Genesis of BIF-hosted hematite iron ore deposits in the central part of the Maremane anticline, Northern Cape Province, South Africa
- Authors: Land, Jarred
- Date: 2014
- Subjects: Hematite -- South Africa -- Northern Cape , Anticlines -- South Africa -- Northern Cape , Geology, Stratigraphic -- Proterozoic , Hydrothermal deposits -- Northern Cape , Rare earth metals -- Northern Cape , Iron ores -- Geology -- Northern Cape , Transvaal Supergroup (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5095 , http://hdl.handle.net/10962/d1020905
- Description: The Paleoproterozoic Transvaal Supergroup in the Northern Cape Province of South Africa is host to high-grade BIF-hosted hematite iron-ore deposits and is the country’s most important source of iron to date. Previous work has failed to provide a robust and all-inclusive genetic model for such deposits in the Transvaal Supergroup; in particular, the role of hydrothermal processes in ore-genesis has not been adequately clarified. Recent studies by the author have produced evidence for hydrothermal alteration in shales (Olifantshoek Supergroup) stratigraphically overlying the iron-ore intervals; this has highlighted the need to reassess current ore-forming models which place residual supergene processes at the core of oregenesis. This thesis focuses on providing new insights into the processes responsible for the genesis of hematite iron ores in the Maremane anticline through the use of newly available exploration drill-core material from the centre of the anticline. The study involved standard mineralogical investigations using transmitted/reflected light microscopy as well as instrumental techniques (XRD, EPMA); and the employment of traditional whole-rock geochemical analysis on samples collected from two boreholes drilled in the centre of the Maremane anticline, Northern Cape Province. Rare earth element analysis (via ICP-MS) and oxygen isotope data from hematite separates complement the whole-rock data. Iron-ore mineralisation examined in this thesis is typified by the dominance of Fe-oxide (as hematite), which reaches whole-rock abundances of up to 98 wt. % Fe₂O₃. Textural and whole-rock geochemical variations in the ores likely reflect a variable protolith, from BIF to Fe-bearing shale. A standard supergene model invoking immobility and residual enrichment of iron is called into question on the basis of the relative degrees of enrichment recorded in the ores with respect to other, traditionally immobile elements during chemical weathering, such as Al₂O₃ and TiO₂. Furthermore, the apparently conservative behaviour of REE in the Fe ore (i.e. low-grade and high-grade iron ore) further emphasises the variable protolith theory. Hydrothermally-induced ferruginisation is suggested to post-date the deposition of the post-Transvaal Olifantshoek shales, and is likely to be linked to a sub-surface transgressive hydrothermal event which indiscriminately transforms both shale and BIF into Fe-ore. A revised, hydrothermal model for the formation of BIF-hosted high-grade hematite iron ore deposits in the central part of the Maremane anticline is proposed, and some ideas of the author for further follow-up research are presented.
- Full Text:
- Date Issued: 2014
- Authors: Land, Jarred
- Date: 2014
- Subjects: Hematite -- South Africa -- Northern Cape , Anticlines -- South Africa -- Northern Cape , Geology, Stratigraphic -- Proterozoic , Hydrothermal deposits -- Northern Cape , Rare earth metals -- Northern Cape , Iron ores -- Geology -- Northern Cape , Transvaal Supergroup (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5095 , http://hdl.handle.net/10962/d1020905
- Description: The Paleoproterozoic Transvaal Supergroup in the Northern Cape Province of South Africa is host to high-grade BIF-hosted hematite iron-ore deposits and is the country’s most important source of iron to date. Previous work has failed to provide a robust and all-inclusive genetic model for such deposits in the Transvaal Supergroup; in particular, the role of hydrothermal processes in ore-genesis has not been adequately clarified. Recent studies by the author have produced evidence for hydrothermal alteration in shales (Olifantshoek Supergroup) stratigraphically overlying the iron-ore intervals; this has highlighted the need to reassess current ore-forming models which place residual supergene processes at the core of oregenesis. This thesis focuses on providing new insights into the processes responsible for the genesis of hematite iron ores in the Maremane anticline through the use of newly available exploration drill-core material from the centre of the anticline. The study involved standard mineralogical investigations using transmitted/reflected light microscopy as well as instrumental techniques (XRD, EPMA); and the employment of traditional whole-rock geochemical analysis on samples collected from two boreholes drilled in the centre of the Maremane anticline, Northern Cape Province. Rare earth element analysis (via ICP-MS) and oxygen isotope data from hematite separates complement the whole-rock data. Iron-ore mineralisation examined in this thesis is typified by the dominance of Fe-oxide (as hematite), which reaches whole-rock abundances of up to 98 wt. % Fe₂O₃. Textural and whole-rock geochemical variations in the ores likely reflect a variable protolith, from BIF to Fe-bearing shale. A standard supergene model invoking immobility and residual enrichment of iron is called into question on the basis of the relative degrees of enrichment recorded in the ores with respect to other, traditionally immobile elements during chemical weathering, such as Al₂O₃ and TiO₂. Furthermore, the apparently conservative behaviour of REE in the Fe ore (i.e. low-grade and high-grade iron ore) further emphasises the variable protolith theory. Hydrothermally-induced ferruginisation is suggested to post-date the deposition of the post-Transvaal Olifantshoek shales, and is likely to be linked to a sub-surface transgressive hydrothermal event which indiscriminately transforms both shale and BIF into Fe-ore. A revised, hydrothermal model for the formation of BIF-hosted high-grade hematite iron ore deposits in the central part of the Maremane anticline is proposed, and some ideas of the author for further follow-up research are presented.
