Oral literature in Africa
- Authors: Kaschula, Russell H
- Date: 2013
- Subjects: Folk literature -- Study and teaching -- Africa , Oral tradition -- Africa , Folklore and education -- Africa , Books -- Africa -- Reviews
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59355 , vital:27563 , https://doi.org/10.1080/13696815.2012.756804
- Description: I have in my possession a first edition, hard copy of Ruth Finnegan’s quintessential work, Oral Literature in Africa. It has a yellow cover, preserved by a plastic sheathe, it is a little frayed around the edges and has that old, musty library smell about it. I love and treasure this book. It is dedicated by Professor Finnegan ‘[t]o all my teachers’. Professor Finnegan is indeed one of my teachers. I properly met Ruth Finnegan at the second International Society for Oral Literature (ISOLA) conference in 1998, which I hosted at the University of Cape Town. She gave a keynote address which included reference to her seminal work and the future of oral literary studies. She has continually influenced our work as researchers following in her footsteps: Isidore Okpewho, Harold Scheub, Abiola Irele, Graham Furniss, Elizabeth Gunner, Karin Barber, Isobel Hofmeyr, John Foley, Olayibi Yai, Edgard Sienaert, Brian Street, Noverino Canonici, Mark Turin, Daniela Merolla, Jan Jansen, Jeff Opland, and many others; some younger, some older, some living, some departed, scholars influenced by this great and humble intellectual and her body of work.
- Full Text:
- Date Issued: 2013
- Authors: Kaschula, Russell H
- Date: 2013
- Subjects: Folk literature -- Study and teaching -- Africa , Oral tradition -- Africa , Folklore and education -- Africa , Books -- Africa -- Reviews
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59355 , vital:27563 , https://doi.org/10.1080/13696815.2012.756804
- Description: I have in my possession a first edition, hard copy of Ruth Finnegan’s quintessential work, Oral Literature in Africa. It has a yellow cover, preserved by a plastic sheathe, it is a little frayed around the edges and has that old, musty library smell about it. I love and treasure this book. It is dedicated by Professor Finnegan ‘[t]o all my teachers’. Professor Finnegan is indeed one of my teachers. I properly met Ruth Finnegan at the second International Society for Oral Literature (ISOLA) conference in 1998, which I hosted at the University of Cape Town. She gave a keynote address which included reference to her seminal work and the future of oral literary studies. She has continually influenced our work as researchers following in her footsteps: Isidore Okpewho, Harold Scheub, Abiola Irele, Graham Furniss, Elizabeth Gunner, Karin Barber, Isobel Hofmeyr, John Foley, Olayibi Yai, Edgard Sienaert, Brian Street, Noverino Canonici, Mark Turin, Daniela Merolla, Jan Jansen, Jeff Opland, and many others; some younger, some older, some living, some departed, scholars influenced by this great and humble intellectual and her body of work.
- Full Text:
- Date Issued: 2013
Overcrowding of false codling moth, Thaumatotibia leucotreta (Meyrick) leads to the isolation of five new Cryptophlebia leucotreta granulovirus (CrleGV-SA) isolates
- Opoku-Debrah, John K, Hill, Martin P, Knox, Caroline M, Moore, Sean D
- Authors: Opoku-Debrah, John K , Hill, Martin P , Knox, Caroline M , Moore, Sean D
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419360 , vital:71637 , xlink:href="https://doi.org/10.1016/j.jip.2012.12.008"
- Description: False codling moth, Thaumatotibia leucotreta (Meyrick) is a serious pest of economic importance to the South African fruit industry. As part of sustainable efforts to control this pest, biological control options that involve the application of baculovirus-based biopesticides such as Cryptogran and Cryptex (both formulated with a South African isolate of Cryptophlebia leucotreta granulovirus, CrleGV-SA) are popularly used by farmers. In order to safeguard the integrity of these biopesticides as well as protect against any future development of resistance in the host, we conducted a study to bioprospect for additional CrleGV isolates as alternatives to existing ones. Using overcrowding as an induction method for latent infection, we recovered five new CrleGV isolates (CrleGV-SA Ado, CrleGV-SA Mbl, CrleGV-SA Cit, CrleGV-SA MixC and CrleGV-SA Nels). Single restriction endonuclease (REN) analysis of viral genomic DNA extracted from purified occlusion bodies showed that isolates differed in their DNA profiles. Partial sequencing of granulin and egt genes from the different isolates and multiple alignments of nucleotide sequences revealed the presence of single nucleotide polymorphisms (SNPs), some of which resulted in amino acid substitutions in the protein sequence. Based on these findings as well as comparisons with other documented CrleGV isolates, we propose two phylogenetic groups for CrleGV-SA isolates recovered in this study.
- Full Text:
- Date Issued: 2013
- Authors: Opoku-Debrah, John K , Hill, Martin P , Knox, Caroline M , Moore, Sean D
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419360 , vital:71637 , xlink:href="https://doi.org/10.1016/j.jip.2012.12.008"
- Description: False codling moth, Thaumatotibia leucotreta (Meyrick) is a serious pest of economic importance to the South African fruit industry. As part of sustainable efforts to control this pest, biological control options that involve the application of baculovirus-based biopesticides such as Cryptogran and Cryptex (both formulated with a South African isolate of Cryptophlebia leucotreta granulovirus, CrleGV-SA) are popularly used by farmers. In order to safeguard the integrity of these biopesticides as well as protect against any future development of resistance in the host, we conducted a study to bioprospect for additional CrleGV isolates as alternatives to existing ones. Using overcrowding as an induction method for latent infection, we recovered five new CrleGV isolates (CrleGV-SA Ado, CrleGV-SA Mbl, CrleGV-SA Cit, CrleGV-SA MixC and CrleGV-SA Nels). Single restriction endonuclease (REN) analysis of viral genomic DNA extracted from purified occlusion bodies showed that isolates differed in their DNA profiles. Partial sequencing of granulin and egt genes from the different isolates and multiple alignments of nucleotide sequences revealed the presence of single nucleotide polymorphisms (SNPs), some of which resulted in amino acid substitutions in the protein sequence. Based on these findings as well as comparisons with other documented CrleGV isolates, we propose two phylogenetic groups for CrleGV-SA isolates recovered in this study.
