Catalytic activity of iron and cobalt phthalocyanine complexes towards the oxidation of cyclohexene using tert-butylhydroperoxide and chloroperoxybenzoic acid
- Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290257 , vital:56729 , xlink:href="https://doi.org/10.1016/j.molcata.2003.08.014"
- Description: Cyclohexene oxidation using tert-butylhydroperoxide (TBHP) or chloroperoxybenzoic acid (CPBA) in the presence of iron(II) polychlorophthalocyanine (Cl16PcFe), iron(II) phthalocyanine (PcFe) and cobalt(II) phthalocyanine (PcCo), results in the formation of the following products: cyclohexene oxide, 2-cyclohexene-1-ol and 2-cyclohexene-1-one. Adipic acid was also formed after long reaction times. The selectivity for 2-cyclohexene-1-one is favoured when Cl16PcFe or PcCo catalysts are employed, while PcFe is selective towards the formation of 2-cyclohexene-1-ol. The Cl16PcFe catalyst is transformed into a μ-oxo dimer (Cl16PcFeIIIOIIIFePcCl16) during the oxidation process. The catalytic process using the unsubstituted PcCoII and PcFeII catalysts involved PcMIII species as an intermediate. The active form of the Cl16PcFe catalyst was stable to degradation in that it was still active even after 4 weeks of continued catalysis.
- Full Text:
- Date Issued: 2004
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290257 , vital:56729 , xlink:href="https://doi.org/10.1016/j.molcata.2003.08.014"
- Description: Cyclohexene oxidation using tert-butylhydroperoxide (TBHP) or chloroperoxybenzoic acid (CPBA) in the presence of iron(II) polychlorophthalocyanine (Cl16PcFe), iron(II) phthalocyanine (PcFe) and cobalt(II) phthalocyanine (PcCo), results in the formation of the following products: cyclohexene oxide, 2-cyclohexene-1-ol and 2-cyclohexene-1-one. Adipic acid was also formed after long reaction times. The selectivity for 2-cyclohexene-1-one is favoured when Cl16PcFe or PcCo catalysts are employed, while PcFe is selective towards the formation of 2-cyclohexene-1-ol. The Cl16PcFe catalyst is transformed into a μ-oxo dimer (Cl16PcFeIIIOIIIFePcCl16) during the oxidation process. The catalytic process using the unsubstituted PcCoII and PcFeII catalysts involved PcMIII species as an intermediate. The active form of the Cl16PcFe catalyst was stable to degradation in that it was still active even after 4 weeks of continued catalysis.
- Full Text:
- Date Issued: 2004
Determination of 2′, 3′-Dideoxyinosine Using Iron (II) Phthalocyanine Modified Carbon Paste Electrode
- Ozoemena, Kenneth I, Stefan, Raluca-Ioana, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Stefan, Raluca-Ioana , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300298 , vital:57914 , xlink:href="https://doi.org/10.1081/AL-200031940"
- Description: An amperometric sensor, based on carbon paste impregnated with iron (II) phthalocyanine complex (FePc), has been constructed for the assay of anti‐HIV agent dideoxyinosine (didanosine, DDI). Using chronoamperometry (E = +1.04 V versus Ag/AgCl) technique, the amperometric sensor can be used reliably for dideoxyinosine assay at pH 7.4 phosphate buffer in the 1.5–9.5 nmol/L concentration range with a detection limit of 5.7 × 10−10 mol/L. The surface of the electrode can easily be regenerated by simple polishing, obtaining a fresh surface ready for use in a new assay. The new amperometric sensor proved to be highly reliable for the assay of dideoxyinosine purity in raw material as well as for the uniformity content test of Videx® tablets.
- Full Text:
- Date Issued: 2004
- Authors: Ozoemena, Kenneth I , Stefan, Raluca-Ioana , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300298 , vital:57914 , xlink:href="https://doi.org/10.1081/AL-200031940"
- Description: An amperometric sensor, based on carbon paste impregnated with iron (II) phthalocyanine complex (FePc), has been constructed for the assay of anti‐HIV agent dideoxyinosine (didanosine, DDI). Using chronoamperometry (E = +1.04 V versus Ag/AgCl) technique, the amperometric sensor can be used reliably for dideoxyinosine assay at pH 7.4 phosphate buffer in the 1.5–9.5 nmol/L concentration range with a detection limit of 5.7 × 10−10 mol/L. The surface of the electrode can easily be regenerated by simple polishing, obtaining a fresh surface ready for use in a new assay. The new amperometric sensor proved to be highly reliable for the assay of dideoxyinosine purity in raw material as well as for the uniformity content test of Videx® tablets.
- Full Text:
- Date Issued: 2004
Electrochemical and catalytic properties of chromium tetraaminophthalocyanine
- Obirai, Joe, Nyokong, Tebello
- Authors: Obirai, Joe , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300310 , vital:57915 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.06.026"
- Description: Chromium tetraaminophthalocyanine (CrIIITAPc) has been synthesized and its electrochemical and spectroelectrochemical properties reported. The first reduction and oxidation in this complex occur at the central metal, giving CrIITAPc and CrIVTAPc complexes, respectively, the latter having been observed for the first time. The CrIIITAPc species was polymerized onto glassy carbon (GCE) or indium tin oxide (ITO) electrodes and the polymer evolution confirmed by UV/Visible spectroscopy and by scanning electron microscopy. The polymers were employed for the catalytic oxidation of nitrite or nitric oxide, and the catalysis involved the CrIVTAPc−1 species.