- Full Text:
- Date Issued: 2014
An investigation of issues of privacy, anonymity and multi-factor authentication in an open environment
- Authors: Miles, Shaun Graeme
- Date: 2012-06-20
- Subjects: Electronic data processing departments -- Security measures , Electronic data processing departments , Privacy, Right of , Computer security , Data protection , Computers -- Access control
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4656 , http://hdl.handle.net/10962/d1006653 , Electronic data processing departments -- Security measures , Electronic data processing departments , Privacy, Right of , Computer security , Data protection , Computers -- Access control
- Description: This thesis performs an investigation into issues concerning the broad area ofIdentity and Access Management, with a focus on open environments. Through literature research the issues of privacy, anonymity and access control are identified. The issue of privacy is an inherent problem due to the nature of the digital network environment. Information can be duplicated and modified regardless of the wishes and intentions ofthe owner of that information unless proper measures are taken to secure the environment. Once information is published or divulged on the network, there is very little way of controlling the subsequent usage of that information. To address this issue a model for privacy is presented that follows the user centric paradigm of meta-identity. The lack of anonymity, where security measures can be thwarted through the observation of the environment, is a concern for users and systems. By an attacker observing the communication channel and monitoring the interactions between users and systems over a long enough period of time, it is possible to infer knowledge about the users and systems. This knowledge is used to build an identity profile of potential victims to be used in subsequent attacks. To address the problem, mechanisms for providing an acceptable level of anonymity while maintaining adequate accountability (from a legal standpoint) are explored. In terms of access control, the inherent weakness of single factor authentication mechanisms is discussed. The typical mechanism is the user-name and password pair, which provides a single point of failure. By increasing the factors used in authentication, the amount of work required to compromise the system increases non-linearly. Within an open network, several aspects hinder wide scale adoption and use of multi-factor authentication schemes, such as token management and the impact on usability. The framework is developed from a Utopian point of view, with the aim of being applicable to many situations as opposed to a single specific domain. The framework incorporates multi-factor authentication over multiple paths using mobile phones and GSM networks, and explores the usefulness of such an approach. The models are in tum analysed, providing a discussion into the assumptions made and the problems faced by each model. , Adobe Acrobat Pro 9.5.1 , Adobe Acrobat 9.51 Paper Capture Plug-in
- Full Text:
- Authors: Miles, Shaun Graeme
- Date: 2012-06-20
- Subjects: Electronic data processing departments -- Security measures , Electronic data processing departments , Privacy, Right of , Computer security , Data protection , Computers -- Access control
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4656 , http://hdl.handle.net/10962/d1006653 , Electronic data processing departments -- Security measures , Electronic data processing departments , Privacy, Right of , Computer security , Data protection , Computers -- Access control
- Description: This thesis performs an investigation into issues concerning the broad area ofIdentity and Access Management, with a focus on open environments. Through literature research the issues of privacy, anonymity and access control are identified. The issue of privacy is an inherent problem due to the nature of the digital network environment. Information can be duplicated and modified regardless of the wishes and intentions ofthe owner of that information unless proper measures are taken to secure the environment. Once information is published or divulged on the network, there is very little way of controlling the subsequent usage of that information. To address this issue a model for privacy is presented that follows the user centric paradigm of meta-identity. The lack of anonymity, where security measures can be thwarted through the observation of the environment, is a concern for users and systems. By an attacker observing the communication channel and monitoring the interactions between users and systems over a long enough period of time, it is possible to infer knowledge about the users and systems. This knowledge is used to build an identity profile of potential victims to be used in subsequent attacks. To address the problem, mechanisms for providing an acceptable level of anonymity while maintaining adequate accountability (from a legal standpoint) are explored. In terms of access control, the inherent weakness of single factor authentication mechanisms is discussed. The typical mechanism is the user-name and password pair, which provides a single point of failure. By increasing the factors used in authentication, the amount of work required to compromise the system increases non-linearly. Within an open network, several aspects hinder wide scale adoption and use of multi-factor authentication schemes, such as token management and the impact on usability. The framework is developed from a Utopian point of view, with the aim of being applicable to many situations as opposed to a single specific domain. The framework incorporates multi-factor authentication over multiple paths using mobile phones and GSM networks, and explores the usefulness of such an approach. The models are in tum analysed, providing a discussion into the assumptions made and the problems faced by each model. , Adobe Acrobat Pro 9.5.1 , Adobe Acrobat 9.51 Paper Capture Plug-in
- Full Text:
The biology of commercially important fish species and a preliminary assessment of the fisheries potential of Katse Dam, Lesotho
- Authors: Nthimo, Mokitinyane Francis
- Date: 2000
- Subjects: Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5238 , http://hdl.handle.net/10962/d1005081 , Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Description: The construction of the Katse dam was completed in 1996. The dam started filling in 1995 and reached full capacity in early 1998. It forms part of Phase 1A of the Lesotho Highlands Water Project (LHWP). The main aim of the project is to provide revenue to Lesotho, by transferring water from the catchment of the Senqu (Orange) River in Lesotho to South Africa’s major industrial and population centres. During the implementation of the project, an estimated 130 people were displaced. However, the most serious impact has been the loss of the traditional way of life in the form of arable and grazing land as a consequence of inundation. One of the obligations of the project is to ensure that the standard of living of those affected by the project is not impaired. The Lesotho Highlands Development Authority identified a number of rural development projects, which included fisheries development. This study is an integral part of fisheries development in Lesotho. The aim of this study was to gain an understanding of the biology and the demographics of the fish species in the lake. This information would serve as the basis for the development of a management plan for the sustainable utilisation of the fisheries resources. To achieve this aim, the following specific objectives were addressed: 1. Investigation of the biology of the three principal species. 2. Description of the key population parameters (growth, mortality & recruitment). 3. Investigation of the distribution and relative abundance of the three species. The three principal species in the Katse dam are rainbow trout, Oncorhynchus mykiss, and the two cyprinids, Barbus aeneus and Labeo capensis. Sectioned otoliths were used to age O. mykiss while both otoliths and scales were used to age B. aeneus and L. capensis. Marginal zone analysis revealed that slow growth was experienced in winter for the three species. The maximum-recorded age for both B. aeneus and L. capensis was 12 years while O. mykiss reached 4 years. There was no significant difference in growth rates of the different sexes and growth was best described by the 3 parameter Von-Bertalanfy growth model as Lt = 603[1-e⁻°·¹⁵⁽t ⁺ °·°³⁾] for B. aeneus, Lt = 526[1-e⁻°·²¹⁽t ⁺ °·⁹⁾] for O. mykiss and Lt = 521[1-e⁻°·¹⁷⁽t ⁺ °·²¹⁾] for L.capensis. Male and female O. mykiss attained 50% sexual maturity (Lm₅₀) at 235 and 275mm FL, respectively. There was no difference in Lm₅₀ for male and female B. aeneus and L. capensis. B. aeneus reached sexual maturity at 285mm FL while L. capensis reached sexual maturity at 244mm. Both cyprinid species spawned in summer (November to January) while O. mykiss spawned in winter (May to August). The mean total mortality rate (Z) estimated from catch curves and Butterworth et al (1989) equation was 0.72 yr⁻¹ for B. aeneus, 0.62 yr⁻¹ for L. capensis and 1.32 yr⁻¹ for O. mykiss. The estimate of natural mortality was 0.41 yr⁻¹ for both B. aeneus and L. capensis and 0.81yr⁻¹ for O. mykiss.
