Photophysical and photochemical properties of tetrasulfonated silicon and germanium phthalocyanine in aqueous and non-aqueous media
- Idowu, Mopolela, Nyokong, Tebello
- Authors: Idowu, Mopolela , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268624 , vital:54215 , xlink:href="https://doi.org/10.1016/j.jphotochem.2008.01.004"
- Description: The photophysical and photochemical properties of tetrasulfonated silicon and germanium phthalocyanine (SiPcS4 and GePcS4) in aqueous solution (phosphate-buffered saline (PBS) solution, pH 7.4) (in the presence and absence of cremophore EL (CEL)) and in dimethylsulphoxide (DMSO) were studied. The complexes have intense absorption in the visible/near-IR region though they highly aggregate in aqueous solution with a dimerization constant of ∼2 × 104 dm3 mol−1. The fluorescence excitation spectra however have only one band suggesting that only the monomer fluoresces. Both the quantum yields of the triplet state (ΦT) and the triplet lifetimes (τT) were found to be higher in DMSO compared to in aqueous solution. Aggregation is hindered by addition of cremophore EL in aqueous solution and this induced disaggregation caused an increased ΦT and τT probably due to the reduced interaction of the phthalocyanines with the aqueous medium in the presence of CEL.
- Full Text:
- Date Issued: 2008
- Authors: Idowu, Mopolela , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268624 , vital:54215 , xlink:href="https://doi.org/10.1016/j.jphotochem.2008.01.004"
- Description: The photophysical and photochemical properties of tetrasulfonated silicon and germanium phthalocyanine (SiPcS4 and GePcS4) in aqueous solution (phosphate-buffered saline (PBS) solution, pH 7.4) (in the presence and absence of cremophore EL (CEL)) and in dimethylsulphoxide (DMSO) were studied. The complexes have intense absorption in the visible/near-IR region though they highly aggregate in aqueous solution with a dimerization constant of ∼2 × 104 dm3 mol−1. The fluorescence excitation spectra however have only one band suggesting that only the monomer fluoresces. Both the quantum yields of the triplet state (ΦT) and the triplet lifetimes (τT) were found to be higher in DMSO compared to in aqueous solution. Aggregation is hindered by addition of cremophore EL in aqueous solution and this induced disaggregation caused an increased ΦT and τT probably due to the reduced interaction of the phthalocyanines with the aqueous medium in the presence of CEL.
- Full Text:
- Date Issued: 2008
Photosensitizing properties of octacarboxy metallophthalocyanines in aqueous medium and their interaction with bovine serum albumin
- Idowu, Mopelola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264552 , vital:53744 , xlink:href="https://doi.org/10.1016/j.jphotochem.2008.09.003"
- Description: Photosensitizing properties of aluminium, silicon, zinc and germanium octacarboxy phthalocyanines ((OH)AlOCPc, (OH)2SiOCPc, ZnOCPc and (OH)2GeOCPc) were studied in aqueous medium and in the presence of bovine serum albumin (BSA). Triplet quantum yields increased with increasing atomic number of the central metals of the metallophthalocyanine. The efficiency of singlet oxygen generation via energy transfer from the excited triplet state of the octacarboxy metallophthalocyanines (MOCPcs) to ground state oxygen increased markedly in the presence of BSA. The triplet state lifetimes of the MOCPc complexes in the presence of BSA were found to be longer than in the absence of BSA, ranging from 110 to 580 μs. These complexes bind readily to BSA. Stern–Volmer quenching constant KSV as well as the binding constant kb values were calculated. The probable mechanism of quenching of BSA fluorescence by the MOCPc complexes is by static quenching.
- Full Text:
- Date Issued: 2008
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264552 , vital:53744 , xlink:href="https://doi.org/10.1016/j.jphotochem.2008.09.003"
- Description: Photosensitizing properties of aluminium, silicon, zinc and germanium octacarboxy phthalocyanines ((OH)AlOCPc, (OH)2SiOCPc, ZnOCPc and (OH)2GeOCPc) were studied in aqueous medium and in the presence of bovine serum albumin (BSA). Triplet quantum yields increased with increasing atomic number of the central metals of the metallophthalocyanine. The efficiency of singlet oxygen generation via energy transfer from the excited triplet state of the octacarboxy metallophthalocyanines (MOCPcs) to ground state oxygen increased markedly in the presence of BSA. The triplet state lifetimes of the MOCPc complexes in the presence of BSA were found to be longer than in the absence of BSA, ranging from 110 to 580 μs. These complexes bind readily to BSA. Stern–Volmer quenching constant KSV as well as the binding constant kb values were calculated. The probable mechanism of quenching of BSA fluorescence by the MOCPc complexes is by static quenching.
- Full Text:
- Date Issued: 2008
Pragmatic research design
- Amos, Trevor L, Pearse, Noel J
- Authors: Amos, Trevor L , Pearse, Noel J
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270943 , vital:54494 , xlink:href="https://academic-publishing.org/index.php/ejbrm/article/view/1230/1193"
- Description: The creation of wealth is an important issue in any society, and entrepreneurship is regarded as an important catalyst in the creation of new wealth. This presents a challenge to develop entrepreneurship successfully. An important site for the development of entrepreneurship is higher education. The challenge however, is that there is a lack of a general understanding on how to educate students for entrepreneurship. In addition, current thought and practice on entrepreneurship education is historically biased, implying that graduates are essentially prepared for the past instead of for the future. From the perspective of higher education, the problem is how to develop current students to be entrepreneurial in the future. What is needed is to project into the future and then to develop an understanding of what should be taught as well as how it should be taught today. A versatile research technique that can assist in achieving this objective is the Delphi technique, as it is used to conduct futures research or research into areas where knowledge is incomplete. The Delphi method is a type of group interview, using the collective opinion of knowledgeable experts. The technique makes use of several rounds of data collection and feedback to create a consensus of opinion. Making use of the Delphi technique, research is being designed that will formulate expert‑based strategic guidelines on entrepreneurial education within the South African higher education sector. The aim of this paper is to illustrate the research design considerations that arise in the use of the Delphi technique for this purpose and how they are addressed. The main characteristics of the Delphi are presented and arguments for the use of the Delphi within a constructivist paradigm are discussed. Practical issues related to the design of the Delphi, panel‑member selection, and the formulation of panel questions, are examined. In illustrating these design considerations, the paper demonstrates a pragmatic approach to research design as well as the importance of creating coherence between the research question, the research paradigm, the research method and its use, encouraging research practitioners to adopt a more systematic, deliberate and philosophically‑based approach to research design.
