Graphicacy as a form of communication in the primary school
- Authors: Wilmot, Pamela Dianne
- Date: 1998
- Subjects: School children -- South Africa Visual communication Perception in children Visual literacy Pictures
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1551 , http://hdl.handle.net/10962/d1003433
- Description: Children of today inhabit a multi-dimensional world, and in order to communicate effectively in it, they need the ability to utilise four forms of communication namely, oracy, literacy, numeracy and graphicacy. Communicating in graphic form requires an ability to both encode and decode spatial information using symbols, which requires the utilisation and application of spatial perceptual skills and concepts. The acquisition of graphic skills has been influenced by traditional developmental perspectives; increasingly the assumptions underpinning these have been challenged by more recent international research findings. The draft Curriculum Framework for General and Further Education and Training (1996: 18) identifies graphic literacy as one of the critical outcomes of the new South African curriculum. For graphic literacy to be an achievable outcome of the new curriculum, we need to investigate the skills and concepts underpinning this form of communication. The goal of this research is to investigate graphicacy as a form of communication in South African primary schools. However, given the scope of a research project of this nature, it was decided that rather than dealing with graphicacy per se, pictures as the most frequent and concrete type of graphic communication encountered by young learners would be focused on. In seeking to investigate pictures, the first stage of the study is concerned with diagnosing and illuminating children's graphic skill development through identifying: what skills they use; how they use and apply these when communicating through and interpreting symbols; and the difficulties they experience when, firstly, encoding spatial information through a series of practical and drawing tasks; and secondly, when reading and interpreting pictures. The second stage of the study investigates the extent to which children's early childhood experiences may or may not have impeded or enhanced the acquisition of skills necessary for understanding and communicating about space. The research findings, evaluated according to existing and emerging theoretical perspectives on graphicacy, will help to illuminate the current situation regarding the graphic literacy of South African primary school children. The study may contribute to wider international debates about graphicacy as a form of communication and the development of graphic literacy, from a South African perspective.
- Full Text:
- Date Issued: 1998
- Authors: Wilmot, Pamela Dianne
- Date: 1998
- Subjects: School children -- South Africa Visual communication Perception in children Visual literacy Pictures
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1551 , http://hdl.handle.net/10962/d1003433
- Description: Children of today inhabit a multi-dimensional world, and in order to communicate effectively in it, they need the ability to utilise four forms of communication namely, oracy, literacy, numeracy and graphicacy. Communicating in graphic form requires an ability to both encode and decode spatial information using symbols, which requires the utilisation and application of spatial perceptual skills and concepts. The acquisition of graphic skills has been influenced by traditional developmental perspectives; increasingly the assumptions underpinning these have been challenged by more recent international research findings. The draft Curriculum Framework for General and Further Education and Training (1996: 18) identifies graphic literacy as one of the critical outcomes of the new South African curriculum. For graphic literacy to be an achievable outcome of the new curriculum, we need to investigate the skills and concepts underpinning this form of communication. The goal of this research is to investigate graphicacy as a form of communication in South African primary schools. However, given the scope of a research project of this nature, it was decided that rather than dealing with graphicacy per se, pictures as the most frequent and concrete type of graphic communication encountered by young learners would be focused on. In seeking to investigate pictures, the first stage of the study is concerned with diagnosing and illuminating children's graphic skill development through identifying: what skills they use; how they use and apply these when communicating through and interpreting symbols; and the difficulties they experience when, firstly, encoding spatial information through a series of practical and drawing tasks; and secondly, when reading and interpreting pictures. The second stage of the study investigates the extent to which children's early childhood experiences may or may not have impeded or enhanced the acquisition of skills necessary for understanding and communicating about space. The research findings, evaluated according to existing and emerging theoretical perspectives on graphicacy, will help to illuminate the current situation regarding the graphic literacy of South African primary school children. The study may contribute to wider international debates about graphicacy as a form of communication and the development of graphic literacy, from a South African perspective.
