Exploring options in reforming South African land ownership: opportunities for sharing land, labour and expertise
- Dlamini, Thula S, Verschoor, Aart-Jan, Fraser, Gavin C G
- Authors: Dlamini, Thula S , Verschoor, Aart-Jan , Fraser, Gavin C G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69331 , vital:29500 , https://doi.org/10.1080/03031853.2013.770951
- Description: In many developing countries, land ownership remains a subject of contention. In South Africa, notwithstanding the strides that have been made to foster equitable land ownership, land reform policies have been unsuccessful in delivering land to the poor majority. Due to the nature of agriculture as a source of food production and national security, and the lack of farming skills and related competencies’ equilibrium, programmes intended to deliver land to black people have been inadequate in their reach. Whereas policy has emphasised the urgency of solving equity issues in land ownership, equally challenging has been finding the right set of programmes to achieve this without triggering a perennial land ownership squabble. After 18 years of democracy, a need remains to find a balance between continuity in food production and equitable redistribution of land in South African agriculture. In this paper, we argue that it is possible to achieve equitable and fair redistribution of land without inhibiting agricultural production, through land sharing. We show that sharing land could help fast-track the development of a farming skills and related competencies’ equilibrium between black and white farmers. The paper further demonstrates that the gains in land sharing far outweigh other programmes of land reform that have been used and suggested thus far.
- Full Text: false
- Date Issued: 2013
- Authors: Dlamini, Thula S , Verschoor, Aart-Jan , Fraser, Gavin C G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69331 , vital:29500 , https://doi.org/10.1080/03031853.2013.770951
- Description: In many developing countries, land ownership remains a subject of contention. In South Africa, notwithstanding the strides that have been made to foster equitable land ownership, land reform policies have been unsuccessful in delivering land to the poor majority. Due to the nature of agriculture as a source of food production and national security, and the lack of farming skills and related competencies’ equilibrium, programmes intended to deliver land to black people have been inadequate in their reach. Whereas policy has emphasised the urgency of solving equity issues in land ownership, equally challenging has been finding the right set of programmes to achieve this without triggering a perennial land ownership squabble. After 18 years of democracy, a need remains to find a balance between continuity in food production and equitable redistribution of land in South African agriculture. In this paper, we argue that it is possible to achieve equitable and fair redistribution of land without inhibiting agricultural production, through land sharing. We show that sharing land could help fast-track the development of a farming skills and related competencies’ equilibrium between black and white farmers. The paper further demonstrates that the gains in land sharing far outweigh other programmes of land reform that have been used and suggested thus far.
- Full Text: false
- Date Issued: 2013
Farewell to Lawrence Schlemmer: initiator of quality-of-life studies in South Africa
- Authors: Moller, Valerie
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67175 , vital:29055 , https://doi.org/10.1007/s11205-011-9965-8
- Description: publisher version , Professor Lawrence Schlemmer, affectionately known as Lawrie, was the father of South Africa’s quality-of-life studies and social indicators movement. He died on 26 October 2011 at the age of 75 after a short illness. In 1978, Lawrence marched into my office at the Centre for Applied Social Sciences, University of Natal, brandishing two books. We need to do some work on quality of life in South Africa, he announced, before handing me the volumes. At the time, South Africa’s leaders assumed that smiling black faces meant that South Africans were happy with their lot in life under apartheid. Our surveys were to prove otherwise. That weekend was spent reading cover to cover the classic works by Frank Andrews, Angus Campbell and their colleagues. The next week we pored over lists of concerns voiced by South Africans which we later put to test in the field. In 1982, we submitted our findings by ‘slug’ post to the editor of Social Indicators Research. We received a letter by return mail from Alex Michalos to say he would publish our paper and we should not be too disappointed with our regression results!
- Full Text: false
- Date Issued: 2013
- Authors: Moller, Valerie
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67175 , vital:29055 , https://doi.org/10.1007/s11205-011-9965-8
- Description: publisher version , Professor Lawrence Schlemmer, affectionately known as Lawrie, was the father of South Africa’s quality-of-life studies and social indicators movement. He died on 26 October 2011 at the age of 75 after a short illness. In 1978, Lawrence marched into my office at the Centre for Applied Social Sciences, University of Natal, brandishing two books. We need to do some work on quality of life in South Africa, he announced, before handing me the volumes. At the time, South Africa’s leaders assumed that smiling black faces meant that South Africans were happy with their lot in life under apartheid. Our surveys were to prove otherwise. That weekend was spent reading cover to cover the classic works by Frank Andrews, Angus Campbell and their colleagues. The next week we pored over lists of concerns voiced by South Africans which we later put to test in the field. In 1982, we submitted our findings by ‘slug’ post to the editor of Social Indicators Research. We received a letter by return mail from Alex Michalos to say he would publish our paper and we should not be too disappointed with our regression results!
- Full Text: false
- Date Issued: 2013
Farmers’ perceptions of the impact of legislation on farm workers’ wages and working conditions: an Eastern Cape case study
- Roberts, Tamaryn, Antrobus, Geoffrey G
- Authors: Roberts, Tamaryn , Antrobus, Geoffrey G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142911 , vital:38175 , DOI: 10.1080/03031853.2013.778464
- Description: The status of South African farm workers has changed significantly over the past five decades. Using data from three major surveys conducted between 1957 and 2008, an Eastern Cape district was used as a case study to assess farmers’ perceptions of the changes that had occurred, particularly as a result of legislation. Considering the changes, the impacts on the farm labour market and wage and non-wage working conditions are analysed. The legislation focused on includes the Extension of Security of Tenure Act 62 (ESTA) of 1997, the Basic Conditions of Employment Act 75 (BCEA) of 1997 and minimum wage legislation. Farmers believed legislation had both positive and negative effects, which were compounded by changes in the political and economic contexts. The case study reveals that government has a role in improving the status of farm labourers, with education and healthcare services requiring special attention. However, caution is needed to ensure that further reductions in farm employment are restricted.