- Full Text:
- Date Issued: 2000
- Authors: Nthimo, Mokitinyane Francis
- Date: 2000
- Subjects: Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5238 , http://hdl.handle.net/10962/d1005081 , Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Description: The construction of the Katse dam was completed in 1996. The dam started filling in 1995 and reached full capacity in early 1998. It forms part of Phase 1A of the Lesotho Highlands Water Project (LHWP). The main aim of the project is to provide revenue to Lesotho, by transferring water from the catchment of the Senqu (Orange) River in Lesotho to South Africa’s major industrial and population centres. During the implementation of the project, an estimated 130 people were displaced. However, the most serious impact has been the loss of the traditional way of life in the form of arable and grazing land as a consequence of inundation. One of the obligations of the project is to ensure that the standard of living of those affected by the project is not impaired. The Lesotho Highlands Development Authority identified a number of rural development projects, which included fisheries development. This study is an integral part of fisheries development in Lesotho. The aim of this study was to gain an understanding of the biology and the demographics of the fish species in the lake. This information would serve as the basis for the development of a management plan for the sustainable utilisation of the fisheries resources. To achieve this aim, the following specific objectives were addressed: 1. Investigation of the biology of the three principal species. 2. Description of the key population parameters (growth, mortality & recruitment). 3. Investigation of the distribution and relative abundance of the three species. The three principal species in the Katse dam are rainbow trout, Oncorhynchus mykiss, and the two cyprinids, Barbus aeneus and Labeo capensis. Sectioned otoliths were used to age O. mykiss while both otoliths and scales were used to age B. aeneus and L. capensis. Marginal zone analysis revealed that slow growth was experienced in winter for the three species. The maximum-recorded age for both B. aeneus and L. capensis was 12 years while O. mykiss reached 4 years. There was no significant difference in growth rates of the different sexes and growth was best described by the 3 parameter Von-Bertalanfy growth model as Lt = 603[1-e⁻°·¹⁵⁽t ⁺ °·°³⁾] for B. aeneus, Lt = 526[1-e⁻°·²¹⁽t ⁺ °·⁹⁾] for O. mykiss and Lt = 521[1-e⁻°·¹⁷⁽t ⁺ °·²¹⁾] for L.capensis. Male and female O. mykiss attained 50% sexual maturity (Lm₅₀) at 235 and 275mm FL, respectively. There was no difference in Lm₅₀ for male and female B. aeneus and L. capensis. B. aeneus reached sexual maturity at 285mm FL while L. capensis reached sexual maturity at 244mm. Both cyprinid species spawned in summer (November to January) while O. mykiss spawned in winter (May to August). The mean total mortality rate (Z) estimated from catch curves and Butterworth et al (1989) equation was 0.72 yr⁻¹ for B. aeneus, 0.62 yr⁻¹ for L. capensis and 1.32 yr⁻¹ for O. mykiss. The estimate of natural mortality was 0.41 yr⁻¹ for both B. aeneus and L. capensis and 0.81yr⁻¹ for O. mykiss.
- Full Text:
- Date Issued: 2000
An investigation into the implementation of group work, as a method of social work intervention, in health settings in South Africa
- Authors: Caires, Juliet Margarita
- Date: 1999
- Subjects: Social group work , Community health services -- South Africa , Medical care -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:691 , http://hdl.handle.net/10962/d1006373 , Social group work , Community health services -- South Africa , Medical care -- South Africa
- Description: This research aims to discover whether social workers employed in health settings in South Africa use group work as a method of intervention with patients. It attempts to explore in which hospitals (or particular patient populations) group work is considered possible, and to discover to what extent social workers in health settings consider group work to be beneficial to patients. It also attempts to discover some of the potential difficulties experienced in initiating group work in medical settings. An effort is also made to establish, from social workers active and experienced in the field of medical social work,what place group work might have in the broader context of health services in the future. Data was obtained through the use of mailed questionnaires, which were sent to 186 health settings, across South Africa. These settings were chosen according to the following priorities: i) those known to have social workers ii) services offered (e.g. oncology, psychotherapy) iii) size of the setting iv) geographical location (both urban and rural in all nine provinces). The sample included general public and private hospitals, psychiatric hospitals (both public and private), mining hospitals and other health settings such as old age homes and facilities for the mentally retarded and for alcohol and drug rehabilitation (accompanied by a medical facility). Responses were received from 90 health settings, with 64 of these being completed questionnaires. The majority of responses came from public hospitals, and the least from the mining hospital category. Findings of this study indicate that group work is used by 50% of the health settings in South Africa. Groups are most often therapeutic or educational in nature, are run on average once a week for an hour, and are usually of open membership. Group work is not used in some health settings, most commonly due to insufficient time (on the part of the social worker). From the findings, it seems that many more social workers would like to run groups for patients than they do presently. The benefits of group work are acknowledged by the majority of this study's sample of social workers, and if solutions could be found to problems such as heavy caseloads and insufficient time, more social workers would choose to use group work than are doing so currently. Group work is considered to be a feasible method, both in the hospitals and at primary health care level. With South Africa's growing emphasis on primary health care, and the proposed inclusion (by the Department of Health) of social work services at this level, it is important that social workers find a way in which to meet the needs of patients at both levels. With group work, this may be possible.