- Full Text:
- Date Issued: 2004
- Authors: Obirai, Joe , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300310 , vital:57915 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.06.026"
- Description: Chromium tetraaminophthalocyanine (CrIIITAPc) has been synthesized and its electrochemical and spectroelectrochemical properties reported. The first reduction and oxidation in this complex occur at the central metal, giving CrIITAPc and CrIVTAPc complexes, respectively, the latter having been observed for the first time. The CrIIITAPc species was polymerized onto glassy carbon (GCE) or indium tin oxide (ITO) electrodes and the polymer evolution confirmed by UV/Visible spectroscopy and by scanning electron microscopy. The polymers were employed for the catalytic oxidation of nitrite or nitric oxide, and the catalysis involved the CrIVTAPc−1 species.
- Full Text:
- Date Issued: 2004
Electrochemical studies of manganese tetraamminophthalocyanine monomer and polymer
- Obirai, Joseph, Nyokong, Tebello
- Authors: Obirai, Joseph , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290330 , vital:56738 , xlink:href="https://doi.org/10.1016/j.electacta.2003.11.006"
- Description: Manganese tetraaminophthalocyanine (MnTAPc) has been synthesised. The cyclic voltammetry and spectroelectrochemistry of the complex have been examined. Spectroelectrochemistry has been used to confirm that the species synthesised in this work contains MnIII, giving (OH)MnIIITAPc. The oxidation and reduction couples obtained from cyclic voltammetry have been assigned to MnIVPc−/MnIVPc2− (couple I), MnIVPc2−/MnIIIPc2− (couple I′), MnIIIPc2−/MnIIPc2− (couple II) and MnIIPc2−/MnIIPc3− (couple III). Electropolymerization of the MnTAPc onto either the indium tin oxide or glassy carbon electrode results in the in the formation of a poly-MnTAPc. The poly-MnTAPc shows improved reversibility at low pH. The poly-MnTAPc electrode was employed to analyse glycine.
- Full Text:
- Date Issued: 2004
- Authors: Obirai, Joseph , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/290330 , vital:56738 , xlink:href="https://doi.org/10.1016/j.electacta.2003.11.006"
- Description: Manganese tetraaminophthalocyanine (MnTAPc) has been synthesised. The cyclic voltammetry and spectroelectrochemistry of the complex have been examined. Spectroelectrochemistry has been used to confirm that the species synthesised in this work contains MnIII, giving (OH)MnIIITAPc. The oxidation and reduction couples obtained from cyclic voltammetry have been assigned to MnIVPc−/MnIVPc2− (couple I), MnIVPc2−/MnIIIPc2− (couple I′), MnIIIPc2−/MnIIPc2− (couple II) and MnIIPc2−/MnIIPc3− (couple III). Electropolymerization of the MnTAPc onto either the indium tin oxide or glassy carbon electrode results in the in the formation of a poly-MnTAPc. The poly-MnTAPc shows improved reversibility at low pH. The poly-MnTAPc electrode was employed to analyse glycine.
- Full Text:
- Date Issued: 2004
Emerging patterns of abstraction in environmental education: A review of materials, methods and professional development perspectives
- O'Donoghue, Rob B, Russo, Vladimir
- Authors: O'Donoghue, Rob B , Russo, Vladimir
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373610 , vital:66707 , xlink:href="https://doi.org/10.1080/1350462042000258170"
- Description: The epistemic unconscious is the history of the field. And it is clear that, to secure some chance of really knowing what one is doing, one has to unfold what is inscribed in the various relations of implication in which the thinker and his thoughts are caught up, that is, the presuppositions he engages and the inclusions and exclusions he unwittingly performs. (Bourdieu, 2000, p. 99).
- Full Text:
- Date Issued: 2004
- Authors: O'Donoghue, Rob B , Russo, Vladimir
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373610 , vital:66707 , xlink:href="https://doi.org/10.1080/1350462042000258170"
- Description: The epistemic unconscious is the history of the field. And it is clear that, to secure some chance of really knowing what one is doing, one has to unfold what is inscribed in the various relations of implication in which the thinker and his thoughts are caught up, that is, the presuppositions he engages and the inclusions and exclusions he unwittingly performs. (Bourdieu, 2000, p. 99).
- Full Text:
- Date Issued: 2004
Environmental education research and social change: Southern African perspectives
- Authors: Lotz-Sisitka, Heila
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182709 , vital:43855 , xlink:href="https://doi.org/10.1080/1350462042000258143"
- Description: Environmental issues and risks in southern Africa have, like elsewhere in the world, their roots in the structures and orientations of modern societies. In modernist fashion, we draw on education and research to address socio-ecological concerns. In 1995 Eureta Janse van Rensburg, then Murray and Roberts Chair of Environmental Education at Rhodes University,1 undertook a study to identify environmental education research priorities, and through her study she provided a description of research in environmental education as a ‘landscape of shifting priorites’ (Janse van Rensburg, 1995). The papers in this journal offer a contemporary ‘snapshot’ of the landscape of environmental education research in southern Africa, illustrating a fresh range of ‘shifting priorities’.
- Full Text:
- Date Issued: 2004
- Authors: Lotz-Sisitka, Heila
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182709 , vital:43855 , xlink:href="https://doi.org/10.1080/1350462042000258143"
- Description: Environmental issues and risks in southern Africa have, like elsewhere in the world, their roots in the structures and orientations of modern societies. In modernist fashion, we draw on education and research to address socio-ecological concerns. In 1995 Eureta Janse van Rensburg, then Murray and Roberts Chair of Environmental Education at Rhodes University,1 undertook a study to identify environmental education research priorities, and through her study she provided a description of research in environmental education as a ‘landscape of shifting priorites’ (Janse van Rensburg, 1995). The papers in this journal offer a contemporary ‘snapshot’ of the landscape of environmental education research in southern Africa, illustrating a fresh range of ‘shifting priorities’.
