Spatial and seasonal distribution patterns of the ragged-tooth shark Carcharias taurus along the coast of South Africa
- Dicken, Matthew L, Booth, Anthony J, Smale, Malcolm J
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127008 , vital:35943 , https://doi.10.2989/18142320609504210
- Description: Off South Africa, the ragged-tooth shark Carcharias Taurus has been occasionally reported from the West Coast, but it is more commonly found along the East and South coasts from Cape Town to northern KwaZulu-Natal (KZN) (Bass et al. 1975, Smale 2002). Mating is thought to occur off the south coast of KZN from October to late November (G Cliff, Natal Sharks Board, unpublished data). Pregnant females then move northward to spend the early part of their gestation in the warmer waters of northern KZN and possibly southern Moçambique. During July and August, the near-term pregnant females begin to move southwards towards the cooler waters of the Eastern Cape (Wallett 1973, Bass et al. 1975, G Cliff, unpublished data), where they give birth from September to November (Smale 2002). After parturition, many of the females migrate back to KZN. The whereabouts of mature males outside of the mating season is unclear. These broadscale distribution and migratory habits for C. taurus have been inferred from limited catch records obtained for only parts of its range along the South African coast.
- Full Text:
- Date Issued: 2010
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127008 , vital:35943 , https://doi.10.2989/18142320609504210
- Description: Off South Africa, the ragged-tooth shark Carcharias Taurus has been occasionally reported from the West Coast, but it is more commonly found along the East and South coasts from Cape Town to northern KwaZulu-Natal (KZN) (Bass et al. 1975, Smale 2002). Mating is thought to occur off the south coast of KZN from October to late November (G Cliff, Natal Sharks Board, unpublished data). Pregnant females then move northward to spend the early part of their gestation in the warmer waters of northern KZN and possibly southern Moçambique. During July and August, the near-term pregnant females begin to move southwards towards the cooler waters of the Eastern Cape (Wallett 1973, Bass et al. 1975, G Cliff, unpublished data), where they give birth from September to November (Smale 2002). After parturition, many of the females migrate back to KZN. The whereabouts of mature males outside of the mating season is unclear. These broadscale distribution and migratory habits for C. taurus have been inferred from limited catch records obtained for only parts of its range along the South African coast.
- Full Text:
- Date Issued: 2010
Spatial description of hake-directed fishing activity off the west coast of South Africa
- Fairweather, T P, Booth, Anthony J, Sauer, Warwick H H, Leslie, Rob W
- Authors: Fairweather, T P , Booth, Anthony J , Sauer, Warwick H H , Leslie, Rob W
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127031 , vital:35945 , https://doi.10.2989/18142320609504129
- Description: Historically, the two species of Cape hakes Merluccius capensis and M. paradoxus off South Africa were commercially exploited exclusively by demersal trawling. In 1994, hake-directed demersal longline was introduced on an experimental basis, and in 1998 was initiated as a commercial fishing sector. The effect of a combined fleet composed of both trawlers and longliners on the Cape hake resource is not fully understood. Analysis of fishing intensity and catch-rate data revealed that the highest catch rates were found around the 400m and 500m isobaths for the trawl and longline fisheries respectively. Catch rates from both fishing sectors were also noted to be higher over sediments with a sand component. Differences between areas of the highest fishing intensity and highest catch rates were noted. In addition to other factors, it is suggested that a ‘friction of distance’ effect applies — vessels will trade-off higher catch rates with the increased costs associated with fishing in deeper waters.
- Full Text:
- Date Issued: 2010
- Authors: Fairweather, T P , Booth, Anthony J , Sauer, Warwick H H , Leslie, Rob W
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127031 , vital:35945 , https://doi.10.2989/18142320609504129
- Description: Historically, the two species of Cape hakes Merluccius capensis and M. paradoxus off South Africa were commercially exploited exclusively by demersal trawling. In 1994, hake-directed demersal longline was introduced on an experimental basis, and in 1998 was initiated as a commercial fishing sector. The effect of a combined fleet composed of both trawlers and longliners on the Cape hake resource is not fully understood. Analysis of fishing intensity and catch-rate data revealed that the highest catch rates were found around the 400m and 500m isobaths for the trawl and longline fisheries respectively. Catch rates from both fishing sectors were also noted to be higher over sediments with a sand component. Differences between areas of the highest fishing intensity and highest catch rates were noted. In addition to other factors, it is suggested that a ‘friction of distance’ effect applies — vessels will trade-off higher catch rates with the increased costs associated with fishing in deeper waters.
- Full Text:
- Date Issued: 2010
Spectroscopic behavior of cationic metallophthalocyanines in the presence of anionic quantum dots
- Idowu, Mopelola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262699 , vital:53545 , xlink:href="https://doi.org/10.1016/j.saa.2009.10.050"
- Description: The interactions and spectroscopic properties between cationic zinc phthalocyanine derivatives (peripherally and non-peripherally tetrasubstituted and peripherally octa substituted with 2-diethylmethylaminoethylsulfanyl (βTZnPc, αTZnPc and βOZnPc)) and CdTe core quantum dots (QDs) capped with mercaptopropionic acid or thioglycolic acid (represented as CdTe@MPA and CdTe@TGA, respectively) have been studied in methanol:water mixture. Strong coupling of MPcs was deduced from the interaction since the UV–vis spectroscopic studies of the ground state complex formed on mixing both components showed loss of the phthalocyanine monomeric band with the formation of a dimeric band (spectrum of aggregated species). The dimerization constants were of the order of 104 M−1.
