Introducing chemistry students to the “real world” of chemistry
- Brown, Michael E, Cosser, Ronald C, Davies-Coleman, Michael T, Kaye, Perry T, Klein, Rosalyn, Lamprecht, Emmanuel, Lobb, Kevin A, Nyokong, Tebello, Sewry, Joyce D, Tshentu, Zenixole R, van der Zeyde, Tino, Watkins, Gareth M
- Authors: Brown, Michael E , Cosser, Ronald C , Davies-Coleman, Michael T , Kaye, Perry T , Klein, Rosalyn , Lamprecht, Emmanuel , Lobb, Kevin A , Nyokong, Tebello , Sewry, Joyce D , Tshentu, Zenixole R , van der Zeyde, Tino , Watkins, Gareth M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449360 , vital:74814 , xlink:href="https://doi.org/10.1021/ed8001539"
- Description: A majority of chemistry graduates seek employment in a rapidly changing chemical industry. Our attempts to provide the graduates with skills in entrepreneurship and the ability to understand and communicate with their chemical engineering colleagues, in addition to their fundamental knowledge of chemistry, are described. This is done at second-year level with practical projects in which student teams formulate and prepare relatively simple chemical products for marketing, followed a year later by a more advanced study of the feasibility of producing and marketing a fine chemical on a commercial scale.
- Full Text:
- Date Issued: 2010
- Authors: Brown, Michael E , Cosser, Ronald C , Davies-Coleman, Michael T , Kaye, Perry T , Klein, Rosalyn , Lamprecht, Emmanuel , Lobb, Kevin A , Nyokong, Tebello , Sewry, Joyce D , Tshentu, Zenixole R , van der Zeyde, Tino , Watkins, Gareth M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449360 , vital:74814 , xlink:href="https://doi.org/10.1021/ed8001539"
- Description: A majority of chemistry graduates seek employment in a rapidly changing chemical industry. Our attempts to provide the graduates with skills in entrepreneurship and the ability to understand and communicate with their chemical engineering colleagues, in addition to their fundamental knowledge of chemistry, are described. This is done at second-year level with practical projects in which student teams formulate and prepare relatively simple chemical products for marketing, followed a year later by a more advanced study of the feasibility of producing and marketing a fine chemical on a commercial scale.
- Full Text:
- Date Issued: 2010
Klaas Koen: identity and belonging in the Berlin Mission Society during the late nineteenth century
- Authors: Kirkaldy, Alan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/450085 , vital:74881 , https://www.scielo.org.za/pdf/hist/v55n2/v55n2a10.pdf
- Description: Klaas Koen should not have belonged. Of Khoisan descent, he wasn’t German, he wasn’t white, and he came from the “wrong” class background to be a missionary.(Indeed, as Elizabeth Elbourne has demonstrated, by the 1830s, many white settlers in the Cape–and some missionaries–saw the Khoikhoi as being sub-human and dismissed missionary notions of the “reclaimability” of those who converted to Christianity. 1) However, after his training in Berlin, Koen became so German that he sat in tears on his first Christmas at his own mission station in South Africa. There was no Christmas tree decorated with candles in German style. Koen died a “blessed death” in the service of the Berlin Mission Society. A tract was produced about his life. This article examines the life history of this man and explores why the mission society treated him, wrote about him, and remembered him as they did. It also suggests some reasons why the young missionary may have made the choices that he did. It concludes with an examination of some aspects of his posthumous identity.
- Full Text:
- Date Issued: 2010
- Authors: Kirkaldy, Alan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/450085 , vital:74881 , https://www.scielo.org.za/pdf/hist/v55n2/v55n2a10.pdf
- Description: Klaas Koen should not have belonged. Of Khoisan descent, he wasn’t German, he wasn’t white, and he came from the “wrong” class background to be a missionary.(Indeed, as Elizabeth Elbourne has demonstrated, by the 1830s, many white settlers in the Cape–and some missionaries–saw the Khoikhoi as being sub-human and dismissed missionary notions of the “reclaimability” of those who converted to Christianity. 1) However, after his training in Berlin, Koen became so German that he sat in tears on his first Christmas at his own mission station in South Africa. There was no Christmas tree decorated with candles in German style. Koen died a “blessed death” in the service of the Berlin Mission Society. A tract was produced about his life. This article examines the life history of this man and explores why the mission society treated him, wrote about him, and remembered him as they did. It also suggests some reasons why the young missionary may have made the choices that he did. It concludes with an examination of some aspects of his posthumous identity.