- Full Text:
- Date Issued: 1998
Group problem solving among community activists in a South African setting: an everyday cognition approach
- Authors: Van Vlaenderen, Hilde
- Date: 1998
- Subjects: Group problem solving Group problem solving -- South Africa Cross-cultural studies -- Methodology Cognition Cross-cultural studies Cognition -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3080 , http://hdl.handle.net/10962/d1002589
- Description: The study focuses on the everyday problem solving processes of a group of community activists in a rural setting in the Eastern Cape Province of South Africa. It aims to uncover: first, the local knowledge of the participants of the study with reference to the concepts problem and problem solving; second, the participants' group problem solving procedure; and third, the dialectical interrelation between the participants' knowledge and practice with reference to everyday group problem solving. It is contended that the mainstream cognitive approach and the cross-cultural tradition are inappropriate for the study of everyday cognitive processes. A ‘situated cognition’ approach, based on the notions of activity and cultural mediation, is proposed as a theoretical framework for the study. The ontological and epistemological assumptions underpinning the empirical study were derived from a scientific realist and a hermeneutical paradigm. Data for the inquiry into the local knowledge of the participants was collected through individual interviews. The data was interpreted, using the grounded theory techniques of constant comparison, coding and compiling theoretical diagrams. Data for the inquiry into the participants' group problem solving practice consisted of video-taped group problem solving processes. This data was analysed, using a multi layered process of progressively deeper interpretation, employing a reading guide technique. Analysis of the research data revealed that the participants perceived a problem as an impediment to satisfactory participation in society. Problem solving was considered as an emotive, cognitive and inter-active process, involving particular role players. This process had a certain structure, involved attitudes and actions and relied on particular resources. Successful problem solving was perceived to result in restoration of social equilibrium. The group problem solving procedure used by the participants consisted of a process of developing a common understanding and group consensus. The strategies employed in the process, the roles played by the participants, the rules adhered to by the participants and the structure underlying the process were all congruent with these aims. There was a mutually reinforcing interrelation between knowledge and practice with reference to the participants’ problem solving.
- Full Text:
- Date Issued: 1998
- Authors: Van Vlaenderen, Hilde
- Date: 1998
- Subjects: Group problem solving Group problem solving -- South Africa Cross-cultural studies -- Methodology Cognition Cross-cultural studies Cognition -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3080 , http://hdl.handle.net/10962/d1002589
- Description: The study focuses on the everyday problem solving processes of a group of community activists in a rural setting in the Eastern Cape Province of South Africa. It aims to uncover: first, the local knowledge of the participants of the study with reference to the concepts problem and problem solving; second, the participants' group problem solving procedure; and third, the dialectical interrelation between the participants' knowledge and practice with reference to everyday group problem solving. It is contended that the mainstream cognitive approach and the cross-cultural tradition are inappropriate for the study of everyday cognitive processes. A ‘situated cognition’ approach, based on the notions of activity and cultural mediation, is proposed as a theoretical framework for the study. The ontological and epistemological assumptions underpinning the empirical study were derived from a scientific realist and a hermeneutical paradigm. Data for the inquiry into the local knowledge of the participants was collected through individual interviews. The data was interpreted, using the grounded theory techniques of constant comparison, coding and compiling theoretical diagrams. Data for the inquiry into the participants' group problem solving practice consisted of video-taped group problem solving processes. This data was analysed, using a multi layered process of progressively deeper interpretation, employing a reading guide technique. Analysis of the research data revealed that the participants perceived a problem as an impediment to satisfactory participation in society. Problem solving was considered as an emotive, cognitive and inter-active process, involving particular role players. This process had a certain structure, involved attitudes and actions and relied on particular resources. Successful problem solving was perceived to result in restoration of social equilibrium. The group problem solving procedure used by the participants consisted of a process of developing a common understanding and group consensus. The strategies employed in the process, the roles played by the participants, the rules adhered to by the participants and the structure underlying the process were all congruent with these aims. There was a mutually reinforcing interrelation between knowledge and practice with reference to the participants’ problem solving.