- Full Text:
- Date Issued: 2008
- Authors: Amos, Trevor L , Pearse, Noel J
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270943 , vital:54494 , xlink:href="https://academic-publishing.org/index.php/ejbrm/article/view/1230/1193"
- Description: The creation of wealth is an important issue in any society, and entrepreneurship is regarded as an important catalyst in the creation of new wealth. This presents a challenge to develop entrepreneurship successfully. An important site for the development of entrepreneurship is higher education. The challenge however, is that there is a lack of a general understanding on how to educate students for entrepreneurship. In addition, current thought and practice on entrepreneurship education is historically biased, implying that graduates are essentially prepared for the past instead of for the future. From the perspective of higher education, the problem is how to develop current students to be entrepreneurial in the future. What is needed is to project into the future and then to develop an understanding of what should be taught as well as how it should be taught today. A versatile research technique that can assist in achieving this objective is the Delphi technique, as it is used to conduct futures research or research into areas where knowledge is incomplete. The Delphi method is a type of group interview, using the collective opinion of knowledgeable experts. The technique makes use of several rounds of data collection and feedback to create a consensus of opinion. Making use of the Delphi technique, research is being designed that will formulate expert‑based strategic guidelines on entrepreneurial education within the South African higher education sector. The aim of this paper is to illustrate the research design considerations that arise in the use of the Delphi technique for this purpose and how they are addressed. The main characteristics of the Delphi are presented and arguments for the use of the Delphi within a constructivist paradigm are discussed. Practical issues related to the design of the Delphi, panel‑member selection, and the formulation of panel questions, are examined. In illustrating these design considerations, the paper demonstrates a pragmatic approach to research design as well as the importance of creating coherence between the research question, the research paradigm, the research method and its use, encouraging research practitioners to adopt a more systematic, deliberate and philosophically‑based approach to research design.
- Full Text:
- Date Issued: 2008
Prototyping a p2p sip user agent with support for multiple overlays
- Tsietsi, Mosiuoa, Terzoli, Alfredo, Wells, George C
- Authors: Tsietsi, Mosiuoa , Terzoli, Alfredo , Wells, George C
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430858 , vital:72722 , 10.1109/PERCOM.2008.102
- Description: This paper describes a systematic approach to provide support at the user agent level for peer-to-peer based multimedia communications us-ing SIP (session initiation protocol). In a society that is becoming in-creasingly mobile, the advantages of engaging in interactive sessions without relying on central servers or infrastructure are clear. Yet, cur-rently many user agents and devices have little support for peer-to-peer communications. In this paper, we motivate for the use of structured peer-to-peer protocols called DHTs, as a foundation for a peer-to-peer layer. We introduce the concept of "DHTplug-ins" which assist in ab-stracting the interface between the higher level application and the pro-prietary APIs exposed by the underlying DHTs, allowing us to manipu-late user agents with peer-to-peer logic. This embeddable-DHT concept allows these user agents to use different DHTs with one common inter-face and participate in multiple overlays. We show how an open source SIP user agent was thus modified and how realtime communications were supported.
- Full Text:
- Date Issued: 2008
- Authors: Tsietsi, Mosiuoa , Terzoli, Alfredo , Wells, George C
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430858 , vital:72722 , 10.1109/PERCOM.2008.102
- Description: This paper describes a systematic approach to provide support at the user agent level for peer-to-peer based multimedia communications us-ing SIP (session initiation protocol). In a society that is becoming in-creasingly mobile, the advantages of engaging in interactive sessions without relying on central servers or infrastructure are clear. Yet, cur-rently many user agents and devices have little support for peer-to-peer communications. In this paper, we motivate for the use of structured peer-to-peer protocols called DHTs, as a foundation for a peer-to-peer layer. We introduce the concept of "DHTplug-ins" which assist in ab-stracting the interface between the higher level application and the pro-prietary APIs exposed by the underlying DHTs, allowing us to manipu-late user agents with peer-to-peer logic. This embeddable-DHT concept allows these user agents to use different DHTs with one common inter-face and participate in multiple overlays. We show how an open source SIP user agent was thus modified and how realtime communications were supported.
