a sample of 6 learners. The experimental teaching content focused on the Early Arithmetic Strategies aspect of the Mathematics Recovery programme. Although limited by time and research focus, this study found that all learners made some progress in early arithmetic strategies, and indicates that the Mathematics Recovery programme has potential for adaptation for early intervention in whole class teaching to address the mathematical education challenges in Zambia and beyond. This study also found that unit counting predominated in the sample learners, but that strategies were not yet entrenched, indicating this was a suitable age for early intervention. This study makes methodological contributions to a growing body of research into the adaptation of the Mathematics Recovery in Southern African contexts and suggests avenues for possible further research.
- Full Text:
- Date Issued: 2017
Exploring the contributions of youth development programme as a poverty eradication strategy: The case study of the National Youth Development Agency in Ezibeleni Township; Queenstown
- Authors: Vazi, Thembelani
- Date: 2017
- Subjects: Youth development -- South Africa -- Eastern Cape Youth -- Political activity -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Social Work
- Identifier: http://hdl.handle.net/10353/6502 , vital:30137
- Description: Youth development programmes in South Africa stirs a lot of debates on whether youth development programmes reach all the young people of South Africa even the rural youth. The youth involved in these programmes argue that even though these youth development programmes were created for all the young people of South Africa, some of them do not get the opportunity to be part of such programmes and they are not getting the proper skills that they need in order to create employment opportunities for themselves. Therefore, this study is aimed at exploring the contributions of the youth development programme as a poverty eradication strategy. The data in the study was collected qualitatively through interviews in which the youth, Social Workers, the ward Councillors and NYDA officials were interviewed. The total sample size in the study was 26 participants. The study established that the lack of youth skills is one of the causes of youth unemployment and poverty. Generally, the quality of these youth development programmes are not up to standard for assisting young people, most importantly these youth programmes lack resources. The study revealed that, even though the youth programmes are available, they do not cater for all the young people of Ezibeleni Township and they do not alleviate poverty for all the youth of Ezibeleni Township. Furthermore, those that are part of these youth programmes further complain about the lack of skills within the staff employed in these youth development programmes.
- Full Text:
- Date Issued: 2017
- Authors: Vazi, Thembelani
- Date: 2017
- Subjects: Youth development -- South Africa -- Eastern Cape Youth -- Political activity -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Social Work
- Identifier: http://hdl.handle.net/10353/6502 , vital:30137
- Description: Youth development programmes in South Africa stirs a lot of debates on whether youth development programmes reach all the young people of South Africa even the rural youth. The youth involved in these programmes argue that even though these youth development programmes were created for all the young people of South Africa, some of them do not get the opportunity to be part of such programmes and they are not getting the proper skills that they need in order to create employment opportunities for themselves. Therefore, this study is aimed at exploring the contributions of the youth development programme as a poverty eradication strategy. The data in the study was collected qualitatively through interviews in which the youth, Social Workers, the ward Councillors and NYDA officials were interviewed. The total sample size in the study was 26 participants. The study established that the lack of youth skills is one of the causes of youth unemployment and poverty. Generally, the quality of these youth development programmes are not up to standard for assisting young people, most importantly these youth programmes lack resources. The study revealed that, even though the youth programmes are available, they do not cater for all the young people of Ezibeleni Township and they do not alleviate poverty for all the youth of Ezibeleni Township. Furthermore, those that are part of these youth programmes further complain about the lack of skills within the staff employed in these youth development programmes.
- Full Text:
- Date Issued: 2017
Needs assessment in the development of a problem-based learning for paediatric nurse specialist programme at the University of Fort Hare Eastern Cape
- Authors: Melitafa, Nomntu
- Date: 2017
- Subjects: Nursing assessment Problem-based learning Nursing -- Study and teaching
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10353/8921 , vital:33966
- Description: The study seeks to assess the need for developing a post graduate child nursing science programme with a problem based learning approach at the University of Fort Hare East London Campus. The aim is to the aim of the study was to conduct a needs assessment in preparation for development of a PBL curriculum so as to produce reflective PNSs. Literature exposed the high mortality rates of children and the competency gaps of trained PNSs. A descriptive quantitative design was used to guide the study. The data were collected by means of self-administered survey questionnaires which constituted closed and open ended questions to yield both quantitative and qualitative data. Data were obtained based on demographic information, performance and importance of the PNS activities, competences of PNSs as well as the prevalence of child health problems at the rural, semi-urban and urban hospitals in the ECP. The purposive sampling technique was used to select participants. The sample size was 70 and 38 participants responded. Quantitative and qualitative data were obtained. Quantitative data were analyzed through use of the Statistical Programme for Social Science software (SPSS) Version 9.0.1 and qualitative data were analyzed manually. Quantitative results were presented with pie graphs, tables and frequencies. Four themes emerged, revealing factors prohibiting the service delivery of PNSs, special training needs of PNSs, prevalent health problems in children and personal interventions. The results showed that in essence there is a need to develop the envisaged Problem Based Learning (PBL) curriculum.
- Full Text:
- Date Issued: 2017
- Authors: Melitafa, Nomntu
- Date: 2017
- Subjects: Nursing assessment Problem-based learning Nursing -- Study and teaching
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10353/8921 , vital:33966
- Description: The study seeks to assess the need for developing a post graduate child nursing science programme with a problem based learning approach at the University of Fort Hare East London Campus. The aim is to the aim of the study was to conduct a needs assessment in preparation for development of a PBL curriculum so as to produce reflective PNSs. Literature exposed the high mortality rates of children and the competency gaps of trained PNSs. A descriptive quantitative design was used to guide the study. The data were collected by means of self-administered survey questionnaires which constituted closed and open ended questions to yield both quantitative and qualitative data. Data were obtained based on demographic information, performance and importance of the PNS activities, competences of PNSs as well as the prevalence of child health problems at the rural, semi-urban and urban hospitals in the ECP. The purposive sampling technique was used to select participants. The sample size was 70 and 38 participants responded. Quantitative and qualitative data were obtained. Quantitative data were analyzed through use of the Statistical Programme for Social Science software (SPSS) Version 9.0.1 and qualitative data were analyzed manually. Quantitative results were presented with pie graphs, tables and frequencies. Four themes emerged, revealing factors prohibiting the service delivery of PNSs, special training needs of PNSs, prevalent health problems in children and personal interventions. The results showed that in essence there is a need to develop the envisaged Problem Based Learning (PBL) curriculum.
- Full Text:
- Date Issued: 2017
Nonlinear optical properties of Sn(IV) phthalocyanines: experimental and theoretical approach
- Authors: Louzada, Marcel Severiano
- Date: 2017
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57852 , vital:26996
- Description: This work presents the nonlinear properties of six Sn(IV) Phthalocyanines. Three of the phthalocyanines are linked by an alkylthiol substituent and the rest are linked with a phenoxy substituent. For all six compounds non-linear optic analysis was carried out in four solvents: chloroform, toluene, dichloromethane, and tetrahydrofuran, and their differences were recorded. Calculation of the linear, singlet excited, triplet excited and two photon absorption cross-sections were also carried out and the results compared. To form a comparison the first order hyperpolarizabilities, DFT calculations were also performed and the results compared to see if the behaviour between the two properties can be predicted using DFT.
- Full Text:
- Date Issued: 2017
- Authors: Louzada, Marcel Severiano
- Date: 2017
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57852 , vital:26996
- Description: This work presents the nonlinear properties of six Sn(IV) Phthalocyanines. Three of the phthalocyanines are linked by an alkylthiol substituent and the rest are linked with a phenoxy substituent. For all six compounds non-linear optic analysis was carried out in four solvents: chloroform, toluene, dichloromethane, and tetrahydrofuran, and their differences were recorded. Calculation of the linear, singlet excited, triplet excited and two photon absorption cross-sections were also carried out and the results compared. To form a comparison the first order hyperpolarizabilities, DFT calculations were also performed and the results compared to see if the behaviour between the two properties can be predicted using DFT.