- Full Text:
- Date Issued: 2010
Land price premiums in South Africa's land redistribution process: a case study of Northern Kwazulu-Natal sugarcane farms
- Mbatha, Cyril N, Antrobus, Geoffrey G, Van Rooyen, Jonathan
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G , Van Rooyen, Jonathan
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142980 , vital:38182 , DOI: 10.1080/03031853.2010.491298
- Description: The desire to transfer 30 per cent of commercial farmland into the hands of black South Africans has progressed slower than anticipated. Politicians and government officials have blamed the market approach to the purchase of land for the challenges and failures in the process. An analysis of the transfer of sugarcane land in two districts in KwaZulu-Natal over the period 2000 to 2006 permitted a comparison of the prices paid to commercial farmers both in private transactions and in the case of sales to government. Data did not support the contention that the slow rate of transfer was due to a manipulation of land prices by landowners in an attempt to stall the process. It was concluded that the state lost most of its bargaining power in the land reform market due to the drawn out nature of the land valuation processes.
- Full Text:
- Date Issued: 2010
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G , Van Rooyen, Jonathan
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142980 , vital:38182 , DOI: 10.1080/03031853.2010.491298
- Description: The desire to transfer 30 per cent of commercial farmland into the hands of black South Africans has progressed slower than anticipated. Politicians and government officials have blamed the market approach to the purchase of land for the challenges and failures in the process. An analysis of the transfer of sugarcane land in two districts in KwaZulu-Natal over the period 2000 to 2006 permitted a comparison of the prices paid to commercial farmers both in private transactions and in the case of sales to government. Data did not support the contention that the slow rate of transfer was due to a manipulation of land prices by landowners in an attempt to stall the process. It was concluded that the state lost most of its bargaining power in the land reform market due to the drawn out nature of the land valuation processes.
- Full Text:
- Date Issued: 2010
Learning to be original
- Authors: Wright, Laurence
- Date: 2010
- Language: English
- Type: text , article
- Identifier: vital:7065 , http://hdl.handle.net/10962/d1007431
- Description: preprint , My topic suggested itself in response to a point made at a seminar on University autonomy. Someone observed that many people, even shack dwellers, are interested in the cosmos and they always would be. The remark came in the course of a debate concerning the cost of the SKA project, the massively expensive square kilometer array telescope for which South Africa is bidding against Australia, viewed in relation to the country’s huge list of social backlogs: Big science versus food and decent housing; a false opposition, or a grim choice? You can imagine the debate. The nugget that stayed with me was the tangential comment that ordinary people are always interested in the cosmos. If so, is this true merely because human cultures traditionally incorporate such an interest, or because humans themselves actually need a relation to the cosmos? What might this need be?
- Full Text:
- Date Issued: 2010
- Authors: Wright, Laurence
- Date: 2010
- Language: English
- Type: text , article
- Identifier: vital:7065 , http://hdl.handle.net/10962/d1007431
- Description: preprint , My topic suggested itself in response to a point made at a seminar on University autonomy. Someone observed that many people, even shack dwellers, are interested in the cosmos and they always would be. The remark came in the course of a debate concerning the cost of the SKA project, the massively expensive square kilometer array telescope for which South Africa is bidding against Australia, viewed in relation to the country’s huge list of social backlogs: Big science versus food and decent housing; a false opposition, or a grim choice? You can imagine the debate. The nugget that stayed with me was the tangential comment that ordinary people are always interested in the cosmos. If so, is this true merely because human cultures traditionally incorporate such an interest, or because humans themselves actually need a relation to the cosmos? What might this need be?
- Full Text:
- Date Issued: 2010
Localisation of Theiler's murine encephalomyelitis virus protein 2C to the golgi apparatus using antibodies generated against a peptide region:
- Jauka, Tembisa, Mutsvunguma, Lorraine Z, Boshoff, Aileen, Edkins, Adrienne L, Knox, Caroline M
- Authors: Jauka, Tembisa , Mutsvunguma, Lorraine Z , Boshoff, Aileen , Edkins, Adrienne L , Knox, Caroline M
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165074 , vital:41206 , DOI: 10.1016/j.jviromet.2010.05.009
- Description: The picornavirus 2C protein is highly conserved and indispensible for virus replication. Polyclonal antibodies against Theiler's murine encephalomyelitis virus (TMEV) 2C protein were generated by immunisation of rabbits with a peptide comprising amino acids 31–210 of the protein. Antibodies were used to investigate the localisation of 2C in infected cells by indirect immunofluorescence and confocal microscopy. Analysis of infected cells revealed that the distribution of 2C changed during infection.