- Full Text:
- Date Issued: 2010
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/262699 , vital:53545 , xlink:href="https://doi.org/10.1016/j.saa.2009.10.050"
- Description: The interactions and spectroscopic properties between cationic zinc phthalocyanine derivatives (peripherally and non-peripherally tetrasubstituted and peripherally octa substituted with 2-diethylmethylaminoethylsulfanyl (βTZnPc, αTZnPc and βOZnPc)) and CdTe core quantum dots (QDs) capped with mercaptopropionic acid or thioglycolic acid (represented as CdTe@MPA and CdTe@TGA, respectively) have been studied in methanol:water mixture. Strong coupling of MPcs was deduced from the interaction since the UV–vis spectroscopic studies of the ground state complex formed on mixing both components showed loss of the phthalocyanine monomeric band with the formation of a dimeric band (spectrum of aggregated species). The dimerization constants were of the order of 104 M−1.
- Full Text:
- Date Issued: 2010
Spectroscopic studies of nanostructures of negatively charged free base porphyrin and positively charged tin porphyrins
- George, Reama C, Egharevba, Gabriel O, Nyokong, Tebello
- Authors: George, Reama C , Egharevba, Gabriel O , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261661 , vital:53432 , xlink:href="https://doi.org/10.1016/j.poly.2010.01.028"
- Description: Spectroscopic studies were carried out on the homoaggregates of negatively charged free base meso-tetraphenylsulfonated porphyrin ([H2TPPS4]4−) and heteroaggregates of a mixture of protonated ([H4TPPS4]2−) and tin meso-tetra (N-methyl-4-pyridyl) porphyrin ([SnTMPyP]4+). The spectroscopic studies were done to determine the optimal conditions required for the fabrication of porphyrin nanorods by ionic self assembly of two oppositely charged porphyrins. In addition, the various spectral changes of [H4TPPS4]2− with concurrent change in pH and concentration are also investigated. In acid media at pH more than 3, and at concentrations less than 1 × 10−5 M, [H4TPPS4]2− molecules form J aggregates. A mixture of [H4TPPS4]2− and [SnTMPyP]4+ forms heteroaggregates of the J type in acid media. At pH’s 2 to 3, the optimum ratio for the formation of J aggregates is 3:1 and for pH 1, the optimum ratio is 2:1. Transmission electron microscope images of the nanostructures formed show that they are of cylindrical shape.
- Full Text:
- Date Issued: 2010
- Authors: George, Reama C , Egharevba, Gabriel O , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261661 , vital:53432 , xlink:href="https://doi.org/10.1016/j.poly.2010.01.028"
- Description: Spectroscopic studies were carried out on the homoaggregates of negatively charged free base meso-tetraphenylsulfonated porphyrin ([H2TPPS4]4−) and heteroaggregates of a mixture of protonated ([H4TPPS4]2−) and tin meso-tetra (N-methyl-4-pyridyl) porphyrin ([SnTMPyP]4+). The spectroscopic studies were done to determine the optimal conditions required for the fabrication of porphyrin nanorods by ionic self assembly of two oppositely charged porphyrins. In addition, the various spectral changes of [H4TPPS4]2− with concurrent change in pH and concentration are also investigated. In acid media at pH more than 3, and at concentrations less than 1 × 10−5 M, [H4TPPS4]2− molecules form J aggregates. A mixture of [H4TPPS4]2− and [SnTMPyP]4+ forms heteroaggregates of the J type in acid media. At pH’s 2 to 3, the optimum ratio for the formation of J aggregates is 3:1 and for pH 1, the optimum ratio is 2:1. Transmission electron microscope images of the nanostructures formed show that they are of cylindrical shape.
- Full Text:
- Date Issued: 2010
Swelling, erosion and drug release characteristics of salbutamol sulfate from hydroxypropyl methylcellulose-based matrix tablets
- Chaibva, Faith A, Khamanga, Sandile M, Walker, Roderick B
- Authors: Chaibva, Faith A , Khamanga, Sandile M , Walker, Roderick B
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184139 , vital:44177 , xlink:href="https://doi.org/10.3109/03639045.2010.488648"
- Description: Background: Hydrophilic matrix formulations are important and simple technologies that are used to manufacture sustained release dosage forms. Method: Hydroxypropyl methylcellulose-based matrix tablets, with and without additives, were manufactured to investigate the rate of hydration, rate of erosion, and rate and mechanism of drug release. Scanning electron microscopy was used to assess changes in the microstructure of the tablets during drug release testing and whether these changes could be related to the rate of drug release from the formulations. Results: The results revealed that the rate of hydration and erosion was dependent on the polymer combination(s) used, which in turn affected the rate and mechanism of drug release from these formulations. It was also apparent that changes in the microstructure of matrix tablets could be related to the different rates of drug release that were observed from the test formulations. Conclusion: The use of scanning electron microscopy provides useful information to further understand drug release mechanisms from matrix tablets.