- Full Text:
- Date Issued: 2004
Harvesting impacts on commonly used medicinal tree species (Catha edulis and Rapanea melanophloeos) under different land management regimes in the Mpumalanga Lowveld, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181379 , vital:43728 , xlink:href="https://doi.org/10.4102/koedoe.v47i2.77"
- Description: Harvesting of products from plants in the wild is widespread throughout southern Africa. Particularly important products are plant parts used in traditional medicine. However, the impacts of harvesting practices are rarely quantified, with as yet insufficient generic rules across species and life forms. This limits the predictive ability to monitor and manage the affected populations. This paper examines the harvesting impact on two popular woody medicinal species used throughout sub-Saharan Africa, namely Catha edulis (Vahl) Forssk. ex Endl. (bushman’s tea) and Rapanea melanophloeos (L.) Mez. (Cape beech). In both species, basal diameters, heights, and the number of size classes in the harvested populations were lower than in unharvested. Densities of harvested populations were higher in both species, including densities of young plants, but the frequency of individuals in larger size classes was lower. The populations of both species being harvested for medicinal products appeared to be withstanding the current levels of harvesting, but the population structure of C. edulis populations being harvested for poles on the roadside and near human settlements had been substantially altered. Despite the resilience of the two species to harvesting for medicinal products, loss of habitat or changes in land use pose a threat to a number of the assessed populations.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181379 , vital:43728 , xlink:href="https://doi.org/10.4102/koedoe.v47i2.77"
- Description: Harvesting of products from plants in the wild is widespread throughout southern Africa. Particularly important products are plant parts used in traditional medicine. However, the impacts of harvesting practices are rarely quantified, with as yet insufficient generic rules across species and life forms. This limits the predictive ability to monitor and manage the affected populations. This paper examines the harvesting impact on two popular woody medicinal species used throughout sub-Saharan Africa, namely Catha edulis (Vahl) Forssk. ex Endl. (bushman’s tea) and Rapanea melanophloeos (L.) Mez. (Cape beech). In both species, basal diameters, heights, and the number of size classes in the harvested populations were lower than in unharvested. Densities of harvested populations were higher in both species, including densities of young plants, but the frequency of individuals in larger size classes was lower. The populations of both species being harvested for medicinal products appeared to be withstanding the current levels of harvesting, but the population structure of C. edulis populations being harvested for poles on the roadside and near human settlements had been substantially altered. Despite the resilience of the two species to harvesting for medicinal products, loss of habitat or changes in land use pose a threat to a number of the assessed populations.
- Full Text:
- Date Issued: 2004
Integrating indigenous ecological knowledge and customary sea tenure with marine and social science for conservation of bumphead parrotfish (Bolbometopon muricatum) in the Roviana Lagoon, Solomon Islands
- Shankar, Aswani, Hamilton, Richard
- Authors: Shankar, Aswani , Hamilton, Richard
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439945 , vital:73722 , xlink:href="https://doi.org/10.1017/S037689290400116X"
- Description: Indigenous ecological knowledge and customary sea tenure may be integrated with marine and social science to conserve the bumphead parrotfish (Bolbometopon muricatum) in the Roviana Lagoon, Western Solomon Islands. Three aspects of indigenous ecological knowledge in Roviana were identified as most relevant for the management and conservation of bumphead parrotfish, and studied through a combination of marine science and anthropological methods. These were (1) local claims that fishing pressure has had a significant impact on bumphead parrotfish populations in the Roviana Lagoon; (2) the claim that only small bumphead parrotfish were ever seen or captured in the inner lagoon and that very small fish were restricted to specific shallow inner-lagoon nursery regions; and (3) assertions made by local divers that bumphead parrotfish predominantly aggregated at night around the new moon period and that catches were highest at that time. The research supported claims (1) and (2), but did not support proposition (3). Although the people of the Roviana Lagoon had similar conceptions about their entitlement rights to sea space, there were marked differences among regional villages in their opinions regarding governance and actual operational rules of management in the Lagoon. Contemporary differences in management strategies resulted from people's historical and spatial patterns of settlement across the landscape and adjoining seascapes, and the attendant impact of these patterns on property relations. This was crucial in distinguishing between those villages that held secure tenure over their contiguous sea estates from those that did not. Indigenous ecological knowledge served to (1) verify that the bumphead parrotfish was a species in urgent need of protection; (2) explain how different habitats structured the size distribution of bumphead parrotfish; (3) identify sensitive locations and habitats in need of protection; and (4) explain the effect of lunar periodicity on bumphead parrotfish behaviour and catch rates. Secure customary sea tenure identified locations best suited to bumphead parrotfish management programmes, with a greater likelihood for local participation and programme success. The information was used to establish two marine protected areas in the region for bumphead parrotfish conservation.
- Full Text:
- Date Issued: 2004
- Authors: Shankar, Aswani , Hamilton, Richard
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439945 , vital:73722 , xlink:href="https://doi.org/10.1017/S037689290400116X"
- Description: Indigenous ecological knowledge and customary sea tenure may be integrated with marine and social science to conserve the bumphead parrotfish (Bolbometopon muricatum) in the Roviana Lagoon, Western Solomon Islands. Three aspects of indigenous ecological knowledge in Roviana were identified as most relevant for the management and conservation of bumphead parrotfish, and studied through a combination of marine science and anthropological methods. These were (1) local claims that fishing pressure has had a significant impact on bumphead parrotfish populations in the Roviana Lagoon; (2) the claim that only small bumphead parrotfish were ever seen or captured in the inner lagoon and that very small fish were restricted to specific shallow inner-lagoon nursery regions; and (3) assertions made by local divers that bumphead parrotfish predominantly aggregated at night around the new moon period and that catches were highest at that time. The research supported claims (1) and (2), but did not support proposition (3). Although the people of the Roviana Lagoon had similar conceptions about their entitlement rights to sea space, there were marked differences among regional villages in their opinions regarding governance and actual operational rules of management in the Lagoon. Contemporary differences in management strategies resulted from people's historical and spatial patterns of settlement across the landscape and adjoining seascapes, and the attendant impact of these patterns on property relations. This was crucial in distinguishing between those villages that held secure tenure over their contiguous sea estates from those that did not. Indigenous ecological knowledge served to (1) verify that the bumphead parrotfish was a species in urgent need of protection; (2) explain how different habitats structured the size distribution of bumphead parrotfish; (3) identify sensitive locations and habitats in need of protection; and (4) explain the effect of lunar periodicity on bumphead parrotfish behaviour and catch rates. Secure customary sea tenure identified locations best suited to bumphead parrotfish management programmes, with a greater likelihood for local participation and programme success. The information was used to establish two marine protected areas in the region for bumphead parrotfish conservation.