- Full Text:
- Date Issued: 2010
- Authors: Jauka, Tembisa , Mutsvunguma, Lorraine Z , Boshoff, Aileen , Edkins, Adrienne L , Knox, Caroline M
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165074 , vital:41206 , DOI: 10.1016/j.jviromet.2010.05.009
- Description: The picornavirus 2C protein is highly conserved and indispensible for virus replication. Polyclonal antibodies against Theiler's murine encephalomyelitis virus (TMEV) 2C protein were generated by immunisation of rabbits with a peptide comprising amino acids 31–210 of the protein. Antibodies were used to investigate the localisation of 2C in infected cells by indirect immunofluorescence and confocal microscopy. Analysis of infected cells revealed that the distribution of 2C changed during infection.
- Full Text:
- Date Issued: 2010
Locating my media DNA
- Authors: Chiwota,Elijah
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454775 , vital:75375 , https://hdl.handle.net/10520/EJC139351
- Description: Imagine after working for seven years as a magazine writer and editor, Rhodes University offers you a place to study for an MA and your first assignment is a critique of a Stuart Hall article.
- Full Text:
- Date Issued: 2010
- Authors: Chiwota,Elijah
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454775 , vital:75375 , https://hdl.handle.net/10520/EJC139351
- Description: Imagine after working for seven years as a magazine writer and editor, Rhodes University offers you a place to study for an MA and your first assignment is a critique of a Stuart Hall article.
- Full Text:
- Date Issued: 2010
Male aggression and mating opportunity in a poeciliid fish
- Magellan, Kit, Kaiser, Horst
- Authors: Magellan, Kit , Kaiser, Horst
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447556 , vital:74656 , https://doi.org/10.1080/15627020.2010.11657250
- Description: One function of aggression in animals is to gain access to mates. Aggression may therefore be favoured by sexual selection, the strength of which can be assessed using repeatability of aggressive behaviour. Here, we tested the hypotheses that male swordtails, Xiphophorus sp., are consistent in the aggressive and mating behaviours exhibited and in the time spent at a close distance to females (female attendance), and that aggressive males gain increased opportunity to attempt copulation compared to their less aggressive conspecifics (sneak frequency). As predicted, aggression between males, and male display and sneak frequency were repeatable. However, male aggression was not significantly correlated with sneak frequency. The function of aggression in this species is not clear-cut and may have an indirect female access function through formation of dominance hierarchies or defence of resources. A surprising finding highlighted by this study was the contradictory results for consistency in female contact, with high repeatability scores indicating consistency in behaviour but the within-subjects component of repeated measures ANOVA showing differences in female contact between trials. The possible reasons for this discrepancy are discussed.
- Full Text:
- Date Issued: 2010
- Authors: Magellan, Kit , Kaiser, Horst
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447556 , vital:74656 , https://doi.org/10.1080/15627020.2010.11657250
- Description: One function of aggression in animals is to gain access to mates. Aggression may therefore be favoured by sexual selection, the strength of which can be assessed using repeatability of aggressive behaviour. Here, we tested the hypotheses that male swordtails, Xiphophorus sp., are consistent in the aggressive and mating behaviours exhibited and in the time spent at a close distance to females (female attendance), and that aggressive males gain increased opportunity to attempt copulation compared to their less aggressive conspecifics (sneak frequency). As predicted, aggression between males, and male display and sneak frequency were repeatable. However, male aggression was not significantly correlated with sneak frequency. The function of aggression in this species is not clear-cut and may have an indirect female access function through formation of dominance hierarchies or defence of resources. A surprising finding highlighted by this study was the contradictory results for consistency in female contact, with high repeatability scores indicating consistency in behaviour but the within-subjects component of repeated measures ANOVA showing differences in female contact between trials. The possible reasons for this discrepancy are discussed.
- Full Text:
- Date Issued: 2010
Minimum spanning trees for valley and ridge characterization in digital elevation maps
- Bangay, Shaun D, de Bruyn, David, Glass, Kevin R
- Authors: Bangay, Shaun D , de Bruyn, David , Glass, Kevin R
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433247 , vital:72955 , https://doi.org/10.1145/1811158.1811171
- Description: Texture synthesis employs neighbourhood matching to generate appropriate new content. Terrain synthesis has the added constraint that new content must be geographically plausible. The profile recognition and polygon breaking algorithm (PPA) [Chang et al. 1998] provides a robust mechanism for characterizing terrain as systems of valley and ridge lines in digital elevation maps. We exploit this to create a terrain characterization metric that is robust, efficient to compute and is sensitive to terrain properties.