- Full Text:
- Date Issued: 2010
- Authors: Chaibva, Faith A , Khamanga, Sandile M , Walker, Roderick B
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184139 , vital:44177 , xlink:href="https://doi.org/10.3109/03639045.2010.488648"
- Description: Background: Hydrophilic matrix formulations are important and simple technologies that are used to manufacture sustained release dosage forms. Method: Hydroxypropyl methylcellulose-based matrix tablets, with and without additives, were manufactured to investigate the rate of hydration, rate of erosion, and rate and mechanism of drug release. Scanning electron microscopy was used to assess changes in the microstructure of the tablets during drug release testing and whether these changes could be related to the rate of drug release from the formulations. Results: The results revealed that the rate of hydration and erosion was dependent on the polymer combination(s) used, which in turn affected the rate and mechanism of drug release from these formulations. It was also apparent that changes in the microstructure of matrix tablets could be related to the different rates of drug release that were observed from the test formulations. Conclusion: The use of scanning electron microscopy provides useful information to further understand drug release mechanisms from matrix tablets.
- Full Text:
- Date Issued: 2010
Symmetrically and unsymmetrically substituted carboxy phthalocyanines as sensitizers for nanoporous ZnO films
- Masilela, Nkosiphile, Nombona, Nolwazi, Loewenstein, Thomas, Nyokong, Tebello, Schlettwein, Derck
- Authors: Masilela, Nkosiphile , Nombona, Nolwazi , Loewenstein, Thomas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249126 , vital:51780 , xlink:href="https://doi.org/10.1142/S1088424610002793"
- Description: The photoelectroectrochemical studies of water soluble octacarboxylated oxotitanium (OTiOCPc), zinc (ZnOCPC), hydroxyaluminium ((OH)AlOCPc), dihydroxysilicon ((OH)2SiOCPc), hydroxygallium (OHGaOCPc) and low symmetry zinc monocarboxy (ZnMCPc) phthalocyanines were performed. The dyes were adsorbed to nanoporous ZnO electrodeposited in the presence of eosin Y as structure directing agent (SDA) on FTO substrates by refluxing or soaking the films in a solution containing the dye of interest such that a full surface coverage was achieved. High external (IPCE) and internal (APCE) quantum efficiencies of up to 50.6% and 96.7% were achieved for the OTiOCPc complex. There was a lower overall cell efficiency for cells sensitized with phthalocyanines containing hydroxyl as axial ligand ZnO/(OH)2SiOCPc, ZnO/(OH)GaOCPc and (OH)AlOCPc because of strong aggregation on the surface of the electrodes. To further suppress dye aggregation, the zinc complex of a new monocarboxylated phthalocyanine sensitizer with bulky naphtho side groups (ZnMCPc) was employed. Among the studied sensitizers, ZnMCPc gave the highest overall cell efficiency of phthalocyanine electrodeposited on ZnO of η = 0.48%.
- Full Text:
- Date Issued: 2010
- Authors: Masilela, Nkosiphile , Nombona, Nolwazi , Loewenstein, Thomas , Nyokong, Tebello , Schlettwein, Derck
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249126 , vital:51780 , xlink:href="https://doi.org/10.1142/S1088424610002793"
- Description: The photoelectroectrochemical studies of water soluble octacarboxylated oxotitanium (OTiOCPc), zinc (ZnOCPC), hydroxyaluminium ((OH)AlOCPc), dihydroxysilicon ((OH)2SiOCPc), hydroxygallium (OHGaOCPc) and low symmetry zinc monocarboxy (ZnMCPc) phthalocyanines were performed. The dyes were adsorbed to nanoporous ZnO electrodeposited in the presence of eosin Y as structure directing agent (SDA) on FTO substrates by refluxing or soaking the films in a solution containing the dye of interest such that a full surface coverage was achieved. High external (IPCE) and internal (APCE) quantum efficiencies of up to 50.6% and 96.7% were achieved for the OTiOCPc complex. There was a lower overall cell efficiency for cells sensitized with phthalocyanines containing hydroxyl as axial ligand ZnO/(OH)2SiOCPc, ZnO/(OH)GaOCPc and (OH)AlOCPc because of strong aggregation on the surface of the electrodes. To further suppress dye aggregation, the zinc complex of a new monocarboxylated phthalocyanine sensitizer with bulky naphtho side groups (ZnMCPc) was employed. Among the studied sensitizers, ZnMCPc gave the highest overall cell efficiency of phthalocyanine electrodeposited on ZnO of η = 0.48%.
- Full Text:
- Date Issued: 2010
Syntheses and investigation of the effects of position and nature of substituent on the spectral, electrochemical and spectroelectrochemical properties of new cobalt phthalocyanine complexes
- Akinbulu, Isaac A, Nyokong, Tebello
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261677 , vital:53434 , xlink:href="https://doi.org/10.1016/j.poly.2010.01.004"
- Description: The syntheses of new cobalt phthalocyanine (CoPc) complexes, tetra-substituted with diethylaminoethanethio at the peripheral (complex 3a) and non-peripheral (complex 3b) positions, and with benzylmercapto at the non-peripheral position (complex 5), are reported. The effects of the nature and position of substituent on the spectral, electrochemical and spectroelectrochemical properties of these complexes are investigated. Solution electrochemistry of complex 3a showed three distinctly resolved redox processes attributed to CoIIIPc−2/CoIIPc−2 (E½ = +0.64 V versus Ag|AgCl), CoIIPc−2/CoIPc−2 (E½ = −0.24 V versus Ag|AgCl) and CoIPc−2/CoIPc−3 (E½ = −1.26 V versus Ag|AgCl) species. No ring oxidation was observed in complex 3a. Complex 3b showed both ring-based oxidation, attributed to CoIIIPc−1/CoIIIPc−2 species (Ep = +0.86 V versus Ag|AgCl), and ring-based reduction associated with CoIPc−2/CoIPc−3 species (E½ = −1.46 V versus Ag|AgCl), with the normal metal-based redox processes in CoPc complexes: CoIIIPc−2/CoIIPc−2 (Ep = +0.41 V versus Ag|AgCl) and CoIIPc−2/CoIPc−2 (E½ = −0.38 V versus Ag|AgCl). Solution electrochemistry of complex 5 showed the same type and number of species observed in complex 3a: CoIIIPc−2/CoIIPc−2 (Ep = +0.59 V versus Ag|AgCl), CoIIPc−2/CoIPc−2 (E½ = −0.26 V versus Ag|AgCl) and CoIPc−2/CoIPc−3 (E½ = −1.39 V versus Ag|AgCl) species. These processes were confirmed using spectroelectrochemistry.