- Full Text:
- Date Issued: 1999
- Authors: Caires, Juliet Margarita
- Date: 1999
- Subjects: Social group work , Community health services -- South Africa , Medical care -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:691 , http://hdl.handle.net/10962/d1006373 , Social group work , Community health services -- South Africa , Medical care -- South Africa
- Description: This research aims to discover whether social workers employed in health settings in South Africa use group work as a method of intervention with patients. It attempts to explore in which hospitals (or particular patient populations) group work is considered possible, and to discover to what extent social workers in health settings consider group work to be beneficial to patients. It also attempts to discover some of the potential difficulties experienced in initiating group work in medical settings. An effort is also made to establish, from social workers active and experienced in the field of medical social work,what place group work might have in the broader context of health services in the future. Data was obtained through the use of mailed questionnaires, which were sent to 186 health settings, across South Africa. These settings were chosen according to the following priorities: i) those known to have social workers ii) services offered (e.g. oncology, psychotherapy) iii) size of the setting iv) geographical location (both urban and rural in all nine provinces). The sample included general public and private hospitals, psychiatric hospitals (both public and private), mining hospitals and other health settings such as old age homes and facilities for the mentally retarded and for alcohol and drug rehabilitation (accompanied by a medical facility). Responses were received from 90 health settings, with 64 of these being completed questionnaires. The majority of responses came from public hospitals, and the least from the mining hospital category. Findings of this study indicate that group work is used by 50% of the health settings in South Africa. Groups are most often therapeutic or educational in nature, are run on average once a week for an hour, and are usually of open membership. Group work is not used in some health settings, most commonly due to insufficient time (on the part of the social worker). From the findings, it seems that many more social workers would like to run groups for patients than they do presently. The benefits of group work are acknowledged by the majority of this study's sample of social workers, and if solutions could be found to problems such as heavy caseloads and insufficient time, more social workers would choose to use group work than are doing so currently. Group work is considered to be a feasible method, both in the hospitals and at primary health care level. With South Africa's growing emphasis on primary health care, and the proposed inclusion (by the Department of Health) of social work services at this level, it is important that social workers find a way in which to meet the needs of patients at both levels. With group work, this may be possible.
- Full Text:
- Date Issued: 1999
Insubordination in the workplace
- Authors: Chadd, Kevin Mark
- Date: 1999
- Subjects: Employees -- Dismissal of -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3668 , http://hdl.handle.net/10962/d1003183 , Employees -- Dismissal of -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa
- Description: This thesis traces the development of insubordination in the employment relationship. The essence of the relationship is that the employee, by contracting out his or her productive capacity, occupies a subordinate position. The primary aim is to locate and define the nature of subordination and to investigate how the breach of this position would justify dismissal as interpreted and applied by the courts. This is achieved by investigating dismissal for insubordination under the common law contract of employment, the unfair labour practice jurisdiction and the 1995 Labour Relations Act. Initially the obligation of the employee to be subordinate, an essential term of the contract of employment, is located and defined by using the tests of Control, Organisation and Dominant Impression, which theoretically indicate the true nature of insubordination. Insubordination under the common law is equated with disobedience to the lawful and reasonable instructions of the employer which were given in good faith and fell squarely within the contractual relationship. Insubordination under the unfair labour practice jurisdiction was equated with a challenge to the authority of the employer of which disobedience was a manifestation of such intention. Instructions given by the employer under the unfair labour practice jurisdiction had to be lawful, reasonable and fair. What was fair depended on the surrounding circumstances of the dismissal and a wilful and unreasonable refusal of the employee to obey the valid instructions of the employer justified dismissal Under the 1995 Labour Relations Act it is submitted that insubordination will be dealt with in essentially the same manner as under the previous jurisdiction, subject to the Act's objectives and purposes. The disobedience of the employee is to be tolerated if that employee is attempting to achieve the Act's objectives, and any dismissal as a result of the disobedience could be unfair, because the employer's conduct fiustrates the purpose of the Act. Therefore, the contractual right of the employer to expect subordination from the employee may have been whittled away to such an extent over time that it seems superficial to regard subordination as an essential term of the contract of employment.