- Full Text:
- Date Issued: 2008
Reading Conference recommendations in a wider context of social change
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373792 , vital:66723 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122783"
- Description: This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373792 , vital:66723 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122783"
- Description: This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
Retrospective stock assessment of the Emperor red snapper (Lutjanus sebae) on the Seychelles Bank between 1977 and 2006
- Grandcourt, E M, Hecht, Thomas, Booth, Anthony J, Robinson, J
- Authors: Grandcourt, E M , Hecht, Thomas , Booth, Anthony J , Robinson, J
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125887 , vital:35829 , https://doi.10.1093/icesjms/fsn064
- Description: The Emperor red snapper, Lutjanus sebae, known as “Bourzwa” in the Seychelles, is distributed throughout the Indo-West Pacific from the southern Red Sea and East Africa to New Caledonia, north to Japan and south to Australia. It occurs near coral or rocky reefs and also over adjacent sand flats and gravel patches between 5 and 180 m deep (Allen, 1985; Anderson, 1986). Juveniles are frequently commensal with sea urchins (Kuiter and Tonozuka, 2001), and are found in nearshore, turbid waters (Williams and Russ, 1992), mangrove areas (Allen, 1985), and around coastal and offshore reefs (Williams and Russ, 1992). Larger L. sebae are generally found deeper, although they are also known to move into shallower water during winter (McPherson et al., 1988; Williams and Russ, 1992). Prey items include fish, crabs, other benthic crustaceans, and cephalopods. Lutjanus sebae is a large, long-lived species, attaining a maximum size of 116 cm fork length (McPherson and Squire, 1992) and maximum age of 34 years (Newman and Dunk, 2002). Despite an absence of data on its population structure, mixing, and identity, the population on the Seychelles Bank has been considered to be a unit stock for assessment purposes because of its remote location (e.g. Lablache and Carrara, 1988; Mees, 1992).
- Full Text:
- Date Issued: 2008
- Authors: Grandcourt, E M , Hecht, Thomas , Booth, Anthony J , Robinson, J
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125887 , vital:35829 , https://doi.10.1093/icesjms/fsn064
- Description: The Emperor red snapper, Lutjanus sebae, known as “Bourzwa” in the Seychelles, is distributed throughout the Indo-West Pacific from the southern Red Sea and East Africa to New Caledonia, north to Japan and south to Australia. It occurs near coral or rocky reefs and also over adjacent sand flats and gravel patches between 5 and 180 m deep (Allen, 1985; Anderson, 1986). Juveniles are frequently commensal with sea urchins (Kuiter and Tonozuka, 2001), and are found in nearshore, turbid waters (Williams and Russ, 1992), mangrove areas (Allen, 1985), and around coastal and offshore reefs (Williams and Russ, 1992). Larger L. sebae are generally found deeper, although they are also known to move into shallower water during winter (McPherson et al., 1988; Williams and Russ, 1992). Prey items include fish, crabs, other benthic crustaceans, and cephalopods. Lutjanus sebae is a large, long-lived species, attaining a maximum size of 116 cm fork length (McPherson and Squire, 1992) and maximum age of 34 years (Newman and Dunk, 2002). Despite an absence of data on its population structure, mixing, and identity, the population on the Seychelles Bank has been considered to be a unit stock for assessment purposes because of its remote location (e.g. Lablache and Carrara, 1988; Mees, 1992).
- Full Text:
- Date Issued: 2008
Rock magnetic stratigraphy of a mafic layered sill: a key to the Karoo volcanics plumbing system
- Maes, S M, Ferré, E E, Tikoff, B, Brown, P E, Marsh, Julian S
- Authors: Maes, S M , Ferré, E E , Tikoff, B , Brown, P E , Marsh, Julian S
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144901 , vital:38389 , https://doi.org/10.1016/j.jvolgeores.2005.07.038
- Description: The Insizwa sill is an 1 km-thick subhorizontal layered mafic intrusion and part of the Karoo Large Igneous Province in South Africa. This well-exposed intrusion consists of several superimposed petrologically and geochemically distinct units. Magnetic methods were used to study the intrusion in order to constrain the physical processes active in these types of bodies during crystallization. Rock magnetism studies indicate that within different petrologic units bulk susceptibility is controlled by primary magnetite (with minor pyrrhotite) and/or paramagnetic minerals (olivine, pyroxene). New magnetic data based on 659 specimens obtained from 3 vertical borehole cores, each spaced 5 km apart, confirm the prominent vertical zonation in low field magnetic susceptibility (Klf), degree of anisotropy (Pj) and orientation of the anisotropy of magnetic susceptibility (AMS) axes.
- Full Text:
- Date Issued: 2008
- Authors: Maes, S M , Ferré, E E , Tikoff, B , Brown, P E , Marsh, Julian S
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144901 , vital:38389 , https://doi.org/10.1016/j.jvolgeores.2005.07.038
- Description: The Insizwa sill is an 1 km-thick subhorizontal layered mafic intrusion and part of the Karoo Large Igneous Province in South Africa. This well-exposed intrusion consists of several superimposed petrologically and geochemically distinct units. Magnetic methods were used to study the intrusion in order to constrain the physical processes active in these types of bodies during crystallization. Rock magnetism studies indicate that within different petrologic units bulk susceptibility is controlled by primary magnetite (with minor pyrrhotite) and/or paramagnetic minerals (olivine, pyroxene). New magnetic data based on 659 specimens obtained from 3 vertical borehole cores, each spaced 5 km apart, confirm the prominent vertical zonation in low field magnetic susceptibility (Klf), degree of anisotropy (Pj) and orientation of the anisotropy of magnetic susceptibility (AMS) axes.
- Full Text:
- Date Issued: 2008
Sing a swansong for the SABC as we know it : keep public broadcasting, redistribute the broadcaster
- Authors: Berger, Guy
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159326 , vital:40288 , https://hdl.handle.net/10520/EJC140098
- Description: Behind the dragged-out confrontations around the SABC are a politics of paralysis. That's not necessarily a bad thing if the alternative is the broadcaster being a tool of a single particular force. But it's also not exactly first prize for South Africans. Power is divided across so many centres that no single force has been able to easily prevail on SABC during the year.
- Full Text:
- Date Issued: 2008
- Authors: Berger, Guy
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159326 , vital:40288 , https://hdl.handle.net/10520/EJC140098
- Description: Behind the dragged-out confrontations around the SABC are a politics of paralysis. That's not necessarily a bad thing if the alternative is the broadcaster being a tool of a single particular force. But it's also not exactly first prize for South Africans. Power is divided across so many centres that no single force has been able to easily prevail on SABC during the year.