- Full Text:
- Date Issued: 2004
Kaleidoscope configurations for reflectance measurement
- Bangay, Shaun D, Radloff, Judith D
- Authors: Bangay, Shaun D , Radloff, Judith D
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432891 , vital:72910 , https://doi.org/10.1145/1029949.1029979
- Description: Simulations of different configurations of the symmetrical tapered kaleidoscope are performed to assess their merits for measurement of BRDFs and BTFs. The relationship between optimal kaleidoscope layout, and factors such as hardware restrictions and the resolution of the required reflectance function, is derived. The effect on the measurement of the reflectance function of changing these independent variables is examined through the simulation. These experiments highlight issues affecting the measurement of BTFs using kaleidoscopes, and suggest configurations that allow sampling at regular parameter intervals. A number of other kaleidoscope architectures are explored, which offer the benefits of potentially doubling the range of directions that can be sampled, and allowing adaptive control of sample intervals.
- Full Text:
- Date Issued: 2004
- Authors: Bangay, Shaun D , Radloff, Judith D
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432891 , vital:72910 , https://doi.org/10.1145/1029949.1029979
- Description: Simulations of different configurations of the symmetrical tapered kaleidoscope are performed to assess their merits for measurement of BRDFs and BTFs. The relationship between optimal kaleidoscope layout, and factors such as hardware restrictions and the resolution of the required reflectance function, is derived. The effect on the measurement of the reflectance function of changing these independent variables is examined through the simulation. These experiments highlight issues affecting the measurement of BTFs using kaleidoscopes, and suggest configurations that allow sampling at regular parameter intervals. A number of other kaleidoscope architectures are explored, which offer the benefits of potentially doubling the range of directions that can be sampled, and allowing adaptive control of sample intervals.
- Full Text:
- Date Issued: 2004
Linda implementations in Java for concurrent systems
- Wells, George C, Chalmers, A G, Clayton, Peter G
- Authors: Wells, George C , Chalmers, A G , Clayton, Peter G
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430555 , vital:72699 , https://doi.org/10.1002/cpe.794
- Description: This paper surveys a number of the implementations of Linda that are available in Java. It provides some discussion of their strengths and weaknesses, and pre-sents the results from benchmarking experiments using a network of commodity workstations. Some extensions to the original Linda programming model are also presented and discussed, together with examples of their application to parallel processing problems.
- Full Text:
- Date Issued: 2004
- Authors: Wells, George C , Chalmers, A G , Clayton, Peter G
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430555 , vital:72699 , https://doi.org/10.1002/cpe.794
- Description: This paper surveys a number of the implementations of Linda that are available in Java. It provides some discussion of their strengths and weaknesses, and pre-sents the results from benchmarking experiments using a network of commodity workstations. Some extensions to the original Linda programming model are also presented and discussed, together with examples of their application to parallel processing problems.
- Full Text:
- Date Issued: 2004
Modelling and rendering techniques for african hairstyles
- Patrick, Deborah, Bangay, Shaun D, Lobb, Adele
- Authors: Patrick, Deborah , Bangay, Shaun D , Lobb, Adele
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432905 , vital:72911 , https://doi.org/10.1145/1029949.1029971
- Description: We develop or enhance hair modelling and rendering techniques to produce three different forms of hair commonly found in African hairstyles. The forms of hair are natural curly hair, straightened hair, and braids or twists of hair. We use an implicit model, implemented as a series of textured layers to represent curly hair. Straightened hair is represented explicitly, and mod-elled by defining and replicating a few control hairs. Braids and twists are implemented as textured generalized cylinders. A synthesis of existing hair illumination models is used as a basis for an African hair illumination model. Parameter values to match African hair characteristics are discussed. A number of complete African hairstyles are shown, demonstrating that the techniques can be used to model and render African hair successfully.
- Full Text:
- Date Issued: 2004
- Authors: Patrick, Deborah , Bangay, Shaun D , Lobb, Adele
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432905 , vital:72911 , https://doi.org/10.1145/1029949.1029971
- Description: We develop or enhance hair modelling and rendering techniques to produce three different forms of hair commonly found in African hairstyles. The forms of hair are natural curly hair, straightened hair, and braids or twists of hair. We use an implicit model, implemented as a series of textured layers to represent curly hair. Straightened hair is represented explicitly, and mod-elled by defining and replicating a few control hairs. Braids and twists are implemented as textured generalized cylinders. A synthesis of existing hair illumination models is used as a basis for an African hair illumination model. Parameter values to match African hair characteristics are discussed. A number of complete African hairstyles are shown, demonstrating that the techniques can be used to model and render African hair successfully.