- Full Text:
- Date Issued: 2013
Oxovanadium (IV)-containing poly (styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) electrospun nanofibers for the catalytic oxidation of thioanisole
- Walmsley, Ryan S, Litwinski, Christian, Antunes, Edith M, Hlangothi, Percy, Hosten, Eric C, McCleland, Cedric, Nyokong, Tebello, Torto, Nelson, Tshentu, Zenixole R
- Authors: Walmsley, Ryan S , Litwinski, Christian , Antunes, Edith M , Hlangothi, Percy , Hosten, Eric C , McCleland, Cedric , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241665 , vital:50959 , xlink:href="https://doi.org/10.1016/j.molcata.2013.07.018"
- Description: The catalytic fibers have been fabricated by the electrospinning of a copolymer of styrene and 2-(2′-hydroxy-4′-ethenylphenyl)imidazole {p(ST-co-VPIM)} followed by a reaction with a methanolic vanadyl solution to afford the oxovanadium(IV)-containing poly(styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) fibers {p(ST-co-VPIM)-VO fibers}. The relationship between polymer concentration and fiber diameter was investigated, and at high concentration (20 wt%) the fibers were quite large (average diameter of 3.8 μm) but as the concentration was reduced fibers of much lower diameter were produced (0.6 μm using 8 wt%). The BET surface area for p(ST-co-VPIM) fibers (0.6 μm diameter) was 47.9 m2 g−1 and functionalization of p(ST-co-VPIM) with vanadyl resulted in an increase in surface area to 60.7 m2 g−1 for p(ST-co-VPIM)-VO. The presence of vanadyl was confirmed by XPS and EPR. The EPR spectral analyses depicted complex speciation of vanadium within these polymer supports. These catalytic fibers were applied under batch and continuous flow conditions for the catalytic oxidation of thioanisole using hydrogen peroxide. The continuous flow method gave excellent and constant conversion throughout the 10 h period studied. The leaching of vanadium from the fiber support was 4% over the 10 h period indicating a significant stability of the material.
- Full Text:
- Date Issued: 2013
- Authors: Walmsley, Ryan S , Litwinski, Christian , Antunes, Edith M , Hlangothi, Percy , Hosten, Eric C , McCleland, Cedric , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241665 , vital:50959 , xlink:href="https://doi.org/10.1016/j.molcata.2013.07.018"
- Description: The catalytic fibers have been fabricated by the electrospinning of a copolymer of styrene and 2-(2′-hydroxy-4′-ethenylphenyl)imidazole {p(ST-co-VPIM)} followed by a reaction with a methanolic vanadyl solution to afford the oxovanadium(IV)-containing poly(styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) fibers {p(ST-co-VPIM)-VO fibers}. The relationship between polymer concentration and fiber diameter was investigated, and at high concentration (20 wt%) the fibers were quite large (average diameter of 3.8 μm) but as the concentration was reduced fibers of much lower diameter were produced (0.6 μm using 8 wt%). The BET surface area for p(ST-co-VPIM) fibers (0.6 μm diameter) was 47.9 m2 g−1 and functionalization of p(ST-co-VPIM) with vanadyl resulted in an increase in surface area to 60.7 m2 g−1 for p(ST-co-VPIM)-VO. The presence of vanadyl was confirmed by XPS and EPR. The EPR spectral analyses depicted complex speciation of vanadium within these polymer supports. These catalytic fibers were applied under batch and continuous flow conditions for the catalytic oxidation of thioanisole using hydrogen peroxide. The continuous flow method gave excellent and constant conversion throughout the 10 h period studied. The leaching of vanadium from the fiber support was 4% over the 10 h period indicating a significant stability of the material.
- Full Text:
- Date Issued: 2013
Perceptions and use of public green space is influenced by its relative abundance in two small towns in South Africa
- Shackleton, Charlie M, Blair, Andrew
- Authors: Shackleton, Charlie M , Blair, Andrew
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181026 , vital:43688 , xlink:href="https://doi.org/10.1016/j.landurbplan.2013.01.011"
- Description: The challenges in planning and maintaining urban public green spaces in poor towns of the developing world differ markedly from those of the developed world. This paper reports on residents’ perceptions, use and willingness to get involved in urban public green space (PGS) issues in two poor towns in South Africa which differed markedly in the amount of PGS. The disparities in PGS between the two towns were also replicated in different suburbs within the two towns. We hypothesised that levels of dissatisfaction would be highest in those suburbs and the town with the least PGS. The results indicated that the distance from residents’ homesteads to the nearest PGS was similar across towns and suburbs. Most residents felt that having accessible PGS was important, and the majority agreed that there was insufficient PGS in their respective town and suburb, and that the local municipality did not do enough in providing PGS or maintaining what there was. The level of dissatisfaction with the amount and condition of PGS was generally highest in the suburbs and town with the least PGS. Many felt that the municipality had insufficient commitment and funds to adequately maintain PGS, and consequently the willingness of residents to get involved through either a commitment of time or funds was high. The more affluent town and suburbs were willing to pay more than the poorer ones, and the poorer ones were willing to provide more time than the more affluent ones.
- Full Text:
- Date Issued: 2013
- Authors: Shackleton, Charlie M , Blair, Andrew
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181026 , vital:43688 , xlink:href="https://doi.org/10.1016/j.landurbplan.2013.01.011"
- Description: The challenges in planning and maintaining urban public green spaces in poor towns of the developing world differ markedly from those of the developed world. This paper reports on residents’ perceptions, use and willingness to get involved in urban public green space (PGS) issues in two poor towns in South Africa which differed markedly in the amount of PGS. The disparities in PGS between the two towns were also replicated in different suburbs within the two towns. We hypothesised that levels of dissatisfaction would be highest in those suburbs and the town with the least PGS. The results indicated that the distance from residents’ homesteads to the nearest PGS was similar across towns and suburbs. Most residents felt that having accessible PGS was important, and the majority agreed that there was insufficient PGS in their respective town and suburb, and that the local municipality did not do enough in providing PGS or maintaining what there was. The level of dissatisfaction with the amount and condition of PGS was generally highest in the suburbs and town with the least PGS. Many felt that the municipality had insufficient commitment and funds to adequately maintain PGS, and consequently the willingness of residents to get involved through either a commitment of time or funds was high. The more affluent town and suburbs were willing to pay more than the poorer ones, and the poorer ones were willing to provide more time than the more affluent ones.