- Full Text:
- Date Issued: 2010
- Authors: Bangay, Shaun D , de Bruyn, David , Glass, Kevin R
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433247 , vital:72955 , https://doi.org/10.1145/1811158.1811171
- Description: Texture synthesis employs neighbourhood matching to generate appropriate new content. Terrain synthesis has the added constraint that new content must be geographically plausible. The profile recognition and polygon breaking algorithm (PPA) [Chang et al. 1998] provides a robust mechanism for characterizing terrain as systems of valley and ridge lines in digital elevation maps. We exploit this to create a terrain characterization metric that is robust, efficient to compute and is sensitive to terrain properties.
- Full Text:
- Date Issued: 2010
Mobile phones, youth radio, citizen journalists: how the news is coming to Grahamstow
- Authors: Dugmore, Harry
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159412 , vital:40295 , https://hdl.handle.net/10520/EJC139343
- Description: Newspapers everywhere are being forced to rethink their role as simply providers of general news of the day. As people can access much more immediate information and news online, from a wide variety of sources, and get to "hear about things" from their friends and contacts through Facebook, Twitter and other "social media", local papers are having to find better ways to provide immediate and more useful information and news.
- Full Text:
- Date Issued: 2010
- Authors: Dugmore, Harry
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159412 , vital:40295 , https://hdl.handle.net/10520/EJC139343
- Description: Newspapers everywhere are being forced to rethink their role as simply providers of general news of the day. As people can access much more immediate information and news online, from a wide variety of sources, and get to "hear about things" from their friends and contacts through Facebook, Twitter and other "social media", local papers are having to find better ways to provide immediate and more useful information and news.
- Full Text:
- Date Issued: 2010
Monitoring perceptions of social progress and pride of place in a South African community
- Moller, Valerie, Radloff, Sarah E
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68468 , vital:29261 , https://doi.org/10.1007/s11482-010-9092-8 https://doi.org/10.1007/s11482-011-9145-7
- Description: Publisher version , A social indicators community project was conducted in 2007 to monitor living standards and quality of life in Rhini, a low-income suburb of Grahamstown, Makana Municipality, South Africa. Since 1994, under democratic rule, considerable progress has been made in service delivery to the formerly disadvantaged in South African society in terms of access to housing, infrastructure, and a social safety net to mitigate the high rate of unemployment. A representative cross-sectional household study (n 1020) conducted in 2007 in Rhini found that a positive assessment of the household’s situation and personal life satisfaction did not reflect better living conditions. Lack of income and employment opportunities appeared to dilute gains from higher living standards. The project also inquired into attitudes to place names and a proposed name change for the city under discussion at the time of the survey. It is argued that a place name with which one can identify may be as important as service delivery to enhance community satisfaction and overall quality of life. Dissatisfied residents who had limited access to services and expressed less civic pride were more likely than others to opt for a proposed name change for the city of Grahamstown that would better reflect the country’s new identity and multicultural heritage. It is concluded that a useful pursuit for community quality-of-life studies in countries undergoing social transformation will be to inquire into the complex combination of factors that drive perceptions of material and symbolic progress.
- Full Text: false
- Date Issued: 2010
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68468 , vital:29261 , https://doi.org/10.1007/s11482-010-9092-8 https://doi.org/10.1007/s11482-011-9145-7
- Description: Publisher version , A social indicators community project was conducted in 2007 to monitor living standards and quality of life in Rhini, a low-income suburb of Grahamstown, Makana Municipality, South Africa. Since 1994, under democratic rule, considerable progress has been made in service delivery to the formerly disadvantaged in South African society in terms of access to housing, infrastructure, and a social safety net to mitigate the high rate of unemployment. A representative cross-sectional household study (n 1020) conducted in 2007 in Rhini found that a positive assessment of the household’s situation and personal life satisfaction did not reflect better living conditions. Lack of income and employment opportunities appeared to dilute gains from higher living standards. The project also inquired into attitudes to place names and a proposed name change for the city under discussion at the time of the survey. It is argued that a place name with which one can identify may be as important as service delivery to enhance community satisfaction and overall quality of life. Dissatisfied residents who had limited access to services and expressed less civic pride were more likely than others to opt for a proposed name change for the city of Grahamstown that would better reflect the country’s new identity and multicultural heritage. It is concluded that a useful pursuit for community quality-of-life studies in countries undergoing social transformation will be to inquire into the complex combination of factors that drive perceptions of material and symbolic progress.
- Full Text: false
- Date Issued: 2010
My First Book of Southern African Insects, C. Uys: book review
- Authors: Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451749 , vital:75074 , https://hdl.handle.net/10520/EJC32855
- Description: I concur with Antoine de Saint-Exupéry (1943): we are born with a strong appreciation of the world around us that most of us lose as we grow up. While few adults have much empathy with insects, they are a source of fascination for most children, at least until they start school. The problem facing professional entomology is how to sustain and encourage that early attitude so that we recruit passionate and well-prepared people into the profession, and sensitise the remainder of the population to the value of insects.