- Full Text:
- Date Issued: 2008
Social and ecological trade offs in combating land degradation: The case of invasion by a woody shrub (Euryops floribundus) at Macubeni, South Africa
- Shackleton, Charlie M, Gambiza, James
- Authors: Shackleton, Charlie M , Gambiza, James
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181235 , vital:43711 , xlink:href="https://doi.org/10.1002/ldr.849"
- Description: Woody plant invasions, either of alien or indigenous species, are deemed to result in loss of ecosystem goods and services in many areas throughout the world, resulting in significant degradation and economic costs. Invasion of Euryops floribundus, a species indigenous to South Africa, is perceived to have reduced the grazing available for domestic livestock. Consequently, a programme of manual eradication has been implemented to improve the grazing resource and provide jobs for poverty alleviation. However, there is potential for a conflict of interest as our study shows that almost all households rely on Euryops for fuel and at times fencing material, whereas only a minority of households own livestock. Moreover, comparison of invaded and non-invaded sites indicated that the invaded sites harbour greater plant species richness and higher grass culm density per unit area of grass cover, as well as higher forb and litter cover. While invaded sites had lower grass cover, overall plant cover was no different between invaded and non-invaded sites. Multivariate analysis indicated no obvious differentiation in community composition between invaded and non-invaded areas, suggesting stronger drivers of community composition other than Euryops invasion presumed to be facilitated by the effects of high livestock densities. Overall, our study suggests that the clearing operation may well benefit from a better understanding of the social needs, perceptions of degradation by the various stakeholders and ecological dynamics of the area, especially local reliance on the resources, and the dynamics of the invasion, particularly its extent, rate of spread and susceptibility for re-invasion in the cleared areas.
- Full Text:
- Date Issued: 2008
- Authors: Shackleton, Charlie M , Gambiza, James
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181235 , vital:43711 , xlink:href="https://doi.org/10.1002/ldr.849"
- Description: Woody plant invasions, either of alien or indigenous species, are deemed to result in loss of ecosystem goods and services in many areas throughout the world, resulting in significant degradation and economic costs. Invasion of Euryops floribundus, a species indigenous to South Africa, is perceived to have reduced the grazing available for domestic livestock. Consequently, a programme of manual eradication has been implemented to improve the grazing resource and provide jobs for poverty alleviation. However, there is potential for a conflict of interest as our study shows that almost all households rely on Euryops for fuel and at times fencing material, whereas only a minority of households own livestock. Moreover, comparison of invaded and non-invaded sites indicated that the invaded sites harbour greater plant species richness and higher grass culm density per unit area of grass cover, as well as higher forb and litter cover. While invaded sites had lower grass cover, overall plant cover was no different between invaded and non-invaded sites. Multivariate analysis indicated no obvious differentiation in community composition between invaded and non-invaded areas, suggesting stronger drivers of community composition other than Euryops invasion presumed to be facilitated by the effects of high livestock densities. Overall, our study suggests that the clearing operation may well benefit from a better understanding of the social needs, perceptions of degradation by the various stakeholders and ecological dynamics of the area, especially local reliance on the resources, and the dynamics of the invasion, particularly its extent, rate of spread and susceptibility for re-invasion in the cleared areas.
- Full Text:
- Date Issued: 2008
Spam Construction Trends
- Irwin, Barry V W, Friedman, Blake
- Authors: Irwin, Barry V W , Friedman, Blake
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428762 , vital:72534 , https://www.researchgate.net/profile/Barry-Ir-win/publication/220803159_Spam_Construction_Trends/links/53fc76bd0cf2dca8ffff22fb/Spam-Construction-Trends.pdf
- Description: This paper replicates and extends Observed Trends in Spam Construction Tech-niques: A Case Study of Spam Evolution. A corpus of 169,274 spam email was col-lected over a period of five years. Each spam email was tested for construction techniques using SpamAssassin’s spamicity tests. The results of these tests were col-lected in a database. Formal definitions of Pu and Webb’s co-existence, extinction and complex trends were developed and applied to the results within the database. A comparison of the Spam Evolution Study and this paper’s results took place to de-termine the relevance of the trends. A geolocation analysis was conducted on the corpus, as an extension, to determine the major geographic sources of the corpus.
- Full Text:
- Date Issued: 2008
- Authors: Irwin, Barry V W , Friedman, Blake
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428762 , vital:72534 , https://www.researchgate.net/profile/Barry-Ir-win/publication/220803159_Spam_Construction_Trends/links/53fc76bd0cf2dca8ffff22fb/Spam-Construction-Trends.pdf
- Description: This paper replicates and extends Observed Trends in Spam Construction Tech-niques: A Case Study of Spam Evolution. A corpus of 169,274 spam email was col-lected over a period of five years. Each spam email was tested for construction techniques using SpamAssassin’s spamicity tests. The results of these tests were col-lected in a database. Formal definitions of Pu and Webb’s co-existence, extinction and complex trends were developed and applied to the results within the database. A comparison of the Spam Evolution Study and this paper’s results took place to de-termine the relevance of the trends. A geolocation analysis was conducted on the corpus, as an extension, to determine the major geographic sources of the corpus.