- Full Text:
- Date Issued: 1998
Growth, reproduction and feeding biology of Turbo sarmaticus (Mollusca : Vetigastropoda) along the coast of the Eastern Cape Province of South Africa
- Authors: Foster, Gregory George
- Date: 1998
- Subjects: Turbinidae -- Ecology -- Research -- South Africa Turbinidae -- Research -- South Africa Mollusks -- Research -- South Africa Abalones -- Ecology -- South Africa -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5705 , http://hdl.handle.net/10962/d1005391
- Description: Investigations were carried out on aspects of the biology of the vetigastropod Turbo sarmaticus. Studies included: 1) the distribution and standing stock of this animal at four sites along the coast of the Eastern Cape Province of South Africa; 2) the growth rate of animals on a wave-cut platform; 3) the reproductive cycle of an intertidal population; and 4) aspects of the feeding biology examining the ability of this mollusc to consume and digest six macroalgae, the influence of algal diet on growth rate and reproductive fitness and the polysaccharolytic activity of the digestive enzymes. On eastern Cape shores, T. sarmaticus had a size related distribution, with smaller animals being found towards the upper mid-shore and larger animals being found in a downshore direction. The mean shore densities of T. sarmaticus at three sites where exploitation of animals was minimal, were very similar (1.2 - 1.7 individuals/m²). The largest animals (up to 110 mm shell length) were found on an offshore island. This may have been a result of animals not being exploited, as well as a possible increase in primary productivity and food availability. The lowest density (0.2 individuals/m²) and animal size (<70 mm shell length) was recorded at a site (Kelly's beach - Port Alfred) where exploitation was more intense. It is probable that intense overexploitation was threatening the populations at this site. The growth rate of T. sarmaticus was determined by means of the von Bertalanffy growth model and expressed by the equation L[subscript]t = 81.07(l-e⁻°·⁵⁴⁴[superscript](t)). The initial growth rate of T. sarmaticus (up to ≈ 80 mm shell length) was similar on shores with different geomorphologies (i.e. boulder shores and wave-cut platforms). Growth rates of individuals were variable, which means that individuals within a population reached exploitable size (3 - 6 years old) and sexual maturity (1.5 - 2 years old) at different ages. Seasonality of reproduction of T. sarmaticus was determined using gonad index, egg diameters and spermatozoa content within the gonad. Turbo sarmaticus was dioecious and had a sex ratio in favour of males (1.2: 1). Animals attained sexual maturity at a size of about 52.5 mm shell length. There was little variation in the reproductive cycle over time with gametogenesis occurring from March/April until August/September, whilst maturity (Gonad Index = 15%) was maintained until the spawning event from December to March. After spawning the gonad regressed. Field and laboratory observations of the feeding biology of T. sarmaticus confirmed that this mollusc was a generalist grazer capable of consuming and digesting algae from the Rhodophyta, Chlorophyta and Phaeophyta. The consumption rates (juveniles: 1.45 - 9.50% body weight/day, adults: 1.06 - 6.08%) and digestibility (9 - 75% apparent dry matter) of six macroalgae was found to vary. For most algae, juvenile T. sarmaticus had higher consumption rates (1.6 - 2.8 times higher) and digestibility values (12 - 24% higher) than adults. It is suggested that consumption rates were dependent on the digestibility of the algae. In addition, it is suggested that the consumption rates of the different algae were not related to the nutritional content, but rather the energetic content of the algae. In both juvenile and adult animals, temperature had a positive influence on consumption rates, resulting in an increase at higher temperatures. However, in both juvenile and adult T. sarmaticus, algal digestibility was not affected by temperature. Finally, it was proposed that Viva rigida, Codium extricatum, Ecklonia radiata and Gelidium pristoides would provide the best nutritional value for growth and reproductive fitness in T. sarmaticus, whilst Jyengaria stellata and Corallina spp. would provide the poorest. Experiments on the effects of four algal diets on the biology of T. sarmaticus showed that the best growth rate (up to 13.8 mm shell length increase per annum), reproductive fitness (Gonad Index up to 33%) and energy levels (up to 4.76% glycogen in the foot) were achieved when T. sarmaticus was fed G. pristoides, U. rigid a or a mixed diet. Turbo sarmaticus fed Corallina spp. showed reduced growth (2.4 mm shell length increase), reproductive fitness (Gonad Index up to 4.4%) and energy levels (up to 3.42% glycogen in the foot). A study of the polysaccharolytic enzyme activity of T. sarmaticus indicated that this mollusc possesses enzymes that can, at least partially, digest most of the storage and structural polysaccharides found in the Chlorophyta, Rhodophyta and Phaeophyta. This further supported the findings that T. sarmaticus was a generalist grazer. Two levels of activity were detected: 1) high levels of enzyme activity (up to 328.2 Ilglmglmllhr)occurred on the storage polysaccharides that occur in the Rhodophyta and Chlorophyta, and 2) lower levels of activity were detected on the storage polysaccharides (up to 44.8 μg/mg/ml/hr) of the Phaeophyta and on all the structural polysaccharides tested (<45.5 μg/mg/ml/hr). It was suggested that T. sarmaticus did not rely heavily on structural carbohydrates as a source of carbon. Finally, the results of this study were discussed in relation to the future management of T. sarmaticus stocks, the possible role of this macro algal grazer in the intertidal zone and the effects of over-exploitation of this animal. The potential aquaculture of this mollusc was also addressed briefly.