- Full Text:
- Date Issued: 2004
Quantification of the photosynthetic performance of phosphorus-deficient Sorghum by means of chlorophyll-a fluorescence kinetics
- Ripley, Bradley S, Redfern, Sally P, Dames, Joanna F
- Authors: Ripley, Bradley S , Redfern, Sally P , Dames, Joanna F
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440444 , vital:73783 , https://hdl.handle.net/10520/EJC96177
- Description: Chlorophyll fluorescence induction curves have been used as a sensitive tool for screening the photosynthetic performance of plants. Experimental treatments involving nitrate supply and chilling stress have been shown to affect fluorescence induction curves and other measures of photosynthesis. We have investigated the photosynthetic performance of Sorghum bicolor supplied with Long Ashton growth solution containing standard (20 mmol mol-1) or low (5 mmol mol-1) phosphorus. The JIP-test based on the chlorophyll fluorescence induction curve was used as a non-destructive method to measure the relative proportions of energy dissipated by different processes (termed energy fluxes) in the light reactions. The various energy fluxes or derived parameters were compared to find the measures that were most sensitive to the experimental conditions. Plant response to treatments was first evident in selected chlorophyll fluorescence parameters, particularly performance index (PIABS); plants with increased PIABS manifested higher electron transport activity and dissipated less energy as heat, possibly as a result of their better phosphorus status, leading to more functional reaction centres. Observed changes in fluorescence were correlated to changes in gas exchange and biomass. Standard phosphorus treatments significantly increased biomass, leaf area, photosynthetic and respiratory rates, carboxylation efficiencies and levels of ribulose biphosphate regeneration rates, relative to plants with low supplies of nutrients.
- Full Text:
- Date Issued: 2004
- Authors: Ripley, Bradley S , Redfern, Sally P , Dames, Joanna F
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440444 , vital:73783 , https://hdl.handle.net/10520/EJC96177
- Description: Chlorophyll fluorescence induction curves have been used as a sensitive tool for screening the photosynthetic performance of plants. Experimental treatments involving nitrate supply and chilling stress have been shown to affect fluorescence induction curves and other measures of photosynthesis. We have investigated the photosynthetic performance of Sorghum bicolor supplied with Long Ashton growth solution containing standard (20 mmol mol-1) or low (5 mmol mol-1) phosphorus. The JIP-test based on the chlorophyll fluorescence induction curve was used as a non-destructive method to measure the relative proportions of energy dissipated by different processes (termed energy fluxes) in the light reactions. The various energy fluxes or derived parameters were compared to find the measures that were most sensitive to the experimental conditions. Plant response to treatments was first evident in selected chlorophyll fluorescence parameters, particularly performance index (PIABS); plants with increased PIABS manifested higher electron transport activity and dissipated less energy as heat, possibly as a result of their better phosphorus status, leading to more functional reaction centres. Observed changes in fluorescence were correlated to changes in gas exchange and biomass. Standard phosphorus treatments significantly increased biomass, leaf area, photosynthetic and respiratory rates, carboxylation efficiencies and levels of ribulose biphosphate regeneration rates, relative to plants with low supplies of nutrients.
- Full Text:
- Date Issued: 2004
Scientific evaluation in women’s participatory management: monitoring marine invertebrate refugia in the Solomon Islands
- Authors: Shankar, Aswani , Weiant, P
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439983 , vital:73725 , xlink:href="https://doi.org/10.17730/humo.63.3.r7kgd4thktmyf7k1"
- Description: This paper summarizes the results of a women’s community-based marine protected area that has been successful in sustaining invertebrate biological resources and in promoting strong community support. We outline the project and the associated biological results, describe the processes involved in attaining a committed level of community participation, and review the lessons learned during the project’s implementation. We attribute the project’s preliminary success—improved shellfish biomass, enhanced local environmental awareness, and the reinvigoration of cultural management practices—to the following factors: 1) the high level of participatory involvement and community leadership; 2) the local perception that shell beds have recovered rapidly and the role that scientific evaluation has played in reinforcing this notion; 3) a research program that is cross-fertilizing indigenous and scientific ecological knowledge; 4) the unique marine tenure system that allows for the project’s development and the area’s policing; and 5) the tangible economic incentives created by the development project, which ultimately empowers local women. We hope that the project’s findings can be generalized to other regions of the world with operational sea-tenure regimes and that it can help to make the establishing of community-based marine protected areas (CBMPAs) across the Pacific region more effective.
- Full Text:
- Date Issued: 2004
- Authors: Shankar, Aswani , Weiant, P
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439983 , vital:73725 , xlink:href="https://doi.org/10.17730/humo.63.3.r7kgd4thktmyf7k1"
- Description: This paper summarizes the results of a women’s community-based marine protected area that has been successful in sustaining invertebrate biological resources and in promoting strong community support. We outline the project and the associated biological results, describe the processes involved in attaining a committed level of community participation, and review the lessons learned during the project’s implementation. We attribute the project’s preliminary success—improved shellfish biomass, enhanced local environmental awareness, and the reinvigoration of cultural management practices—to the following factors: 1) the high level of participatory involvement and community leadership; 2) the local perception that shell beds have recovered rapidly and the role that scientific evaluation has played in reinforcing this notion; 3) a research program that is cross-fertilizing indigenous and scientific ecological knowledge; 4) the unique marine tenure system that allows for the project’s development and the area’s policing; and 5) the tangible economic incentives created by the development project, which ultimately empowers local women. We hope that the project’s findings can be generalized to other regions of the world with operational sea-tenure regimes and that it can help to make the establishing of community-based marine protected areas (CBMPAs) across the Pacific region more effective.