- Full Text:
- Date Issued: 2013
- Authors: Roberts, Tamaryn , Antrobus, Geoffrey G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142911 , vital:38175 , DOI: 10.1080/03031853.2013.778464
- Description: The status of South African farm workers has changed significantly over the past five decades. Using data from three major surveys conducted between 1957 and 2008, an Eastern Cape district was used as a case study to assess farmers’ perceptions of the changes that had occurred, particularly as a result of legislation. Considering the changes, the impacts on the farm labour market and wage and non-wage working conditions are analysed. The legislation focused on includes the Extension of Security of Tenure Act 62 (ESTA) of 1997, the Basic Conditions of Employment Act 75 (BCEA) of 1997 and minimum wage legislation. Farmers believed legislation had both positive and negative effects, which were compounded by changes in the political and economic contexts. The case study reveals that government has a role in improving the status of farm labourers, with education and healthcare services requiring special attention. However, caution is needed to ensure that further reductions in farm employment are restricted.
- Full Text:
- Date Issued: 2013
Fluorescence behavior of glutathione capped CdTe@ ZnS quantum dots chemically coordinated to zinc octacarboxy phthalocyanines
- Sekhosana, Kutloano E, Antunes, Edith M, Khene, Samson M, D'Souza, Sarah, Nyokong, Tebello
- Authors: Sekhosana, Kutloano E , Antunes, Edith M , Khene, Samson M , D'Souza, Sarah , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242019 , vital:50993 , xlink:href="https://doi.org/10.1016/j.jlumin.2012.11.044"
- Description: Core–shell CdTe@ZnS quantum dots capped with glutathione (CdTe@ZnS–GSH) were covalently linked to zinc octacarboxy phthalocyanine (ZnPc(COOH)8). The conjugate was characterized by UV/Vis, infrared and X-Ray photoelectron spectroscopies as well as transmission electron and atomic force microscopies. The fluorescence quantum yields of the core CdTe capped with thioglycolic acid increased upon formation of the core-shell. Upon conjugation with ZnPc(COOH)8, the fluorescence quantum yield of CdTe@ZnS–GSH decreased due to energy transfer from the latter to the Pc. The average fluorescence lifetime of the CdTe@ZnS–GSH QD also decreased upon conjugation from 26.2 to 13.3 ns.
- Full Text:
- Date Issued: 2013
- Authors: Sekhosana, Kutloano E , Antunes, Edith M , Khene, Samson M , D'Souza, Sarah , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242019 , vital:50993 , xlink:href="https://doi.org/10.1016/j.jlumin.2012.11.044"
- Description: Core–shell CdTe@ZnS quantum dots capped with glutathione (CdTe@ZnS–GSH) were covalently linked to zinc octacarboxy phthalocyanine (ZnPc(COOH)8). The conjugate was characterized by UV/Vis, infrared and X-Ray photoelectron spectroscopies as well as transmission electron and atomic force microscopies. The fluorescence quantum yields of the core CdTe capped with thioglycolic acid increased upon formation of the core-shell. Upon conjugation with ZnPc(COOH)8, the fluorescence quantum yield of CdTe@ZnS–GSH decreased due to energy transfer from the latter to the Pc. The average fluorescence lifetime of the CdTe@ZnS–GSH QD also decreased upon conjugation from 26.2 to 13.3 ns.
- Full Text:
- Date Issued: 2013
Fluorescence “switch on” of conjugates of CdTe@ ZnS quantum dots with Al, Ni and Zn tetraamino-phthalocyanines by hydrogen peroxide
- Adegoke, Oluwasesan, Khene, Samson M, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Khene, Samson M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241750 , vital:50966 , xlink:href="https://doi.org/10.1007/s10895-013-1222-x"
- Description: In this study, we have developed a novel nanoprobe for H2O2 based on the conjugation of CdTe@ZnS quantum dots (QDs) to different metal tetraamino-phthalocyanine (MTAPc): (M = (OAc)Al, {OAc = acetate}, Ni and Zn). Chemical coordination of the QDs to the MTAPc resulted in the fluorescence “switch off” of the linked QDs which was associated with Förster resonance energy transfer (FRET). In the presence of varying concentration of H2O2, the fluorescence of the linked QDs was progressively “switched on” and the FRET mechanism between the QDs and the MTAPc was disrupted. The sensitivity/limit of detection of the nanoprobe followed the order: QDs-ZnTAPc (2.2 μM) > QDs-NiTAPc (4.4 μM) > QDs-AlTAPc (9.8 μM) while the selectivity followed the order: QDs-NiTAPc > QDs-AlTAPc > QDs-ZnTAPc. The varying degree of sensitivity/selectivity and mechanism of detection is discussed in detail.