- Full Text:
- Date Issued: 2010
- Authors: Akinbulu, Isaac A , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261677 , vital:53434 , xlink:href="https://doi.org/10.1016/j.poly.2010.01.004"
- Description: The syntheses of new cobalt phthalocyanine (CoPc) complexes, tetra-substituted with diethylaminoethanethio at the peripheral (complex 3a) and non-peripheral (complex 3b) positions, and with benzylmercapto at the non-peripheral position (complex 5), are reported. The effects of the nature and position of substituent on the spectral, electrochemical and spectroelectrochemical properties of these complexes are investigated. Solution electrochemistry of complex 3a showed three distinctly resolved redox processes attributed to CoIIIPc−2/CoIIPc−2 (E½ = +0.64 V versus Ag|AgCl), CoIIPc−2/CoIPc−2 (E½ = −0.24 V versus Ag|AgCl) and CoIPc−2/CoIPc−3 (E½ = −1.26 V versus Ag|AgCl) species. No ring oxidation was observed in complex 3a. Complex 3b showed both ring-based oxidation, attributed to CoIIIPc−1/CoIIIPc−2 species (Ep = +0.86 V versus Ag|AgCl), and ring-based reduction associated with CoIPc−2/CoIPc−3 species (E½ = −1.46 V versus Ag|AgCl), with the normal metal-based redox processes in CoPc complexes: CoIIIPc−2/CoIIPc−2 (Ep = +0.41 V versus Ag|AgCl) and CoIIPc−2/CoIPc−2 (E½ = −0.38 V versus Ag|AgCl). Solution electrochemistry of complex 5 showed the same type and number of species observed in complex 3a: CoIIIPc−2/CoIIPc−2 (Ep = +0.59 V versus Ag|AgCl), CoIIPc−2/CoIPc−2 (E½ = −0.26 V versus Ag|AgCl) and CoIPc−2/CoIPc−3 (E½ = −1.39 V versus Ag|AgCl) species. These processes were confirmed using spectroelectrochemistry.
- Full Text:
- Date Issued: 2010
Synthesis and electrochemical characterisation of new tantalum (V) alkythio phthalocyanines
- Chauke, Vongani, Nyokong, Tebello
- Authors: Chauke, Vongani , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249093 , vital:51777 , xlink:href="https://doi.org/10.1016/j.ica.2010.05.003"
- Description: The synthesis and electrochemical characterisation of octa-pentylthio (4a) and octa-octylthio (4b) – phthalocyaninato tantalum (III) hydroxide are hereby reported. These TaPc complexes absorb in the near infrared region (∼800 nm in dichloromethane). They show good solubility in most common solvents especially non-viscous solvents such as dichloromethane and chloroform. NMR, mass and infrared spectroscopy and elemental analysis confirmed the structures and purity of the synthesised complexes. The cyclic voltammograms (CVs) showed reversible reduction couples and irreversible oxidation peaks. The latter exhibited adsorption behavior. The reduction processes were observed at −0.74 and −1.13 V (versus Ag|AgCl) for 4a, and −0.67, −1.02 and −1.48 V (versus Ag|AgCl) for 4b. Spectroelectrochemistry confirmed one metal reduction, with the rest of the redox processes being centered on the phthalocyanine ring.
- Full Text:
- Date Issued: 2010
- Authors: Chauke, Vongani , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249093 , vital:51777 , xlink:href="https://doi.org/10.1016/j.ica.2010.05.003"
- Description: The synthesis and electrochemical characterisation of octa-pentylthio (4a) and octa-octylthio (4b) – phthalocyaninato tantalum (III) hydroxide are hereby reported. These TaPc complexes absorb in the near infrared region (∼800 nm in dichloromethane). They show good solubility in most common solvents especially non-viscous solvents such as dichloromethane and chloroform. NMR, mass and infrared spectroscopy and elemental analysis confirmed the structures and purity of the synthesised complexes. The cyclic voltammograms (CVs) showed reversible reduction couples and irreversible oxidation peaks. The latter exhibited adsorption behavior. The reduction processes were observed at −0.74 and −1.13 V (versus Ag|AgCl) for 4a, and −0.67, −1.02 and −1.48 V (versus Ag|AgCl) for 4b. Spectroelectrochemistry confirmed one metal reduction, with the rest of the redox processes being centered on the phthalocyanine ring.