- Full Text:
- Date Issued: 2013
Perceptions of fortune and misfortune in older South African households: social assistance and the ‘Good Life’
- Moller, Valerie, Radloff, Sarah E
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67165 , vital:29043 , https://doi.org/10.1007/s11205-012-0026-8
- Description: publisher version , It is commonly assumed that better living standards will boost subjective well-being. The post-apartheid South African government subscribes to this idea; its social policies aim to provide ‘a better life for all’. Since the coming of democracy in 1994, the state has built over 3 million houses and supplied electricity and clean water to poor households. By 2009, an estimated 43 % of households were beneficiaries of social grants. The question is whether this investment in services and social assistance translates into higher well-being of citizens. It is argued that older people’s experience of positive change in their life circumstances can be taken as a litmus test of progress in society. The paper reports results of a sample survey conducted in 2009 that inquired into the living circumstances and well-being of 1,000 older low-income households in two provinces linked by a labour migration route. Older households were defined as ones with a member 55 years and older. The sample was drawn among three approximately equal-sized subgroups: Rural black households in the former ‘homelands’ of the Eastern Cape Province, and black and coloured households in Cape Town in the Western Cape Province. The majority of the households in the survey had been interviewed in an earlier survey conducted in late 2002. Both material and non-material changes had occurred in the household situation over the 6-year period between 2002 and 2009. Access to housing and infrastructure had improved but financial difficulties and debts continued to plague many of the surveyed households. Rural black households appeared to be worst off among the three categories of older households with the lowest level of living; coloured households best situated with the highest level of living. Urban black households, many of whom were immigrants to Cape Town, appeared to have experienced the greatest fluctuations in their material circumstances between 2002 and 2009 and a mix of fortune and misfortune. Results indicated that social grants, which provided a modicum of financial security and peace of mind, made the crucial difference between fortune and misfortune for vulnerable households. Securing a social pension and other grants appeared to be the main route to good fortune for the rural households in the study. Households in Cape Town required wage income in addition to grant income to get by in the city. This mix of income sources diluted urban households’ dependence on social assistance. Regression model results suggest that income and financial security play a significantly more important role in boosting the well-being of low-income older households than access to services. Pooling of income, a common practice in pensioner households, contributed significantly to household satisfaction.
- Full Text: false
- Date Issued: 2013
- Authors: Moller, Valerie , Radloff, Sarah E
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67165 , vital:29043 , https://doi.org/10.1007/s11205-012-0026-8
- Description: publisher version , It is commonly assumed that better living standards will boost subjective well-being. The post-apartheid South African government subscribes to this idea; its social policies aim to provide ‘a better life for all’. Since the coming of democracy in 1994, the state has built over 3 million houses and supplied electricity and clean water to poor households. By 2009, an estimated 43 % of households were beneficiaries of social grants. The question is whether this investment in services and social assistance translates into higher well-being of citizens. It is argued that older people’s experience of positive change in their life circumstances can be taken as a litmus test of progress in society. The paper reports results of a sample survey conducted in 2009 that inquired into the living circumstances and well-being of 1,000 older low-income households in two provinces linked by a labour migration route. Older households were defined as ones with a member 55 years and older. The sample was drawn among three approximately equal-sized subgroups: Rural black households in the former ‘homelands’ of the Eastern Cape Province, and black and coloured households in Cape Town in the Western Cape Province. The majority of the households in the survey had been interviewed in an earlier survey conducted in late 2002. Both material and non-material changes had occurred in the household situation over the 6-year period between 2002 and 2009. Access to housing and infrastructure had improved but financial difficulties and debts continued to plague many of the surveyed households. Rural black households appeared to be worst off among the three categories of older households with the lowest level of living; coloured households best situated with the highest level of living. Urban black households, many of whom were immigrants to Cape Town, appeared to have experienced the greatest fluctuations in their material circumstances between 2002 and 2009 and a mix of fortune and misfortune. Results indicated that social grants, which provided a modicum of financial security and peace of mind, made the crucial difference between fortune and misfortune for vulnerable households. Securing a social pension and other grants appeared to be the main route to good fortune for the rural households in the study. Households in Cape Town required wage income in addition to grant income to get by in the city. This mix of income sources diluted urban households’ dependence on social assistance. Regression model results suggest that income and financial security play a significantly more important role in boosting the well-being of low-income older households than access to services. Pooling of income, a common practice in pensioner households, contributed significantly to household satisfaction.
- Full Text: false
- Date Issued: 2013
Persistence and virulence of promising entomopathogenic fungal isolates for use in citrus orchards in South Africa
- Coombes, Candice A, Hill, Martin P, Moore, Sean D, Dames, Joanna F, Fullard, T
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416893 , vital:71394 , xlink:href="https://doi.org/10.1080/09583157.2013.819489"
- Description: Thaumatotibia leucotreta (Meyrick) (1912) (Lepidoptera: Tortricidae) is a key economic pest of citrus in South Africa. Although a variety of control options are available, none currently registered target the soil-dwelling life stages of the pest. Three fungal isolates, two Metarhizium anisopliae sensu lato Metschnikoff (Sorokin) isolates (G 11 3 L6 and FCM Ar 23 B3) and one Beauveria bassiana sensu lato Balsamo (Vuillemin) isolate (G Ar 17 B3) have been identified as showing the greatest potential against T. leucotreta soil-dwelling life stages. Since environmental persistence is an important factor in the success of entomopathogenic fungi against soil pests, the isolates, along with two commercial isolates (B. bassiana Eco-Bb® and M. anisopliae ICIPE 69), were subjected to a six-month field persistence trial. Every month after burial of the fungal isolates, inside net bags, in orchard soil, the number of colony forming units (CFUs) per gram of soil was measured and the viability of the conidia was assessed using bioassays. All isolates investigated were capable of persisting in the soil for the duration of the trial period and in addition, were capable of initiating infection in T. leucotreta late fifth instar larvae and subsequent pupae. However, with the exception of the commercial isolates which showed some correlation, no correlation was found between the number of CFUs recorded and percentage T. leucotreta mycosis. Persistence of entomopathogenic fungi in the field is affected by a series of factors, and although the effect of these factors was not measured, the data have provided preliminary evidence towards the persistence capability of these candidate biopesticides against T. leucotreta.