- Full Text:
- Date Issued: 2013
- Authors: Adegoke, Oluwasesan , Khene, Samson M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241750 , vital:50966 , xlink:href="https://doi.org/10.1007/s10895-013-1222-x"
- Description: In this study, we have developed a novel nanoprobe for H2O2 based on the conjugation of CdTe@ZnS quantum dots (QDs) to different metal tetraamino-phthalocyanine (MTAPc): (M = (OAc)Al, {OAc = acetate}, Ni and Zn). Chemical coordination of the QDs to the MTAPc resulted in the fluorescence “switch off” of the linked QDs which was associated with Förster resonance energy transfer (FRET). In the presence of varying concentration of H2O2, the fluorescence of the linked QDs was progressively “switched on” and the FRET mechanism between the QDs and the MTAPc was disrupted. The sensitivity/limit of detection of the nanoprobe followed the order: QDs-ZnTAPc (2.2 μM) > QDs-NiTAPc (4.4 μM) > QDs-AlTAPc (9.8 μM) while the selectivity followed the order: QDs-NiTAPc > QDs-AlTAPc > QDs-ZnTAPc. The varying degree of sensitivity/selectivity and mechanism of detection is discussed in detail.
- Full Text:
- Date Issued: 2013
Fluorescence “turn on” probe for bromide ion using nanoconjugates of glutathione-capped CdTe@ ZnS quantum dots with nickel tetraamino-phthalocyanine
- Adegoke, Oluwasesan, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190479 , vital:44998 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.05.013"
- Description: In this paper, three differently sized glutathione (GSH)-capped CdTe@ZnS quantum dots (QDs) have been successfully conjugated to nickel tetraamino-phthalocyanine (NiTAPc) to form different QDs-NiTAPc nanocomplexes. Several techniques such as TEM, FT-IR, time-resolved fluorescence measurement and electronic spectroscopy were employed to characterize the nanocomplex. Bromide ion was chosen as a model anion to test the efficacy of the nanoprobe. The fluorescence of the nanoconjugate was “turned off” upon binding but was progressively “turned on” upon interaction with varying concentrations of bromide ion. Experimental results showed that the quantum size effect of nanocrystal QD determined the overall sensitivity and selectivity of the nanoprobe and followed the order QD563-NiTAPc > QD605-NiTAPc > QD621-NiTAPc. The mechanism of reaction is proposed.
- Full Text:
- Date Issued: 2013
- Authors: Adegoke, Oluwasesan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190479 , vital:44998 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.05.013"
- Description: In this paper, three differently sized glutathione (GSH)-capped CdTe@ZnS quantum dots (QDs) have been successfully conjugated to nickel tetraamino-phthalocyanine (NiTAPc) to form different QDs-NiTAPc nanocomplexes. Several techniques such as TEM, FT-IR, time-resolved fluorescence measurement and electronic spectroscopy were employed to characterize the nanocomplex. Bromide ion was chosen as a model anion to test the efficacy of the nanoprobe. The fluorescence of the nanoconjugate was “turned off” upon binding but was progressively “turned on” upon interaction with varying concentrations of bromide ion. Experimental results showed that the quantum size effect of nanocrystal QD determined the overall sensitivity and selectivity of the nanoprobe and followed the order QD563-NiTAPc > QD605-NiTAPc > QD621-NiTAPc. The mechanism of reaction is proposed.
- Full Text:
- Date Issued: 2013
Forced degradation studies of clobetasol 17‐propionate in methanol, propylene glycol, as bulk drug and cream formulations by RP‐HPLC
- Fauzee, Ayesha F, Walker, Roderick B
- Authors: Fauzee, Ayesha F , Walker, Roderick B
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184005 , vital:44154 , xlink:href="https://doi.org/10.1002/jssc.201200969"
- Description: A rapid, simple, stability-indicating forced degradation study of clobetasol 17-propionate was conducted using RP-HPLC. The method was used to analyze clobetasol 17-propionate in methanol, propylene glycol, and a cream formulation. Isocratic elution of clobetasol and its degradation products was achieved using a Nova-Pak® 4 μm C18 150 mm × 3.9 mm id cartridge column and a mobile phase of methanol: water (68:32 v/v) at a flow rate of 0.9 mL min−1. Quantitation was achieved with UV detection at 239 nm. Nondegraded clobetasol was eluted at a retention time of 6.0 min. Clobetasol 17-propionate was subjected to different stress conditions viz., acidic, basic, heat, oxidation, light, and neutral hydrolysis. The greatest degradation occurred under strong base and oxidative conditions. Strong base-degraded clobetasol produced additional peaks at retention times of 1.8, 4.0, 5.0, and 8.0 min and clobetasol oxidation degradation peaks eluted at 2.2 and 24 min. Complete validation was performed for linearity, accuracy, and precision over the concentration range 0.15–15 μg mL−1. All data were analyzed statistically and this RP-HPLC method proved to be accurate, precise, linear, and stability indicating for the quantitation of clobetasol 17-propionate in methanol, propylene glycol, and cream formulations.