- Full Text:
- Date Issued: 2017
Template-assisted sol-gel synthesis of carbon doped titanium dioxide nanotubes and their characterization
- Authors: Takata, Nwabisa
- Date: 2017
- Subjects: Nanotechnology Titanium dioxide Nanostructures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13194 , vital:39473
- Description: This study reveals the effects of doping on the morphological, structural and optical properties of titanium dioxide (TiO2) nanotubes (TNTs), synthesized by sol-gel template-assisted sol-gel technique. The nanotubes (TNTs) were prepared in anodic alumina membranes (AAM) with a pore diameter range of 110-210 nm by using titanium tetra butoxide as a sol-gel precursor and oxalic acid dihydrate as a dopant source. The synthesized nanotubes were evaluated using scanning electron microscope (SEM), energy dispersive spectroscopy (EDX), fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), confocal Raman spectroscopy (CRS) and photoluminescence spectroscopy (PL). SEM analysis has revealed the presence of closely-packed TNTs, with a modal external tube diameters of 150, 170, 210,190 and 210 nm for the un-doped TNTs, 9 mM carbon doped-TNTs (C-TNTs), 27 mM C-TNTs, 45 mM C-TNTs and 75 mM C-TNTs respectively. The diameters are consistent with the AAM diameter range. EDX spectra revealed the presence of Ti peaks at 0.45 and 4.9 keV corresponding to Kα1 and Kβ1 emission lines respectively. Oxygen exhibits a signal at 0.5 keV corresponding to Kα1 emission line. The occurrence of these peaks in the EDX spectra endorses the existence of Ti and O atoms in the prepared titanium dioxide nanotubes. FTIR spectroscopy has revealed the presence of vibration modes at 580-660 cm-1 indicating the presence of Ti-O bonds and additional vibration modes at 2324 cm-1 resulting from C-O stretching in the C-TNTs. The XRD analysis has revealed the presence of a mixed anatase-brookite phase with diffraction peaks at 2θ angles of 25.49⁰, 38.11⁰, 40.60º, 48.14⁰, 54.58⁰, 63.00⁰, 70.11⁰ and 75.66⁰. Additionally, XRD analysis has revealed elongation of lattice parameter “c” from 9.143 to 9.830 Å with carbon concentration increase. Lattice expansion indicates the possibility of carbon substituting oxygen sites. Raman large area scan has revealed the presence of rutile, brookite and anatase for the undoped samples. On doping the rutile phase of TiO2 has shown to be suppressed by the presence of carbon atoms such that the doped samples consist of brookite and anatase phases only. The Eg1 mode of anatase of the undoped TNTs at 153. 78 cm-1 was red shifted by Δ9.78 cm-1 relative to the bulk anatase TiO2. This was attributed to decrease in particle size, presence of brookite and phonon confinement. Upon doping, the 9 mM C-TNTs, 27 mM TNTs and 75 mM TNTs have shown a red shift of Δ0. 09 cm-1, Δ1. 39 cm-1 and 1.81 cm-1 respectively, suggesting the incorporation of carbon in the TiO2 matrix. CRS depth profiling in the XZ direction has also validated the presence of a mixed anatase-brookite phase at Raman active modes 153.19 cm-1, 208.87 cm-1, 404.55 cm-1, 523.26 cm-1 and 648.55 cm-1. Photoluminescence spectra of carbon doped TiO2 showed two emission peaks at 398 nm attributed to annihilation of excitons while the broad peak at 400-460 nm was attributed to the presence of oxygen vacancies. The peak intensity of the 45 mM C-TNTs has shown a lower PL intensity suggesting that efficiency of charge separation was higher and recombination rate was lower than other carbon containing samples.
- Full Text:
- Date Issued: 2017
- Authors: Takata, Nwabisa
- Date: 2017
- Subjects: Nanotechnology Titanium dioxide Nanostructures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13194 , vital:39473
- Description: This study reveals the effects of doping on the morphological, structural and optical properties of titanium dioxide (TiO2) nanotubes (TNTs), synthesized by sol-gel template-assisted sol-gel technique. The nanotubes (TNTs) were prepared in anodic alumina membranes (AAM) with a pore diameter range of 110-210 nm by using titanium tetra butoxide as a sol-gel precursor and oxalic acid dihydrate as a dopant source. The synthesized nanotubes were evaluated using scanning electron microscope (SEM), energy dispersive spectroscopy (EDX), fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), confocal Raman spectroscopy (CRS) and photoluminescence spectroscopy (PL). SEM analysis has revealed the presence of closely-packed TNTs, with a modal external tube diameters of 150, 170, 210,190 and 210 nm for the un-doped TNTs, 9 mM carbon doped-TNTs (C-TNTs), 27 mM C-TNTs, 45 mM C-TNTs and 75 mM C-TNTs respectively. The diameters are consistent with the AAM diameter range. EDX spectra revealed the presence of Ti peaks at 0.45 and 4.9 keV corresponding to Kα1 and Kβ1 emission lines respectively. Oxygen exhibits a signal at 0.5 keV corresponding to Kα1 emission line. The occurrence of these peaks in the EDX spectra endorses the existence of Ti and O atoms in the prepared titanium dioxide nanotubes. FTIR spectroscopy has revealed the presence of vibration modes at 580-660 cm-1 indicating the presence of Ti-O bonds and additional vibration modes at 2324 cm-1 resulting from C-O stretching in the C-TNTs. The XRD analysis has revealed the presence of a mixed anatase-brookite phase with diffraction peaks at 2θ angles of 25.49⁰, 38.11⁰, 40.60º, 48.14⁰, 54.58⁰, 63.00⁰, 70.11⁰ and 75.66⁰. Additionally, XRD analysis has revealed elongation of lattice parameter “c” from 9.143 to 9.830 Å with carbon concentration increase. Lattice expansion indicates the possibility of carbon substituting oxygen sites. Raman large area scan has revealed the presence of rutile, brookite and anatase for the undoped samples. On doping the rutile phase of TiO2 has shown to be suppressed by the presence of carbon atoms such that the doped samples consist of brookite and anatase phases only. The Eg1 mode of anatase of the undoped TNTs at 153. 78 cm-1 was red shifted by Δ9.78 cm-1 relative to the bulk anatase TiO2. This was attributed to decrease in particle size, presence of brookite and phonon confinement. Upon doping, the 9 mM C-TNTs, 27 mM TNTs and 75 mM TNTs have shown a red shift of Δ0. 09 cm-1, Δ1. 39 cm-1 and 1.81 cm-1 respectively, suggesting the incorporation of carbon in the TiO2 matrix. CRS depth profiling in the XZ direction has also validated the presence of a mixed anatase-brookite phase at Raman active modes 153.19 cm-1, 208.87 cm-1, 404.55 cm-1, 523.26 cm-1 and 648.55 cm-1. Photoluminescence spectra of carbon doped TiO2 showed two emission peaks at 398 nm attributed to annihilation of excitons while the broad peak at 400-460 nm was attributed to the presence of oxygen vacancies. The peak intensity of the 45 mM C-TNTs has shown a lower PL intensity suggesting that efficiency of charge separation was higher and recombination rate was lower than other carbon containing samples.
- Full Text:
- Date Issued: 2017
The effects of changing western worldviews on morals and ethics in economics: a protestant perspective
- Authors: Appalraju, Nerusha
- Date: 2017
- Subjects: Economics -- Moral and ethical aspects , Neoclassical school of economics , Capitalism -- Religious aspects -- Protestant churches , Feminist economics , Economics -- Religious aspects , Environmental economics -- Moral and ethical aspects , Smith, Adam, 1723-1790 , Weber, Max, 1864-1920
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/32480 , vital:24050
- Description: The World Economics Association held an online conference in 2012 where they published many papers on ethics in economics. The topic of ethics in economics became more serious and popular following the 2008 financial crisis. However the case for a professional code of ethics in economics is difficult to introduce and implement due to the multidisciplinary approach of the discipline. Therefore authors such as Dow (2012), De Martino (2012), Freeman (2012) and Earl (2012) urged economists to start thinking about ethics in economics from a pluralistic view. This thesis studied the effects of changing Western worldviews on morals and ethics in economics from a Protestant perspective. Numerous authoritative sources were considered and used to create a discussion and analysis of how diverse Western worldviews impact on the type of economics which is prescribed and practiced. It was found that different Western worldviews create various standards of understanding and evaluation, which result in varying opinions on what constitutes as morally or ethically acceptable within the discipline of economics.
- Full Text:
- Date Issued: 2017
- Authors: Appalraju, Nerusha
- Date: 2017
- Subjects: Economics -- Moral and ethical aspects , Neoclassical school of economics , Capitalism -- Religious aspects -- Protestant churches , Feminist economics , Economics -- Religious aspects , Environmental economics -- Moral and ethical aspects , Smith, Adam, 1723-1790 , Weber, Max, 1864-1920
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/32480 , vital:24050
- Description: The World Economics Association held an online conference in 2012 where they published many papers on ethics in economics. The topic of ethics in economics became more serious and popular following the 2008 financial crisis. However the case for a professional code of ethics in economics is difficult to introduce and implement due to the multidisciplinary approach of the discipline. Therefore authors such as Dow (2012), De Martino (2012), Freeman (2012) and Earl (2012) urged economists to start thinking about ethics in economics from a pluralistic view. This thesis studied the effects of changing Western worldviews on morals and ethics in economics from a Protestant perspective. Numerous authoritative sources were considered and used to create a discussion and analysis of how diverse Western worldviews impact on the type of economics which is prescribed and practiced. It was found that different Western worldviews create various standards of understanding and evaluation, which result in varying opinions on what constitutes as morally or ethically acceptable within the discipline of economics.