- Full Text:
- Date Issued: 1999
- Authors: Chadd, Kevin Mark
- Date: 1999
- Subjects: Employees -- Dismissal of -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3668 , http://hdl.handle.net/10962/d1003183 , Employees -- Dismissal of -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa
- Description: This thesis traces the development of insubordination in the employment relationship. The essence of the relationship is that the employee, by contracting out his or her productive capacity, occupies a subordinate position. The primary aim is to locate and define the nature of subordination and to investigate how the breach of this position would justify dismissal as interpreted and applied by the courts. This is achieved by investigating dismissal for insubordination under the common law contract of employment, the unfair labour practice jurisdiction and the 1995 Labour Relations Act. Initially the obligation of the employee to be subordinate, an essential term of the contract of employment, is located and defined by using the tests of Control, Organisation and Dominant Impression, which theoretically indicate the true nature of insubordination. Insubordination under the common law is equated with disobedience to the lawful and reasonable instructions of the employer which were given in good faith and fell squarely within the contractual relationship. Insubordination under the unfair labour practice jurisdiction was equated with a challenge to the authority of the employer of which disobedience was a manifestation of such intention. Instructions given by the employer under the unfair labour practice jurisdiction had to be lawful, reasonable and fair. What was fair depended on the surrounding circumstances of the dismissal and a wilful and unreasonable refusal of the employee to obey the valid instructions of the employer justified dismissal Under the 1995 Labour Relations Act it is submitted that insubordination will be dealt with in essentially the same manner as under the previous jurisdiction, subject to the Act's objectives and purposes. The disobedience of the employee is to be tolerated if that employee is attempting to achieve the Act's objectives, and any dismissal as a result of the disobedience could be unfair, because the employer's conduct fiustrates the purpose of the Act. Therefore, the contractual right of the employer to expect subordination from the employee may have been whittled away to such an extent over time that it seems superficial to regard subordination as an essential term of the contract of employment.
- Full Text:
- Date Issued: 1999
Removal of lead from solution by the non-viable biomass of the water fern Azolla filiculoides
- Authors: Sanyahumbi, Douglas
- Date: 1999
- Subjects: Azolla , Heavy metals -- Absorption and adsorption , Lead , Water -- Purification -- Biological treatment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3901 , http://hdl.handle.net/10962/d1003960 , Azolla , Heavy metals -- Absorption and adsorption , Lead , Water -- Purification -- Biological treatment
- Description: The removal of lead from aqueous solution and lead-acid battery manufacturing waste-water by the non-viable biomass of the water fern Azolla filiculoides was investigated in both batch and column reactors. The maximum lead uptake by the Azolla biomass at a pH value of approximately 5, was found to be 100 mg lead/g biomass from aqueous solution. Lead removal varied from 30% of the initial lead concentration at pH 1.5 to approximately 95% at pH values of 3.5 and 5.6. Lead removal from aqueous solution decreased to 30% of the initial lead concentration if the lead concentration was initially over 400 mg/l. At initial lead concentrations of less than 400 mg/l, percentage lead removal was found to be over 90% of the initial lead concentration. Lead removal remained at approximately 90% between 10°C and 50°C. Biomass concentration (4-8 mg/l) had little effect on lead removal. The presence of iron (Fe) and lead, copper (Cu) and lead or all three metal ions in solution at varying ratios to each other did not appear to have any significant effect on lead removal. Percentage lead, copper and iron removal from aqueous solution was 80-95, 45-50 and 65-75% respectively for the different multiple-metal solutions studied. No break-through points were observed for lead removal from aqueous solutions in column reactors, with initial lead concentrations of less than 100 mg/l at varying flow rates of 2, 5 and 10 ml/min. This suggested that flow rate, and therefore retention time, had little effect on percentage lead removal from aqueous solution, which was more that 95%, at low initial lead concentrations (less than 100 mg/l). At initial lead concentrations of 200 mg/l or more, an increase in flow rate, which equates to a decrease in column retention time, resulted in break-through points occurring earlier in the column run. Percentage lead removal values, from lead-acid battery efiluent in column systems, of over 95% were achieved. Desorption of approximately 30% and 40% of bound lead was achieved, with 0.5 M HNO₃ in a volume of 50 ml, from two lead-acid battery. Repeated adsorption and desorption of lead by the Azalia biomass over 10 cycles did not result in any decrease in the percentage lead removal from effluent, which strongly suggested that the Azalla biomass could be re-used a number of times without deterioration in its physical integrity, or lead removal capacity. No evidence of deterioration in the Azolla biomass's physical integrity after 10 successive adsorption and desorption procedures was observed using scanning electron microscopy. The Azolla filiculoides biomass was, therefore, found to be able to effectively remove lead from aqueous solution and lead-acid battery effluent repeatedly, with no observed reduction in it's uptake capacity or physical integrity.
- Full Text:
- Date Issued: 1999
- Authors: Sanyahumbi, Douglas
- Date: 1999
- Subjects: Azolla , Heavy metals -- Absorption and adsorption , Lead , Water -- Purification -- Biological treatment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3901 , http://hdl.handle.net/10962/d1003960 , Azolla , Heavy metals -- Absorption and adsorption , Lead , Water -- Purification -- Biological treatment
- Description: The removal of lead from aqueous solution and lead-acid battery manufacturing waste-water by the non-viable biomass of the water fern Azolla filiculoides was investigated in both batch and column reactors. The maximum lead uptake by the Azolla biomass at a pH value of approximately 5, was found to be 100 mg lead/g biomass from aqueous solution. Lead removal varied from 30% of the initial lead concentration at pH 1.5 to approximately 95% at pH values of 3.5 and 5.6. Lead removal from aqueous solution decreased to 30% of the initial lead concentration if the lead concentration was initially over 400 mg/l. At initial lead concentrations of less than 400 mg/l, percentage lead removal was found to be over 90% of the initial lead concentration. Lead removal remained at approximately 90% between 10°C and 50°C. Biomass concentration (4-8 mg/l) had little effect on lead removal. The presence of iron (Fe) and lead, copper (Cu) and lead or all three metal ions in solution at varying ratios to each other did not appear to have any significant effect on lead removal. Percentage lead, copper and iron removal from aqueous solution was 80-95, 45-50 and 65-75% respectively for the different multiple-metal solutions studied. No break-through points were observed for lead removal from aqueous solutions in column reactors, with initial lead concentrations of less than 100 mg/l at varying flow rates of 2, 5 and 10 ml/min. This suggested that flow rate, and therefore retention time, had little effect on percentage lead removal from aqueous solution, which was more that 95%, at low initial lead concentrations (less than 100 mg/l). At initial lead concentrations of 200 mg/l or more, an increase in flow rate, which equates to a decrease in column retention time, resulted in break-through points occurring earlier in the column run. Percentage lead removal values, from lead-acid battery efiluent in column systems, of over 95% were achieved. Desorption of approximately 30% and 40% of bound lead was achieved, with 0.5 M HNO₃ in a volume of 50 ml, from two lead-acid battery. Repeated adsorption and desorption of lead by the Azalia biomass over 10 cycles did not result in any decrease in the percentage lead removal from effluent, which strongly suggested that the Azalla biomass could be re-used a number of times without deterioration in its physical integrity, or lead removal capacity. No evidence of deterioration in the Azolla biomass's physical integrity after 10 successive adsorption and desorption procedures was observed using scanning electron microscopy. The Azolla filiculoides biomass was, therefore, found to be able to effectively remove lead from aqueous solution and lead-acid battery effluent repeatedly, with no observed reduction in it's uptake capacity or physical integrity.