- Full Text:
- Date Issued: 2010
- Authors: Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451749 , vital:75074 , https://hdl.handle.net/10520/EJC32855
- Description: I concur with Antoine de Saint-Exupéry (1943): we are born with a strong appreciation of the world around us that most of us lose as we grow up. While few adults have much empathy with insects, they are a source of fascination for most children, at least until they start school. The problem facing professional entomology is how to sustain and encourage that early attitude so that we recruit passionate and well-prepared people into the profession, and sensitise the remainder of the population to the value of insects.
- Full Text:
- Date Issued: 2010
Natural enemies from South Africa for biological control of Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae) in Europe
- Baars, Jan-Robert, Coetzee, Julie A, Martin, Grant D, Hill, Martin P, Caffrey, J M
- Authors: Baars, Jan-Robert , Coetzee, Julie A , Martin, Grant D , Hill, Martin P , Caffrey, J M
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76914 , vital:30637 , https://doi.org/10.1007/s10750-010-0427-0
- Description: The non-native invasive plant, Lagarosiphon major (Hydrocharitaceae) is a submersed aquatic macrophyte that poses a significant threat to water bodies in Europe. Dense infestations prove difficult to manage using traditional methods. In order to initiate a biocontrol programme, a survey for natural enemies of Lagarosiphon was conducted in South Africa. Several phytophagous species were recorded for the first time, with at least three showing notable promise as candidate agents. Amongst these, a leaf-mining fly, Hydrellia sp. (Ephydridae) that occurred over a wide distribution causes significant leaf damage despite high levels of parasitism by braconid wasps. Another yet unidentified fly was recorded mining the stem of L. major. Two leaf-feeding and shoot boring weevils, cf. Bagous sp. (Curculionidae) were recorded damaging the shoot tips and stunting the growth of the stem. Several leaf-feeding lepidopteran species (Nymphulinae) were frequently recorded, but are expected to feed on a wide range of plant species and are not considered for importation before other candidates are assessed. The discovery of several natural enemies in the country of origin improves the biological control prospects of L. major in Europe.
- Full Text:
- Date Issued: 2010
- Authors: Baars, Jan-Robert , Coetzee, Julie A , Martin, Grant D , Hill, Martin P , Caffrey, J M
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76914 , vital:30637 , https://doi.org/10.1007/s10750-010-0427-0
- Description: The non-native invasive plant, Lagarosiphon major (Hydrocharitaceae) is a submersed aquatic macrophyte that poses a significant threat to water bodies in Europe. Dense infestations prove difficult to manage using traditional methods. In order to initiate a biocontrol programme, a survey for natural enemies of Lagarosiphon was conducted in South Africa. Several phytophagous species were recorded for the first time, with at least three showing notable promise as candidate agents. Amongst these, a leaf-mining fly, Hydrellia sp. (Ephydridae) that occurred over a wide distribution causes significant leaf damage despite high levels of parasitism by braconid wasps. Another yet unidentified fly was recorded mining the stem of L. major. Two leaf-feeding and shoot boring weevils, cf. Bagous sp. (Curculionidae) were recorded damaging the shoot tips and stunting the growth of the stem. Several leaf-feeding lepidopteran species (Nymphulinae) were frequently recorded, but are expected to feed on a wide range of plant species and are not considered for importation before other candidates are assessed. The discovery of several natural enemies in the country of origin improves the biological control prospects of L. major in Europe.
- Full Text:
- Date Issued: 2010
Newspaper literacy and communication for democracy: is there a crisis in South African journalism?
- Siebörger, Ian, Adendorff, Ralph D
- Authors: Siebörger, Ian , Adendorff, Ralph D
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125304 , vital:35770 , https://doi.org/10.2989/SALALS.2009.27.4.4.1024
- Description: Media theorists such as Barnett (2002), Buckingham (1997 & 2000) and Sampson (1999) describe a perceived crisis hindering the media’s ability to inform citizens for participation in democracy. One of the symptoms and causes of this crisis, they argue, is that the media use language that many citizens cannot understand. This article draws on theories and methodologies from linguistics to investigate whether this claim holds true for South African newspapers. The concept of the crisis in journalism is deconstructed in the light of Street’s (1984) ideological model of literacy. In a pilot study, multiple readability tests were conducted on one article from each of three newspapers, Business Day, The Herald and Daily Sun. The findings of these tests, and a systemic functional grammar analysis of cohesion and lexical density in the three articles, show that all three newspapers tailor their language to fit their target markets. This, triangulated with the rapid growth in readership of the Daily Sun and the more modest growth of The Herald, suggests that many South Africans are better informed for participation in democracy than in the past, although newspapers can do more to help readers learn a plurality of literacy practices.