- Full Text:
- Date Issued: 2013
- Authors: Fauzee, Ayesha F , Walker, Roderick B
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184005 , vital:44154 , xlink:href="https://doi.org/10.1002/jssc.201200969"
- Description: A rapid, simple, stability-indicating forced degradation study of clobetasol 17-propionate was conducted using RP-HPLC. The method was used to analyze clobetasol 17-propionate in methanol, propylene glycol, and a cream formulation. Isocratic elution of clobetasol and its degradation products was achieved using a Nova-Pak® 4 μm C18 150 mm × 3.9 mm id cartridge column and a mobile phase of methanol: water (68:32 v/v) at a flow rate of 0.9 mL min−1. Quantitation was achieved with UV detection at 239 nm. Nondegraded clobetasol was eluted at a retention time of 6.0 min. Clobetasol 17-propionate was subjected to different stress conditions viz., acidic, basic, heat, oxidation, light, and neutral hydrolysis. The greatest degradation occurred under strong base and oxidative conditions. Strong base-degraded clobetasol produced additional peaks at retention times of 1.8, 4.0, 5.0, and 8.0 min and clobetasol oxidation degradation peaks eluted at 2.2 and 24 min. Complete validation was performed for linearity, accuracy, and precision over the concentration range 0.15–15 μg mL−1. All data were analyzed statistically and this RP-HPLC method proved to be accurate, precise, linear, and stability indicating for the quantitation of clobetasol 17-propionate in methanol, propylene glycol, and cream formulations.
- Full Text:
- Date Issued: 2013
Gazing at Exhibit A
- Authors: Krueger, Anton
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229643 , vital:49696 , xlink:href="http://liminalities.net/9-1/exhibit.pdf"
- Description: Brett Bailey recently toured a new work in Europe and South Africa, called The Exhibit Series (2010-2013). In different countries the work has appeared under different titles—Exhibit A and Exhibit B, while Exhibit C will be produced in 2014. These productions replicate and parody ethnographic spectacles of the nineteenth century, interrogating European colonial atrocities in Africa, as well as contemporary xenophobia. They consist of a series of installations housed in individual rooms that audience members enter one by one. Inside these rooms one is confronted by beautifully arranged spectacles referencing historical atrocities committed in Namibia by German speaking peoples, as well as atrocities under the Belgian and French colonial regimes in the two Congos. The “exhibits” also include references to more recent incidents of European racism against migrants from Africa. The work has been both applauded and derided. In Berlin, for example, activists called it “a human zoo” and protested that this was “the wrong way to discuss a violent colonial history,”1 while others have called the work “haunting”, praising the production for its “dignity” and “beauty.”2
- Full Text:
- Date Issued: 2013
- Authors: Krueger, Anton
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229643 , vital:49696 , xlink:href="http://liminalities.net/9-1/exhibit.pdf"
- Description: Brett Bailey recently toured a new work in Europe and South Africa, called The Exhibit Series (2010-2013). In different countries the work has appeared under different titles—Exhibit A and Exhibit B, while Exhibit C will be produced in 2014. These productions replicate and parody ethnographic spectacles of the nineteenth century, interrogating European colonial atrocities in Africa, as well as contemporary xenophobia. They consist of a series of installations housed in individual rooms that audience members enter one by one. Inside these rooms one is confronted by beautifully arranged spectacles referencing historical atrocities committed in Namibia by German speaking peoples, as well as atrocities under the Belgian and French colonial regimes in the two Congos. The “exhibits” also include references to more recent incidents of European racism against migrants from Africa. The work has been both applauded and derided. In Berlin, for example, activists called it “a human zoo” and protested that this was “the wrong way to discuss a violent colonial history,”1 while others have called the work “haunting”, praising the production for its “dignity” and “beauty.”2
- Full Text:
- Date Issued: 2013
Glutathione capped CdTe@ ZnS quantum dots–zinc tetracarboxy phthalocyanine conjugates
- Sekhosana, Kutloana E, Antunes, Edith M, Nyokong, Tebello
- Authors: Sekhosana, Kutloana E , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193780 , vital:45395 , xlink:href="https://doi.org/10.1016/j.poly.2013.02.060"
- Description: Conjugates of zinc tetracarboxy phthalocyanine (ZnPc(COOH)4) with CdTe@ZnS–GSH quantum dots (QDs) were synthesized and characterized by several techniques including X-ray powder diffraction and infrared spectroscopy. There was an observed decrease in both the fluorescence quantum yields and lifetimes of the quantum dots when they were linked or mixed with ZnPc(COOH)4 due to Förster resonance energy transfer (FRET). The FRET behavior of CdTe@ZnS–GSH–ZnPc(COOH)4 conjugates was compared to that of CdTe@ZnS–GSH–ZnPc(COOH)8. Higher FRET efficiencies were observed for CdTe@ZnS–GSH–ZnPc(COOH)4-mixed or CdTe@ZnS–GSH–ZnPc(COOH)4-linked compared to the corresponding CdTe@ZnS–GSH–ZnPc(COOH)8-mixed or CdTe@ZnS–GSH–ZnPc(COOH)8-linked. Also CdTe@ZnS–GSH–ZnPc(COOH)4-mixed (containing coreshell QDs) showed higher FRET efficiency than CdTE–TGA–ZnPc(COOH)4-mixed containing core QDs. The FRET efficiencies were found to be 63% and 59% for the CdTe@ZnS–GSH–ZnPc(COOH)4-linked and CdTe@ZnS–GSH–ZnPc(COOH)4-mixed samples, respectively.