- Full Text:
- Date Issued: 1999
An evaluation of small scale open cast mining of UG2 in the Bushveld complex
- Authors: Mooney, David G
- Date: 1997
- Subjects: Platinum mines and mining -- South Africa , Strip mining -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4943 , http://hdl.handle.net/10962/d1005555 , Platinum mines and mining -- South Africa , Strip mining -- South Africa
- Description: The current weak state of the platinum market, as well as the large inventory of platinum group metals held by Russia, necessitates that the South African platinum mining industry must carefully evaluate the benefits and disadvantage of small-scale mining of shallow, open castable ore resources. Until the late 1980's, these resources were ignored due to the metallurgical complexities of treating oxidized ore, as well as the mind set that existed within the South African mining industry which militated against open cast mining in the Bushveld. During the latter part of the 1980's and early 1990's, advances in the metallurgical treatment of oxidized ore, specifically the UG2, as well as operational problems, created the impetus to begin the exploitation of these resources. Small-scale open cast mining has become viable due to the development of suitable mining methods that facilitate mining practices acceptable to the Department of Mineral and Energy Affairs, in terms of environmental legislation. Metallurgical advances and growing experience, especially with respect to the UG2, enables reasonable platinum group metals recovery from oxidized ore. The problems experienced in doing this can, and are being overcome. With growing public awareness of environmental issues, particularly related to the mining industry, the requirement to ensure that the small-scale open cast mine site is well managed is paramount. A methodology for the evaluation is presented along with a case study of a small-scale UG2 open cast pit. Evidence is presented that shows that these small-scale open cast mining operations are extremely profitable and require minimal capital expenditure. However, caution is advised when evaluating Merensky Reef open cast operations because of the problems that they present.
- Full Text:
- Date Issued: 1997
- Authors: Mooney, David G
- Date: 1997
- Subjects: Platinum mines and mining -- South Africa , Strip mining -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4943 , http://hdl.handle.net/10962/d1005555 , Platinum mines and mining -- South Africa , Strip mining -- South Africa
- Description: The current weak state of the platinum market, as well as the large inventory of platinum group metals held by Russia, necessitates that the South African platinum mining industry must carefully evaluate the benefits and disadvantage of small-scale mining of shallow, open castable ore resources. Until the late 1980's, these resources were ignored due to the metallurgical complexities of treating oxidized ore, as well as the mind set that existed within the South African mining industry which militated against open cast mining in the Bushveld. During the latter part of the 1980's and early 1990's, advances in the metallurgical treatment of oxidized ore, specifically the UG2, as well as operational problems, created the impetus to begin the exploitation of these resources. Small-scale open cast mining has become viable due to the development of suitable mining methods that facilitate mining practices acceptable to the Department of Mineral and Energy Affairs, in terms of environmental legislation. Metallurgical advances and growing experience, especially with respect to the UG2, enables reasonable platinum group metals recovery from oxidized ore. The problems experienced in doing this can, and are being overcome. With growing public awareness of environmental issues, particularly related to the mining industry, the requirement to ensure that the small-scale open cast mine site is well managed is paramount. A methodology for the evaluation is presented along with a case study of a small-scale UG2 open cast pit. Evidence is presented that shows that these small-scale open cast mining operations are extremely profitable and require minimal capital expenditure. However, caution is advised when evaluating Merensky Reef open cast operations because of the problems that they present.
- Full Text:
- Date Issued: 1997
South Africa's post-apartheid foreign policy : towards a diplomacy of trade
- Authors: Dullabh, Nitesh Amratlal
- Date: 1994
- Subjects: Foreign trade regulation -- South Africa , South Africa -- Foreign relations
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2774 , http://hdl.handle.net/10962/d1002984 , Foreign trade regulation -- South Africa , South Africa -- Foreign relations
- Description: This thesis attempts to argue that a post-apartheid foreign policy will no longer be based on seeking legitimacy for the South African Government. Instead, it argues that if South Africa wants to grow, both domestically and nternationally, it will be imperative for it (South Africa) to move from an import substitution trade policy to an export-oriented trade policy. It is further suggested that the export-led strategy will be an important component for the promotion of South African international trade in the post-Cold War era. South Africa cannot improve the status of its trade regime by its own doing. It will require the support and assistance of international organizations and hence, the international community. Following the principles, rules and procedures of the General Agreement on Tariffs and Trade (GATT); it is argued, will help South Africa reconstruct its trade policies on the basis that they are free, fair and above all competitive. Furthermore, maintaining a constantly favourable relationship with the international community will allow easy access to international markets for South African goods and services, and eventually the smooth integration of the South African economy in the international political economy. This study, noting the importance of trade with a dedicated commitment to exports, concludes that although exports would flourish, there will be an immediate need for diplomats to be conversant with contemporary international trade developments. This would require diplomats to be innovative, steadfast and disciplined in their day-to-day negotiations. In the final instance, the role of trade in South Africa's future will ultimately be determined by its trade postures and the type of diplomacy to be used by its diplomats.