- Full Text:
- Date Issued: 2010
Synthesis and photophysical properties of 1, 1′-binaphthol substituted phthalocyanines
- Canlica, Meylude, Nyokong, Tebello
- Authors: Canlica, Meylude , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249148 , vital:51782 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.034"
- Description: We report on the synthesis, characterization and photophysical properties of a new symmetrically tetra substituted {at non-peripheral positions with tetra(1,1′-bi-binaphtoxy)} phthalocyanines containing H2, Mg(II), Al(III)Cl, Si(IV)Cl2 in the central cavity. The synthesized compounds were characterized by the elemental analyses, UV–Vis, FT-IR and 1H NMR spectroscopies. The fluorescence quantum yields, triplet quantum yields and lifetimes of the newly synthesized H2, Mg, Al, and Si phthalocyanines were explored. Triplet quantum yields ranged from 0.24 to 0.54. The triplet lifetime for the silicon phthalocyanine derivative was the highest ever reported for a phthalocyanine (∼3.5 ms).
- Full Text:
- Date Issued: 2010
- Authors: Canlica, Meylude , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249148 , vital:51782 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.034"
- Description: We report on the synthesis, characterization and photophysical properties of a new symmetrically tetra substituted {at non-peripheral positions with tetra(1,1′-bi-binaphtoxy)} phthalocyanines containing H2, Mg(II), Al(III)Cl, Si(IV)Cl2 in the central cavity. The synthesized compounds were characterized by the elemental analyses, UV–Vis, FT-IR and 1H NMR spectroscopies. The fluorescence quantum yields, triplet quantum yields and lifetimes of the newly synthesized H2, Mg, Al, and Si phthalocyanines were explored. Triplet quantum yields ranged from 0.24 to 0.54. The triplet lifetime for the silicon phthalocyanine derivative was the highest ever reported for a phthalocyanine (∼3.5 ms).
- Full Text:
- Date Issued: 2010
Synthetic pathways to water-soluble phthalocyanines and close analogs
- Dumoulin, Fabienne, Durmus, Mahmut, Ahsen, Vefa, Nyokong, Tebello
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249082 , vital:51776 , xlink:href="https://doi.org/10.1016/j.ccr.2010.05.002"
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed.
- Full Text:
- Date Issued: 2010
- Authors: Dumoulin, Fabienne , Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249082 , vital:51776 , xlink:href="https://doi.org/10.1016/j.ccr.2010.05.002"
- Description: The different types of water-soluble phthalocyanines are presented and their synthesis is reviewed.
- Full Text:
- Date Issued: 2010
Teaching conflict-sensitive journalism:
- Authors: du Toit, Peter
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159449 , vital:40298 , https://hdl.handle.net/10520/EJC139358
- Description: We expect court reporters to know something about the law, financial journalists to have a grounding in economics, and parliamentary correspondents to understand politics, but many journalists are ill-equipped handle social phenomenon that is ubiquitous to most beats - conflict.
- Full Text:
- Date Issued: 2010
- Authors: du Toit, Peter
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159449 , vital:40298 , https://hdl.handle.net/10520/EJC139358
- Description: We expect court reporters to know something about the law, financial journalists to have a grounding in economics, and parliamentary correspondents to understand politics, but many journalists are ill-equipped handle social phenomenon that is ubiquitous to most beats - conflict.
- Full Text:
- Date Issued: 2010
Teaching journalism to produce “interpretive communities" rather than just “professionals”:
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159846 , vital:40349 , DOI: 10.1080/02560054.2005.9653330
- Description: Debates about whether journalism is a “trade” and can only be learnt “on the job”, or whether journalism should even be taught at universities, are no longer fruitful or even interesting for teachers in tertiary environments. The far more important discussion around the teaching of journalism should be on the approach which focuses too exclusively on its nature as a “profession” and so ignores the critical function of journalists in the world as “interpretive communities”.
- Full Text:
- Date Issued: 2010
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159846 , vital:40349 , DOI: 10.1080/02560054.2005.9653330
- Description: Debates about whether journalism is a “trade” and can only be learnt “on the job”, or whether journalism should even be taught at universities, are no longer fruitful or even interesting for teachers in tertiary environments. The far more important discussion around the teaching of journalism should be on the approach which focuses too exclusively on its nature as a “profession” and so ignores the critical function of journalists in the world as “interpretive communities”.
- Full Text:
- Date Issued: 2010
Technology solutions to strengthen the integration of marginalized communities into the global knowledge society
- Hlungulu, Bulumko, Kunjuzwa, Dumani, Ndlovu, Nyankiso, Samalenge, Jimmy, Sikhumbuzo, Ngwenya, Thinyane, Mamello, Terzoli, Alfredo
- Authors: Hlungulu, Bulumko , Kunjuzwa, Dumani , Ndlovu, Nyankiso , Samalenge, Jimmy , Sikhumbuzo, Ngwenya , Thinyane, Mamello , Terzoli, Alfredo
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430769 , vital:72714 , https://ieeexplore.ieee.org/abstract/document/5753005
- Description: Information and Communication Technology (ICT) has made it possible to explore novel and innovative mechanisms to leap-frog socio-economic development in rural and marginalized communities. An ICT for development intervention called Siyakhula Living Lab (SLL) has been underway in Dwesa, a rural community in the Eastern Cape Prov-ince, for the past four years. The living lab methodology, which enables user-driven innovation within a multi-stakeholder relationship of aca-demia, user communities, government and private industry, has facili-tated greater integration of the Dwesa community into the digital ecolo-gy and subsequently the knowledge society. This paper introduces the SLL intervention, discusses the SLL's supporting technical infrastruc-ture and the interventions that are undertaken towards long-term sus-tainability of the project. The developed eServices are also discussed, with a view to highlighting the key characteristics that contribute to in-creased context-sensitivity, ownership, and buy-in from the community.