- Full Text:
- Date Issued: 2017
The potential of hydrellia egeriae rodrigues (diptera: ephydridae) as a biocontrol agent for egeria densa planch. (hydrocharitaceae) in South Africa
- Authors: Smith, Rosali
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/53733 , vital:26314
- Description: The integrity of South Africa’s valuable freshwater ecosystems has been threatened by aquatic invasive plants since the 1900s. Floating aquatic weeds, such as Eichhornia crassipes (C. Mart) Solms (Pondederiaceae), Pistia stratiotes L. (Araceae), Salvinia molesta D.S. Mitchell (Salviniaceae), Azolla filiculoides Lam. (Azollaceae), and the emergent weed, Myriophyllum aquaticum Verdc. (Haloragaceae) benefited from open, nutrient-rich water bodies. Due to the limitations of mechanical and chemical control in aquatic environments, classical biological control has been a huge asset in managing these weeds; consequently bringing them under complete or substantial control. However, submerged aquatic weeds are widely distributed through the aquarium trade in South Africa; facilitating their invasion into new habitats. The removal of surface mats following the successful management of floating weeds has enhanced the growth and competitive ability of submerged aquatic weeds, such as Hydrilla verticillata (L.f.) Royle (Hydrocharitaceae), Myriophyllum spicatum L. (Haloragaceae) and Egeria densa Planch. (Hydrocharitaceae) in South Africa. Of these species, E. densa has become the most widely distributed, invading numerous systems across South Africa. Compared to other exotic submerged aquatic plants, E. densa is the only species capable of inhabiting freshwater systems in every province and therefore, it is vital to manage existing populations and prevent its further distribution and invasion. Hydrellia spp. (Diptera: Ephydridae) biological control agents have been used extensively in the management of submerged aquatic weeds elsewhere, particularly those in the Hydrocharitaceae (Balciunas and Burrows 1996; Wheeler and Center 2001. Hydrellia egeriae Rodrigues (Diptera: Ephydridae) has been identified as a promising candidate for E. densa and was imported into quarantine at Rhodes University, Grahamstown in 2014. The aims of this study were to conduct a pre-release assessment of the potential of H. egeriae as a biological control agent for E. densa in South Africa. The first objective of this study was to establish the life history of the agent under controlled conditions on E. densa found in South Africa, as well as its population growth parameters to predict its invasion success in the field. Secondly, laboratory host-specificity testing was conducted to validate the host range of the agent, in view of published native range host-specificity testing, and to establish potential risks to non-target species, should it be released. Finally, a biological control agent should also effectively reduce the fitness of its host plant, and therefore, impact studies were conducted. Laboratory impact studies have been limited in the past, in that they only investigate agent damage for short ecological periods, thus underestimating the damage capacity of the agent under investigation. Therefore, the damage capacity of H. egeriae was investigated over three consecutive generations in multi-generational impact trials. In a controlled environment of 22 ± 2°C, H. egeriae exhibited the ability to rapidly increase in population size within a short period of time, which will enhance agent establishment and build-up in the field. Host-specificity trials indicated that H. egeriae has a host range restricted to the Hydrocharitaceae, with exploratory feeding and development on Lagarosiphon major Ridley, L. muscoides Harvey and Vallisneria spiralis L. However, only L. major supported agent development during paired larval choice tests, and continuation trials showed that the test species was not physiologically capable of supporting viable agent populations. Risk analysis illustrated that the feeding and reproductive risks that H. egeriae pose to non-target species are very low and therefore, H. egeriae should be safe for release in South Africa. Additionally, significant damage to vital plant structures (shoot growth and side shoot length) was only recorded under high (five larvae) agent abundances. Encouragingly, the number of leaves mined at the end of the experiment was similar for both intermediate (three) and high (five) larval abundances, suggesting that cumulative leaf-mining under intermediate larval abundances has the potential to reduce the fitness of E. densa, given sufficient time. Results from pre-release assessments provide a robust understanding of the specialization of the potential biological control agent to its host plant. Nevertheless, the absolute success of a biological control programme depends on the many factors after prerelease assessments that determine agent establishment, persistence and target weed suppression, e.g. mass-rearing, release protocols and a/biotic factors within the recipient community. Considering these factors, the best mass-rearing and release protocols are proposed here and future research priorities are identified. Finally, the long term success for managing E. densa in South Africa will require a holistic approach to address the underlying factors, such as eutrophication and human-mediated distribution that drive submerged aquatic plant invasions.
- Full Text:
- Date Issued: 2017
- Authors: Smith, Rosali
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/53733 , vital:26314
- Description: The integrity of South Africa’s valuable freshwater ecosystems has been threatened by aquatic invasive plants since the 1900s. Floating aquatic weeds, such as Eichhornia crassipes (C. Mart) Solms (Pondederiaceae), Pistia stratiotes L. (Araceae), Salvinia molesta D.S. Mitchell (Salviniaceae), Azolla filiculoides Lam. (Azollaceae), and the emergent weed, Myriophyllum aquaticum Verdc. (Haloragaceae) benefited from open, nutrient-rich water bodies. Due to the limitations of mechanical and chemical control in aquatic environments, classical biological control has been a huge asset in managing these weeds; consequently bringing them under complete or substantial control. However, submerged aquatic weeds are widely distributed through the aquarium trade in South Africa; facilitating their invasion into new habitats. The removal of surface mats following the successful management of floating weeds has enhanced the growth and competitive ability of submerged aquatic weeds, such as Hydrilla verticillata (L.f.) Royle (Hydrocharitaceae), Myriophyllum spicatum L. (Haloragaceae) and Egeria densa Planch. (Hydrocharitaceae) in South Africa. Of these species, E. densa has become the most widely distributed, invading numerous systems across South Africa. Compared to other exotic submerged aquatic plants, E. densa is the only species capable of inhabiting freshwater systems in every province and therefore, it is vital to manage existing populations and prevent its further distribution and invasion. Hydrellia spp. (Diptera: Ephydridae) biological control agents have been used extensively in the management of submerged aquatic weeds elsewhere, particularly those in the Hydrocharitaceae (Balciunas and Burrows 1996; Wheeler and Center 2001. Hydrellia egeriae Rodrigues (Diptera: Ephydridae) has been identified as a promising candidate for E. densa and was imported into quarantine at Rhodes University, Grahamstown in 2014. The aims of this study were to conduct a pre-release assessment of the potential of H. egeriae as a biological control agent for E. densa in South Africa. The first objective of this study was to establish the life history of the agent under controlled conditions on E. densa found in South Africa, as well as its population growth parameters to predict its invasion success in the field. Secondly, laboratory host-specificity testing was conducted to validate the host range of the agent, in view of published native range host-specificity testing, and to establish potential risks to non-target species, should it be released. Finally, a biological control agent should also effectively reduce the fitness of its host plant, and therefore, impact studies were conducted. Laboratory impact studies have been limited in the past, in that they only investigate agent damage for short ecological periods, thus underestimating the damage capacity of the agent under investigation. Therefore, the damage capacity of H. egeriae was investigated over three consecutive generations in multi-generational impact trials. In a controlled environment of 22 ± 2°C, H. egeriae exhibited the ability to rapidly increase in population size within a short period of time, which will enhance agent establishment and build-up in the field. Host-specificity trials indicated that H. egeriae has a host range restricted to the Hydrocharitaceae, with exploratory feeding and development on Lagarosiphon major Ridley, L. muscoides Harvey and Vallisneria spiralis L. However, only L. major supported agent development during paired larval choice tests, and continuation trials showed that the test species was not physiologically capable of supporting viable agent populations. Risk analysis illustrated that the feeding and reproductive risks that H. egeriae pose to non-target species are very low and therefore, H. egeriae should be safe for release in South Africa. Additionally, significant damage to vital plant structures (shoot growth and side shoot length) was only recorded under high (five larvae) agent abundances. Encouragingly, the number of leaves mined at the end of the experiment was similar for both intermediate (three) and high (five) larval abundances, suggesting that cumulative leaf-mining under intermediate larval abundances has the potential to reduce the fitness of E. densa, given sufficient time. Results from pre-release assessments provide a robust understanding of the specialization of the potential biological control agent to its host plant. Nevertheless, the absolute success of a biological control programme depends on the many factors after prerelease assessments that determine agent establishment, persistence and target weed suppression, e.g. mass-rearing, release protocols and a/biotic factors within the recipient community. Considering these factors, the best mass-rearing and release protocols are proposed here and future research priorities are identified. Finally, the long term success for managing E. densa in South Africa will require a holistic approach to address the underlying factors, such as eutrophication and human-mediated distribution that drive submerged aquatic plant invasions.