- Full Text:
- Date Issued: 1994
- Authors: Dullabh, Nitesh Amratlal
- Date: 1994
- Subjects: Foreign trade regulation -- South Africa , South Africa -- Foreign relations
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2774 , http://hdl.handle.net/10962/d1002984 , Foreign trade regulation -- South Africa , South Africa -- Foreign relations
- Description: This thesis attempts to argue that a post-apartheid foreign policy will no longer be based on seeking legitimacy for the South African Government. Instead, it argues that if South Africa wants to grow, both domestically and nternationally, it will be imperative for it (South Africa) to move from an import substitution trade policy to an export-oriented trade policy. It is further suggested that the export-led strategy will be an important component for the promotion of South African international trade in the post-Cold War era. South Africa cannot improve the status of its trade regime by its own doing. It will require the support and assistance of international organizations and hence, the international community. Following the principles, rules and procedures of the General Agreement on Tariffs and Trade (GATT); it is argued, will help South Africa reconstruct its trade policies on the basis that they are free, fair and above all competitive. Furthermore, maintaining a constantly favourable relationship with the international community will allow easy access to international markets for South African goods and services, and eventually the smooth integration of the South African economy in the international political economy. This study, noting the importance of trade with a dedicated commitment to exports, concludes that although exports would flourish, there will be an immediate need for diplomats to be conversant with contemporary international trade developments. This would require diplomats to be innovative, steadfast and disciplined in their day-to-day negotiations. In the final instance, the role of trade in South Africa's future will ultimately be determined by its trade postures and the type of diplomacy to be used by its diplomats.
- Full Text:
- Date Issued: 1994
The exploration for and possible genesis of, some Archaean granite/gneiss-hosted gold deposits in the Pietersburg granite-greenstone terrane
- Linklater, Michael Anthony Leonard Flanders
- Authors: Linklater, Michael Anthony Leonard Flanders
- Date: 1992
- Subjects: Gold ores -- Geology -- South Africa , Gneiss , Granite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4945 , http://hdl.handle.net/10962/d1005557 , Gold ores -- Geology -- South Africa , Gneiss , Granite
- Description: Abstract The gold mineralization event within Archaean granite-greenstone terranes occurred during the late Archaean, and followed the intrusion of syn- to late-tectonic granitic plutons into previously deformed greenstone belts. An Archaean granite/gneiss-hosted gold deposit, in terms of this project, is classified as having a gold-assay cutoff of 1g/metric ton over widths of at least several metres, or higher grades over narrower widths and/or verbal descriptions that indicate such values. Fluid inclusion studies and isotopic data identify two possible origins for the auriferous fluids; namely magmatic and metamorphic. The exploration target according to the magmatic model, is a late-Archaean, hydrothermally altered, mineralized and fractured granitic intrusion preferably with a granodioritic or quartz-dioritic composition. The exploration target according to the metamorphic replacement model is a granitic stock that has intruded a zone of crustal weakness such as a shear zone, active during the late Archaean. Alternatively, the granitic intrusion should be affected by regionally extensive late-Archaean shearing. It should be hydrothermally altered, deformed and mineralized. Five areas within the Pietersburg granite-greenstone terrane were selected for the 'Regional Area Selection' phase of exploration for Archaean granite/gneiss-hosted gold deposits; namely Roodepoort, Waterval, Ramagoep, Moletsie and Matlala. Roodepoort contains a known granodiorite-hosted gold deposit; the Knight's Pluton, and served as an orientation survey for this project. The use and interpretation of LANDSAT images formed an integral part of exploration techniques; to assess their usefulness in the exploration of Archaean granite/gneiss-hosted gold deposits. Area selection criteria for granite/gneiss-hosted gold mineralization at Roodepoort are the major ENE-trending shear zone, the NNW-trending lineament and hydrothermal alteration, shearing, quartz-stockworks and sulphide mineralization within the Knight's Pluton. The origin of the gold within the Knight's Pluton is uncertain; both magmatic and metamorphic models are possibilities. Ongoing exploration is in progress at Roodepoort. The only area selection criterion for granite/gneiss-hosted gold mineralization at Waterval is the sericitized, subcropping granites located within trenches. Gold mineralization is insignificant. No area selection criteria for Archaean granite/gneiss-hosted gold mineralization were located at Ramagoep, Matlala and Moletsie. No further exploration is recommended for all these areas. The MES image interpretations were successful in identifying lineaments, granitic outcrops, greenstones, vegetation and soil cover. The Clay-iron images adequately differentiated betweeen iron-rich and clay-bearing areas. However, not all clay-bearing areas were associated with hydrothermal alteratian; field checks were necessary to discriminate between weathered granites and hydrothermally altered granites. The Wallis images served to locally enhance the contrasts of the MES and Clay-iron images.