- Full Text:
- Date Issued: 2010
- Authors: Hlungulu, Bulumko , Kunjuzwa, Dumani , Ndlovu, Nyankiso , Samalenge, Jimmy , Sikhumbuzo, Ngwenya , Thinyane, Mamello , Terzoli, Alfredo
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430769 , vital:72714 , https://ieeexplore.ieee.org/abstract/document/5753005
- Description: Information and Communication Technology (ICT) has made it possible to explore novel and innovative mechanisms to leap-frog socio-economic development in rural and marginalized communities. An ICT for development intervention called Siyakhula Living Lab (SLL) has been underway in Dwesa, a rural community in the Eastern Cape Prov-ince, for the past four years. The living lab methodology, which enables user-driven innovation within a multi-stakeholder relationship of aca-demia, user communities, government and private industry, has facili-tated greater integration of the Dwesa community into the digital ecolo-gy and subsequently the knowledge society. This paper introduces the SLL intervention, discusses the SLL's supporting technical infrastruc-ture and the interventions that are undertaken towards long-term sus-tainability of the project. The developed eServices are also discussed, with a view to highlighting the key characteristics that contribute to in-creased context-sensitivity, ownership, and buy-in from the community.
- Full Text:
- Date Issued: 2010
The ambivalence of African elitehood:
- Authors: Matthews, Sally
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142442 , vital:38080 , DOI: 10.1177/0021909609357416
- Description: Recent discussions in South Africa about the role of the so-called patriotic bourgeoisie highlight the much debated question of what role elite Africans can and ought to play in the upliftment of the poor. Those supporting the notion of a patriotic bourgeoisie believe that national or racial solidarity is sufficient to allow privileged Africans to act in the interests of their poorer fellow citizens. However, a reconsideration of an older discussion of African elitehood, that of Amilcar Cabral, suggests that something more may be needed before elites can act in the interests of the poor. Cabral argues that elites need to renounce their privilege and to live and struggle alongside the poor if pro-poor societal transformation is to be achieved. While Cabral may be right that shared racial or national identity is insufficient for elite solidarity with the poor, he does not consider all the complexities that arise when elites actually try to work with and for the poor. A consideration of the experiences of a long-standing Senegalese NGO reveal some of these complexities and suggest that any attempt by African elites to engage meaningfully in the upliftment of the poor, will inevitably involve continuous and difficult negotiation between paternalism and naïve egalitarianism.
- Full Text:
- Date Issued: 2010
- Authors: Matthews, Sally
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142442 , vital:38080 , DOI: 10.1177/0021909609357416
- Description: Recent discussions in South Africa about the role of the so-called patriotic bourgeoisie highlight the much debated question of what role elite Africans can and ought to play in the upliftment of the poor. Those supporting the notion of a patriotic bourgeoisie believe that national or racial solidarity is sufficient to allow privileged Africans to act in the interests of their poorer fellow citizens. However, a reconsideration of an older discussion of African elitehood, that of Amilcar Cabral, suggests that something more may be needed before elites can act in the interests of the poor. Cabral argues that elites need to renounce their privilege and to live and struggle alongside the poor if pro-poor societal transformation is to be achieved. While Cabral may be right that shared racial or national identity is insufficient for elite solidarity with the poor, he does not consider all the complexities that arise when elites actually try to work with and for the poor. A consideration of the experiences of a long-standing Senegalese NGO reveal some of these complexities and suggest that any attempt by African elites to engage meaningfully in the upliftment of the poor, will inevitably involve continuous and difficult negotiation between paternalism and naïve egalitarianism.
- Full Text:
- Date Issued: 2010
The commercial agricultural economy of the East Cape: Die kommersiële landbou-ekonomie van die Oos-Kaap
- Authors: Antrobus, Geoffrey G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143079 , vital:38199 , DOI: 10.1080/03031853.1991.9524228
- Description: The East Cape, and in particular the Smaldeel area, is used to exemplify some of the characteristics and problems of commercial farming over a period of about three decades to serve as a backdrop for the broader theme of normalising South African agriculture. The regional economy is dominated by Port Elizabeth-Uitenhage and East London which account for most of the population and three-fourths of the Gross Geographic Product (GGP). Agriculture accounts for only 10% of GGP, but is one of the most labour intensive sectors in a region with 24% of its population unemployed. The agricultural economy of the region is very diversified, but livestock farming plays the most important part in all areas contributing 72% of gross income. The chief changes which have occured in East Cape farming, as elsewhere, have been the decline in the number of farms and increase in farm size, greater capital investment, increased specialisation and declining employment.