- Full Text:
- Date Issued: 2004
Socio-economic differentiation in the trade of wildlife species for traditional medicines in the Lowveld, South Africa: Implications for resource management initiatives
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M, Fairbanks, Dean H K
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M , Fairbanks, Dean H K
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183071 , vital:43909 , xlink:href="https://doi.org/10.1080/13504500409469832"
- Description: Surveys of trade in wildlife products utilised in traditional medicine were conducted between 1997 and 1999 on the western boundary of the Kruger National Park, South Africa. Although the extent of trade and numbers of people operating in this sector were lower than other regions of South Africa, this study again highlighted the value of indigenous wildlife products to subsistence economies. Apart from cultural diversity, socioeconomic differentiation occurred at a number of levels. (i) There were socio-economic differences between the traders and vendors. (ii) Gender differences were apparent, with women earning significantly less than men and having to undergo more social challenges in their operation in the market place. (iii) Operational differences were noted between the vendors and traders, as well as between the street and pension day vendors. (iv) Multidimensional Scaling (MDS) highlighted the socio-economic differentiation at the household level, emphasizing in particular one of the most vulnerable groups, the elderly. The potential influence of this socio-economic differentiation needs to be considered during the development of Community-Based Conservation programmes, if the dual aims of conserving biodiversity and improving the lives and livelihoods of those who traditionally rely on medicinal plants are to be met.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M , Fairbanks, Dean H K
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183071 , vital:43909 , xlink:href="https://doi.org/10.1080/13504500409469832"
- Description: Surveys of trade in wildlife products utilised in traditional medicine were conducted between 1997 and 1999 on the western boundary of the Kruger National Park, South Africa. Although the extent of trade and numbers of people operating in this sector were lower than other regions of South Africa, this study again highlighted the value of indigenous wildlife products to subsistence economies. Apart from cultural diversity, socioeconomic differentiation occurred at a number of levels. (i) There were socio-economic differences between the traders and vendors. (ii) Gender differences were apparent, with women earning significantly less than men and having to undergo more social challenges in their operation in the market place. (iii) Operational differences were noted between the vendors and traders, as well as between the street and pension day vendors. (iv) Multidimensional Scaling (MDS) highlighted the socio-economic differentiation at the household level, emphasizing in particular one of the most vulnerable groups, the elderly. The potential influence of this socio-economic differentiation needs to be considered during the development of Community-Based Conservation programmes, if the dual aims of conserving biodiversity and improving the lives and livelihoods of those who traditionally rely on medicinal plants are to be met.
- Full Text:
- Date Issued: 2004
Spiders (Arachnida: Araneae) from black cotton soil habitats of a highland savanna biome in Laikipia, central Kenya
- Warui, Charles M, Villet, Martin H, Young, Truman P
- Authors: Warui, Charles M , Villet, Martin H , Young, Truman P
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/442705 , vital:74025 , https://tpyoung.ucdavis.edu/sites/g/files/dgvnsk4821/files/inline-files/spiders%20in%20highlands.pdf
- Description: Spiders were sampled at Mpala Research Centre, Laikipia, Kenya using pitfall trapping and sweep netting. Sampling was conducted from May 2001 to July 2002. A total of 10,487 individuals from 132 species belonging to 30 families were recorded. The family Salticidae had the highest number of species (24), followed by Gnaphosidae (20), Araneidae and Lycosidae (15 each), Theridiidae and Thomisidae (8 each) and Zodariidae (4). Most of the other families had fewer than 4 species. Throughout the study period, species not previously sampled emerged after rainfall peaks. Many species are apparently undescribed, highlighting the inadequate documentation of these taxa in Kenya. We suggest that the spider fauna of black cotton soil habitats is rich and useful for environmental monitoring, that further surveys using other collecting methods are needed, and that support for the conservation of this ecosystem should be continued. The study once more reveals the urgent need for taxonomic studies on Kenyan invertebrates.
- Full Text:
- Date Issued: 2004
- Authors: Warui, Charles M , Villet, Martin H , Young, Truman P
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/442705 , vital:74025 , https://tpyoung.ucdavis.edu/sites/g/files/dgvnsk4821/files/inline-files/spiders%20in%20highlands.pdf
- Description: Spiders were sampled at Mpala Research Centre, Laikipia, Kenya using pitfall trapping and sweep netting. Sampling was conducted from May 2001 to July 2002. A total of 10,487 individuals from 132 species belonging to 30 families were recorded. The family Salticidae had the highest number of species (24), followed by Gnaphosidae (20), Araneidae and Lycosidae (15 each), Theridiidae and Thomisidae (8 each) and Zodariidae (4). Most of the other families had fewer than 4 species. Throughout the study period, species not previously sampled emerged after rainfall peaks. Many species are apparently undescribed, highlighting the inadequate documentation of these taxa in Kenya. We suggest that the spider fauna of black cotton soil habitats is rich and useful for environmental monitoring, that further surveys using other collecting methods are needed, and that support for the conservation of this ecosystem should be continued. The study once more reveals the urgent need for taxonomic studies on Kenyan invertebrates.
- Full Text:
- Date Issued: 2004
Synthesis and photochemical studies of substituted adjacent binaphthalophthalocyanines
- Seotsanyana-Mokhosi, Itumeleng, Nyokong, Tebello
- Authors: Seotsanyana-Mokhosi, Itumeleng , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289883 , vital:56689 , xlink:href="https://doi.org/10.1142/S1088424604000568"
- Description: Adjacent phthalocyanines with a binaphthalo backbone and phenoxy substituents were synthesized and their photochemical properties were investigated. The adjacent phthalocyanines are the binaphthalophthalocyanines, with the phenoxy, 4-tert-butylphenoxy and the sulfophenoxy substituents, respectively and bis-binaphthalophthalocyanine which has an extended π conjugation system and larger singlet oxygen quantum yield compared to the other compounds. The presence of the phenoxy substituents as well as the binaphthalo bridge does not cause a marked difference on the fluorescing properties of these complexes when compared to zinc phthalocyanine. The binaphthalo backbone allowed the molecules to photoswitch during photolysis affording them very high photostability.
- Full Text:
- Date Issued: 2004
- Authors: Seotsanyana-Mokhosi, Itumeleng , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289883 , vital:56689 , xlink:href="https://doi.org/10.1142/S1088424604000568"
- Description: Adjacent phthalocyanines with a binaphthalo backbone and phenoxy substituents were synthesized and their photochemical properties were investigated. The adjacent phthalocyanines are the binaphthalophthalocyanines, with the phenoxy, 4-tert-butylphenoxy and the sulfophenoxy substituents, respectively and bis-binaphthalophthalocyanine which has an extended π conjugation system and larger singlet oxygen quantum yield compared to the other compounds. The presence of the phenoxy substituents as well as the binaphthalo bridge does not cause a marked difference on the fluorescing properties of these complexes when compared to zinc phthalocyanine. The binaphthalo backbone allowed the molecules to photoswitch during photolysis affording them very high photostability.