- Full Text:
- Date Issued: 1998
- Authors: Foster, Gregory George
- Date: 1998
- Subjects: Turbinidae -- Ecology -- Research -- South Africa Turbinidae -- Research -- South Africa Mollusks -- Research -- South Africa Abalones -- Ecology -- South Africa -- Research
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5705 , http://hdl.handle.net/10962/d1005391
- Description: Investigations were carried out on aspects of the biology of the vetigastropod Turbo sarmaticus. Studies included: 1) the distribution and standing stock of this animal at four sites along the coast of the Eastern Cape Province of South Africa; 2) the growth rate of animals on a wave-cut platform; 3) the reproductive cycle of an intertidal population; and 4) aspects of the feeding biology examining the ability of this mollusc to consume and digest six macroalgae, the influence of algal diet on growth rate and reproductive fitness and the polysaccharolytic activity of the digestive enzymes. On eastern Cape shores, T. sarmaticus had a size related distribution, with smaller animals being found towards the upper mid-shore and larger animals being found in a downshore direction. The mean shore densities of T. sarmaticus at three sites where exploitation of animals was minimal, were very similar (1.2 - 1.7 individuals/m²). The largest animals (up to 110 mm shell length) were found on an offshore island. This may have been a result of animals not being exploited, as well as a possible increase in primary productivity and food availability. The lowest density (0.2 individuals/m²) and animal size (<70 mm shell length) was recorded at a site (Kelly's beach - Port Alfred) where exploitation was more intense. It is probable that intense overexploitation was threatening the populations at this site. The growth rate of T. sarmaticus was determined by means of the von Bertalanffy growth model and expressed by the equation L[subscript]t = 81.07(l-e⁻°·⁵⁴⁴[superscript](t)). The initial growth rate of T. sarmaticus (up to ≈ 80 mm shell length) was similar on shores with different geomorphologies (i.e. boulder shores and wave-cut platforms). Growth rates of individuals were variable, which means that individuals within a population reached exploitable size (3 - 6 years old) and sexual maturity (1.5 - 2 years old) at different ages. Seasonality of reproduction of T. sarmaticus was determined using gonad index, egg diameters and spermatozoa content within the gonad. Turbo sarmaticus was dioecious and had a sex ratio in favour of males (1.2: 1). Animals attained sexual maturity at a size of about 52.5 mm shell length. There was little variation in the reproductive cycle over time with gametogenesis occurring from March/April until August/September, whilst maturity (Gonad Index = 15%) was maintained until the spawning event from December to March. After spawning the gonad regressed. Field and laboratory observations of the feeding biology of T. sarmaticus confirmed that this mollusc was a generalist grazer capable of consuming and digesting algae from the Rhodophyta, Chlorophyta and Phaeophyta. The consumption rates (juveniles: 1.45 - 9.50% body weight/day, adults: 1.06 - 6.08%) and digestibility (9 - 75% apparent dry matter) of six macroalgae was found to vary. For most algae, juvenile T. sarmaticus had higher consumption rates (1.6 - 2.8 times higher) and digestibility values (12 - 24% higher) than adults. It is suggested that consumption rates were dependent on the digestibility of the algae. In addition, it is suggested that the consumption rates of the different algae were not related to the nutritional content, but rather the energetic content of the algae. In both juvenile and adult animals, temperature had a positive influence on consumption rates, resulting in an increase at higher temperatures. However, in both juvenile and adult T. sarmaticus, algal digestibility was not affected by temperature. Finally, it was proposed that Viva rigida, Codium extricatum, Ecklonia radiata and Gelidium pristoides would provide the best nutritional value for growth and reproductive fitness in T. sarmaticus, whilst Jyengaria stellata and Corallina spp. would provide the poorest. Experiments on the effects of four algal diets on the biology of T. sarmaticus showed that the best growth rate (up to 13.8 mm shell length increase per annum), reproductive fitness (Gonad Index up to 33%) and energy levels (up to 4.76% glycogen in the foot) were achieved when T. sarmaticus was fed G. pristoides, U. rigid a or a mixed diet. Turbo sarmaticus fed Corallina spp. showed reduced growth (2.4 mm shell length increase), reproductive fitness (Gonad Index up to 4.4%) and energy levels (up to 3.42% glycogen in the foot). A study of the polysaccharolytic enzyme activity of T. sarmaticus indicated that this mollusc possesses enzymes that can, at least partially, digest most of the storage and structural polysaccharides found in the Chlorophyta, Rhodophyta and Phaeophyta. This further supported the findings that T. sarmaticus was a generalist grazer. Two levels of activity were detected: 1) high levels of enzyme activity (up to 328.2 Ilglmglmllhr)occurred on the storage polysaccharides that occur in the Rhodophyta and Chlorophyta, and 2) lower levels of activity were detected on the storage polysaccharides (up to 44.8 μg/mg/ml/hr) of the Phaeophyta and on all the structural polysaccharides tested (<45.5 μg/mg/ml/hr). It was suggested that T. sarmaticus did not rely heavily on structural carbohydrates as a source of carbon. Finally, the results of this study were discussed in relation to the future management of T. sarmaticus stocks, the possible role of this macro algal grazer in the intertidal zone and the effects of over-exploitation of this animal. The potential aquaculture of this mollusc was also addressed briefly.