- Full Text:
- Date Issued: 2017
The WTO agreement on technical barriers to trade : a critical appraisal of its implementation within the Southern African Development Community
- Authors: Chimeri, Vongai
- Date: 2017
- Subjects: Tariff -- Law and legislation Non-tariff trade barriers -- Law and legislation Foreign trade regulation
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10353/2855 , vital:28108
- Description: The World Trade Organisation Agreement on Technical Barriers to Trade (TBT Agreement) was crafted with the aim of ensuring that technical regulations, standards and conformity assessment procedure do not constitute unnecessary obstacles to international trade. Southern African Development Community (SADC) countries have since ratified this Agreement and took a step further to incorporate its principles into the Technical Barriers to Trade Annex to the SADC Protocol on Trade. Despite this effort, SADC countries are still grappling with implementing the TBT Agreement in their domestic frameworks. Consequently, technical barriers to trade have become impediments to both regional and international trade. It is in this context that this study aims to examine the implementation of the TBT Agreement within the SADC. The study answers the question what are the challenges facing SADC Member states to fully implement the TBT Agreement? The study demonstrates that SADC Member face challenges which include of lack adequate resources, technical expertise and enforcement mechanisms to effectively implement the TBT Agreement. In the finality, the study recommends SADC Member states to deepen regional integration in order to collaborate on matters relating to technical barriers to trade within the region. Member states should also share information and learn from the experiences of other countries on how to effectively implement the TBT Agreement. Further, government officials should be educated on trade-friendly regulations that do not compromise on the principles of the TBT Agreement. To this end, regulatory impact assessments should be established in order to assess the trade effects of both new and old regulations. Effective enforcement mechanisms should also be introduced in order to coerce Member states to comply with their regional obligations. By effecting these recommendations, SADC states have the opportunity to eradicate technical barriers to trade thereby increasing both regional and international trade.
- Full Text:
- Date Issued: 2017
- Authors: Chimeri, Vongai
- Date: 2017
- Subjects: Tariff -- Law and legislation Non-tariff trade barriers -- Law and legislation Foreign trade regulation
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10353/2855 , vital:28108
- Description: The World Trade Organisation Agreement on Technical Barriers to Trade (TBT Agreement) was crafted with the aim of ensuring that technical regulations, standards and conformity assessment procedure do not constitute unnecessary obstacles to international trade. Southern African Development Community (SADC) countries have since ratified this Agreement and took a step further to incorporate its principles into the Technical Barriers to Trade Annex to the SADC Protocol on Trade. Despite this effort, SADC countries are still grappling with implementing the TBT Agreement in their domestic frameworks. Consequently, technical barriers to trade have become impediments to both regional and international trade. It is in this context that this study aims to examine the implementation of the TBT Agreement within the SADC. The study answers the question what are the challenges facing SADC Member states to fully implement the TBT Agreement? The study demonstrates that SADC Member face challenges which include of lack adequate resources, technical expertise and enforcement mechanisms to effectively implement the TBT Agreement. In the finality, the study recommends SADC Member states to deepen regional integration in order to collaborate on matters relating to technical barriers to trade within the region. Member states should also share information and learn from the experiences of other countries on how to effectively implement the TBT Agreement. Further, government officials should be educated on trade-friendly regulations that do not compromise on the principles of the TBT Agreement. To this end, regulatory impact assessments should be established in order to assess the trade effects of both new and old regulations. Effective enforcement mechanisms should also be introduced in order to coerce Member states to comply with their regional obligations. By effecting these recommendations, SADC states have the opportunity to eradicate technical barriers to trade thereby increasing both regional and international trade.
- Full Text:
- Date Issued: 2017
Evaluation of physiochemical qualities and heavy metal levels of the final effluents of some wastewater treatment facilities in the Eastern Cape Province of South Africa
- Authors: Kulati, Thanduxolo Cullinan
- Date: 2016
- Subjects: Water -- Purification Sewage -- Purification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1547 , vital:27417
- Description: Water is the most abundant substance in nature and vital for life activities. The major water sources for use are surface water bodies such as rivers and lakes, and underground aquifers and pore spaces down the water table (Ring, 2003). Water derived from these sources is not necessarily pure since it contains dissolved inorganic and organic substances, living organisms (viruses, bacteria, etc). For these reasons, water intended for domestic uses should be free from toxic substances and microorganisms that are of health significance (WHO, 2005). The availability and quality of water always have played an important role in determining the quality of life. Water quality is closely linked to water use and to the state of economic development (Chennakrishnan et al., 2008). Ground and surface waters can be contaminated by several sources. In urban areas, the careless disposal of industrial effluents and other wastes may contribute greatly to the poor quality of water (Mathuthu et al., 1997). In most developing countries, most areas are located on the watersheds which are the end points of effluents discharged from various industries (Oberholster and Ashton, 2008). South Africa, as a developing country, is experiencing rapid demographic changes due to urbanization, industrialization and population growth. The country has also been identified as being water-scarce, which can lead to a challenge of meeting the increasing water demand due to industrialization and urbanization. Such population growth increase may result in an increase in wastewater output, especially around urban areas.
- Full Text:
- Date Issued: 2016
- Authors: Kulati, Thanduxolo Cullinan
- Date: 2016
- Subjects: Water -- Purification Sewage -- Purification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1547 , vital:27417
- Description: Water is the most abundant substance in nature and vital for life activities. The major water sources for use are surface water bodies such as rivers and lakes, and underground aquifers and pore spaces down the water table (Ring, 2003). Water derived from these sources is not necessarily pure since it contains dissolved inorganic and organic substances, living organisms (viruses, bacteria, etc). For these reasons, water intended for domestic uses should be free from toxic substances and microorganisms that are of health significance (WHO, 2005). The availability and quality of water always have played an important role in determining the quality of life. Water quality is closely linked to water use and to the state of economic development (Chennakrishnan et al., 2008). Ground and surface waters can be contaminated by several sources. In urban areas, the careless disposal of industrial effluents and other wastes may contribute greatly to the poor quality of water (Mathuthu et al., 1997). In most developing countries, most areas are located on the watersheds which are the end points of effluents discharged from various industries (Oberholster and Ashton, 2008). South Africa, as a developing country, is experiencing rapid demographic changes due to urbanization, industrialization and population growth. The country has also been identified as being water-scarce, which can lead to a challenge of meeting the increasing water demand due to industrialization and urbanization. Such population growth increase may result in an increase in wastewater output, especially around urban areas.
- Full Text:
- Date Issued: 2016
Geology, regional diamond exploration and diamond provenance of the proterozoic diamondiferous Umkondo conglomerates, Umkondo group, eastern Zimbabwe
- Authors: Zhou, Takawira
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3598 , vital:20528
- Description: The Umkondo Sedimentary Basin in eastern Zimbabwe has been studied by various individuals and organizations since 1901. Their interest had been in finding limestone and beryl and base metal deposits, especially copper, iron and uranium, but these occurrences had proved to be of no economic value (Watson, 1969). The recent discovery of placer diamonds within the Proterozoic basal conglomerates of the Umkondo Sedimentary Basin has now attracted worldwide interest in the basin’s diamond economic potential, in understanding of the geology, and the diamond provenance of the Umkondo conglomerates. The Umkondo Sedimentary Basin basal conglomerate placer deposit might narrowly be defined as a mega-placer because of its sheer large size and high grades, especially on the 70,000 hectare western margin diamond dispersion halo where alluvial diamonds are being mined. Bluck, et al., (2005, pp 213) defines a diamond mega-placer as: . . . a number of linked deposits that are a result of one or a continuous process of transportation and deposition and holds or have held at least >= 50 million carats at >= 95% gem quality, for example, the Orange-Vaal dispersal, off the Kaapvaal craton in South Africa. On craton placers are residual, and transient placers are eroded and deposited into the exit drainage, while terminal placers, the final depositories of diamonds with the highest chances of being mega-placers are deposited into terminal basins like oceans and foreland basins. Though data is limited at the moment, the Umkondo conglomerates caratage is likely to run into hundreds of millions of carats, with a diamond gem content of between twenty and twenty-five percent, as is indicated from recent diamond production data. The greater part of the Umkondo diamonds are likely to be lodged beneath the deep gravels of the Middle and Lower Save River basin, because small remnant tilted mountain blocks and inselbergs forming the caps of hills are what remains of the host conglomerate on the western margin of the Umkondo Basin. Areas to be examined in this document will be the geology; the mode of formation of the Umkondo basin and its sedimentary system; the regional kimberlite exploration around the basin; and diamond production in the Marange diamond field, in order to come up with indications of the provenance of the diamonds within the Umkondo conglomerates. The kimberlite clusters in and around the Umkondo sedimentary basin have all proved to be barren or only nominally diamondiferous and that the kimberlites are between 200Ma and 500Ma and thus much younger than the greater than 1.1Ga Umkondo diamondiferous conglomerates. Studies so far undertaken have not managed to point to the origin, or provenance, of the Umkondo or Marange diamonds, which were discovered on the western edge of the Umkondo Basin and in the east of the basin below the Chimanimani Mountains along the Haroni River. This paper is an attempt to clear up some of the misconceptions surrounding the Marange diamond deposit and to raise interest in the urgent rquirement to study and understand the Umkondo Basin and the origin of its diamonds. The only meaningful studies on diamond occurrence and diamond exploration of the basin were undertaken from 1996 to 2006 by Kimberlitic Searches Zimbabwe (Pvt) Ltd, the then Zimbabwe kimberlite exploration arm of De Beers, Zimbabwe, in their quest to find kimberlites, which were thought to be related to the Umkondo alluvial diamond deposit. As will be shown in the following chapters, many of the discovered kimberlites range from very low grade to non-diamondiferous, and are much younger than the Umkondo conglomerates, whose diamonds are in turn a great deal older. Thus the basic question concerning the origin or provenance of the Umkondo placer diamonds still remains unresolved. Because of the sheer size of the basin, modern, wide-area-coverage, geophysical exploration methods become appropriate to effectively generate diamond potential targets for further examination. This document will attempt to collate various data available to paint a true picture of the state of exploration within the Umkondo Basin.