- Full Text:
- Date Issued: 2013
- Authors: Coombes, Candice A , Hill, Martin P , Moore, Sean D , Dames, Joanna F , Fullard, T
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416893 , vital:71394 , xlink:href="https://doi.org/10.1080/09583157.2013.819489"
- Description: Thaumatotibia leucotreta (Meyrick) (1912) (Lepidoptera: Tortricidae) is a key economic pest of citrus in South Africa. Although a variety of control options are available, none currently registered target the soil-dwelling life stages of the pest. Three fungal isolates, two Metarhizium anisopliae sensu lato Metschnikoff (Sorokin) isolates (G 11 3 L6 and FCM Ar 23 B3) and one Beauveria bassiana sensu lato Balsamo (Vuillemin) isolate (G Ar 17 B3) have been identified as showing the greatest potential against T. leucotreta soil-dwelling life stages. Since environmental persistence is an important factor in the success of entomopathogenic fungi against soil pests, the isolates, along with two commercial isolates (B. bassiana Eco-Bb® and M. anisopliae ICIPE 69), were subjected to a six-month field persistence trial. Every month after burial of the fungal isolates, inside net bags, in orchard soil, the number of colony forming units (CFUs) per gram of soil was measured and the viability of the conidia was assessed using bioassays. All isolates investigated were capable of persisting in the soil for the duration of the trial period and in addition, were capable of initiating infection in T. leucotreta late fifth instar larvae and subsequent pupae. However, with the exception of the commercial isolates which showed some correlation, no correlation was found between the number of CFUs recorded and percentage T. leucotreta mycosis. Persistence of entomopathogenic fungi in the field is affected by a series of factors, and although the effect of these factors was not measured, the data have provided preliminary evidence towards the persistence capability of these candidate biopesticides against T. leucotreta.
- Full Text:
- Date Issued: 2013
Photodegradation of Orange-G using zinc octacarboxyphthalocyanine supported on Fe3O4 nanoparticles
- Modisha, Phillimon, Nyokong, Tebello, Antunes, Edith M
- Authors: Modisha, Phillimon , Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241653 , vital:50958 , xlink:href="https://doi.org/10.1016/j.molcata.2013.09.030"
- Description: Zinc octacarboxy phthalocyanine (ZnOCPc) was covalently immobilized on the surface of magnetite nanoparticles (MNPs) for the photocatalytic degradation of Orange G (OG) under visible light irradiation. It is noteworthy that the catalyst can be easily recovered using an external magnet and that it is reusable. The ZnOCPc remained bound to the MNP surface even after 25 min of photolysis as confirmed by the FT-IR and X-ray diffraction spectra. Kinetic analysis shows that the photodegradation rates of OG can be approximated to be pseudo-first order, according to the Langmuir–Hinshelwood kinetics model.
- Full Text:
- Date Issued: 2013
- Authors: Modisha, Phillimon , Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241653 , vital:50958 , xlink:href="https://doi.org/10.1016/j.molcata.2013.09.030"
- Description: Zinc octacarboxy phthalocyanine (ZnOCPc) was covalently immobilized on the surface of magnetite nanoparticles (MNPs) for the photocatalytic degradation of Orange G (OG) under visible light irradiation. It is noteworthy that the catalyst can be easily recovered using an external magnet and that it is reusable. The ZnOCPc remained bound to the MNP surface even after 25 min of photolysis as confirmed by the FT-IR and X-ray diffraction spectra. Kinetic analysis shows that the photodegradation rates of OG can be approximated to be pseudo-first order, according to the Langmuir–Hinshelwood kinetics model.
- Full Text:
- Date Issued: 2013
Photophysical and photochemical properties of a novel thiol terminated low symmetry zinc phthalocyanine complex and its gold nanoparticles conjugate
- Mthethwa, Thandekile P, Durmus, Mahmut, Nyokong, Tebello
- Authors: Mthethwa, Thandekile P , Durmus, Mahmut , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231474 , vital:49891 , xlink:href="https://doi.org/10.1039/C3DT32698E"
- Description: A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed from the UV-Vis spectra. The conjugate showed a decrease in the fluorescence quantum yield and lifetime. An increase in the triplet quantum yield and lifetime was observed for ZnPcSH following conjugation to gold nanoparticles. Both ZnPcSH and its conjugate with gold nanoparticles showed high singlet oxygen quantum yields with the conjugate being higher than the Pc alone.
- Full Text:
- Date Issued: 2013
- Authors: Mthethwa, Thandekile P , Durmus, Mahmut , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231474 , vital:49891 , xlink:href="https://doi.org/10.1039/C3DT32698E"
- Description: A novel thiol functionalized zinc phthalocyanine complex (ZnPcSH) is reported in this work. This complex was conjugated to gold nanoparticles. The photophysical and photochemical properties of the complex and the conjugate were investigated. Upon conjugation a blue shift was observed from the UV-Vis spectra. The conjugate showed a decrease in the fluorescence quantum yield and lifetime. An increase in the triplet quantum yield and lifetime was observed for ZnPcSH following conjugation to gold nanoparticles. Both ZnPcSH and its conjugate with gold nanoparticles showed high singlet oxygen quantum yields with the conjugate being higher than the Pc alone.
- Full Text:
- Date Issued: 2013
Physicochemical properties of a zinc phthalocyanine–pyrene conjugate adsorbed onto single walled carbon nanotubes
- Ogbodu, Racheal O, Antunes, Edith M, Nyokong, Tebello
- Authors: Ogbodu, Racheal O , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242314 , vital:51029 , xlink:href="https://doi.org/10.1039/C3DT50335F"
- Description: A conjugate between zinc monoamino phthalocyanine (ZnMAPc) and pyrene (Py) represented as ZnMAPc–Py (complex 3) was synthesized and characterized by various spectroscopic techniques and by elemental analysis. This manuscript also reports on the photochemical and photophysical properties of 3. This new compound exhibited higher triplet, fluorescence and singlet oxygen quantum yields in comparison to the phthalocyanine alone, hence showing the advantages of attaching pyrene to the Pc without breaking the conjugation. We also observed a decrease in photophysical parameters upon adsorbing the ZnMAPc–Py complex onto single walled carbon nanotubes (SWCNT). However, ZnMAPc–Py still generated some singlet oxygen when adsorbed onto SWCNT.