- Full Text:
- Date Issued: 1998
HIV and metaphor: an imaginative response to illness
- Authors: Cardo, Julia Claire
- Date: 1998
- Subjects: HIV infections , Metaphor -- Psychological aspects , Imagery (Psychology) -- Therapeutic use
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2945 , http://hdl.handle.net/10962/d1002454 , HIV infections , Metaphor -- Psychological aspects , Imagery (Psychology) -- Therapeutic use
- Description: The medical model has been criticised for its failure to attend to individuals' experience of illness and the meaning they attribute to illness. HIV / AIDS has challenged its adequacy and brought the question of meaning in illness into sharp focus. This study aimed to understand what it means to live with HIV by exploring the fantasies, images and metaphors that make up the depth of such an experience. Phenomenology was deemed the appropriate approach, as it assigns epistemological significance to metaphor and ontological primacy to the lifeworld. An interview guide was fashioned from existing phenomenological literature and in-depth interviews were conducted with eight HIV -infected individuals. Five protocols were selected to constitute the study. In addition, an audio tape recording of one individual's metaphorical dialogue with HIV was obtained and transcribed. The three protocols with the richest content of imagery and metaphor were subjected to phenomenological explication. The remaining two protocols were used to support and clarify emergent meaning. A phenomenological explication of the data revealed a number of salient metaphors and themes. Upon being diagnosed with HIV, individuals were confronted with a socially and institutionally prescribed understanding of the disease; HIV as synonymous with AIDS and immediate death, HIV as sexual deviance, and HIV as myth. These metaphors influenced their conceptualisation and handling of HIV. Individual embodied metaphors included: embodying a heart of stone to live with HIV and perceiving HIV as a punishment from God, a demon from the Devil, a death sentence and a torture. Affectively, the experience of HIV was constituted as fear of physical disfigurement and exposure, anxiety, vulnerability, anger, betrayal, injustice and isolation. In a process of resolution and transformation, individuals imbibed positive metaphors with which to continue living with HIV. In order to cope with HIV, individuals seemed to negotiate a metaphorical space in which to dwell with their virus. This entailed establishing some form of dialogue with HIV or a Higher Power. This study revealed that metaphorical thinking about HIV /AIDS has a powerful impact on individuals' embodiment of their world. Metaphor is also an effective means Clf conveying and eliciting meaning in the experience of illness. Based upon these findings, it was suggested that metaphor be a prime focus for future research endeavours.