- Full Text:
- Date Issued: 2008
Spontaneous charge transfer between zinc tetramethyl-tetra-2, 3-pyridinoporphyrazine and CdTe and ZnS quantum dots
- Moeno, Sharon, Idowu, Mopelola, Nyokong, Tebello
- Authors: Moeno, Sharon , Idowu, Mopelola , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265997 , vital:53908 , xlink:href="https://doi.org/10.1016/j.ica.2008.02.048"
- Description: Zinc tetramethyl-tetra-2,3-pyridinoporphyrazine (ZnTmtppa(-2)) gets reduced to the ZnTmtppa(-3) species on interaction with CdTe QDs capped with 2-mercaptoethanol (2-ME) or thioglycolic acid (TGA) and ZnS QDs capped with 2-ME. The interaction occurs without photolysis. The fluorescence of the QDs is quenched by ZnTmtppa resulting in large quenching constants. Binding of ZnTmtppa to QDs occurs with two molecules of the former binding to the latter.
- Full Text:
- Date Issued: 2008
- Authors: Moeno, Sharon , Idowu, Mopelola , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265997 , vital:53908 , xlink:href="https://doi.org/10.1016/j.ica.2008.02.048"
- Description: Zinc tetramethyl-tetra-2,3-pyridinoporphyrazine (ZnTmtppa(-2)) gets reduced to the ZnTmtppa(-3) species on interaction with CdTe QDs capped with 2-mercaptoethanol (2-ME) or thioglycolic acid (TGA) and ZnS QDs capped with 2-ME. The interaction occurs without photolysis. The fluorescence of the QDs is quenched by ZnTmtppa resulting in large quenching constants. Binding of ZnTmtppa to QDs occurs with two molecules of the former binding to the latter.
- Full Text:
- Date Issued: 2008
Sustainability assessment using a unit-based sustainability assessment tool: The case of three teaching departments at Rhodes University, South Africa
- Authors: Togo, Muchaiteyi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386863 , vital:68182 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122776"
- Description: A sustainability assessment study was performed with three teaching departments at Rhodes University – Ichthyology and Fisheries Science, Anthropology, and Accounting. The assessment used a Unit-based Sustainability Assessment Tool (USAT) and was guided by systems thinking and the ontological framework provided by critical realism. Results of the study showed that the Department of Ichthyology and Fisheries Science had a higher integration of sustainability issues in its activities than the other departments sampled, with Accounting having the lowest integration. Interviews conducted with departmental heads and content analyses of documents revealed differences in sustainability issues addressed and in approaches used in tackling them among these departments. The study is intended to inform the Mainstreaming of Environment and Sustainability in African (MESA) Universities Partnership, which promotes mainstreaming environment and sustainability in universities during the United Nations Decade of Education for Sustainable Development. The study does not provide answers to mainstreaming activities, but opens up space to debate and deliberate how to deal with the mainstreaming of sustainability in universities. It identified some of the challenges to be addressed in university-wide mainstreaming work, and affirmed the need for systems thinking in bringing about change at institutional level to extend changes taking place in individual teaching contexts.
- Full Text:
- Date Issued: 2008
- Authors: Togo, Muchaiteyi
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386863 , vital:68182 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122776"
- Description: A sustainability assessment study was performed with three teaching departments at Rhodes University – Ichthyology and Fisheries Science, Anthropology, and Accounting. The assessment used a Unit-based Sustainability Assessment Tool (USAT) and was guided by systems thinking and the ontological framework provided by critical realism. Results of the study showed that the Department of Ichthyology and Fisheries Science had a higher integration of sustainability issues in its activities than the other departments sampled, with Accounting having the lowest integration. Interviews conducted with departmental heads and content analyses of documents revealed differences in sustainability issues addressed and in approaches used in tackling them among these departments. The study is intended to inform the Mainstreaming of Environment and Sustainability in African (MESA) Universities Partnership, which promotes mainstreaming environment and sustainability in universities during the United Nations Decade of Education for Sustainable Development. The study does not provide answers to mainstreaming activities, but opens up space to debate and deliberate how to deal with the mainstreaming of sustainability in universities. It identified some of the challenges to be addressed in university-wide mainstreaming work, and affirmed the need for systems thinking in bringing about change at institutional level to extend changes taking place in individual teaching contexts.
- Full Text:
- Date Issued: 2008
Synthesis and electrochemical characterisation of a near infrared absorbing oxo vanadium (IV) octapentylthio-phthalocyanine
- Mbambisa, Gcineka, Nyokong, Tebello
- Authors: Mbambisa, Gcineka , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266008 , vital:53909 , xlink:href="https://doi.org/10.1016/j.poly.2008.06.004"
- Description: The synthesis of an α-substituted phthalocyanine oxo vanadium(IV) 1,4,8,11,15,18,22,25-octapentathiophthalocyanine (4) which absorbs at 850 nm in dichloromethane is reported. The complex is purple in colour and becomes green on reduction. The cyclic and square wave voltammetries of the complex show five redox couples. The spectroelectrochemical data showed only ring based processes. The ring reduced species is observed at wavelengths greater than 680 nm rather than the usual 500–600 nm range typical of ring reduced phthalocyanine complexes.
- Full Text:
- Date Issued: 2008
- Authors: Mbambisa, Gcineka , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266008 , vital:53909 , xlink:href="https://doi.org/10.1016/j.poly.2008.06.004"
- Description: The synthesis of an α-substituted phthalocyanine oxo vanadium(IV) 1,4,8,11,15,18,22,25-octapentathiophthalocyanine (4) which absorbs at 850 nm in dichloromethane is reported. The complex is purple in colour and becomes green on reduction. The cyclic and square wave voltammetries of the complex show five redox couples. The spectroelectrochemical data showed only ring based processes. The ring reduced species is observed at wavelengths greater than 680 nm rather than the usual 500–600 nm range typical of ring reduced phthalocyanine complexes.