- Full Text:
- Date Issued: 2013
- Authors: Sekhosana, Kutloana E , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/193780 , vital:45395 , xlink:href="https://doi.org/10.1016/j.poly.2013.02.060"
- Description: Conjugates of zinc tetracarboxy phthalocyanine (ZnPc(COOH)4) with CdTe@ZnS–GSH quantum dots (QDs) were synthesized and characterized by several techniques including X-ray powder diffraction and infrared spectroscopy. There was an observed decrease in both the fluorescence quantum yields and lifetimes of the quantum dots when they were linked or mixed with ZnPc(COOH)4 due to Förster resonance energy transfer (FRET). The FRET behavior of CdTe@ZnS–GSH–ZnPc(COOH)4 conjugates was compared to that of CdTe@ZnS–GSH–ZnPc(COOH)8. Higher FRET efficiencies were observed for CdTe@ZnS–GSH–ZnPc(COOH)4-mixed or CdTe@ZnS–GSH–ZnPc(COOH)4-linked compared to the corresponding CdTe@ZnS–GSH–ZnPc(COOH)8-mixed or CdTe@ZnS–GSH–ZnPc(COOH)8-linked. Also CdTe@ZnS–GSH–ZnPc(COOH)4-mixed (containing coreshell QDs) showed higher FRET efficiency than CdTE–TGA–ZnPc(COOH)4-mixed containing core QDs. The FRET efficiencies were found to be 63% and 59% for the CdTe@ZnS–GSH–ZnPc(COOH)4-linked and CdTe@ZnS–GSH–ZnPc(COOH)4-mixed samples, respectively.
- Full Text:
- Date Issued: 2013
Halogenated oxindole and indoles from the South African marine ascidian Distaplia skoogi:
- Bromley, Candice L, Parker-Nance, Shirley, de la Mare, Jo-Anne, Edkins, Adrienne L, Beukes, Denzil R, Davies-Coleman, Michael T
- Authors: Bromley, Candice L , Parker-Nance, Shirley , de la Mare, Jo-Anne , Edkins, Adrienne L , Beukes, Denzil R , Davies-Coleman, Michael T
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164918 , vital:41184
- Description: The known 3,6-dibromoindole (1), 6-bromo-3-chloroindole (2) and 6-bromo-2-oxindole (3) were isolated from the marine ascidian (sea squirt) Distapia skoogi collected from Algoa Bay, South Africa. Standard spectroscopic techniques were used to elucidate the structures of 1-3. All three compounds were found to be moderately cytotoxic to metastatic MDA-MB-231 breast cancer cells.
- Full Text:
- Date Issued: 2013
- Authors: Bromley, Candice L , Parker-Nance, Shirley , de la Mare, Jo-Anne , Edkins, Adrienne L , Beukes, Denzil R , Davies-Coleman, Michael T
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164918 , vital:41184
- Description: The known 3,6-dibromoindole (1), 6-bromo-3-chloroindole (2) and 6-bromo-2-oxindole (3) were isolated from the marine ascidian (sea squirt) Distapia skoogi collected from Algoa Bay, South Africa. Standard spectroscopic techniques were used to elucidate the structures of 1-3. All three compounds were found to be moderately cytotoxic to metastatic MDA-MB-231 breast cancer cells.
- Full Text:
- Date Issued: 2013
How does subjective well-being evolve with age? A literature review
- López Ulloa, Beatriz Fabiola, Moller, Valerie, Sousa-Poza, Alfonso
- Authors: López Ulloa, Beatriz Fabiola , Moller, Valerie , Sousa-Poza, Alfonso
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67185 , vital:29056 , https://doi.org/10.1007/s12062-013-9085-0
- Description: publisher version , This literature review provides an overview of the theoretical and empirical research in several disciplines on the relation between ageing and subjective well-being, i.e., how subjective well-being evolves across the lifespan. Because of the different methodologies, data sets and samples used, comparison among disciplines and studies is difficult. However, extant studies do show either a U-shaped, inverted U-shaped or linear relation between ageing and subjective well-being.
- Full Text: false
- Date Issued: 2013
- Authors: López Ulloa, Beatriz Fabiola , Moller, Valerie , Sousa-Poza, Alfonso
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67185 , vital:29056 , https://doi.org/10.1007/s12062-013-9085-0
- Description: publisher version , This literature review provides an overview of the theoretical and empirical research in several disciplines on the relation between ageing and subjective well-being, i.e., how subjective well-being evolves across the lifespan. Because of the different methodologies, data sets and samples used, comparison among disciplines and studies is difficult. However, extant studies do show either a U-shaped, inverted U-shaped or linear relation between ageing and subjective well-being.
- Full Text: false
- Date Issued: 2013
Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), a potential biological control agent for the submerged aquatic weed, Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae)
- Martin, Grant D, Coetzee, Julie A, Baars, Jan-Robert
- Authors: Martin, Grant D , Coetzee, Julie A , Baars, Jan-Robert
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/103912 , vital:32322 , https://doi.org/10.4001/003.021.0118
- Description: The leaf-mining fly, Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), was investigated in its native range in South Africa, to determine its potential as a biological control agent for Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae), an invasive submerged macrophyte that is weedy in many parts of the world. The fly was found throughout the indigenous range of the plant in South Africa. High larval abundance was recorded at field sites with nearly all L. major shoots sampled ontaining larvae, with densities of up to 10 larvae per shoot. Adults laid batches of up to 15 eggs, usually on the abaxial sides of L. major leaves. The larvae mined internally, leaving the epidermal tissues of the upper and lower leaves intact. The larvae underwent three instars which took an average of 24 days and pupated within the leaf tissue, from which the adults emerged. Impact studies in the laboratory showed that H. lagarosiphon larval feeding significantly restricted the formation of L. major side branches. Based on its biology and damage caused to the plant, Hydrellia lagarosiphon could be considered as a useful biological control candidate for L. major in countries where the plant is invasive.