- Full Text:
- Date Issued: 2016
- Authors: Zhou, Takawira
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3598 , vital:20528
- Description: The Umkondo Sedimentary Basin in eastern Zimbabwe has been studied by various individuals and organizations since 1901. Their interest had been in finding limestone and beryl and base metal deposits, especially copper, iron and uranium, but these occurrences had proved to be of no economic value (Watson, 1969). The recent discovery of placer diamonds within the Proterozoic basal conglomerates of the Umkondo Sedimentary Basin has now attracted worldwide interest in the basin’s diamond economic potential, in understanding of the geology, and the diamond provenance of the Umkondo conglomerates. The Umkondo Sedimentary Basin basal conglomerate placer deposit might narrowly be defined as a mega-placer because of its sheer large size and high grades, especially on the 70,000 hectare western margin diamond dispersion halo where alluvial diamonds are being mined. Bluck, et al., (2005, pp 213) defines a diamond mega-placer as: . . . a number of linked deposits that are a result of one or a continuous process of transportation and deposition and holds or have held at least >= 50 million carats at >= 95% gem quality, for example, the Orange-Vaal dispersal, off the Kaapvaal craton in South Africa. On craton placers are residual, and transient placers are eroded and deposited into the exit drainage, while terminal placers, the final depositories of diamonds with the highest chances of being mega-placers are deposited into terminal basins like oceans and foreland basins. Though data is limited at the moment, the Umkondo conglomerates caratage is likely to run into hundreds of millions of carats, with a diamond gem content of between twenty and twenty-five percent, as is indicated from recent diamond production data. The greater part of the Umkondo diamonds are likely to be lodged beneath the deep gravels of the Middle and Lower Save River basin, because small remnant tilted mountain blocks and inselbergs forming the caps of hills are what remains of the host conglomerate on the western margin of the Umkondo Basin. Areas to be examined in this document will be the geology; the mode of formation of the Umkondo basin and its sedimentary system; the regional kimberlite exploration around the basin; and diamond production in the Marange diamond field, in order to come up with indications of the provenance of the diamonds within the Umkondo conglomerates. The kimberlite clusters in and around the Umkondo sedimentary basin have all proved to be barren or only nominally diamondiferous and that the kimberlites are between 200Ma and 500Ma and thus much younger than the greater than 1.1Ga Umkondo diamondiferous conglomerates. Studies so far undertaken have not managed to point to the origin, or provenance, of the Umkondo or Marange diamonds, which were discovered on the western edge of the Umkondo Basin and in the east of the basin below the Chimanimani Mountains along the Haroni River. This paper is an attempt to clear up some of the misconceptions surrounding the Marange diamond deposit and to raise interest in the urgent rquirement to study and understand the Umkondo Basin and the origin of its diamonds. The only meaningful studies on diamond occurrence and diamond exploration of the basin were undertaken from 1996 to 2006 by Kimberlitic Searches Zimbabwe (Pvt) Ltd, the then Zimbabwe kimberlite exploration arm of De Beers, Zimbabwe, in their quest to find kimberlites, which were thought to be related to the Umkondo alluvial diamond deposit. As will be shown in the following chapters, many of the discovered kimberlites range from very low grade to non-diamondiferous, and are much younger than the Umkondo conglomerates, whose diamonds are in turn a great deal older. Thus the basic question concerning the origin or provenance of the Umkondo placer diamonds still remains unresolved. Because of the sheer size of the basin, modern, wide-area-coverage, geophysical exploration methods become appropriate to effectively generate diamond potential targets for further examination. This document will attempt to collate various data available to paint a true picture of the state of exploration within the Umkondo Basin.
- Full Text:
- Date Issued: 2016
An analysis of malware evasion techniques against modern AV engines
- Authors: Haffejee, Jameel
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:20979 , http://hdl.handle.net/10962/5821
- Description: This research empirically tested the response of antivirus applications to binaries that use virus-like evasion techniques. In order to achieve this, a number of binaries are processed using a number of evasion methods and are then deployed against several antivirus engines. The research also documents the process of setting up an environment for testing antivirus engines, including building the evasion techniques used in the tests. The results of the empirical tests illustrate that an attacker can evade multiple antivirus engines without much effort using well-known evasion techniques. Furthermore, some antivirus engines may respond to the occurrence of an evasion technique instead of the presence of any malicious code. In practical terms, this shows that while antivirus applications are useful for protecting against known threats, their effectiveness against unknown or modified threats is limited.
- Full Text:
- Date Issued: 2015
- Authors: Haffejee, Jameel
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:20979 , http://hdl.handle.net/10962/5821
- Description: This research empirically tested the response of antivirus applications to binaries that use virus-like evasion techniques. In order to achieve this, a number of binaries are processed using a number of evasion methods and are then deployed against several antivirus engines. The research also documents the process of setting up an environment for testing antivirus engines, including building the evasion techniques used in the tests. The results of the empirical tests illustrate that an attacker can evade multiple antivirus engines without much effort using well-known evasion techniques. Furthermore, some antivirus engines may respond to the occurrence of an evasion technique instead of the presence of any malicious code. In practical terms, this shows that while antivirus applications are useful for protecting against known threats, their effectiveness against unknown or modified threats is limited.
- Full Text:
- Date Issued: 2015
The role of leadership style and organisational structure in organisational effectiveness: a case study
- Authors: Messaris, Annette
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/54452 , vital:26566
- Description: This research explores the role leadership style and organisational structure play in organisational effectiveness. Organisational effectiveness is one of the more complex terms to define although essential to understand in order for an organisation to grow and develop. A small to medium wine sales and distribution organisation, its leadership style and organisational structure were chosen as a focus of this case study. Organisational effectiveness in this study is understood by the terms growth and development using the Greiner Theory of Evolution and Revolution (1983). The literature explores the role of leadership style in organisational effectiveness by exploring various theories and focusing on The Full Range Leadership Model by Bass and Avolio (1994). In order to analyse the role of organisational structure in organisational effectiveness, the different forms of organisational structure and the role they have on the organisation’s ability to grow and develop are explored. The primary purpose of this study is to investigate the role leadership style and organisational structure play in organisational effectiveness. A qualitative content analysis paradigm was used with a Case Study method. The data was gathered using structured interviews conducted on all 39 permanent staff members, day to day observation and the Multifactor Leadership Questionnaire (MLQ). The MLQ is used as a supporting tool to verify the leadership findings in the interviews. The data was analysed using NVivo10 and STATISTICA to gain insight into the leadership style and organisational structure of the organisation. The findings reflected that certain themes were repeatedly mentioned in the interviews and the definition of organisational effectiveness: structured leadership, more active leadership, lack of communication, staff motivation, staff training and development and organisational culture. As regards organisational structure, the following themes arose: The need for regular meetings, increased team work and more structured job descriptions. Through the analysis of all the components, leadership style and organisational structure were identified as having a significant role in organisational effectiveness which will be further analysed in this study.