- Full Text:
- Date Issued: 2004
The fuelwood crisis in southern Africa: Relating fuelwood use to livelihoods in a rural village
- Dovie, Delali B K, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Dovie, Delali B K , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181402 , vital:43730 , xlink:href="https://doi.org/10.1023/B:GEJO.0000033597.34013.9f"
- Description: The aim of the paper is to examine wood as a source of fuel energy in rural South Africa and factors influencing its usage. The analysis is based on household profiles and characteristics (e.g., gender, caste, population and income) in a livelihood framework. Fuelwood consumption was estimated to be 692 kg/capita, and 4343 kg/user household per annum, valued at $311 per household. Consumption was modelled in relation to informal and formal cash incomes, and population of children, female and male adults. However, only the population of female adults could significantly influence consumption of fuelwood. This implied that where there were more women in a household, consumption was likely to be high. This might be due to the majority of women doing the cooking and heating in the household. Any change in the value of cash income of households had no significant impacts on fuelwood consumed. Cash incomes might therefore not be strong determinants of the types of energy used by rural households. The average quantity of wood consumed for fuel energy in summer was not significantly different from consumption in winter. Some households perpetually used more wood than others. The study further showed that harvesting of wood for fuel energy is not opportunistic, but requires reallocation of time for other livelihood activities in times of shortage. The fuelwood crisis is not simple and not only about shortage of fuelwood and/or population growth but linked to household profiles and other livelihood strategies and subsequently vulnerability of households. These would require thorough investigation and understanding in relation to precise demand and supply data for fuelwood before the fuelwood problem can be sufficiently managed.
- Full Text:
- Date Issued: 2004
- Authors: Dovie, Delali B K , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181402 , vital:43730 , xlink:href="https://doi.org/10.1023/B:GEJO.0000033597.34013.9f"
- Description: The aim of the paper is to examine wood as a source of fuel energy in rural South Africa and factors influencing its usage. The analysis is based on household profiles and characteristics (e.g., gender, caste, population and income) in a livelihood framework. Fuelwood consumption was estimated to be 692 kg/capita, and 4343 kg/user household per annum, valued at $311 per household. Consumption was modelled in relation to informal and formal cash incomes, and population of children, female and male adults. However, only the population of female adults could significantly influence consumption of fuelwood. This implied that where there were more women in a household, consumption was likely to be high. This might be due to the majority of women doing the cooking and heating in the household. Any change in the value of cash income of households had no significant impacts on fuelwood consumed. Cash incomes might therefore not be strong determinants of the types of energy used by rural households. The average quantity of wood consumed for fuel energy in summer was not significantly different from consumption in winter. Some households perpetually used more wood than others. The study further showed that harvesting of wood for fuel energy is not opportunistic, but requires reallocation of time for other livelihood activities in times of shortage. The fuelwood crisis is not simple and not only about shortage of fuelwood and/or population growth but linked to household profiles and other livelihood strategies and subsequently vulnerability of households. These would require thorough investigation and understanding in relation to precise demand and supply data for fuelwood before the fuelwood problem can be sufficiently managed.
- Full Text:
- Date Issued: 2004
The impact of commercial harvesting on Warburgia salutaris (‘pepper-bark tree’) in Mpumalanga, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181391 , vital:43729 , xlink:href="https://doi.org/10.1023/B:BIOC.0000029333.72945.b0"
- Description: Commercialisation often increases the difficulty in managing harvested plant populations sustainably. The bark of the popular medicinal species, Warburgia salutaris (Bertol.f.) Chiov. (Canellaceae) (‘pepper-bark tree’), is widely traded throughout southern Africa. The impact of commercial harvesting on this Red Data species was assessed by comparing commercially harvested populations with populations growing on private land or in protected areas (termed ‘protected populations’) in Mpumalanga and Limpopo Province, South Africa. The basal diameters and heights of stems in commercially harvested populations were significantly lower than those of the protected populations. The density of young/small plants was low in all populations. W. salutaris is usually resilient to high levels of bark harvesting. In this study, 75% of heavily harvested stems (>10% of the stem below 2 m) coppiced (resprouted). However, individuals that had been affected by regular fires, or repeatedly harvested, appeared prone to a fungal disease and had high percentage mortality. The populations occurring on private land appeared the most vigorous. Habitat in one protected area had been reduced through the construction of a dam. In another, small W. salutaris populations exhibited a shrubby growth form, probably due to frequent fires. Our current knowledge for this species supports a global IUCN status of EN A4acd. Plant conservation needs to become a higher priority both within and outside protected areas. Commercially harvested populations should be better managed through improved harvesting techniques and monitoring. Cultivation levels urgently need to be increased. Further research should be conducted on factors limiting regeneration, including the most appropriate fire regime.
- Full Text:
- Date Issued: 2004
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181391 , vital:43729 , xlink:href="https://doi.org/10.1023/B:BIOC.0000029333.72945.b0"
- Description: Commercialisation often increases the difficulty in managing harvested plant populations sustainably. The bark of the popular medicinal species, Warburgia salutaris (Bertol.f.) Chiov. (Canellaceae) (‘pepper-bark tree’), is widely traded throughout southern Africa. The impact of commercial harvesting on this Red Data species was assessed by comparing commercially harvested populations with populations growing on private land or in protected areas (termed ‘protected populations’) in Mpumalanga and Limpopo Province, South Africa. The basal diameters and heights of stems in commercially harvested populations were significantly lower than those of the protected populations. The density of young/small plants was low in all populations. W. salutaris is usually resilient to high levels of bark harvesting. In this study, 75% of heavily harvested stems (>10% of the stem below 2 m) coppiced (resprouted). However, individuals that had been affected by regular fires, or repeatedly harvested, appeared prone to a fungal disease and had high percentage mortality. The populations occurring on private land appeared the most vigorous. Habitat in one protected area had been reduced through the construction of a dam. In another, small W. salutaris populations exhibited a shrubby growth form, probably due to frequent fires. Our current knowledge for this species supports a global IUCN status of EN A4acd. Plant conservation needs to become a higher priority both within and outside protected areas. Commercially harvested populations should be better managed through improved harvesting techniques and monitoring. Cultivation levels urgently need to be increased. Further research should be conducted on factors limiting regeneration, including the most appropriate fire regime.