- Full Text:
- Date Issued: 2010
- Authors: Siebörger, Ian , Adendorff, Ralph D
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125304 , vital:35770 , https://doi.org/10.2989/SALALS.2009.27.4.4.1024
- Description: Media theorists such as Barnett (2002), Buckingham (1997 & 2000) and Sampson (1999) describe a perceived crisis hindering the media’s ability to inform citizens for participation in democracy. One of the symptoms and causes of this crisis, they argue, is that the media use language that many citizens cannot understand. This article draws on theories and methodologies from linguistics to investigate whether this claim holds true for South African newspapers. The concept of the crisis in journalism is deconstructed in the light of Street’s (1984) ideological model of literacy. In a pilot study, multiple readability tests were conducted on one article from each of three newspapers, Business Day, The Herald and Daily Sun. The findings of these tests, and a systemic functional grammar analysis of cohesion and lexical density in the three articles, show that all three newspapers tailor their language to fit their target markets. This, triangulated with the rapid growth in readership of the Daily Sun and the more modest growth of The Herald, suggests that many South Africans are better informed for participation in democracy than in the past, although newspapers can do more to help readers learn a plurality of literacy practices.
- Full Text:
- Date Issued: 2010
Novel, soluble, FluXoro functional substituted zinc phthalocyanines; synthesis, characterization and photophysicochemical properties
- Erdoğmuş, Ali, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261258 , vital:53378 , xlink:href="https://doi.org/10.1016/j.dyepig.2010.01.001"
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041.
- Full Text:
- Date Issued: 2010
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261258 , vital:53378 , xlink:href="https://doi.org/10.1016/j.dyepig.2010.01.001"
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041.
- Full Text:
- Date Issued: 2010
Optical limiting properties of zinc phthalocyanines in solution and solid PMMA composite films
- Tekin, Sezen, Kürüm, Ulaş, Durmus, Mahmut, Yaglioglu, H Gul, Nyokong, Tebello, Elmali, Ayhan
- Authors: Tekin, Sezen , Kürüm, Ulaş , Durmus, Mahmut , Yaglioglu, H Gul , Nyokong, Tebello , Elmali, Ayhan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249071 , vital:51775 , xlink:href="https://doi.org/10.1016/j.optcom.2010.07.003"
- Description: The nonlinear absorption and optical limiting (OL) performance of tetra- and octasubstituted zinc phthalocyanine complexes were described in solution and in the solid state using the open-aperture Z-scan technique. The measurements were performed using collimated 4 ns pulses generated from a frequency-doubled Nd:YAG laser at 532 nm wavelength. The polymeric films exhibit a much larger effective nonlinear absorption coefficient in comparison with solution. However, the parameters of the ratio of the excited to ground state absorption cross section and energy-dependent saturation in solution are much better compared to properties in the polymeric film. In terms of the ratio of the excited to ground state absorption cross section, the peripherally substituted complexes show better OL performance than the non-peripherally substituted derivative.
- Full Text:
- Date Issued: 2010
- Authors: Tekin, Sezen , Kürüm, Ulaş , Durmus, Mahmut , Yaglioglu, H Gul , Nyokong, Tebello , Elmali, Ayhan
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249071 , vital:51775 , xlink:href="https://doi.org/10.1016/j.optcom.2010.07.003"
- Description: The nonlinear absorption and optical limiting (OL) performance of tetra- and octasubstituted zinc phthalocyanine complexes were described in solution and in the solid state using the open-aperture Z-scan technique. The measurements were performed using collimated 4 ns pulses generated from a frequency-doubled Nd:YAG laser at 532 nm wavelength. The polymeric films exhibit a much larger effective nonlinear absorption coefficient in comparison with solution. However, the parameters of the ratio of the excited to ground state absorption cross section and energy-dependent saturation in solution are much better compared to properties in the polymeric film. In terms of the ratio of the excited to ground state absorption cross section, the peripherally substituted complexes show better OL performance than the non-peripherally substituted derivative.