- Full Text:
- Date Issued: 2015
- Authors: Messaris, Annette
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/54452 , vital:26566
- Description: This research explores the role leadership style and organisational structure play in organisational effectiveness. Organisational effectiveness is one of the more complex terms to define although essential to understand in order for an organisation to grow and develop. A small to medium wine sales and distribution organisation, its leadership style and organisational structure were chosen as a focus of this case study. Organisational effectiveness in this study is understood by the terms growth and development using the Greiner Theory of Evolution and Revolution (1983). The literature explores the role of leadership style in organisational effectiveness by exploring various theories and focusing on The Full Range Leadership Model by Bass and Avolio (1994). In order to analyse the role of organisational structure in organisational effectiveness, the different forms of organisational structure and the role they have on the organisation’s ability to grow and develop are explored. The primary purpose of this study is to investigate the role leadership style and organisational structure play in organisational effectiveness. A qualitative content analysis paradigm was used with a Case Study method. The data was gathered using structured interviews conducted on all 39 permanent staff members, day to day observation and the Multifactor Leadership Questionnaire (MLQ). The MLQ is used as a supporting tool to verify the leadership findings in the interviews. The data was analysed using NVivo10 and STATISTICA to gain insight into the leadership style and organisational structure of the organisation. The findings reflected that certain themes were repeatedly mentioned in the interviews and the definition of organisational effectiveness: structured leadership, more active leadership, lack of communication, staff motivation, staff training and development and organisational culture. As regards organisational structure, the following themes arose: The need for regular meetings, increased team work and more structured job descriptions. Through the analysis of all the components, leadership style and organisational structure were identified as having a significant role in organisational effectiveness which will be further analysed in this study.
- Full Text:
- Date Issued: 2015
A comparative analysis of the phonological acquisition of consonants in the speech of pre-school age isiXhosa and English-speaking children in selected schools in the East London area
- Authors: Myoli, Ndileka
- Date: 2014
- Language: English
- Type: Thesis , Masters , MA (African Languages)
- Identifier: vital:11151 , http://hdl.handle.net/10353/d1015437
- Description: The problems of reading and incomprehension found in South African schools are often linked to children‟s differences of phonological acquisition rates and the articulation of consonants. This is according to the report of the Impact Study of the System Method for Reading Success study (SMRS) of 2009. This problem has always been associated with the racial inequalities that have previously ruled the South African education system. An understanding of the existence of the differences in children‟s articulation of consonants between the English-speaking and the isiXhosa-speaking children may lead to further understanding of the causes of such differences and the application of strategies that are aimed at remedying that situation. While many studies have been conducted in the area of language acquisition, this study found it necessary to contribute further to this debate. This study investigated the different rates of consonant articulation between pre-school-going Englishspeaking and isiXhosa-speaking children of 2-6 years of age. The main aim was to establish which of these two cohorts have early phonological acquisition of consonants and, therefore, master their articulation and why. 26 children from the two pre-schools within the East London directorate weren sampled, 13 consisting of females and males from each of the two pre-primary schools. This study used informal interviews and case study as the means of data collection as well as a case study as its investigation strategy. Children‟s speech utterances were recorded in order to analyse and compare with respect to order of acquisition, types of errors as well as the ages at which consonants were acquired. This study ensured a high degree of validity as well as giving due consideration to ethical matters in order to ensure the reliability of the results. The problems of reading and incomprehension found in South African schools are often linked to children‟s differences of phonological acquisition rates and the articulation of consonants. This is according to the report of the Impact Study of the System Method for Reading Success study (SMRS) of 2009. This problem has always been associated with the racial inequalities that have previously ruled the South African education system. An understanding of the existence of the differences in children‟s articulation of consonants between the English-speaking and the isiXhosa-speaking children may lead to further understanding of the causes of such differences and the application of strategies that are aimed at remedying that situation. While many studies have been conducted in the area of language acquisition, this study found it necessary to contribute further to this debate. This study investigated the different rates of consonant articulation between pre-school-going Englishspeaking and isiXhosa-speaking children of 2-6 years of age. The main aim was to establish which of these two cohorts have early phonological acquisition of consonants and, therefore, master their articulation and why. 26 children from the two pre-schools within the East London directorate weren sampled, 13 consisting of females and males from each of the two pre-primary schools. This study used informal interviews and case study as the means of data collection as well as a case study as its investigation strategy. Children‟s speech utterances were recorded in order to analyse and compare with respect to order of acquisition, types of errors as well as the ages at which consonants were acquired. This study ensured a high degree of validity as well as giving due consideration to ethical matters in order to ensure the reliability of the results. The study found that isiXhosa speaking children have earlier consonant acquisition than English-speaking children do. While that is the case, the study also found that English-speaking children‟s rates of phonological acquisition accelerated from the age of 4 years to the age of 6 years much more than the isiXhosa-speaking children of the same age could do. The implications of these results to education stakeholders, particularly the teachers and other related professionals who deal with children with articulation disorders on a daily basis, will create an understanding as well as an awareness of the existence of such problems. Policies formulated will have to take the existence of articulation disorders into consideration. The distribution of resources relevant to the needs of children will include and cater for children with such disorders. Further research is recommended to investigate more around this area of study to a point where solutions for the existing differences of articulation of consonants for one group of children over another are realised.The study found that isiXhosa speaking children have earlier consonant acquisition than English-speaking children do. While that is the case, the study also found that English-speaking children‟s rates of phonological acquisition accelerated from the age of 4 years to the age of 6 years much more than the isiXhosa-speaking children of the same age could do. The implications of these results to education stakeholders, particularly the teachers and other related professionals who deal with children with articulation disorders on a daily basis, will create an understanding as well as an awareness of the existence of such problems. Policies formulated will have to take the existence of articulation disorders into consideration. The distribution of resources relevant to the needs of children will include and cater for children with such disorders. Further research is recommended to investigate more around this area of study to a point where solutions for the existing differences of articulation of consonants for one group of children over another are realised.
- Full Text:
- Date Issued: 2014
- Authors: Myoli, Ndileka
- Date: 2014
- Language: English
- Type: Thesis , Masters , MA (African Languages)
- Identifier: vital:11151 , http://hdl.handle.net/10353/d1015437
- Description: The problems of reading and incomprehension found in South African schools are often linked to children‟s differences of phonological acquisition rates and the articulation of consonants. This is according to the report of the Impact Study of the System Method for Reading Success study (SMRS) of 2009. This problem has always been associated with the racial inequalities that have previously ruled the South African education system. An understanding of the existence of the differences in children‟s articulation of consonants between the English-speaking and the isiXhosa-speaking children may lead to further understanding of the causes of such differences and the application of strategies that are aimed at remedying that situation. While many studies have been conducted in the area of language acquisition, this study found it necessary to contribute further to this debate. This study investigated the different rates of consonant articulation between pre-school-going Englishspeaking and isiXhosa-speaking children of 2-6 years of age. The main aim was to establish which of these two cohorts have early phonological acquisition of consonants and, therefore, master their articulation and why. 26 children from the two pre-schools within the East London directorate weren sampled, 13 consisting of females and males from each of the two pre-primary schools. This study used informal interviews and case study as the means of data collection as well as a case study as its investigation strategy. Children‟s speech utterances were recorded in order to analyse and compare with respect to order of acquisition, types of errors as well as the ages at which consonants were acquired. This study ensured a high degree of validity as well as giving due consideration to ethical matters in order to ensure the reliability of the results. The problems of reading and incomprehension found in South African schools are often linked to children‟s differences of phonological acquisition rates and the articulation of consonants. This is according to the report of the Impact Study of the System Method for Reading Success study (SMRS) of 2009. This problem has always been associated with the racial inequalities that have previously ruled the South African education system. An understanding of the existence of the differences in children‟s articulation of consonants between the English-speaking and the isiXhosa-speaking children may lead to further understanding of the causes of such differences and the application of strategies that are aimed at remedying that situation. While many studies have been conducted in the area of language acquisition, this study found it necessary to contribute further to this debate. This study investigated the different rates of consonant articulation between pre-school-going Englishspeaking and isiXhosa-speaking children of 2-6 years of age. The main aim was to establish which of these two cohorts have early phonological acquisition of consonants and, therefore, master their articulation and why. 26 children from the two pre-schools within the East London directorate weren sampled, 13 consisting of females and males from each of the two pre-primary schools. This study used informal interviews and case study as the means of data collection as well as a case study as its investigation strategy. Children‟s speech utterances were recorded in order to analyse and compare with respect to order of acquisition, types of errors as well as the ages at which consonants were acquired. This study ensured a high degree of validity as well as giving due consideration to ethical matters in order to ensure the reliability of the results. The study found that isiXhosa speaking children have earlier consonant acquisition than English-speaking children do. While that is the case, the study also found that English-speaking children‟s rates of phonological acquisition accelerated from the age of 4 years to the age of 6 years much more than the isiXhosa-speaking children of the same age could do. The implications of these results to education stakeholders, particularly the teachers and other related professionals who deal with children with articulation disorders on a daily basis, will create an understanding as well as an awareness of the existence of such problems. Policies formulated will have to take the existence of articulation disorders into consideration. The distribution of resources relevant to the needs of children will include and cater for children with such disorders. Further research is recommended to investigate more around this area of study to a point where solutions for the existing differences of articulation of consonants for one group of children over another are realised.The study found that isiXhosa speaking children have earlier consonant acquisition than English-speaking children do. While that is the case, the study also found that English-speaking children‟s rates of phonological acquisition accelerated from the age of 4 years to the age of 6 years much more than the isiXhosa-speaking children of the same age could do. The implications of these results to education stakeholders, particularly the teachers and other related professionals who deal with children with articulation disorders on a daily basis, will create an understanding as well as an awareness of the existence of such problems. Policies formulated will have to take the existence of articulation disorders into consideration. The distribution of resources relevant to the needs of children will include and cater for children with such disorders. Further research is recommended to investigate more around this area of study to a point where solutions for the existing differences of articulation of consonants for one group of children over another are realised.