- Full Text:
- Date Issued: 2013
- Authors: Ogbodu, Racheal O , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242314 , vital:51029 , xlink:href="https://doi.org/10.1039/C3DT50335F"
- Description: A conjugate between zinc monoamino phthalocyanine (ZnMAPc) and pyrene (Py) represented as ZnMAPc–Py (complex 3) was synthesized and characterized by various spectroscopic techniques and by elemental analysis. This manuscript also reports on the photochemical and photophysical properties of 3. This new compound exhibited higher triplet, fluorescence and singlet oxygen quantum yields in comparison to the phthalocyanine alone, hence showing the advantages of attaching pyrene to the Pc without breaking the conjugation. We also observed a decrease in photophysical parameters upon adsorbing the ZnMAPc–Py complex onto single walled carbon nanotubes (SWCNT). However, ZnMAPc–Py still generated some singlet oxygen when adsorbed onto SWCNT.
- Full Text:
- Date Issued: 2013
Physicochemical properties of zinc monoamino phthalocyanine conjugated to folic acid and single walled carbon nanotubes
- Ogbodu, Racheal O, Antunes, Edith M, Nyokong, Tebello
- Authors: Ogbodu, Racheal O , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241761 , vital:50967 , xlink:href="https://doi.org/10.1016/j.poly.2013.05.025"
- Description: This study reports on the photophysical and photochemical behavior of the conjugates formed by covalent and non-covalent bonding between zinc monoamino phthalocyanine (ZnMAPc) and either single walled carbon nanotubes (SWCNTs) or folic acid (FA). The conjugates were characterized using FTIR, X-ray powder diffractometry, thermogravimetric analyses, transmission electron microscopy and Raman spectroscopy. 1H NMR and mass spectroscopies were only employed for ZnMAPc–FA conjugate. There was a slight increase in the triplet and singlet oxygen quantum yields on conjugating ZnMAPc to SWCNTs (or FA), while a decrease in the photophysical and photochemical parameters were observed upon adsorption of the ZnMAPc–FA conjugate to SWCNTs.
- Full Text:
- Date Issued: 2013
- Authors: Ogbodu, Racheal O , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241761 , vital:50967 , xlink:href="https://doi.org/10.1016/j.poly.2013.05.025"
- Description: This study reports on the photophysical and photochemical behavior of the conjugates formed by covalent and non-covalent bonding between zinc monoamino phthalocyanine (ZnMAPc) and either single walled carbon nanotubes (SWCNTs) or folic acid (FA). The conjugates were characterized using FTIR, X-ray powder diffractometry, thermogravimetric analyses, transmission electron microscopy and Raman spectroscopy. 1H NMR and mass spectroscopies were only employed for ZnMAPc–FA conjugate. There was a slight increase in the triplet and singlet oxygen quantum yields on conjugating ZnMAPc to SWCNTs (or FA), while a decrease in the photophysical and photochemical parameters were observed upon adsorption of the ZnMAPc–FA conjugate to SWCNTs.
- Full Text:
- Date Issued: 2013
Playing with the forest: Invasive alien plants, policy and protected areas in India
- Kannan, Ramesh, Shackleton, Charlie M, Shaanker, Ramanan U
- Authors: Kannan, Ramesh , Shackleton, Charlie M , Shaanker, Ramanan U
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182334 , vital:43821 , xlink:href="https://www.jstor.org/stable/24092395"
- Description: Protected areas (PAs) are inviolate and invaluable landscapes that promote the in situ conservation of endangered, threatened and rare species. Accordingly, and in keeping with this definition, PA managers ensure that PAs are free from fire, poaching, grazing, non-timber forest products collection, mining, etc. In India, following the Indian Wildlife (Protection) Act (1972), there are today 102 and 515 National Parks and Wildlife Sanctuaries respectively. Many of these have in recent decades been heavily threatened by the spread of invasive alien plant species, notable among them being Lantana and Eupatorium. These species may have usurped as yet unestimated number of native plants and fauna, besides depressing the reproduction of native plant species. In fact, it is realized that the threat to biodiversity by invasive alien species (IAS) may only be second to that of fragmentation. Yet there seems to be no major attempts to eradicate, contain or manage IAS in PAs. Ironically, the justification for the lack of action lies in the definition of PAs - that they need to be kept inviolate and therefore above any active intervention. In this article we bring home this serious contradiction in the approach to management of PAs in India and discuss the philosophical origins of this practice. We argue that if we are to protect our PAs from the serious scourge of invasive species, we would have to relook at the policy governing PA management and revise it to be more inclusive than exclusive.
- Full Text:
- Date Issued: 2013
- Authors: Kannan, Ramesh , Shackleton, Charlie M , Shaanker, Ramanan U
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182334 , vital:43821 , xlink:href="https://www.jstor.org/stable/24092395"
- Description: Protected areas (PAs) are inviolate and invaluable landscapes that promote the in situ conservation of endangered, threatened and rare species. Accordingly, and in keeping with this definition, PA managers ensure that PAs are free from fire, poaching, grazing, non-timber forest products collection, mining, etc. In India, following the Indian Wildlife (Protection) Act (1972), there are today 102 and 515 National Parks and Wildlife Sanctuaries respectively. Many of these have in recent decades been heavily threatened by the spread of invasive alien plant species, notable among them being Lantana and Eupatorium. These species may have usurped as yet unestimated number of native plants and fauna, besides depressing the reproduction of native plant species. In fact, it is realized that the threat to biodiversity by invasive alien species (IAS) may only be second to that of fragmentation. Yet there seems to be no major attempts to eradicate, contain or manage IAS in PAs. Ironically, the justification for the lack of action lies in the definition of PAs - that they need to be kept inviolate and therefore above any active intervention. In this article we bring home this serious contradiction in the approach to management of PAs in India and discuss the philosophical origins of this practice. We argue that if we are to protect our PAs from the serious scourge of invasive species, we would have to relook at the policy governing PA management and revise it to be more inclusive than exclusive.
- Full Text:
- Date Issued: 2013
Politics of the strange: revisiting Pieter Hugo's Nollywood
- Authors: Makhubu, Nomusa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147582 , vital:38651 , https://doi.org/10.1162/AFAR_a_00044
- Description: In a photographic essay accomplished between 2008 and 2009, South African photographer Pieter Hugo depicts ambiguous images of “supernatural” characters in Nigeria’s Nollywood.1 The majority of these photographs were taken in Enugu. Hugo’s Nollywood (2008/2009) has been exhibited widely in South Africa and in European, Australian, and American cities such as Rome, London, Paris, Amsterdam, Terragona, New York, Los Angeles, Sydney, and Adelaide as well as Auckland, New Zealand. Each portrait illustrates the grotesque in Nollywood.