- Full Text:
- Date Issued: 2004
The renaissance in optical spectroscopy of phthalocyanines and other tetraazaporphyrins
- Nyokong, Tebello, Isago, Hiroaki
- Authors: Nyokong, Tebello , Isago, Hiroaki
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289388 , vital:56628 , xlink:href="https://doi.org/10.1142/S1088424604000453"
- Description: Spectral properties of metallophthalocyanines and other tetraazaporphyrins are governed mainly by the Q band which originates from the π-π* transitions within the ring. The position and intensity of the Q band is important in tailoring new phthalocyanine derivatives for particular applications. Aggregation, the nature of the central metal, π conjugation, symmetry of the molecules, and axial, peripheral or non-peripheral substitutions affect the spectra and hence the properties of the phthalocyanine molecule. This review gives a brief outline on how optical spectroscopy provides useful informations on molecular and electronic structures, chemistry and physics of phthalocyanines and other tetraazaporphyrins.
- Full Text:
- Date Issued: 2004
- Authors: Nyokong, Tebello , Isago, Hiroaki
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289388 , vital:56628 , xlink:href="https://doi.org/10.1142/S1088424604000453"
- Description: Spectral properties of metallophthalocyanines and other tetraazaporphyrins are governed mainly by the Q band which originates from the π-π* transitions within the ring. The position and intensity of the Q band is important in tailoring new phthalocyanine derivatives for particular applications. Aggregation, the nature of the central metal, π conjugation, symmetry of the molecules, and axial, peripheral or non-peripheral substitutions affect the spectra and hence the properties of the phthalocyanine molecule. This review gives a brief outline on how optical spectroscopy provides useful informations on molecular and electronic structures, chemistry and physics of phthalocyanines and other tetraazaporphyrins.
- Full Text:
- Date Issued: 2004
The value of many small vs. few large marine protected areas in the Western Solomon Islands
- Shankar, Aswani, Hamilton, Richard
- Authors: Shankar, Aswani , Hamilton, Richard
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440050 , vital:73731
- Description: Scientists and policy makers are universally promoting marine protected areas (MPAs) as a fisheries and ecosystem management tool. Experts generally agree that MPAs, particularly fully protected “no-take” zones, can enhance spawning stock biomass, allow for larval dispersal and the export of adults to adjacent non-protected areas, maintain species diversity, preserve habitat, and sustain ecosystem function (eg Bergen and Carr 2003; Johnson et al. 1999; Russ and Alcala 1999). In the case of tropical multi-species fisheries, in which absolute yields are difficult to predict and in which there are multiple users and fishing techniques, marine reserves also can act as precautionary tools to prevent overexploitation. Considering that orthodox fisheries management strategies have generally failed to prevent overfishing globally, the inception of MPAs as a management tool is of particular preventive significance (Russ 2002). Proponents of MPAs have broadly debated the appropriate size and number of MPAs that should be established in order to produce what a particular management prescription proposes to deliver. Some scientists argue that for MPAs to be effective they should cover areas in the magnitude of hundreds or even thousands of square miles, depending upon the type of environment (eg Beattie et al. 2002; Man et al. 1995; Walters 2000). Others have suggested that from a fisheries enhancement perspective, many small reserves in a network are preferred over fewer, larger reserves (eg Roberts et al. 2003). Other debates have centred on how much attention should be paid to science-driven vs. stakeholder-driven considerations when designing MPAs (eg Agardy 1997; Alder et al. 2002; Christie et al. 2003; Jones 2002).
- Full Text:
- Date Issued: 2004
- Authors: Shankar, Aswani , Hamilton, Richard
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440050 , vital:73731
- Description: Scientists and policy makers are universally promoting marine protected areas (MPAs) as a fisheries and ecosystem management tool. Experts generally agree that MPAs, particularly fully protected “no-take” zones, can enhance spawning stock biomass, allow for larval dispersal and the export of adults to adjacent non-protected areas, maintain species diversity, preserve habitat, and sustain ecosystem function (eg Bergen and Carr 2003; Johnson et al. 1999; Russ and Alcala 1999). In the case of tropical multi-species fisheries, in which absolute yields are difficult to predict and in which there are multiple users and fishing techniques, marine reserves also can act as precautionary tools to prevent overexploitation. Considering that orthodox fisheries management strategies have generally failed to prevent overfishing globally, the inception of MPAs as a management tool is of particular preventive significance (Russ 2002). Proponents of MPAs have broadly debated the appropriate size and number of MPAs that should be established in order to produce what a particular management prescription proposes to deliver. Some scientists argue that for MPAs to be effective they should cover areas in the magnitude of hundreds or even thousands of square miles, depending upon the type of environment (eg Beattie et al. 2002; Man et al. 1995; Walters 2000). Others have suggested that from a fisheries enhancement perspective, many small reserves in a network are preferred over fewer, larger reserves (eg Roberts et al. 2003). Other debates have centred on how much attention should be paid to science-driven vs. stakeholder-driven considerations when designing MPAs (eg Agardy 1997; Alder et al. 2002; Christie et al. 2003; Jones 2002).
- Full Text:
- Date Issued: 2004