- Full Text:
- Date Issued: 2013
- Authors: Martin, Grant D , Coetzee, Julie A , Baars, Jan-Robert
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/103912 , vital:32322 , https://doi.org/10.4001/003.021.0118
- Description: The leaf-mining fly, Hydrellia lagarosiphon Deeming (Diptera: Ephydridae), was investigated in its native range in South Africa, to determine its potential as a biological control agent for Lagarosiphon major (Ridl.) Moss ex Wager (Hydrocharitaceae), an invasive submerged macrophyte that is weedy in many parts of the world. The fly was found throughout the indigenous range of the plant in South Africa. High larval abundance was recorded at field sites with nearly all L. major shoots sampled ontaining larvae, with densities of up to 10 larvae per shoot. Adults laid batches of up to 15 eggs, usually on the abaxial sides of L. major leaves. The larvae mined internally, leaving the epidermal tissues of the upper and lower leaves intact. The larvae underwent three instars which took an average of 24 days and pupated within the leaf tissue, from which the adults emerged. Impact studies in the laboratory showed that H. lagarosiphon larval feeding significantly restricted the formation of L. major side branches. Based on its biology and damage caused to the plant, Hydrellia lagarosiphon could be considered as a useful biological control candidate for L. major in countries where the plant is invasive.
- Full Text:
- Date Issued: 2013
Identity and origins of introduced and native Azolla species in Florida
- Madeira, Paul T, Center, Ted D, Coetzee, Julie A, Pemberton, Robert W, Purcell, Matthew F, Hill, Martin P
- Authors: Madeira, Paul T , Center, Ted D , Coetzee, Julie A , Pemberton, Robert W , Purcell, Matthew F , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419313 , vital:71634 , xlink:href="https://doi.org/10.1016/j.aquabot.2013.07.009"
- Description: Azolla pinnata, an introduced aquatic fern, is spreading rapidly causing concern that it may displace native Azolla. It is now present in the Arthur R. Marshall Loxahatchee National Wildlife Refuge, the northernmost portion of the Florida Everglades. Because A. pinnata subspecies are native to Africa, Southeast Asia, and Australia, determining the actual geographic origin of the Florida exotic is important to the discovery of efficacious biological control agents. Both the exotic and native Azollas were examined using morphological and molecular criteria. Both criteria distinguished three A. pinnata subspecies with the Florida exotic matching the Australian A. pinnata subsp. pinnata. Molecular divergence between the A. pinnata subspecies indicates the three types should be considered separate species. The Florida native was characterized by both molecular and morphological methods as Azolla caroliniana. The discovery of a previously uncharacterized Ecuadorian Azolla, which appears to be a paternal ancestor of A. caroliniana, indicates that A. caroliniana is a hybrid species.
- Full Text:
- Date Issued: 2013
- Authors: Madeira, Paul T , Center, Ted D , Coetzee, Julie A , Pemberton, Robert W , Purcell, Matthew F , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/419313 , vital:71634 , xlink:href="https://doi.org/10.1016/j.aquabot.2013.07.009"
- Description: Azolla pinnata, an introduced aquatic fern, is spreading rapidly causing concern that it may displace native Azolla. It is now present in the Arthur R. Marshall Loxahatchee National Wildlife Refuge, the northernmost portion of the Florida Everglades. Because A. pinnata subspecies are native to Africa, Southeast Asia, and Australia, determining the actual geographic origin of the Florida exotic is important to the discovery of efficacious biological control agents. Both the exotic and native Azollas were examined using morphological and molecular criteria. Both criteria distinguished three A. pinnata subspecies with the Florida exotic matching the Australian A. pinnata subsp. pinnata. Molecular divergence between the A. pinnata subspecies indicates the three types should be considered separate species. The Florida native was characterized by both molecular and morphological methods as Azolla caroliniana. The discovery of a previously uncharacterized Ecuadorian Azolla, which appears to be a paternal ancestor of A. caroliniana, indicates that A. caroliniana is a hybrid species.
- Full Text:
- Date Issued: 2013
Impact of insecticides on the reproductive potential of false codling moth, Thaumatotibia leucotreta (Meyrick, 1913)(Lepidoptera: Tortricidae)
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
- Date Issued: 2013
- Authors: Fullard, T , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406092 , vital:70238 , xlink:href="https://hdl.handle.net/10520/EJC141302"
- Description: False codling moth, Thaumatotibia leucotreta(Meyrick, 1913) (Lepidoptera: Tortricidae), is animportant pest on citrus in South Africa. Several new insecticides were screened for theirpotential negative impacts onT. leucotreta’s reproduction through topical insecticide applica-tions and detached fruit bioassays. Detached fruit bioassays showed that the registeredstandard concentration of Delegate®20 g/100 l and DPX-HGW86 35 ml/100 l caused femalesto oviposit significantly fewer eggs (P= 0.0016) than the controls. The same was found forthe registered concentration of Coragen® (P is less than 0.0001). Topical insecticide trials showed thatonly concentrations of Coragen®, at the registered field rate and above had an effect on themoths’ reproductive output (P is less than 0.0001). Alsystin®and Meothrin™, which were used asindustry standards, did not negatively affect the reproductive output of the moths duringtopical or detached fruit bioassay trials. This study helps to better understand the impor-tance of the application mode,i.e.directly on moths or fruit and implies secondary benefits tosome insecticide applications.