- Full Text:
- Date Issued: 1992
- Authors: Linklater, Michael Anthony Leonard Flanders
- Date: 1992
- Subjects: Gold ores -- Geology -- South Africa , Gneiss , Granite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4945 , http://hdl.handle.net/10962/d1005557 , Gold ores -- Geology -- South Africa , Gneiss , Granite
- Description: Abstract The gold mineralization event within Archaean granite-greenstone terranes occurred during the late Archaean, and followed the intrusion of syn- to late-tectonic granitic plutons into previously deformed greenstone belts. An Archaean granite/gneiss-hosted gold deposit, in terms of this project, is classified as having a gold-assay cutoff of 1g/metric ton over widths of at least several metres, or higher grades over narrower widths and/or verbal descriptions that indicate such values. Fluid inclusion studies and isotopic data identify two possible origins for the auriferous fluids; namely magmatic and metamorphic. The exploration target according to the magmatic model, is a late-Archaean, hydrothermally altered, mineralized and fractured granitic intrusion preferably with a granodioritic or quartz-dioritic composition. The exploration target according to the metamorphic replacement model is a granitic stock that has intruded a zone of crustal weakness such as a shear zone, active during the late Archaean. Alternatively, the granitic intrusion should be affected by regionally extensive late-Archaean shearing. It should be hydrothermally altered, deformed and mineralized. Five areas within the Pietersburg granite-greenstone terrane were selected for the 'Regional Area Selection' phase of exploration for Archaean granite/gneiss-hosted gold deposits; namely Roodepoort, Waterval, Ramagoep, Moletsie and Matlala. Roodepoort contains a known granodiorite-hosted gold deposit; the Knight's Pluton, and served as an orientation survey for this project. The use and interpretation of LANDSAT images formed an integral part of exploration techniques; to assess their usefulness in the exploration of Archaean granite/gneiss-hosted gold deposits. Area selection criteria for granite/gneiss-hosted gold mineralization at Roodepoort are the major ENE-trending shear zone, the NNW-trending lineament and hydrothermal alteration, shearing, quartz-stockworks and sulphide mineralization within the Knight's Pluton. The origin of the gold within the Knight's Pluton is uncertain; both magmatic and metamorphic models are possibilities. Ongoing exploration is in progress at Roodepoort. The only area selection criterion for granite/gneiss-hosted gold mineralization at Waterval is the sericitized, subcropping granites located within trenches. Gold mineralization is insignificant. No area selection criteria for Archaean granite/gneiss-hosted gold mineralization were located at Ramagoep, Matlala and Moletsie. No further exploration is recommended for all these areas. The MES image interpretations were successful in identifying lineaments, granitic outcrops, greenstones, vegetation and soil cover. The Clay-iron images adequately differentiated betweeen iron-rich and clay-bearing areas. However, not all clay-bearing areas were associated with hydrothermal alteratian; field checks were necessary to discriminate between weathered granites and hydrothermally altered granites. The Wallis images served to locally enhance the contrasts of the MES and Clay-iron images.
- Full Text:
- Date Issued: 1992
The contribution of Spartina Maratima (Curtis) Fernald to the primary production of the Swartkops estuary
- Authors: Pierce, Shirley May
- Date: 1979
- Subjects: Estuarine biology -- South Africa -- Swartkops River Estuary , Spartina
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4174 , http://hdl.handle.net/10962/d1002022 , Estuarine biology -- South Africa -- Swartkops River Estuary , Spartina
- Description: The primary production of Spartina maritima, the dominant macrophyte of the intertidal salt marshes of the Swartkops estuary, was determined for inclusion into the proposed ecosystem model. Several methods for measuring net production devised for North temperate Spartina species were used, as no single method was considered reliable for the local species. In addition, a new method was devised to take into account the aseasonal growth behaviour of S. maritima . Most energy for growth appears to be directed into leaf production, rather than shoot growth. Live net production values were 523-680 g m⁻² yr ⁻¹, which are generally lower than estimates of N. American Spartina species. Total Live production of S. maritima for the whole Swartkops estuary was 495,6 x I0³kg yr ⁻¹, which is an estimation of potential food resources. Formation of S. maritima detritus by decomposition was significantly related to air and water temperatures. Thus detritus production showed a wide seasonal variation about a mean of 374 g m⁻² yr⁻¹. The total S. maritima detritus production of 307,5 x I0³kg for the whole Swartkops estuary was determined as an estimate of available food resources. Export of detrital material from Spartina marshes to estuarine waters was negligible. Even during a maximal Equinoctial tide, only 6,26 dry g m⁻² detritus was exported from the creek catchment area of Spartina stands. This study has shown that concepts evolved for North temperate estuaries should be carefully considered before being applied to local situations, particularly in view of the relatively low, aseasonal production of S. maritima and the negligible contribution of its detritus to estuarine waters. Furthermore, it is essential that utilisation of primary production by secondary producers be determined before the function of the estuarine ecosystem may be understood
- Full Text:
- Date Issued: 1979
- Authors: Pierce, Shirley May
- Date: 1979
- Subjects: Estuarine biology -- South Africa -- Swartkops River Estuary , Spartina
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4174 , http://hdl.handle.net/10962/d1002022 , Estuarine biology -- South Africa -- Swartkops River Estuary , Spartina
- Description: The primary production of Spartina maritima, the dominant macrophyte of the intertidal salt marshes of the Swartkops estuary, was determined for inclusion into the proposed ecosystem model. Several methods for measuring net production devised for North temperate Spartina species were used, as no single method was considered reliable for the local species. In addition, a new method was devised to take into account the aseasonal growth behaviour of S. maritima . Most energy for growth appears to be directed into leaf production, rather than shoot growth. Live net production values were 523-680 g m⁻² yr ⁻¹, which are generally lower than estimates of N. American Spartina species. Total Live production of S. maritima for the whole Swartkops estuary was 495,6 x I0³kg yr ⁻¹, which is an estimation of potential food resources. Formation of S. maritima detritus by decomposition was significantly related to air and water temperatures. Thus detritus production showed a wide seasonal variation about a mean of 374 g m⁻² yr⁻¹. The total S. maritima detritus production of 307,5 x I0³kg for the whole Swartkops estuary was determined as an estimate of available food resources. Export of detrital material from Spartina marshes to estuarine waters was negligible. Even during a maximal Equinoctial tide, only 6,26 dry g m⁻² detritus was exported from the creek catchment area of Spartina stands. This study has shown that concepts evolved for North temperate estuaries should be carefully considered before being applied to local situations, particularly in view of the relatively low, aseasonal production of S. maritima and the negligible contribution of its detritus to estuarine waters. Furthermore, it is essential that utilisation of primary production by secondary producers be determined before the function of the estuarine ecosystem may be understood
- Full Text:
- Date Issued: 1979
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