- Full Text:
- Date Issued: 2008
Synthesis and photophysical properties of lead phthalocyanines
- Modibane, D.K., Nyokong, Tebello
- Authors: Modibane, D.K. , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268636 , vital:54216 , xlink:href="https://doi.org/10.1016/j.poly.2007.12.004"
- Description: This work reports on the synthesis and photophysical parameters of tetra-and octa-substituted new lead phthalocyanines. The complexes synthesized are: 1,4-(tetraphenoxyphthalocyaninato)lead (7a), 1,4-(tetra-tert-butylphenoxyphthalocyaninato)lead (7b), 2,3-(tetraphenoxyphthalocyaninato)lead (8a), 2,3-(tetra-tert-butylphenoxyphthalocyaninato)lead (8b), 2,3-octaphenoxyphthalocyaninatolead (9a) 2,3-[octakis(4-t-butylphenoxyphthalocyaninato)]lead (9b). Photophysical properties were studied for these complexes in a dimethylsulfoxide, dimethylformamide, toluene, tetrahydrofuran and chloroform. The fluorescence spectra were different from excitation spectra due to demetallation upon excitation. High triplet quantum yields ranging from 0.70 to 0.88 (in DMSO, DMF and toluene) and low triplet lifetimes (20–50 μs in DMSO, and more than 10 μs in the rest of the solvents) were observed due to the presence of heavy atom.
- Full Text:
- Date Issued: 2008
- Authors: Modibane, D.K. , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268636 , vital:54216 , xlink:href="https://doi.org/10.1016/j.poly.2007.12.004"
- Description: This work reports on the synthesis and photophysical parameters of tetra-and octa-substituted new lead phthalocyanines. The complexes synthesized are: 1,4-(tetraphenoxyphthalocyaninato)lead (7a), 1,4-(tetra-tert-butylphenoxyphthalocyaninato)lead (7b), 2,3-(tetraphenoxyphthalocyaninato)lead (8a), 2,3-(tetra-tert-butylphenoxyphthalocyaninato)lead (8b), 2,3-octaphenoxyphthalocyaninatolead (9a) 2,3-[octakis(4-t-butylphenoxyphthalocyaninato)]lead (9b). Photophysical properties were studied for these complexes in a dimethylsulfoxide, dimethylformamide, toluene, tetrahydrofuran and chloroform. The fluorescence spectra were different from excitation spectra due to demetallation upon excitation. High triplet quantum yields ranging from 0.70 to 0.88 (in DMSO, DMF and toluene) and low triplet lifetimes (20–50 μs in DMSO, and more than 10 μs in the rest of the solvents) were observed due to the presence of heavy atom.
- Full Text:
- Date Issued: 2008
Synthesis and solvent effects on the photophysicochemical properties of novel cadmium phenoxy phthalocyanines
- Chidawanyika, Wadzanai J U, Antunes, Edith M, Nyokong, Tebello
- Authors: Chidawanyika, Wadzanai J U , Antunes, Edith M , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268649 , vital:54217 , xlink:href="https://doi.org/10.1016/j.jphotochem.2007.09.020"
- Description: The syntheses of novel cadmium phenoxy complexes; tetrakis{1,(4)-tert-butylphenoxyphthalocyaninato}cadmium(II) (5a), tetrakis{1,(4)-phenoxyphthalocyaninato}cadmium(II) (5b), tetrakis{2,(3)-tert-butylphenoxyphthalocyaninato}cadmium(II) (6a) and tetrakis{2,(3)-phenoxyphthalocyaninato}cadmium(II) (6b) are presented herein. The spectroscopic and photophysicochemical properties have also been carried out and discussed together with the influence of various organic solvents on these properties. Spectroscopic properties, i.e. ground state electronic absorption and fluorescence spectra have been found to vary as a function of substituent position on the phthalocyanine macrocycle, i.e. α-substitution versus β-substitution. The photophysical parameters are reported as well as the photodegradation and singlet oxygen quantum yields, where the complexes were found to exhibit good photostability with the production of appreciable amounts of singlet oxygen.
- Full Text:
- Date Issued: 2008
- Authors: Chidawanyika, Wadzanai J U , Antunes, Edith M , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268649 , vital:54217 , xlink:href="https://doi.org/10.1016/j.jphotochem.2007.09.020"
- Description: The syntheses of novel cadmium phenoxy complexes; tetrakis{1,(4)-tert-butylphenoxyphthalocyaninato}cadmium(II) (5a), tetrakis{1,(4)-phenoxyphthalocyaninato}cadmium(II) (5b), tetrakis{2,(3)-tert-butylphenoxyphthalocyaninato}cadmium(II) (6a) and tetrakis{2,(3)-phenoxyphthalocyaninato}cadmium(II) (6b) are presented herein. The spectroscopic and photophysicochemical properties have also been carried out and discussed together with the influence of various organic solvents on these properties. Spectroscopic properties, i.e. ground state electronic absorption and fluorescence spectra have been found to vary as a function of substituent position on the phthalocyanine macrocycle, i.e. α-substitution versus β-substitution. The photophysical parameters are reported as well as the photodegradation and singlet oxygen quantum yields, where the complexes were found to exhibit good photostability with the production of appreciable amounts of singlet oxygen.
- Full Text:
- Date Issued: 2008
Synthesis, electrochemical characterization of tetra-and octa-substituted dodecyl-mercapto tin phthalocyanines in solution and as self-assembled monolayers
- Khene, Samson M, Geraldo, Daniela A, Togo, Chamunorwa A, Limson, Janice L, Nyokong, Tebello
- Authors: Khene, Samson M , Geraldo, Daniela A , Togo, Chamunorwa A , Limson, Janice L , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264541 , vital:53743 , xlink:href="https://doi.org/10.1016/j.electacta.2008.08.018"
- Description: Non-peripherally (α) tetra- (9) and octa-(7) substituted dodecyl-mercapto tin(IV) phthalocyanines were synthesized and their electrochemical behavior studied. Cyclic voltammetry and spectroelectrochemistry show ring-based reductions for 7 and 9, the former shows two ring oxidations, while the latter shows only one ring-based oxidation. The adsorption kinetics of (7) and (9) on gold electrode were investigated by electrochemical impedance spectroscopy (EIS). The equilibrium constant (K) for the adsorption and the Gibbs free energy (ΔGads) of the SAMs were evaluated based on the Frumkin isotherm.