- Full Text:
- Date Issued: 2013
- Authors: Makhubu, Nomusa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147582 , vital:38651 , https://doi.org/10.1162/AFAR_a_00044
- Description: In a photographic essay accomplished between 2008 and 2009, South African photographer Pieter Hugo depicts ambiguous images of “supernatural” characters in Nigeria’s Nollywood.1 The majority of these photographs were taken in Enugu. Hugo’s Nollywood (2008/2009) has been exhibited widely in South Africa and in European, Australian, and American cities such as Rome, London, Paris, Amsterdam, Terragona, New York, Los Angeles, Sydney, and Adelaide as well as Auckland, New Zealand. Each portrait illustrates the grotesque in Nollywood.
- Full Text:
- Date Issued: 2013
Poly methyl methacrylate films containing metallophthalocyanines in the presence of CdTe quantum dots
- Britton, Jonathan, Durmus, Mahmut, Chauke, Vongani, Nyokong, Tebello
- Authors: Britton, Jonathan , Durmus, Mahmut , Chauke, Vongani , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241629 , vital:50956 , xlink:href="https://doi.org/10.1016/j.molstruc.2013.09.017"
- Description: Non-linear optical (NLO) parameters were determined for phthalocyanine complexes containing In, Ga and Zn as central metals when embedded in poly (methyl methacrylate) polymer in the absence and presence of quantum dots (QDs) in an effort to create the most optimal optical limiting material. The QDs employed were CdTe–TGA (TGA = thioglylcolic acid). Triplet lifetimes generally increased as the value of the ratio of absorption cross sections of the excited state to that of the ground state (k) decreased on addition of CdTe–TGA to the phthalocyanines. The saturation energy density (Fsat) values were generally smaller in the films when compared to the solutions. Fsat, Ilim, Im[χ(3)]/α and γ all gave values which were of optimal range (i.e. the Im[χ(3)]/α and γ values were high enough to ensure adequate optical limiting but not too high to make the compounds behave like optical filters. Also, the Fsat and Ilim values were small enough to mean that the optical limiting process started at an intensity which was not too high) for complex 10 containing Zn central metal and tetrasubstituted with amino groups.
- Full Text:
- Date Issued: 2013
- Authors: Britton, Jonathan , Durmus, Mahmut , Chauke, Vongani , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241629 , vital:50956 , xlink:href="https://doi.org/10.1016/j.molstruc.2013.09.017"
- Description: Non-linear optical (NLO) parameters were determined for phthalocyanine complexes containing In, Ga and Zn as central metals when embedded in poly (methyl methacrylate) polymer in the absence and presence of quantum dots (QDs) in an effort to create the most optimal optical limiting material. The QDs employed were CdTe–TGA (TGA = thioglylcolic acid). Triplet lifetimes generally increased as the value of the ratio of absorption cross sections of the excited state to that of the ground state (k) decreased on addition of CdTe–TGA to the phthalocyanines. The saturation energy density (Fsat) values were generally smaller in the films when compared to the solutions. Fsat, Ilim, Im[χ(3)]/α and γ all gave values which were of optimal range (i.e. the Im[χ(3)]/α and γ values were high enough to ensure adequate optical limiting but not too high to make the compounds behave like optical filters. Also, the Fsat and Ilim values were small enough to mean that the optical limiting process started at an intensity which was not too high) for complex 10 containing Zn central metal and tetrasubstituted with amino groups.
- Full Text:
- Date Issued: 2013
Predicted mbira found
- Authors: Tracey, Andrew
- Date: 2013
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59732 , vital:27643 , http://dx.doi.org/10.21504/amj.v9i3.1908
- Description: This article is written as a follow-up to my article “The original African mbira?” (1972). I can report that an instrument which I predicted to have existed in that article actually did/does exist! In the original article I compared the tuning layouts of two related present-day members of the mbira family, hera, also called matepe, (found in northern Zimbabwe and northeast Zimbabwe into Mozambique) and nyonganyonga (found in central Mozambique, from Mutare, Zimbabwe to Beira, Mozambique and also into southern Malawi).
- Full Text:
- Date Issued: 2013
- Authors: Tracey, Andrew
- Date: 2013
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59732 , vital:27643 , http://dx.doi.org/10.21504/amj.v9i3.1908
- Description: This article is written as a follow-up to my article “The original African mbira?” (1972). I can report that an instrument which I predicted to have existed in that article actually did/does exist! In the original article I compared the tuning layouts of two related present-day members of the mbira family, hera, also called matepe, (found in northern Zimbabwe and northeast Zimbabwe into Mozambique) and nyonganyonga (found in central Mozambique, from Mutare, Zimbabwe to Beira, Mozambique and also into southern Malawi).
- Full Text:
- Date Issued: 2013
Preliminary assessment of the gender aspects of disaster vulnerability and loss of human life in South Africa
- Tandlich, Roman, Chirenda, Tatenda G, Srinivas, Sunitha C
- Authors: Tandlich, Roman , Chirenda, Tatenda G , Srinivas, Sunitha C
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76183 , vital:30518 , https://doi.org/10.4102/jamba.v5i2.84
- Description: South Africa has reached a medium level of human development and has a heterogeneous situation with respect to disaster risk management. In this article, a preliminary assessment of the gender aspects of disaster vulnerability and fatalities is presented. The United Nations, the Health Systems Trust and Statistics South Africa were used as data sources for the following gender-segregated values: the life expectancy at birth, unemployment rates, the human development index values, the maternal mortality rates and the number of deaths from unnatural and non-natural causes. The relevant inequality indices were then calculated and used to draw conclusions regarding the gender aspects of disaster risk management in South Africa. Results of the calculations indicate that between 1980 and 2011 men were 10% more vulnerable with respect to their health status. However, the gender differences have been decreasing in recent years. Access of women to healthcare is decreasing with time, potentially decreasing the recovery potential of whole families. Women are more economically vulnerable than men in South Africa, as they are 16.3% – 33% more likely to be unemployed than men. Educational status of both genders in South Africa is comparable based on literacy and enrolment rates at primary and secondary level. On the other hand, men are five times more likely to suffer fatal injuries during disasters.