- Full Text:
- Date Issued: 2010
Parallel packet classification using GPU co-processors
- Nottingham, Alistair, Irwin, Barry V W
- Authors: Nottingham, Alistair , Irwin, Barry V W
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430250 , vital:72677 , https://doi.org/10.1145/1899503.1899529
- Description: In the domain of network security, packet filtering for classification pur-poses is of significant interest. Packet classification provides a mecha-nism for understanding the composition of packet streams arriving at distinct network interfaces, and is useful in diagnosing threats and un-covering vulnerabilities so as to maximise data integrity and system se-curity. Traditional packet classifiers, such as PCAP, have utilised Con-trol Flow Graphs (CFGs) in representing filter sets, due to both their amenability to optimisation, and their inherent structural applicability to the metaphor of decision-based classification. Unfortunately, CFGs do not map well to cooperative processing implementations, and single-threaded CPU-based implementations have proven too slow for real-time classification against multiple arbitrary filters on next generation networks. In this paper, we consider a novel multithreaded classification algorithm, optimised for execution on GPU co-processors, intended to accelerate classification throughput and maximise processing efficien-cy in a highly parallel execution context.
- Full Text:
- Date Issued: 2010
- Authors: Nottingham, Alistair , Irwin, Barry V W
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430250 , vital:72677 , https://doi.org/10.1145/1899503.1899529
- Description: In the domain of network security, packet filtering for classification pur-poses is of significant interest. Packet classification provides a mecha-nism for understanding the composition of packet streams arriving at distinct network interfaces, and is useful in diagnosing threats and un-covering vulnerabilities so as to maximise data integrity and system se-curity. Traditional packet classifiers, such as PCAP, have utilised Con-trol Flow Graphs (CFGs) in representing filter sets, due to both their amenability to optimisation, and their inherent structural applicability to the metaphor of decision-based classification. Unfortunately, CFGs do not map well to cooperative processing implementations, and single-threaded CPU-based implementations have proven too slow for real-time classification against multiple arbitrary filters on next generation networks. In this paper, we consider a novel multithreaded classification algorithm, optimised for execution on GPU co-processors, intended to accelerate classification throughput and maximise processing efficien-cy in a highly parallel execution context.
- Full Text:
- Date Issued: 2010
Philosophers and the Poor
- Authors: Jones, Ward E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/275671 , vital:55068 , xlink:href="https://doi.org/10.3167/th.2010.5712506"
- Description: This is a programmatic paper, calling for the renewal andmodernisation of the therapeutic approach to philosophy found inEpicureans, Stoics, and Skeptics; and, in particular, for an applicationof the therapeutic approach to the life of poverty. The general assump-tion behind a therapeutic approach to philosophy is that it is possiblefor someone to be exposed to philosophical work which leads her toan improved understanding of herself and her situation, and for herlife to be improved by this understanding. After offering a sketch ofhow, given the current nature of academic philosophy, such work willbe carried out and disseminated, I suggest three areas in which philo-sophical discourse could have a therapeutic affect on the poor.
- Full Text:
- Date Issued: 2010
- Authors: Jones, Ward E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/275671 , vital:55068 , xlink:href="https://doi.org/10.3167/th.2010.5712506"
- Description: This is a programmatic paper, calling for the renewal andmodernisation of the therapeutic approach to philosophy found inEpicureans, Stoics, and Skeptics; and, in particular, for an applicationof the therapeutic approach to the life of poverty. The general assump-tion behind a therapeutic approach to philosophy is that it is possiblefor someone to be exposed to philosophical work which leads her toan improved understanding of herself and her situation, and for herlife to be improved by this understanding. After offering a sketch ofhow, given the current nature of academic philosophy, such work willbe carried out and disseminated, I suggest three areas in which philo-sophical discourse could have a therapeutic affect on the poor.
- Full Text:
- Date Issued: 2010
Photoelectrochemical characterization of electrodeposited ZnO thin films sensitized by octacarboxymetallophthalocyanine derivatives
- Idowu, Mopelola, Loewenstein, Thomas, Hastall, Andreas, Nyokong, Tebello, Schlettwein, Derck
- Authors: Idowu, Mopelola , Loewenstein, Thomas , Hastall, Andreas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262655 , vital:53541 , xlink:href="https://doi.org/10.1142/S1088424610001854"
- Description: Hybrid thin films of crystalline zinc oxide (ZnO) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine (ZnOCPc) showed considerably large quantum efficiency in sensitization of ZnO, one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.
- Full Text:
- Date Issued: 2010
- Authors: Idowu, Mopelola , Loewenstein, Thomas , Hastall, Andreas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262655 , vital:53541 , xlink:href="https://doi.org/10.1142/S1088424610001854"
- Description: Hybrid thin films of crystalline zinc oxide (ZnO) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine (ZnOCPc) showed considerably large quantum efficiency in sensitization of ZnO, one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.