- Full Text:
- Date Issued: 2008
- Authors: Khene, Samson M , Geraldo, Daniela A , Togo, Chamunorwa A , Limson, Janice L , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264541 , vital:53743 , xlink:href="https://doi.org/10.1016/j.electacta.2008.08.018"
- Description: Non-peripherally (α) tetra- (9) and octa-(7) substituted dodecyl-mercapto tin(IV) phthalocyanines were synthesized and their electrochemical behavior studied. Cyclic voltammetry and spectroelectrochemistry show ring-based reductions for 7 and 9, the former shows two ring oxidations, while the latter shows only one ring-based oxidation. The adsorption kinetics of (7) and (9) on gold electrode were investigated by electrochemical impedance spectroscopy (EIS). The equilibrium constant (K) for the adsorption and the Gibbs free energy (ΔGads) of the SAMs were evaluated based on the Frumkin isotherm.
- Full Text:
- Date Issued: 2008
Synthesis, photophysical and photochemical studies on long chain zinc phthalocyanine derivatives
- Ogunsipe, Abimbola, Durmus, Mahmut, Atilla, Devrim, Gürek, Ayşe Gül, Ahsen, Vefa, Nyokong, Tebello
- Authors: Ogunsipe, Abimbola , Durmus, Mahmut , Atilla, Devrim , Gürek, Ayşe Gül , Ahsen, Vefa , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266019 , vital:53910 , xlink:href="https://doi.org/10.1016/j.synthmet.2008.06.007"
- Description: The synthesis and characterization of 2,9,16,23-chloro-3,10,17,24-triethyleneoxysulphanylphthalocyaninato zinc(II) (CTESZnPc) is described. The photophysics and photochemistry of CTESZnPc and those of tetrakis(triethyleneoxysulphanyl)zinc phthalocyanine (TTESZnPc) and octakis(triethyleneoxysulphanyl)zinc phthalocyanine (OTESZnPc), are presented and compared with those of unsubstituted zinc phthalocyanine (ZnPc). The presence of triethyleneoxysulphanyl substituents on the ZnPc ring gave rise to higher values of singlet oxygen (ΦΔ) and photodegradation (ΦPd) quantum yields in DMF. However, TTESZnPc, OTESZnPc and CTESZnPc are less fluorescent than ZnPc, judging from their fluorescence quantum yield (ΦF) values. Fluorescence was lower in toluene than in DMF due to aggregation in the former solvent. Triplet quantum yield (ΦT) values were found to increase with the presence of substituents on the ZnPc ring, while triplet lifetimes (τT) were found to vary linearly with the logarithms of solvent viscosities. The fluorescences of the substituted ZnPc complexes were effectively quenched by benzoquinone (BQ), and the quenching data analyzed by the Stern–Volmer equation. The Stern–Volmer constants and the diffusion-controlled bimolecular rate constants were calculated.
- Full Text:
- Date Issued: 2008
- Authors: Ogunsipe, Abimbola , Durmus, Mahmut , Atilla, Devrim , Gürek, Ayşe Gül , Ahsen, Vefa , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266019 , vital:53910 , xlink:href="https://doi.org/10.1016/j.synthmet.2008.06.007"
- Description: The synthesis and characterization of 2,9,16,23-chloro-3,10,17,24-triethyleneoxysulphanylphthalocyaninato zinc(II) (CTESZnPc) is described. The photophysics and photochemistry of CTESZnPc and those of tetrakis(triethyleneoxysulphanyl)zinc phthalocyanine (TTESZnPc) and octakis(triethyleneoxysulphanyl)zinc phthalocyanine (OTESZnPc), are presented and compared with those of unsubstituted zinc phthalocyanine (ZnPc). The presence of triethyleneoxysulphanyl substituents on the ZnPc ring gave rise to higher values of singlet oxygen (ΦΔ) and photodegradation (ΦPd) quantum yields in DMF. However, TTESZnPc, OTESZnPc and CTESZnPc are less fluorescent than ZnPc, judging from their fluorescence quantum yield (ΦF) values. Fluorescence was lower in toluene than in DMF due to aggregation in the former solvent. Triplet quantum yield (ΦT) values were found to increase with the presence of substituents on the ZnPc ring, while triplet lifetimes (τT) were found to vary linearly with the logarithms of solvent viscosities. The fluorescences of the substituted ZnPc complexes were effectively quenched by benzoquinone (BQ), and the quenching data analyzed by the Stern–Volmer equation. The Stern–Volmer constants and the diffusion-controlled bimolecular rate constants were calculated.
- Full Text:
- Date Issued: 2008
The Cultural Use of the Wild Olive Tree by the amaXhosa People in the Eastern Cape Province of South Africa:
- Cocks, Michelle L, Dold, Anthony P
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141314 , vital:37961 , DOI: 10.1558/jsrnc.v2i3.292
- Description: The cultural meanings of harvested plants have for the most part been ignored in academic research on non-timber forest products (NTFPs) in southern Africa. Historically scientists have tended to ignore the complex relationships between nature and culture. Given the country's unique political and economic past and the current search for sustainable use of natural resources, a focus on the convergence of natural science and cultural diversity is important at this time. Empirical data on cultural practices is being collected in order to develop fresh and relevant insights into the complex relationships between culture and bítKÜversity. The purpose of this paper is to demonstrate that the concept of culture needs to be brought into our understanding of the role of NTFPs. We dtxrument the use and value of a specific tree, Olea europaea L. subsp. africana (Mill.) P,S. Green, called Umiicjuma in the Xhosa language, for cultural purposes, by both rural and urban households.