- Full Text:
- Date Issued: 2013
- Authors: Tandlich, Roman , Chirenda, Tatenda G , Srinivas, Sunitha C
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76183 , vital:30518 , https://doi.org/10.4102/jamba.v5i2.84
- Description: South Africa has reached a medium level of human development and has a heterogeneous situation with respect to disaster risk management. In this article, a preliminary assessment of the gender aspects of disaster vulnerability and fatalities is presented. The United Nations, the Health Systems Trust and Statistics South Africa were used as data sources for the following gender-segregated values: the life expectancy at birth, unemployment rates, the human development index values, the maternal mortality rates and the number of deaths from unnatural and non-natural causes. The relevant inequality indices were then calculated and used to draw conclusions regarding the gender aspects of disaster risk management in South Africa. Results of the calculations indicate that between 1980 and 2011 men were 10% more vulnerable with respect to their health status. However, the gender differences have been decreasing in recent years. Access of women to healthcare is decreasing with time, potentially decreasing the recovery potential of whole families. Women are more economically vulnerable than men in South Africa, as they are 16.3% – 33% more likely to be unemployed than men. Educational status of both genders in South Africa is comparable based on literacy and enrolment rates at primary and secondary level. On the other hand, men are five times more likely to suffer fatal injuries during disasters.
- Full Text:
- Date Issued: 2013
Prevalence of sustainability reporting practices of a sample of listed companies on established and emerging stock exchanges
- Turk, Brendan K, Shackleton, Charlie M, Whittington-Jones, Kevin J
- Authors: Turk, Brendan K , Shackleton, Charlie M , Whittington-Jones, Kevin J
- Date: 2013
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/60995 , vital:27908 , DOI: https://doi.org/10.4102/sajems.v16i1.234
- Description: The business sector has a substantial role in addressing current environmental issues and concerns. Consequently, there is a growing adoption of corporate sustainability principles and practices across all market sectors. This study examined four developed and four emerging stock markets and the sustainability reporting practices of the top 20 and bottom 20 companies in each. The results illustrate that the developed market sector was more advanced in its corporate sustainability reporting, both in the proportion of companies issuing a sustainability report (approximately 60 per cent) and the proportion of company webpages dedicated to sustainability reporting. This difference was largely due to the effect of the top 20 companies. There was little difference between developed and developing markets when only the bottom 20 companies were considered, of which less than one-third provided sustainability reports. These results show that sustainability reporting is prevalent in both developed and developing markets, especially among market leading companies, but that overall, most developing markets have some catching up to do.
- Full Text:
- Date Issued: 2013
- Authors: Turk, Brendan K , Shackleton, Charlie M , Whittington-Jones, Kevin J
- Date: 2013
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/60995 , vital:27908 , DOI: https://doi.org/10.4102/sajems.v16i1.234
- Description: The business sector has a substantial role in addressing current environmental issues and concerns. Consequently, there is a growing adoption of corporate sustainability principles and practices across all market sectors. This study examined four developed and four emerging stock markets and the sustainability reporting practices of the top 20 and bottom 20 companies in each. The results illustrate that the developed market sector was more advanced in its corporate sustainability reporting, both in the proportion of companies issuing a sustainability report (approximately 60 per cent) and the proportion of company webpages dedicated to sustainability reporting. This difference was largely due to the effect of the top 20 companies. There was little difference between developed and developing markets when only the bottom 20 companies were considered, of which less than one-third provided sustainability reports. These results show that sustainability reporting is prevalent in both developed and developing markets, especially among market leading companies, but that overall, most developing markets have some catching up to do.
- Full Text:
- Date Issued: 2013
Probing the sensitive and selective luminescent detection of peroxynitrite using thiol-capped CdTe and CdTe@ ZnS quantum dots
- Adegoke, Oluwasesan, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193757 , vital:45393 , xlink:href="https://doi.org/10.1016/j.jlumin.2012.08.002"
- Description: CdTe and CdTe@ZnS quantum dots (QDs) capped with 3-mercaptopropionic acid (MPA), thioglycolic acid (TGA), or glutathione (GSH) have been employed for the first time as luminescent probes for the sensitive and selective detection of peroxynitrite (ONOO−) in aqueous solution. The sensitivity of the proposed probe followed the order: MPA–TGA–CdTe@ZnS>GSH–TGA–CdTe@ZnS>MPA–CdTe QDs. The varying degree of quenching is elucidated based on the QD–thiolate bond of CdTe@ZnS being more sensitive to oxidation from ONOO− than CdTe. The selectivity of the probe in the presence of co-existing species followed the order: GSH–TGA–CdTe@ZnS>MPA–TGA–CdTe@ZnS>MPA–CdTe QDs. QDs capped with MPA showed less selectivity for ONOO− than GSH. The best limit of detection (LOD) of 12.6 nM was obtained for MPA–TGA–CdTe@ZnS QDs. Time-resolved fluorescence measurements indicated that the interaction between ONOO− and the QDs is static in nature.
- Full Text:
- Date Issued: 2013
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193757 , vital:45393 , xlink:href="https://doi.org/10.1016/j.jlumin.2012.08.002"
- Description: CdTe and CdTe@ZnS quantum dots (QDs) capped with 3-mercaptopropionic acid (MPA), thioglycolic acid (TGA), or glutathione (GSH) have been employed for the first time as luminescent probes for the sensitive and selective detection of peroxynitrite (ONOO−) in aqueous solution. The sensitivity of the proposed probe followed the order: MPA–TGA–CdTe@ZnS>GSH–TGA–CdTe@ZnS>MPA–CdTe QDs. The varying degree of quenching is elucidated based on the QD–thiolate bond of CdTe@ZnS being more sensitive to oxidation from ONOO− than CdTe. The selectivity of the probe in the presence of co-existing species followed the order: GSH–TGA–CdTe@ZnS>MPA–TGA–CdTe@ZnS>MPA–CdTe QDs. QDs capped with MPA showed less selectivity for ONOO− than GSH. The best limit of detection (LOD) of 12.6 nM was obtained for MPA–TGA–CdTe@ZnS QDs. Time-resolved fluorescence measurements indicated that the interaction between ONOO− and the QDs is static in nature.
- Full Text:
- Date Issued: 2013
Protection of development-induced internally displaced persons under the African Charter: the case of the Endorois community of Northern Kenya
- Authors: Juma, Laurence
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127100 , vital:35955 , https://heinonline.org./HOL/Page?handle=hein.journals/ciminsfri46amp;div=15amp;g_sent=1amp;casa_token=amp;collection=journals
- Description: The discourse on development-induced displacement has highlighted the enormity of problems faced by communities who are forcefully removed to create room for development projects, while at the same time, exposed the insularity of national and international legal frameworks for their protection. Using the case of Centre for Minority Rights Development (CEMIRIDE) on behalf of the Endorois Community v Kenya (No 276/200), decided by the African Commission on Human and People's Rights in November 2009, this article analyses the support that regional and continental rights enforcement mechanisms could provide to the protection of IDPs, particularly those displaced by development projects.