- Full Text:
- Date Issued: 2010
- Authors: Antrobus, Geoffrey G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143079 , vital:38199 , DOI: 10.1080/03031853.1991.9524228
- Description: The East Cape, and in particular the Smaldeel area, is used to exemplify some of the characteristics and problems of commercial farming over a period of about three decades to serve as a backdrop for the broader theme of normalising South African agriculture. The regional economy is dominated by Port Elizabeth-Uitenhage and East London which account for most of the population and three-fourths of the Gross Geographic Product (GGP). Agriculture accounts for only 10% of GGP, but is one of the most labour intensive sectors in a region with 24% of its population unemployed. The agricultural economy of the region is very diversified, but livestock farming plays the most important part in all areas contributing 72% of gross income. The chief changes which have occured in East Cape farming, as elsewhere, have been the decline in the number of farms and increase in farm size, greater capital investment, increased specialisation and declining employment.
- Full Text:
- Date Issued: 2010
The effects of economic incentives in controlling pollution in the South African leather industry: die uitwerking van ekonomiese insentiewe op die beheer van besoedeling in die Suid-Afrikaanse leerbedryf
- Mowat, Shaun P, Antrobus, Geoffrey G, Fraser, Gavin C G
- Authors: Mowat, Shaun P , Antrobus, Geoffrey G , Fraser, Gavin C G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143057 , vital:38197 , DOI: 10.1080/03031853.1997.9523487
- Description: Pollution of the environment is becoming an increasingly serious problem. A large contributor to this is industry which generates effluent as a by-product of its production process. Two methods of controlling the pollution generated by industry are the so-called “command and control” techniques and economic incentives. In theory, economic incentives promise a more economically efficient and equitable means of pollution control. This paper sets out to ascertain whether this would hold in practice by applying environmental economic theory to the practical problem of controlling the effluent generated by one particular industry, viz the South African leather industry.
- Full Text:
- Date Issued: 2010
- Authors: Mowat, Shaun P , Antrobus, Geoffrey G , Fraser, Gavin C G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143057 , vital:38197 , DOI: 10.1080/03031853.1997.9523487
- Description: Pollution of the environment is becoming an increasingly serious problem. A large contributor to this is industry which generates effluent as a by-product of its production process. Two methods of controlling the pollution generated by industry are the so-called “command and control” techniques and economic incentives. In theory, economic incentives promise a more economically efficient and equitable means of pollution control. This paper sets out to ascertain whether this would hold in practice by applying environmental economic theory to the practical problem of controlling the effluent generated by one particular industry, viz the South African leather industry.
- Full Text:
- Date Issued: 2010
The effects of point of substitution on the electrochemical behavior of new manganese phthalocyanines, tetra-substituted with diethylaminoethanethiol
- Akinbulu, Isaac Adebayo, Nyokong, Tebello
- Authors: Akinbulu, Isaac Adebayo , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249137 , vital:51781 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.003"
- Description: The syntheses and comparative studies of the spectral, voltammetry and spectroelectrochemical properties of new manganese phthalocyanine complexes, tetra-substituted with diethylaminoethanethio at the peripheral (complex 3a) and non-peripheral positions (complex 3b) are reported. Solution electrochemistry of complex 3a showed quasi-reversible metal-based (MnIIIPc−2/MnIIPc−2, E1/2 = −0.07 V vs. Ag|AgCl) and ring-based (MnIIPc−2/MnIIPc−3, E1/2 = −0.78 V vs. Ag|AgCl) reductions, but no ring-based oxidation. However, complex 3b showed weak irreversible ring-oxidation signal (Ep = +0.86 vs. Ag|AgCl). Reversible metal-based (MnIIIPc−2/MnIIPc−2, E1/2 = −0.04 V vs. Ag|AgCl) and ring-based (MnIIPc−2/MnIIPc−3, E1/2 = −0.68 V vs. Ag|AgCl) reductions were also observed for complex 3b. Spectroelectrochemistry was used to confirm these processes. Reduction process involving the metal (MnIIIPc−2/MnIIPc−2) was associated with the formation of manganese μ-oxo complex in complex 3a.
- Full Text:
- Date Issued: 2010
- Authors: Akinbulu, Isaac Adebayo , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249137 , vital:51781 , xlink:href="https://doi.org/10.1016/j.ica.2010.06.003"
- Description: The syntheses and comparative studies of the spectral, voltammetry and spectroelectrochemical properties of new manganese phthalocyanine complexes, tetra-substituted with diethylaminoethanethio at the peripheral (complex 3a) and non-peripheral positions (complex 3b) are reported. Solution electrochemistry of complex 3a showed quasi-reversible metal-based (MnIIIPc−2/MnIIPc−2, E1/2 = −0.07 V vs. Ag|AgCl) and ring-based (MnIIPc−2/MnIIPc−3, E1/2 = −0.78 V vs. Ag|AgCl) reductions, but no ring-based oxidation. However, complex 3b showed weak irreversible ring-oxidation signal (Ep = +0.86 vs. Ag|AgCl). Reversible metal-based (MnIIIPc−2/MnIIPc−2, E1/2 = −0.04 V vs. Ag|AgCl) and ring-based (MnIIPc−2/MnIIPc−3, E1/2 = −0.68 V vs. Ag|AgCl) reductions were also observed for complex 3b. Spectroelectrochemistry was used to confirm these processes. Reduction process involving the metal (MnIIIPc−2/MnIIPc−2) was associated with the formation of manganese μ-oxo complex in complex 3a.
