The effect of an alkyl chain and β-diketonato-metal moiety on the photochromic behaviour of azobenzene compounds as materials for solar thermal fuels
- Authors: Bokhe, Witness Londi
- Date: 2024-10-11
- Subjects: Photochemistry , Isomerization , Solar thermal energy , Solar thermal fuel , Liquid crystals , Optical materials
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464510 , vital:76517
- Description: Scientists have been studying the development of renewable energy technologies in detail to create a sustainable energy supply. Among many new advanced material classes being researched recently are photo functional and photo responsive materials. These classes include azobenzene derivatives which are characterized by azo linkage (N=N) sandwiched by two phenyl rings. The trans-to-cis isomerization of azobenzene is a highly efficient and reversible process, making it an ideal candidate for solar thermal energy storage. This research investigates the impact of alkyl chain modifications and the incorporation of a β-diketonato-copper(II) complex on azobenzene derivatives, aiming to optimize their performance as efficient components in solar thermal fuel cells (STFs). The study focuses on a comprehensive analysis of these materials' ability to capture, convert, store, and release solar energy for enhanced sustainability in renewable energy applications. Experimental methodologies include synthesis of azobenzene derivatives with varying alkyl chain length, n (where n =8 & 10) and coordination of these compounds with a β-diketonato-copper(II) complex. Standard analytical techniques such as Nuclear Magnetic Resonance (1H and 13C NMR), Fourier Transform Infrared Spectroscopy (FTIR) and Ultraviolet/visible spectroscopy (UV/vis) were employed for chemical analysis of the synthesized material. Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), and Polarised Optical Microscope (POM) were used to study the thermal properties and morphology. The photostationery states were determined using NMR spectroscopy and the kinetic parameters of the cis-to-trans relaxation process determined by a UV spectroscopy study. The cis-to-trans isomerisation had a longer half-life than the trans-to-cis isomerisation. The band gap of the isomers is within the range of semiconducting inorganic materials. DSC and POM thermograms showed that the compounds are liquid crystalline. Finally, the study reports that the synthesised azobenzene derivatives show potential as material for solar thermal fuel cells because of their photo-isomerization ability. Furthermore, the synthesised compounds contribute to the advancement of sustainable and efficient solar energy utilization technologies, addressing the growing demand for clean energy solutions in the face of global environmental challenges. Because solar energy may be stored and used without causing direct emissions or pollution, they are considered clean energy. If solar thermal fuels fulfil sustainability standards, they may qualify as green energy. This entails minimising adverse effects on the environment, using non-toxic chemicals and procedures. , Thesis (MSc) -- Faculty of Science, Chemistry, 2024
- Full Text:
- Date Issued: 2024-10-11
- Authors: Bokhe, Witness Londi
- Date: 2024-10-11
- Subjects: Photochemistry , Isomerization , Solar thermal energy , Solar thermal fuel , Liquid crystals , Optical materials
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464510 , vital:76517
- Description: Scientists have been studying the development of renewable energy technologies in detail to create a sustainable energy supply. Among many new advanced material classes being researched recently are photo functional and photo responsive materials. These classes include azobenzene derivatives which are characterized by azo linkage (N=N) sandwiched by two phenyl rings. The trans-to-cis isomerization of azobenzene is a highly efficient and reversible process, making it an ideal candidate for solar thermal energy storage. This research investigates the impact of alkyl chain modifications and the incorporation of a β-diketonato-copper(II) complex on azobenzene derivatives, aiming to optimize their performance as efficient components in solar thermal fuel cells (STFs). The study focuses on a comprehensive analysis of these materials' ability to capture, convert, store, and release solar energy for enhanced sustainability in renewable energy applications. Experimental methodologies include synthesis of azobenzene derivatives with varying alkyl chain length, n (where n =8 & 10) and coordination of these compounds with a β-diketonato-copper(II) complex. Standard analytical techniques such as Nuclear Magnetic Resonance (1H and 13C NMR), Fourier Transform Infrared Spectroscopy (FTIR) and Ultraviolet/visible spectroscopy (UV/vis) were employed for chemical analysis of the synthesized material. Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), and Polarised Optical Microscope (POM) were used to study the thermal properties and morphology. The photostationery states were determined using NMR spectroscopy and the kinetic parameters of the cis-to-trans relaxation process determined by a UV spectroscopy study. The cis-to-trans isomerisation had a longer half-life than the trans-to-cis isomerisation. The band gap of the isomers is within the range of semiconducting inorganic materials. DSC and POM thermograms showed that the compounds are liquid crystalline. Finally, the study reports that the synthesised azobenzene derivatives show potential as material for solar thermal fuel cells because of their photo-isomerization ability. Furthermore, the synthesised compounds contribute to the advancement of sustainable and efficient solar energy utilization technologies, addressing the growing demand for clean energy solutions in the face of global environmental challenges. Because solar energy may be stored and used without causing direct emissions or pollution, they are considered clean energy. If solar thermal fuels fulfil sustainability standards, they may qualify as green energy. This entails minimising adverse effects on the environment, using non-toxic chemicals and procedures. , Thesis (MSc) -- Faculty of Science, Chemistry, 2024
- Full Text:
- Date Issued: 2024-10-11
On the characterisation of diffused light and optical elements in high concentrator photovoltaic modules
- Authors: Schultz, Ross Dane
- Date: 2015
- Subjects: Photovoltaic cells , Solar concentrators , Optical materials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/5170 , vital:20817
- Description: High Concentrated Photovoltaics (H-CPV) promise a more efficient, higher power output than traditional photovoltaic modules. This is achieved by concentrating sunlight onto a small triple junction (CTJ) InGaP/InGaAs/Ge cell (ranging from 3.14 mm2 to 1 cm2) by using precision optical systems. These systems utilise non-imaging optics to concentrate and distribute the incident solar flux uniformly onto the CTJ device receiver to achieve maximum performance and power output from an H-CPV module. However, the performance of the device can be reduced due to the partial or complete absorption of a range of wavelengths present in the solar spectrum by the optical materials that are used for concentration. An investigation to determine the current density topographies of each subcell in a CTJ cell by multiple raster scans of an optical fibre receiver of a spectrometer in the plane of the aperture of the secondary’s optical element was conducted. Results showed that the physical properties of the optical elements’ material absorbed different amounts of the spectral content with respect to the subcell photosensitive wavelength regions. The facet properties of the primary optical Fresnel lens showed that the more rounded the Fresnel facets were, the lower the concentration of sunlight incident onto the CTJ cell. The increase in facet numbers showed an increase in scattering of the incident sunlight and chromatic aberrations. Chromatic aberration created by the refractive optics showed a variation in the amount of concentration on each individual subcell as well as the difference in intensity profiles across for the different subcells. Based on these results and the development of new multi-junction devices by industry, the performance of a four and six-junction device with the optical materials was investigated by simulations. The simulations showed that the careful integration of an additional subcell in a multi-junction device could rectify current mismatch between the subcells in the device. Based on the simulations, the best performing multi-junction cell was identified as the four-junction device that showed a cell and module efficiency under operation of 42.5 % and 35.5 %, respectively. Additionally, based on the performance results observed from the H-CPV module, the development of an HCPV module that would attempt to harness the incident tracked diffuse sunlight available to a concentrator photovoltaic (CPV) module for additional energy yield was undertaken. The part of the study comprised of measurements of the solar source, design of a prototype Hybrid High Concentrator Photovoltaic (HH-CPV) module. Results showed that power generation from the H-CPV system was highly dependent on the DNI levels and fluctuates greatly with variation in the DNI. The irradiance levels within the diffuse regions of the H-CPV module showed that the baseplate and vertical sides had an average irradiance range of 140-450 and 50-225 W.m-2, respectively. Irradiance topographic raster scans revealed that the baseplate and vertical sides had a relatively uniform intensity distribution and was identified as favourable sites for diffuse cell population. Simulations of various PV technologies showed the most suitable technology for the placement within the cavity of the HH-CPV module. The developed HH-CPV module was finalized with the utilization of CIS modules to harness the diffuse irradiance. During a 3 month power monitoring of the HH-CPV system, it was determined that the major power generation for the HH-CPV module come from the CPV component, while the CIS modules showed a minor power contribution. The total energy yield for the monitoring period was 45.99, 3.89 and 1.76 kW.h for the CPV, four-vertical sides and baseplate components, respectively. The increase in energy yield of the HH-CPV module when compared to the standard H-CPV module was determined to be 12.35 % for the monitoring period. The incorporation of the CIS modules into the H-CPV module to create the HH-CPV module did increase the energy yield of the module during high DNI conditions and did offset the almost zero power generation during low DNI conditions.