- Full Text:
- Date Issued: 2008
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141314 , vital:37961 , DOI: 10.1558/jsrnc.v2i3.292
- Description: The cultural meanings of harvested plants have for the most part been ignored in academic research on non-timber forest products (NTFPs) in southern Africa. Historically scientists have tended to ignore the complex relationships between nature and culture. Given the country's unique political and economic past and the current search for sustainable use of natural resources, a focus on the convergence of natural science and cultural diversity is important at this time. Empirical data on cultural practices is being collected in order to develop fresh and relevant insights into the complex relationships between culture and bítKÜversity. The purpose of this paper is to demonstrate that the concept of culture needs to be brought into our understanding of the role of NTFPs. We dtxrument the use and value of a specific tree, Olea europaea L. subsp. africana (Mill.) P,S. Green, called Umiicjuma in the Xhosa language, for cultural purposes, by both rural and urban households.
- Full Text:
- Date Issued: 2008
The development of ICT networks for South African schools: Two pilot studies in disadvantaged areas
- Siebörger, Ingrid, Terzoli, Alfredo, Hodgkinson-Williams, Cheryl
- Authors: Siebörger, Ingrid , Terzoli, Alfredo , Hodgkinson-Williams, Cheryl
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431018 , vital:72737 , https://doi.org/10.1007/978-0-387-09729-9_25
- Description: Information and Communication Technologies (ICTs) are increasingly considered valuable tools in educa-tion, promoting the development of higher cognitive processes and allowing teachers and learners access to a plethora of information. This paper reports on two pilot studies conducted in South Africa in proto-typical previously disadvantaged schools and their surrounding communities. Each pilot study deployed a local loop network within impoverished communi-ties, connecting schools to one another and central services such as email and voice communications. The benefits of these networks were that teachers, learners and the local community had access to in-formation, and communication and collaboration channels, providing potential test beds for investigat-ing the use of computers as mind tools.
- Full Text:
- Date Issued: 2008
- Authors: Siebörger, Ingrid , Terzoli, Alfredo , Hodgkinson-Williams, Cheryl
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431018 , vital:72737 , https://doi.org/10.1007/978-0-387-09729-9_25
- Description: Information and Communication Technologies (ICTs) are increasingly considered valuable tools in educa-tion, promoting the development of higher cognitive processes and allowing teachers and learners access to a plethora of information. This paper reports on two pilot studies conducted in South Africa in proto-typical previously disadvantaged schools and their surrounding communities. Each pilot study deployed a local loop network within impoverished communi-ties, connecting schools to one another and central services such as email and voice communications. The benefits of these networks were that teachers, learners and the local community had access to in-formation, and communication and collaboration channels, providing potential test beds for investigat-ing the use of computers as mind tools.
- Full Text:
- Date Issued: 2008
The Internet in rural communities: unrestricted and contextualized
- Thinyane, Mamello, Dalvit, Lorenzo, Terzoli, Alfredo, Clayton, Peter G
- Authors: Thinyane, Mamello , Dalvit, Lorenzo , Terzoli, Alfredo , Clayton, Peter G
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431344 , vital:72766 , https://www.researchgate.net/profile/Alfredo-Ter-zoli/publication/262259378_The_Internet_in_rural_communities_unrestricted_and_contextualized/links/6597ec140bb2c7472b35fcac/The-Internet-in-rural-communities-unrestricted-and-contextualized.pdf
- Description: The benefits of the Internet are still not available to many marginalized communities because of lack of connectivity, costs of infrastructure and scarcity of skills. Many ICTforDevelopment (ICT4D) projects offer piecemeal interventions relying either on restricted (and often decontex-tualised) access to the Internet or on isolated Local Area Networks (LANs). In this paper we argue that marginalized rural communities should have unrestricted access to the Internet in order to exploit its full potential. We also believe that the Internet could be contextualized through an optional adaptation layer which would facilitate access. We discuss an ICT4D project which was shaped from the very beginning according to these principles. It involves the deployment of an eCom-merce platform (soon to be integrated with eHealth, eLearning and eGovernment capabilities) in a rural community in South Africa. We re-port on how the various components of this intervention fit into the model, and the benefits for the community.
- Full Text:
- Date Issued: 2008
- Authors: Thinyane, Mamello , Dalvit, Lorenzo , Terzoli, Alfredo , Clayton, Peter G
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431344 , vital:72766 , https://www.researchgate.net/profile/Alfredo-Ter-zoli/publication/262259378_The_Internet_in_rural_communities_unrestricted_and_contextualized/links/6597ec140bb2c7472b35fcac/The-Internet-in-rural-communities-unrestricted-and-contextualized.pdf
- Description: The benefits of the Internet are still not available to many marginalized communities because of lack of connectivity, costs of infrastructure and scarcity of skills. Many ICTforDevelopment (ICT4D) projects offer piecemeal interventions relying either on restricted (and often decontex-tualised) access to the Internet or on isolated Local Area Networks (LANs). In this paper we argue that marginalized rural communities should have unrestricted access to the Internet in order to exploit its full potential. We also believe that the Internet could be contextualized through an optional adaptation layer which would facilitate access. We discuss an ICT4D project which was shaped from the very beginning according to these principles. It involves the deployment of an eCom-merce platform (soon to be integrated with eHealth, eLearning and eGovernment capabilities) in a rural community in South Africa. We re-port on how the various components of this intervention fit into the model, and the benefits for the community.
- Full Text:
- Date Issued: 2008