- Full Text:
- Date Issued: 1998
- Authors: Cardo, Julia Claire
- Date: 1998
- Subjects: HIV infections , Metaphor -- Psychological aspects , Imagery (Psychology) -- Therapeutic use
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2945 , http://hdl.handle.net/10962/d1002454 , HIV infections , Metaphor -- Psychological aspects , Imagery (Psychology) -- Therapeutic use
- Description: The medical model has been criticised for its failure to attend to individuals' experience of illness and the meaning they attribute to illness. HIV / AIDS has challenged its adequacy and brought the question of meaning in illness into sharp focus. This study aimed to understand what it means to live with HIV by exploring the fantasies, images and metaphors that make up the depth of such an experience. Phenomenology was deemed the appropriate approach, as it assigns epistemological significance to metaphor and ontological primacy to the lifeworld. An interview guide was fashioned from existing phenomenological literature and in-depth interviews were conducted with eight HIV -infected individuals. Five protocols were selected to constitute the study. In addition, an audio tape recording of one individual's metaphorical dialogue with HIV was obtained and transcribed. The three protocols with the richest content of imagery and metaphor were subjected to phenomenological explication. The remaining two protocols were used to support and clarify emergent meaning. A phenomenological explication of the data revealed a number of salient metaphors and themes. Upon being diagnosed with HIV, individuals were confronted with a socially and institutionally prescribed understanding of the disease; HIV as synonymous with AIDS and immediate death, HIV as sexual deviance, and HIV as myth. These metaphors influenced their conceptualisation and handling of HIV. Individual embodied metaphors included: embodying a heart of stone to live with HIV and perceiving HIV as a punishment from God, a demon from the Devil, a death sentence and a torture. Affectively, the experience of HIV was constituted as fear of physical disfigurement and exposure, anxiety, vulnerability, anger, betrayal, injustice and isolation. In a process of resolution and transformation, individuals imbibed positive metaphors with which to continue living with HIV. In order to cope with HIV, individuals seemed to negotiate a metaphorical space in which to dwell with their virus. This entailed establishing some form of dialogue with HIV or a Higher Power. This study revealed that metaphorical thinking about HIV /AIDS has a powerful impact on individuals' embodiment of their world. Metaphor is also an effective means Clf conveying and eliciting meaning in the experience of illness. Based upon these findings, it was suggested that metaphor be a prime focus for future research endeavours.
- Full Text:
- Date Issued: 1998
Homogenous and heterogenous catalytic activity of metallophthalocyanines towards electrochemical detection of organic compounds
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
How green is our future? Thor Chemicals: a case study in South African environmental policy
- Authors: Flint, Adrian
- Date: 1998
- Subjects: Environmental ethics , Environmental policy -- South Africa , Environmental policy -- South Africa -- Case studies , Environmental degradation -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2776 , http://hdl.handle.net/10962/d1002986 , Environmental ethics , Environmental policy -- South Africa , Environmental policy -- South Africa -- Case studies , Environmental degradation -- South Africa
- Description: This study focuses on South African Environmefltal policy; in particular its policies regarding hazardous waste. These policies are addressed within the framework of a case study which serves as basis to critically evaluate government environmental policies both past and present. The thesis examines South African environmental policy against the backdrop of competing schools of thought regarding the relationship between growth and development on the one hand and long term environmental security on the other. Development strategies such as Sustainable Development and the government's Growth, Employment and Redistribution as well as philosophies such as Deep Ecology will be discussed. The thesis argues that Non-Governmental Organisations are the holders of a real environmental ethic and thus their role in preventing environmental degradation is of critical importance. Furthermore, it is imperative that this ethic be disseminated across society if South Africa is to successfully pursue sound environmental policies. This argument is pursued by way of a case study, Thor Chemicals: a company responsible for the running of the largest mercury recovery facility in the world. This plant, which operated in Cato Ridge, KwaZulu-Natal, has been the source of much controversy since it was found that many of its employees and ex-employees were suffering from severe mercury poisoning resulting in two fatalities. The company was also involved in the importation of hazardous wastes as well as the pollution of the surrounding environment. Thor is currently the subject of inquiry by the government-appointed Davis Commission. It is pointed out that ill the past South Africa held no real environmental ethic and environmental degradation ensued as a result. The presented thesis argues that, despite assurances to the contrary, the present government is also without a true environmental ethic that will be effective in preventing future degradation.