- Full Text:
- Date Issued: 2015
- Authors: Schultz, Ross Dane
- Date: 2015
- Subjects: Photovoltaic cells , Solar concentrators , Optical materials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/5170 , vital:20817
- Description: High Concentrated Photovoltaics (H-CPV) promise a more efficient, higher power output than traditional photovoltaic modules. This is achieved by concentrating sunlight onto a small triple junction (CTJ) InGaP/InGaAs/Ge cell (ranging from 3.14 mm2 to 1 cm2) by using precision optical systems. These systems utilise non-imaging optics to concentrate and distribute the incident solar flux uniformly onto the CTJ device receiver to achieve maximum performance and power output from an H-CPV module. However, the performance of the device can be reduced due to the partial or complete absorption of a range of wavelengths present in the solar spectrum by the optical materials that are used for concentration. An investigation to determine the current density topographies of each subcell in a CTJ cell by multiple raster scans of an optical fibre receiver of a spectrometer in the plane of the aperture of the secondary’s optical element was conducted. Results showed that the physical properties of the optical elements’ material absorbed different amounts of the spectral content with respect to the subcell photosensitive wavelength regions. The facet properties of the primary optical Fresnel lens showed that the more rounded the Fresnel facets were, the lower the concentration of sunlight incident onto the CTJ cell. The increase in facet numbers showed an increase in scattering of the incident sunlight and chromatic aberrations. Chromatic aberration created by the refractive optics showed a variation in the amount of concentration on each individual subcell as well as the difference in intensity profiles across for the different subcells. Based on these results and the development of new multi-junction devices by industry, the performance of a four and six-junction device with the optical materials was investigated by simulations. The simulations showed that the careful integration of an additional subcell in a multi-junction device could rectify current mismatch between the subcells in the device. Based on the simulations, the best performing multi-junction cell was identified as the four-junction device that showed a cell and module efficiency under operation of 42.5 % and 35.5 %, respectively. Additionally, based on the performance results observed from the H-CPV module, the development of an HCPV module that would attempt to harness the incident tracked diffuse sunlight available to a concentrator photovoltaic (CPV) module for additional energy yield was undertaken. The part of the study comprised of measurements of the solar source, design of a prototype Hybrid High Concentrator Photovoltaic (HH-CPV) module. Results showed that power generation from the H-CPV system was highly dependent on the DNI levels and fluctuates greatly with variation in the DNI. The irradiance levels within the diffuse regions of the H-CPV module showed that the baseplate and vertical sides had an average irradiance range of 140-450 and 50-225 W.m-2, respectively. Irradiance topographic raster scans revealed that the baseplate and vertical sides had a relatively uniform intensity distribution and was identified as favourable sites for diffuse cell population. Simulations of various PV technologies showed the most suitable technology for the placement within the cavity of the HH-CPV module. The developed HH-CPV module was finalized with the utilization of CIS modules to harness the diffuse irradiance. During a 3 month power monitoring of the HH-CPV system, it was determined that the major power generation for the HH-CPV module come from the CPV component, while the CIS modules showed a minor power contribution. The total energy yield for the monitoring period was 45.99, 3.89 and 1.76 kW.h for the CPV, four-vertical sides and baseplate components, respectively. The increase in energy yield of the HH-CPV module when compared to the standard H-CPV module was determined to be 12.35 % for the monitoring period. The incorporation of the CIS modules into the H-CPV module to create the HH-CPV module did increase the energy yield of the module during high DNI conditions and did offset the almost zero power generation during low DNI conditions.
- Full Text:
- Date Issued: 2015
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