- Full Text:
- Date Issued: 2010
The effects of point of substitution on the formation of manganese phthalocyanine-based molecular materials
- Akinbulu, Isaac Adebayo, Khene, Samson, Nyokong, Tebello
- Authors: Akinbulu, Isaac Adebayo , Khene, Samson , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249103 , vital:51778 , xlink:href="https://doi.org/10.1016/j.tsf.2010.08.145"
- Description: Molecular films of manganese phthalocyanine (MnPc) complexes, tetra-substituted with 2-diethylaminoethanethio at the peripheral (Mn(OAc)-β-TDEAETPc, 1) and non-peripheral (Mn(OAc)-α-TDEAETPc, 2) positions were formed on glassy carbon electrode by electropolymerization and electrodeposition respectively. Atomic force microscopy images confirmed the presence of the films and revealed significant morphological differences. The films exhibited an electrocatalytic activity towards the oxidation of the insecticide, bendiocarb. Hydrodynamic technique, using rotating disc electrode voltammetry, was used to investigate the kinetics of electro-oxidation of the insecticide. Morphological differences of the films significantly influenced kinetic parameters. Values of Tafel slopes, obtained from Tafel plots, suggested that catalysis of bendiocarb occurred via outer sphere mechanism.
- Full Text:
- Date Issued: 2010
- Authors: Akinbulu, Isaac Adebayo , Khene, Samson , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249103 , vital:51778 , xlink:href="https://doi.org/10.1016/j.tsf.2010.08.145"
- Description: Molecular films of manganese phthalocyanine (MnPc) complexes, tetra-substituted with 2-diethylaminoethanethio at the peripheral (Mn(OAc)-β-TDEAETPc, 1) and non-peripheral (Mn(OAc)-α-TDEAETPc, 2) positions were formed on glassy carbon electrode by electropolymerization and electrodeposition respectively. Atomic force microscopy images confirmed the presence of the films and revealed significant morphological differences. The films exhibited an electrocatalytic activity towards the oxidation of the insecticide, bendiocarb. Hydrodynamic technique, using rotating disc electrode voltammetry, was used to investigate the kinetics of electro-oxidation of the insecticide. Morphological differences of the films significantly influenced kinetic parameters. Values of Tafel slopes, obtained from Tafel plots, suggested that catalysis of bendiocarb occurred via outer sphere mechanism.
- Full Text:
- Date Issued: 2010
The gap between what 'ought' to be and what students want
- Authors: Boshoff, Priscilla A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70812 , vital:29747
- Description: There’s no curriculum! There’s no curriculum!” The young man in the focus group was so frustrated that he had to repeat himself, not just once, but several times. I had just asked the group what their feelings were about their second-year coursework. His sentiments were echoed by many of the students in the group, all of whom had passed the rigorous application process into second year at Rhodes University’s School of Journalism and Media Studies.
- Full Text:
- Date Issued: 2010
- Authors: Boshoff, Priscilla A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70812 , vital:29747
- Description: There’s no curriculum! There’s no curriculum!” The young man in the focus group was so frustrated that he had to repeat himself, not just once, but several times. I had just asked the group what their feelings were about their second-year coursework. His sentiments were echoed by many of the students in the group, all of whom had passed the rigorous application process into second year at Rhodes University’s School of Journalism and Media Studies.
- Full Text:
- Date Issued: 2010
The geochemistry and evolution of Palaeogene phonolites, central Namibia:
- Authors: Marsh, Julian S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145000 , vital:38399 , https://doi.org/10.1016/j.lithos.2010.02.012
- Description: Phonolites of Palaeogene age occur at two different localities in central Namibia, occurring as clusters of eroded monogenetic lava domes. Six phonolites at Aris collectively exhibit a narrow compositional range and represent a single magma system of highly evolved phonolite with high concentrations of Na2O, Rb, Th, Zr, Zn, Pb, and REE and very low abundances of MgO, P2O5, Sr and Ba. No mafic rocks are associated with the Aris phonolites and their ultimate petrogenetic origin remains obscure. The more abundant Staalhart phonolites exhibit more variable but scattered compositional variation consistent with fractional crystallization dominated by sanidine (and nepheline) and pyroxene. The behaviour of REE is decoupled from Zr, Nb, and Th in this suite indicating a controlling role for minor phases in their evolution. The least evolved phonolites have initial 87Sr/86Sr 0.7043, which is identical to a small occurrence of associated plagioclase-bearing nephelinite indicating a possible petrogenetic link.
- Full Text:
- Date Issued: 2010
- Authors: Marsh, Julian S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145000 , vital:38399 , https://doi.org/10.1016/j.lithos.2010.02.012
- Description: Phonolites of Palaeogene age occur at two different localities in central Namibia, occurring as clusters of eroded monogenetic lava domes. Six phonolites at Aris collectively exhibit a narrow compositional range and represent a single magma system of highly evolved phonolite with high concentrations of Na2O, Rb, Th, Zr, Zn, Pb, and REE and very low abundances of MgO, P2O5, Sr and Ba. No mafic rocks are associated with the Aris phonolites and their ultimate petrogenetic origin remains obscure. The more abundant Staalhart phonolites exhibit more variable but scattered compositional variation consistent with fractional crystallization dominated by sanidine (and nepheline) and pyroxene. The behaviour of REE is decoupled from Zr, Nb, and Th in this suite indicating a controlling role for minor phases in their evolution. The least evolved phonolites have initial 87Sr/86Sr 0.7043, which is identical to a small occurrence of associated plagioclase-bearing nephelinite indicating a possible petrogenetic link.
- Full Text:
- Date Issued: 2010