- Full Text:
- Date Issued: 2013
Impacts of a sub-lethal dose of glyphosate on water hyacinth nutrients and its indirect effects on Neochetina weevils
- Katembo, Naweji, Hill, Martin P, Byrne, Marcus J
- Authors: Katembo, Naweji , Hill, Martin P , Byrne, Marcus J
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417726 , vital:71481 , xlink:href="https://doi.org/10.1080/09583157.2013.839982"
- Description: A sub-lethal dose of a herbicide under field conditions was applied to determine if it stimulates an increase in water hyacinth nutrients, thereby increasing feeding intensity by Neochetina spp. weevils used as biocontrol agents of the weed. Nitrogen (N) and carbon (C) were measured and compared between sprayed plants and control plants. At one site (Delta Park), N levels were lower in the sprayed plants compared to the control plants both in the leaves and the crown. At the second site (Farm Dam), leaf N was also lower in the sprayed plants than in the control plants, while no difference was found in crown N. Mean number of feeding scars per cm2 at Delta Park was significantly higher on the sprayed plants compared to the control plants, while no significant difference was found at Farm Dam. At Delta Park, there was no correlation, however, between the number of weevil feeding scars and leaf N or C:N ratio in sprayed plants. In conclusion, the sub-lethal dose of glyphosate did not directly result in an increase in weevil feeding intensity but it can be recommended in an integrated control system to retard water hyacinth growth while conserving the weevil population.
- Full Text:
- Date Issued: 2013
- Authors: Katembo, Naweji , Hill, Martin P , Byrne, Marcus J
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417726 , vital:71481 , xlink:href="https://doi.org/10.1080/09583157.2013.839982"
- Description: A sub-lethal dose of a herbicide under field conditions was applied to determine if it stimulates an increase in water hyacinth nutrients, thereby increasing feeding intensity by Neochetina spp. weevils used as biocontrol agents of the weed. Nitrogen (N) and carbon (C) were measured and compared between sprayed plants and control plants. At one site (Delta Park), N levels were lower in the sprayed plants compared to the control plants both in the leaves and the crown. At the second site (Farm Dam), leaf N was also lower in the sprayed plants than in the control plants, while no difference was found in crown N. Mean number of feeding scars per cm2 at Delta Park was significantly higher on the sprayed plants compared to the control plants, while no significant difference was found at Farm Dam. At Delta Park, there was no correlation, however, between the number of weevil feeding scars and leaf N or C:N ratio in sprayed plants. In conclusion, the sub-lethal dose of glyphosate did not directly result in an increase in weevil feeding intensity but it can be recommended in an integrated control system to retard water hyacinth growth while conserving the weevil population.
- Full Text:
- Date Issued: 2013
Implementation of AES-64 connection management for Ethernet Audio/Video Bridging devices
- Dibley, James, Foss, Richard
- Authors: Dibley, James , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426875 , vital:72397 , https://www.aes.org/e-lib/online/browse.cfm?elib=17014
- Description: AES-64 is a standard for the discovery, enumeration, connection management, and control of multimedia network devices. This paper describes the implementation of an AES-64 protocol stack and control application on devices that support the IEEE Ethernet Audio/Video Bridging standards for streaming multimedia, enabling connection management of network audio streams.
- Full Text:
- Date Issued: 2013
- Authors: Dibley, James , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426875 , vital:72397 , https://www.aes.org/e-lib/online/browse.cfm?elib=17014
- Description: AES-64 is a standard for the discovery, enumeration, connection management, and control of multimedia network devices. This paper describes the implementation of an AES-64 protocol stack and control application on devices that support the IEEE Ethernet Audio/Video Bridging standards for streaming multimedia, enabling connection management of network audio streams.
- Full Text:
- Date Issued: 2013
In search of the Holy Grail: youth media consumption and the construction of citizenship
- Authors: Steenveld, Lynette N
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158597 , vital:40210 , https://hdl.handle.net/10520/EJC141601
- Description: Rather than support the democratic process, as in the ideal scheme of things it should be doing, journalism has become an alienating, cynicism-inducing, narcoticising force in our political culture, turning people off citizenship rather than equipping them to fulfil their democratic potential.
- Full Text:
- Date Issued: 2013
- Authors: Steenveld, Lynette N
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158597 , vital:40210 , https://hdl.handle.net/10520/EJC141601
- Description: Rather than support the democratic process, as in the ideal scheme of things it should be doing, journalism has become an alienating, cynicism-inducing, narcoticising force in our political culture, turning people off citizenship rather than equipping them to fulfil their democratic potential.
- Full Text:
- Date Issued: 2013
Influence of nanoparticle materials on the photophysical behavior of phthalocyanines
- Nyokong, Tebello, Antunes, Edith M
- Authors: Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190450 , vital:44995 , xlink:href="https://doi.org/10.1016/j.ccr.2013.03.016"
- Description: This review presents recent data on the photophysical behavior of phthalocyanines when conjugated to quantum dots, gold and magnetic nanoparticles. In some cases such conjugates offer the possibility of being used in “combination therapy”, where two or more substances may be used for treating one disease. The review focuses on the effect that the presence of nanoparticles has on the excited and triplet state parameters of the phthalocyanines. Five tables listing these parameters are presented.