- Full Text:
- Date Issued: 2014
An investigation into the nature of grade 4 learners’ evolving mathematics learning dispositions: a case study of 3 learners participating in an after school mathematics club
- Authors: Hewana, Diliza Ronald
- Date: 2014
- Subjects: Mathematics -- Study and teaching (Elementary) -- Case studies , Mathematics -- Study and teaching (Elementary) -- Psychological aspects , After-school programs -- South Africa -- Grahamstown , Students -- Attitudes -- Case studies , Education, Elementary -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1983 , http://hdl.handle.net/10962/d1013140
- Description: Through a qualitative case study approach this research investigated the nature of three Grade 4 learners’ mathematical learning dispositions. It further explored how these dispositions evolve within the context of their participation in a weekly after school mathematics club over time. Of particular significance the research drew on the dispositional frameworks of Kilpatrick, Swafford and Findell’s (2001) and Carr & Claxton (2002) and pointed to ways in which these framework can be usefully brought together to provide a richer picture of learning dispositions. Kilpatrick, Swafford and Findell’s (2001) framework of mathematical proficiency involves five interrelated strands of which productive disposition is the fifth strand and largely underresearched (Graven, 2012). This strand is defined as ‘the tendency to see sense in mathematics, to perceive it as both useful and worthwhile, to believe that steady effort in learning mathematics pays off, and to see oneself as an effective learner and doer of mathematics’ (Kilpatrick, Swafford and Findell, 2001, p. 131). Carr & Claxton (2002) similarly argue for the importance of learning dispositions and point to the importance of resilience, playfulness and resourcefulness as three key indicators. The research outlines findings of the three case study learners in terms of data obtained from a questionnaire and interview about students’ learning dispositions. The interview asked learners various questions including for example, complete the sentence ‘Maths is…’, describe an effective learner of mathematics and say what you do if you don’t know an answer. The instrument was first administered orally and learners were asked to write their answers (in May 2012) and a year later it was administered as an interview by the club facilitator (in May 2013). While there is the limitation of comparison due to the different ways in which learners responded in 2012 (written) and 2013 (oral) the shifting nature of responses in certain respects provides some indication of shifts towards increasingly productive dispositions. Additionally the research analysed detailed transcripts of video recordings of several club sessions over a five-month period. Findings suggest ways of extending dispositional frameworks and that learners have restricted dispositions particularly in terms of sense making and resourcefulness across time. The findings also suggest shifts in dispositions over time especially in terms of seeing steady effort as paying off.
- Full Text:
- Date Issued: 2014
- Authors: Hewana, Diliza Ronald
- Date: 2014
- Subjects: Mathematics -- Study and teaching (Elementary) -- Case studies , Mathematics -- Study and teaching (Elementary) -- Psychological aspects , After-school programs -- South Africa -- Grahamstown , Students -- Attitudes -- Case studies , Education, Elementary -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1983 , http://hdl.handle.net/10962/d1013140
- Description: Through a qualitative case study approach this research investigated the nature of three Grade 4 learners’ mathematical learning dispositions. It further explored how these dispositions evolve within the context of their participation in a weekly after school mathematics club over time. Of particular significance the research drew on the dispositional frameworks of Kilpatrick, Swafford and Findell’s (2001) and Carr & Claxton (2002) and pointed to ways in which these framework can be usefully brought together to provide a richer picture of learning dispositions. Kilpatrick, Swafford and Findell’s (2001) framework of mathematical proficiency involves five interrelated strands of which productive disposition is the fifth strand and largely underresearched (Graven, 2012). This strand is defined as ‘the tendency to see sense in mathematics, to perceive it as both useful and worthwhile, to believe that steady effort in learning mathematics pays off, and to see oneself as an effective learner and doer of mathematics’ (Kilpatrick, Swafford and Findell, 2001, p. 131). Carr & Claxton (2002) similarly argue for the importance of learning dispositions and point to the importance of resilience, playfulness and resourcefulness as three key indicators. The research outlines findings of the three case study learners in terms of data obtained from a questionnaire and interview about students’ learning dispositions. The interview asked learners various questions including for example, complete the sentence ‘Maths is…’, describe an effective learner of mathematics and say what you do if you don’t know an answer. The instrument was first administered orally and learners were asked to write their answers (in May 2012) and a year later it was administered as an interview by the club facilitator (in May 2013). While there is the limitation of comparison due to the different ways in which learners responded in 2012 (written) and 2013 (oral) the shifting nature of responses in certain respects provides some indication of shifts towards increasingly productive dispositions. Additionally the research analysed detailed transcripts of video recordings of several club sessions over a five-month period. Findings suggest ways of extending dispositional frameworks and that learners have restricted dispositions particularly in terms of sense making and resourcefulness across time. The findings also suggest shifts in dispositions over time especially in terms of seeing steady effort as paying off.
- Full Text:
- Date Issued: 2014
On the implementation effectiveness and efficiency of ecological interventions in operational contexts : the case of Working for Water
- Authors: McConnachie, Matthew Morgan
- Date: 2013
- Subjects: Working for Water Programme Alien plants -- South Africa -- Eastern Cape Alien plants -- Control -- South Africa -- Eastern Cape Alien plants -- Control -- Cost effectiveness -- South Africa -- Eastern Cape Conservation of natural resources -- South Africa -- Eastern Cape Acacia mearnsii -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape Revegetation -- South Africa -- Eastern Cape Restoration ecology -- South Africa -- Eastern Cape Environmental degradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4729 , http://hdl.handle.net/10962/d1001956
- Description: There is little understanding of the implementation efficiency and effectiveness of restoring plant invaded landscapes within operational contexts. South Africa's Working for Water (WfW) programme is arguably the most ambitious alien plant control programme in the world, yet little is known about its cost-effectiveness and the challenges it faces in linking poverty and environmental objectives. My first aim was to assess the cost-effectiveness of invasive plant removal, and the factors that underpin its effectiveness over large spatial and temporal scales. The second aim was to compare the accuracy of evidence-based findings with managers' experience-based beliefs, and to assess whether managers are willing to change their beliefs after being exposed to it. The third aim was to assess the costs and benefits of removal versus removal followed by active native re-vegetation. My final aim is to assess the challenges and lessons learnt by managers linking ecological restoration with poverty alleviation objectives, specifically within the public works model. My study area was focused primarily on two WfW river catchment projects in the western region of the Eastern Cape province. I adopted an interdisciplinary approach drawing from a range of methods such as observational studies, statistical modelling and interviews with managers. The key findings were that control efforts in the two catchment projects are largely inadequate owing to many sites being re-invaded and not enough resources being allocated to the catchments. It would take between 54 and 695 years to clear the respective catchments. In terms of cost-effectiveness, my results exceeded previous estimates by 1.5 to 8.6 times for each catchment project. After being exposed to the evidence-based findings, the managers did not change their beliefs when it came to forecasting the future effectiveness. I found that active native re-vegetation after removal of invasive plants is very costly and that priority should be given to understanding the effectiveness of the removal treatments on native species recovery. The managers cited significant challenges in effectively and efficiently meeting the programmes dual objectives. Based on a broader review of the public works literature I recommend WfW re-examine the type of public works they currently use.