- Full Text:
- Date Issued: 2010
Photophysical and photochemical parameters of octakis (benzylthio) phthalocyaninato zinc, aluminium and tin
- Akpe, Victor, Brismar, Hjalmar, Nyokong, Tebello, Osadebe, Patience Ogoamak
- Authors: Akpe, Victor , Brismar, Hjalmar , Nyokong, Tebello , Osadebe, Patience Ogoamak
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248472 , vital:51689 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.08.033"
- Description: This paper addresses the synthesis of octa-substituted benzylthio metallophthalocyanines (OBTMPcs) that contain the central metal ions of Zn2+, Al3+ and Sn4+. The ground state absorption of ZnPc(SR)8 (OBTZnPc) along with the ZnPc derivatives, well documented in literature were used to study a new concept called the red shift index (RsI). The concept is based on the empirical values of RsI of the different complexes in solvent media. Unequivocally, parameters used in this paper show strong correlations that are consistent with the results obtained. For instance, RsI of the complexes tend to increase as the refractive index, nD, and solvent donor, DN, of solvent increases. Photodegradation (photobleaching) quantum yield, ϕd measurements of these compounds show that they are highly photostable, ϕd (0.03–0.33 × 10−5). The triplet quantum yield, ϕT (0.40–0.53) and the triplet lifetime, τT (610–810 μs) are within the typical range for metallophthalocyanines in DMSO. The photosensitisation efficiency, SΔ, is relatively high for all the molecules (0.74–0.90).
- Full Text:
- Date Issued: 2010
- Authors: Akpe, Victor , Brismar, Hjalmar , Nyokong, Tebello , Osadebe, Patience Ogoamak
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248472 , vital:51689 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.08.033"
- Description: This paper addresses the synthesis of octa-substituted benzylthio metallophthalocyanines (OBTMPcs) that contain the central metal ions of Zn2+, Al3+ and Sn4+. The ground state absorption of ZnPc(SR)8 (OBTZnPc) along with the ZnPc derivatives, well documented in literature were used to study a new concept called the red shift index (RsI). The concept is based on the empirical values of RsI of the different complexes in solvent media. Unequivocally, parameters used in this paper show strong correlations that are consistent with the results obtained. For instance, RsI of the complexes tend to increase as the refractive index, nD, and solvent donor, DN, of solvent increases. Photodegradation (photobleaching) quantum yield, ϕd measurements of these compounds show that they are highly photostable, ϕd (0.03–0.33 × 10−5). The triplet quantum yield, ϕT (0.40–0.53) and the triplet lifetime, τT (610–810 μs) are within the typical range for metallophthalocyanines in DMSO. The photosensitisation efficiency, SΔ, is relatively high for all the molecules (0.74–0.90).
- Full Text:
- Date Issued: 2010
Photophysical and photochemical properties of Ni (II), Pd (II) and Pt (II) aryloxo and alkylthio derivatised phthalocyanine
- Ogunbayo, Taofeek B, Nyokong, Tebello
- Authors: Ogunbayo, Taofeek B , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261511 , vital:53416 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.03.047"
- Description: Several aryloxo (3a–6a and 3b–6b) and alkylthio (3d and 3e) derivatised phthalocyanines were synthesized, characterized and the photochemical and photophysical properties investigated along with those of the previously reported (3c–5c, 4d, 5d, 4e and 5e) complexes. The effects of open-shell metals (Ni(II), Pd(II) and Pt(II)) on the photophysical and photochemical properties of the phthalocyanine ligands were investigated. Palladium and platinum improved the triplet quantum yield and singlet oxygen generation capacities of the unmetalated phthalocyanines (3a–3e) making their complexes candidates for further investigation in photocatalysis. Ni(II)Pc analogues gave poor results compared with their Pd(II)Pc and Pt(II)Pc counterparts.
- Full Text:
- Date Issued: 2010
- Authors: Ogunbayo, Taofeek B , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261511 , vital:53416 , xlink:href="https://doi.org/10.1016/j.molstruc.2010.03.047"
- Description: Several aryloxo (3a–6a and 3b–6b) and alkylthio (3d and 3e) derivatised phthalocyanines were synthesized, characterized and the photochemical and photophysical properties investigated along with those of the previously reported (3c–5c, 4d, 5d, 4e and 5e) complexes. The effects of open-shell metals (Ni(II), Pd(II) and Pt(II)) on the photophysical and photochemical properties of the phthalocyanine ligands were investigated. Palladium and platinum improved the triplet quantum yield and singlet oxygen generation capacities of the unmetalated phthalocyanines (3a–3e) making their complexes candidates for further investigation in photocatalysis. Ni(II)Pc analogues gave poor results compared with their Pd(II)Pc and Pt(II)Pc counterparts.
- Full Text:
- Date Issued: 2010