- Full Text:
- Date Issued: 2013
- Authors: Nyokong, Tebello , Antunes, Edith M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190450 , vital:44995 , xlink:href="https://doi.org/10.1016/j.ccr.2013.03.016"
- Description: This review presents recent data on the photophysical behavior of phthalocyanines when conjugated to quantum dots, gold and magnetic nanoparticles. In some cases such conjugates offer the possibility of being used in “combination therapy”, where two or more substances may be used for treating one disease. The review focuses on the effect that the presence of nanoparticles has on the excited and triplet state parameters of the phthalocyanines. Five tables listing these parameters are presented.
- Full Text:
- Date Issued: 2013
Inkcubeko Nendalo: a bio-cultural diversity schools education project in South Africa and its implications for inclusive Indigenous Knowledge Systems (IKS) Sustainability.
- Cocks, Michelle L, Alexander, Jamie K, Dold, Anthony P
- Authors: Cocks, Michelle L , Alexander, Jamie K , Dold, Anthony P
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141187 , vital:37951 , DOI: 10.1177/0973408212475232
- Description: South Africa is currently the world’s third most biodiverse country, with one of the highest concentrations of threatened biodiversity in the world. Emerging research reveals the increasing pressure on this biodiversity with many wild resources continuing to be utilised for livelihood purposes even within urban environments. The Rio conventions, particularly the CBD, call for an integrated approach to conservation that incorporates local environmental knowledge and practices. In a bid to market itself as globally competitive, South Africa’s Curriculum 2005 (C 2005) is primarily focused on Western-based scientific knowledge, which sidelines the contribution of indigenous knowledge systems (IKS) and ignores the holistic nature of indigenous worldviews. The Inkcubeko Nendalo programme is designed to revitalise cultural identity, showing children the value of local indigenous knowledge and cultural environmental values.
- Full Text:
- Date Issued: 2013
- Authors: Cocks, Michelle L , Alexander, Jamie K , Dold, Anthony P
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141187 , vital:37951 , DOI: 10.1177/0973408212475232
- Description: South Africa is currently the world’s third most biodiverse country, with one of the highest concentrations of threatened biodiversity in the world. Emerging research reveals the increasing pressure on this biodiversity with many wild resources continuing to be utilised for livelihood purposes even within urban environments. The Rio conventions, particularly the CBD, call for an integrated approach to conservation that incorporates local environmental knowledge and practices. In a bid to market itself as globally competitive, South Africa’s Curriculum 2005 (C 2005) is primarily focused on Western-based scientific knowledge, which sidelines the contribution of indigenous knowledge systems (IKS) and ignores the holistic nature of indigenous worldviews. The Inkcubeko Nendalo programme is designed to revitalise cultural identity, showing children the value of local indigenous knowledge and cultural environmental values.
- Full Text:
- Date Issued: 2013
Insights from experimental economics on local cooperation in a small-scale fishery management system:
- Aswani, Shankar, Gurney, Georgina G, Mulville, Sara, Matera, Jaime, Gurven, Michael
- Authors: Aswani, Shankar , Gurney, Georgina G , Mulville, Sara , Matera, Jaime , Gurven, Michael
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145437 , vital:38438 , DOI: 10.1016/j.gloenvcha.2013.08.003
- Description: Cooperation is central to collective management of small-scale fisheries management, including marine protected areas. Thus an understanding of the factors influencing stakeholders’ propensity to cooperate to achieve shared benefits is essential to accomplishing successful collective fisheries management. In this paper we study stakeholders’ cooperative behavioral disposition and elucidate the role of various socio-economic factors in influencing it in the Roviana Lagoon, Western Solomon Islands. We employed a Public Goods Game from experimental economics tailored to mimic the problem of common pool fisheries management to elucidate peoples’ cooperative behavior. Using Ostrom's framework for analyzing social-ecological systems to guide our analysis, we examined how individual-scale variables (e.g., age, education, family size, ethnicity, occupational status, personal norms), in the context of village-scale variables (e.g., village, governance institutions, group coercive action), influence cooperative behavior, as indexed by game contribution. Ostrom's framework provides an effective window for conceptually peeling back the various socio-economic and governance layers which influence cooperation within these communities.
- Full Text:
- Date Issued: 2013
- Authors: Aswani, Shankar , Gurney, Georgina G , Mulville, Sara , Matera, Jaime , Gurven, Michael
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145437 , vital:38438 , DOI: 10.1016/j.gloenvcha.2013.08.003
- Description: Cooperation is central to collective management of small-scale fisheries management, including marine protected areas. Thus an understanding of the factors influencing stakeholders’ propensity to cooperate to achieve shared benefits is essential to accomplishing successful collective fisheries management. In this paper we study stakeholders’ cooperative behavioral disposition and elucidate the role of various socio-economic factors in influencing it in the Roviana Lagoon, Western Solomon Islands. We employed a Public Goods Game from experimental economics tailored to mimic the problem of common pool fisheries management to elucidate peoples’ cooperative behavior. Using Ostrom's framework for analyzing social-ecological systems to guide our analysis, we examined how individual-scale variables (e.g., age, education, family size, ethnicity, occupational status, personal norms), in the context of village-scale variables (e.g., village, governance institutions, group coercive action), influence cooperative behavior, as indexed by game contribution. Ostrom's framework provides an effective window for conceptually peeling back the various socio-economic and governance layers which influence cooperation within these communities.
- Full Text:
- Date Issued: 2013