- Full Text:
- Date Issued: 2013
- Authors: McConnachie, Matthew Morgan
- Date: 2013
- Subjects: Working for Water Programme Alien plants -- South Africa -- Eastern Cape Alien plants -- Control -- South Africa -- Eastern Cape Alien plants -- Control -- Cost effectiveness -- South Africa -- Eastern Cape Conservation of natural resources -- South Africa -- Eastern Cape Acacia mearnsii -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape Revegetation -- South Africa -- Eastern Cape Restoration ecology -- South Africa -- Eastern Cape Environmental degradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4729 , http://hdl.handle.net/10962/d1001956
- Description: There is little understanding of the implementation efficiency and effectiveness of restoring plant invaded landscapes within operational contexts. South Africa's Working for Water (WfW) programme is arguably the most ambitious alien plant control programme in the world, yet little is known about its cost-effectiveness and the challenges it faces in linking poverty and environmental objectives. My first aim was to assess the cost-effectiveness of invasive plant removal, and the factors that underpin its effectiveness over large spatial and temporal scales. The second aim was to compare the accuracy of evidence-based findings with managers' experience-based beliefs, and to assess whether managers are willing to change their beliefs after being exposed to it. The third aim was to assess the costs and benefits of removal versus removal followed by active native re-vegetation. My final aim is to assess the challenges and lessons learnt by managers linking ecological restoration with poverty alleviation objectives, specifically within the public works model. My study area was focused primarily on two WfW river catchment projects in the western region of the Eastern Cape province. I adopted an interdisciplinary approach drawing from a range of methods such as observational studies, statistical modelling and interviews with managers. The key findings were that control efforts in the two catchment projects are largely inadequate owing to many sites being re-invaded and not enough resources being allocated to the catchments. It would take between 54 and 695 years to clear the respective catchments. In terms of cost-effectiveness, my results exceeded previous estimates by 1.5 to 8.6 times for each catchment project. After being exposed to the evidence-based findings, the managers did not change their beliefs when it came to forecasting the future effectiveness. I found that active native re-vegetation after removal of invasive plants is very costly and that priority should be given to understanding the effectiveness of the removal treatments on native species recovery. The managers cited significant challenges in effectively and efficiently meeting the programmes dual objectives. Based on a broader review of the public works literature I recommend WfW re-examine the type of public works they currently use.
- Full Text:
- Date Issued: 2013
Psychodynamic case formulations : reflections of a neophyte therapist's experiences of how developing and using a psychodynamic formulation may have influenced treatment?
- Authors: Tebbutt, Hayley Lynne
- Date: 2013 , 2013-11-04
- Subjects: Psychodynamic psychotherapy Psychiatry -- Case formulation Eating disorders
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3133 , http://hdl.handle.net/10962/d1006812
- Description: Although it is generally acknowledged and accepted that case formulations are useful in psychotherapy treatment, there is significantly little research illustrating how case formulations are useful in treatment. Research also suggests that case formulations are seldom used in practice after initial training (Eells, 1997; Sim, Gwee, & Bateman, 2005). This research was premised on a particular case study which appeared to highlight shifts in psychotherapy treatment in the sessions directly after the writing or revising of the case formulation, thus prompting the inquiry into the influence of the case formulation on therapeutic work. The research utilised a qualitative methodology and focused on a single case which was a 19 year old university student who expressed a problem with binge eating. The data was drawn from five original and revised case formulations. The participant was seen for 27 therapy sessions, over which time five case formulations were developed and revised. The findings in this study highlight the process of how a psychodynamic case formulation can influence therapeutic work, as reflected in three broad themes of adherence to the case formulation, the confidence of the therapist, and using the formulation as an intervention. The study contributes to arguments for the revival of the case formulation as a necessary therapeutic tool. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
- Authors: Tebbutt, Hayley Lynne
- Date: 2013 , 2013-11-04
- Subjects: Psychodynamic psychotherapy Psychiatry -- Case formulation Eating disorders
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3133 , http://hdl.handle.net/10962/d1006812
- Description: Although it is generally acknowledged and accepted that case formulations are useful in psychotherapy treatment, there is significantly little research illustrating how case formulations are useful in treatment. Research also suggests that case formulations are seldom used in practice after initial training (Eells, 1997; Sim, Gwee, & Bateman, 2005). This research was premised on a particular case study which appeared to highlight shifts in psychotherapy treatment in the sessions directly after the writing or revising of the case formulation, thus prompting the inquiry into the influence of the case formulation on therapeutic work. The research utilised a qualitative methodology and focused on a single case which was a 19 year old university student who expressed a problem with binge eating. The data was drawn from five original and revised case formulations. The participant was seen for 27 therapy sessions, over which time five case formulations were developed and revised. The findings in this study highlight the process of how a psychodynamic case formulation can influence therapeutic work, as reflected in three broad themes of adherence to the case formulation, the confidence of the therapist, and using the formulation as an intervention. The study contributes to arguments for the revival of the case formulation as a necessary therapeutic tool. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
Appraisal of community-based childcare practices in rural Malawi: the case of Malili traditional authority area, Lilongwe District
- Authors: Alufandika, Dina
- Date: 2012
- Subjects: Tribal government -- Malawi , Child welfare -- Malawi , Child development -- Malawi , Child care services -- Malawi , Community development -- Malawi , Rural development -- Malawi , Malawi -- Social policy , Lilongwe (Malawi)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11945 , http://hdl.handle.net/10353/d1005968 , Tribal government -- Malawi , Child welfare -- Malawi , Child development -- Malawi , Child care services -- Malawi , Community development -- Malawi , Rural development -- Malawi , Malawi -- Social policy , Lilongwe (Malawi)
- Description: The government of Malawi established the community based childcare (CBCC) programme with the aim of addressing early childhood problems and achieve national development in the long run. The CBCC programme, as one of the approaches to early childhood development (ECD), is guided by the national early childhood development policy. It promotes some practices that somehow deviate from the traditional childcare ways that communities have always known. Experience has shown that programmes that have elements of conflict with commonly held beliefs are bound to meet with resistance in society. The study employed a mini survey, focus group discussion, observation and document review to understand how the CBCC childcare practices in Malili intersect with commonly held beliefs about childcare as well as how they reflect on the national ECD policy. The study also focused on understanding the perceptions of community members on the CBCC programme. The study revealed that while some aspects of CBCC delivery conform to commonly held beliefs about childcare in the area under study, others diverge from such beliefs. Such convergence and divergence appear to be in line with the propositions of transformalist globalisation theory- one of the perspectives adopted for the study. The study also found that care practices at CBCC are not a true reflection of the national ECD policy as community members’ perceptions, poor community participation, poverty and lack of caregiver training in ECD contribute towards poor quality of care in CBCC, contrary to what is defined in the national ECD policy. The study also found that while both CBCC caregivers and sampled community members perceived the quality of care at the centers as poor, caregivers had a more positive perception towards the CBCC than community members. The study indicated that CBCC are centres of desperation for low economic status communities. Findings from the research have revealed that cultural values and commonly held beliefs, and exposure to new knowledge through globalisation play a role in determining childcare practices as well as perceptions towards them. In this sense the study has indicated that meanings that communities attach to development interventions influence their actions and perceptions towards it.
- Full Text:
- Date Issued: 2012
- Authors: Alufandika, Dina
- Date: 2012
- Subjects: Tribal government -- Malawi , Child welfare -- Malawi , Child development -- Malawi , Child care services -- Malawi , Community development -- Malawi , Rural development -- Malawi , Malawi -- Social policy , Lilongwe (Malawi)
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11945 , http://hdl.handle.net/10353/d1005968 , Tribal government -- Malawi , Child welfare -- Malawi , Child development -- Malawi , Child care services -- Malawi , Community development -- Malawi , Rural development -- Malawi , Malawi -- Social policy , Lilongwe (Malawi)
- Description: The government of Malawi established the community based childcare (CBCC) programme with the aim of addressing early childhood problems and achieve national development in the long run. The CBCC programme, as one of the approaches to early childhood development (ECD), is guided by the national early childhood development policy. It promotes some practices that somehow deviate from the traditional childcare ways that communities have always known. Experience has shown that programmes that have elements of conflict with commonly held beliefs are bound to meet with resistance in society. The study employed a mini survey, focus group discussion, observation and document review to understand how the CBCC childcare practices in Malili intersect with commonly held beliefs about childcare as well as how they reflect on the national ECD policy. The study also focused on understanding the perceptions of community members on the CBCC programme. The study revealed that while some aspects of CBCC delivery conform to commonly held beliefs about childcare in the area under study, others diverge from such beliefs. Such convergence and divergence appear to be in line with the propositions of transformalist globalisation theory- one of the perspectives adopted for the study. The study also found that care practices at CBCC are not a true reflection of the national ECD policy as community members’ perceptions, poor community participation, poverty and lack of caregiver training in ECD contribute towards poor quality of care in CBCC, contrary to what is defined in the national ECD policy. The study also found that while both CBCC caregivers and sampled community members perceived the quality of care at the centers as poor, caregivers had a more positive perception towards the CBCC than community members. The study indicated that CBCC are centres of desperation for low economic status communities. Findings from the research have revealed that cultural values and commonly held beliefs, and exposure to new knowledge through globalisation play a role in determining childcare practices as well as perceptions towards them. In this sense the study has indicated that meanings that communities attach to development interventions influence their actions and perceptions towards it.
- Full Text:
- Date Issued: 2012