- Full Text:
- Date Issued: 2013
- Authors: Juma, Laurence
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127100 , vital:35955 , https://heinonline.org./HOL/Page?handle=hein.journals/ciminsfri46amp;div=15amp;g_sent=1amp;casa_token=amp;collection=journals
- Description: The discourse on development-induced displacement has highlighted the enormity of problems faced by communities who are forcefully removed to create room for development projects, while at the same time, exposed the insularity of national and international legal frameworks for their protection. Using the case of Centre for Minority Rights Development (CEMIRIDE) on behalf of the Endorois Community v Kenya (No 276/200), decided by the African Commission on Human and People's Rights in November 2009, this article analyses the support that regional and continental rights enforcement mechanisms could provide to the protection of IDPs, particularly those displaced by development projects.
- Full Text:
- Date Issued: 2013
Real-time distributed malicious traffic monitoring for honeypots and network telescopes
- Hunter, Samuel O, Irwin, Barry V W, Stalmans, Etienne
- Authors: Hunter, Samuel O , Irwin, Barry V W , Stalmans, Etienne
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429660 , vital:72630 , 10.1109/ISSA.2013.6641050
- Description: Network telescopes and honeypots have been used with great success to record malicious network traffic for analysis, however, this is often done off-line well after the traffic was observed. This has left us with only a cursory understanding of malicious hosts and no knowledge of the software they run, uptime or other malicious activity they may have participated in. This work covers a messaging framework (rDSN) that was developed to allow for the real-time analysis of malicious traffic. This data was captured from multiple, distributed honeypots and network telescopes. Data was collected over a period of two months from these data sensors. Using this data new techniques for malicious host analysis and re-identification in dynamic IP address space were explored. An Automated Reconnaissance (AR) Framework was developed to aid the process of data collection, this framework was responsible for gathering information from malicious hosts through both passive and active fingerprinting techniques. From the analysis of this data; correlations between malicious hosts were identified based on characteristics such as Operating System, targeted service, location and services running on the malicious hosts. An initial investigation in Latency Based Multilateration (LBM), a novel technique to assist in host re-identification was tested and proved successful as a supporting metric for host re-identification.
- Full Text:
- Date Issued: 2013
- Authors: Hunter, Samuel O , Irwin, Barry V W , Stalmans, Etienne
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429660 , vital:72630 , 10.1109/ISSA.2013.6641050
- Description: Network telescopes and honeypots have been used with great success to record malicious network traffic for analysis, however, this is often done off-line well after the traffic was observed. This has left us with only a cursory understanding of malicious hosts and no knowledge of the software they run, uptime or other malicious activity they may have participated in. This work covers a messaging framework (rDSN) that was developed to allow for the real-time analysis of malicious traffic. This data was captured from multiple, distributed honeypots and network telescopes. Data was collected over a period of two months from these data sensors. Using this data new techniques for malicious host analysis and re-identification in dynamic IP address space were explored. An Automated Reconnaissance (AR) Framework was developed to aid the process of data collection, this framework was responsible for gathering information from malicious hosts through both passive and active fingerprinting techniques. From the analysis of this data; correlations between malicious hosts were identified based on characteristics such as Operating System, targeted service, location and services running on the malicious hosts. An initial investigation in Latency Based Multilateration (LBM), a novel technique to assist in host re-identification was tested and proved successful as a supporting metric for host re-identification.
- Full Text:
- Date Issued: 2013
Reconstructing the history of introduction and spread of the invasive species, Lantana, at three spatial scales in India
- Kannan, Ramesh, Shackleton, Charlie M, Shaanker, Ramanan U
- Authors: Kannan, Ramesh , Shackleton, Charlie M , Shaanker, Ramanan U
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181015 , vital:43687 , xlink:href="https://doi.org/10.1007/s10530-012-0365-z"
- Description: This study sought to reconstruct the history of Lantana invasion and spread in India by considering two questions; (a) from where, by who, and when were Lantana species introduced into India? and (b) given its long history in the country, is it still spreading or more or less stable? We critically evaluated the archival and historical information on plant imports by the European powers into India during the period before and after British colonization. We then reconstructed the path of spread by analyzing the spatio-temporal patterns of occurrence and distribution of Lantana in India at both the national and local scale using a GIS platform. The spread of Lantana across the globe started as early as the 1690s. The European colonial powers moved the plants from Latin America to Europe and to their colonial countries in the early 1800s. Lantana species were introduced in India from 1807 onwards and thereafter the colonial powers moved this plant across the country. Following its introduction into India, the spread of Lantana across the country, either through subsequent multiple introductions from Europe to different British cantonments, or through moving the plants between cantonments within India, were reasonably rapid spanning only a few decades. In the absence of a rigorous control program, the spread of Lantana has gone on unabated and thereby impacting both wildlife and biodiversity.
- Full Text:
- Date Issued: 2013
- Authors: Kannan, Ramesh , Shackleton, Charlie M , Shaanker, Ramanan U
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181015 , vital:43687 , xlink:href="https://doi.org/10.1007/s10530-012-0365-z"
- Description: This study sought to reconstruct the history of Lantana invasion and spread in India by considering two questions; (a) from where, by who, and when were Lantana species introduced into India? and (b) given its long history in the country, is it still spreading or more or less stable? We critically evaluated the archival and historical information on plant imports by the European powers into India during the period before and after British colonization. We then reconstructed the path of spread by analyzing the spatio-temporal patterns of occurrence and distribution of Lantana in India at both the national and local scale using a GIS platform. The spread of Lantana across the globe started as early as the 1690s. The European colonial powers moved the plants from Latin America to Europe and to their colonial countries in the early 1800s. Lantana species were introduced in India from 1807 onwards and thereafter the colonial powers moved this plant across the country. Following its introduction into India, the spread of Lantana across the country, either through subsequent multiple introductions from Europe to different British cantonments, or through moving the plants between cantonments within India, were reasonably rapid spanning only a few decades. In the absence of a rigorous control program, the spread of Lantana has gone on unabated and thereby impacting both wildlife and biodiversity.
- Full Text:
- Date Issued: 2013