- Full Text:
- Date Issued: 1998
- Authors: Flint, Adrian
- Date: 1998
- Subjects: Environmental ethics , Environmental policy -- South Africa , Environmental policy -- South Africa -- Case studies , Environmental degradation -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2776 , http://hdl.handle.net/10962/d1002986 , Environmental ethics , Environmental policy -- South Africa , Environmental policy -- South Africa -- Case studies , Environmental degradation -- South Africa
- Description: This study focuses on South African Environmefltal policy; in particular its policies regarding hazardous waste. These policies are addressed within the framework of a case study which serves as basis to critically evaluate government environmental policies both past and present. The thesis examines South African environmental policy against the backdrop of competing schools of thought regarding the relationship between growth and development on the one hand and long term environmental security on the other. Development strategies such as Sustainable Development and the government's Growth, Employment and Redistribution as well as philosophies such as Deep Ecology will be discussed. The thesis argues that Non-Governmental Organisations are the holders of a real environmental ethic and thus their role in preventing environmental degradation is of critical importance. Furthermore, it is imperative that this ethic be disseminated across society if South Africa is to successfully pursue sound environmental policies. This argument is pursued by way of a case study, Thor Chemicals: a company responsible for the running of the largest mercury recovery facility in the world. This plant, which operated in Cato Ridge, KwaZulu-Natal, has been the source of much controversy since it was found that many of its employees and ex-employees were suffering from severe mercury poisoning resulting in two fatalities. The company was also involved in the importation of hazardous wastes as well as the pollution of the surrounding environment. Thor is currently the subject of inquiry by the government-appointed Davis Commission. It is pointed out that ill the past South Africa held no real environmental ethic and environmental degradation ensued as a result. The presented thesis argues that, despite assurances to the contrary, the present government is also without a true environmental ethic that will be effective in preventing future degradation.
- Full Text:
- Date Issued: 1998
Human rights: an investigation into the importance of second generation rights
- Authors: Bentley, Kristina Anne
- Date: 1998
- Subjects: Human rights -- Philosophy , Human rights
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2759 , http://hdl.handle.net/10962/d1002969 , Human rights -- Philosophy , Human rights
- Description: This study examines the notion of universal human rights in the context of the importance of social and economic rights for the agency and dignity of human beings. It argues that the recognition of basic rights to what is necessary for physical well-being is essential to any adequate theory of human rights, and that rights of the civil and political variety depend on the recognition of social and economic rights if they are to be exercised. Therefore the secondary status which is usually accorded to social and economic rights results in an imbalanced ideal of human rights both in theory and in practice. This study is an attempt to place second generation rights in their proper context and to argue for them as human rights of equal status and importance. It focuses on the derivation of human rights in general, and shows that second generation rights may be accommodated within this structure. It further supports this position by showing that the categorical differences which are asserted to exist between first and second generation rights are based on a mistaken conception of positive and negative rights and duties, as well as an inadequate conception of liberty. The thesis shows that all rights generate a variety of duties, both positive and negative, and that an adequate theory of rights has to be able to accommodate the inevitability of conflicts of rights at the level of their enforcement. Consequently, this study argues there is no reason to give either class of right primary importance, as both first and second generation human rights are essential to the agency and dignity of a human being, and they are thus interdependent. Furthermore, the thesis shows that human rights can be balanced at the level of the obligations which they generate without compromising the deontological nature of such rights. This thesis argues that a theory of rights which is rooted in the liberal democratic notion of rights, such as that characterised by the choice theory of rights, is inadequate. It therefore argues that a benefit theory of rights must be adopted in order to accommodate conflicts of rights when they arise. The thesis argues that as such conflicts of rights are" most common in cases involving the assertion of social and economic rights, this balancing of rights is of special significance for the enforcement of second generation rights. Furthermore, this thesis argues for a theory of minimal interdependence of first and second generation rights, in order to accommodate the notion of first and second generation rights of equal status and importance, as well as to prevent an inflation of rights claims which would compromise the balancing of rights. It is argued that a reordering of values is necessary to take account of material well-being, as well as civil freedom, as both of these generate fundamental rights of equal status and importance.
- Full Text:
- Date Issued: 1998
- Authors: Bentley, Kristina Anne
- Date: 1998
- Subjects: Human rights -- Philosophy , Human rights
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2759 , http://hdl.handle.net/10962/d1002969 , Human rights -- Philosophy , Human rights
- Description: This study examines the notion of universal human rights in the context of the importance of social and economic rights for the agency and dignity of human beings. It argues that the recognition of basic rights to what is necessary for physical well-being is essential to any adequate theory of human rights, and that rights of the civil and political variety depend on the recognition of social and economic rights if they are to be exercised. Therefore the secondary status which is usually accorded to social and economic rights results in an imbalanced ideal of human rights both in theory and in practice. This study is an attempt to place second generation rights in their proper context and to argue for them as human rights of equal status and importance. It focuses on the derivation of human rights in general, and shows that second generation rights may be accommodated within this structure. It further supports this position by showing that the categorical differences which are asserted to exist between first and second generation rights are based on a mistaken conception of positive and negative rights and duties, as well as an inadequate conception of liberty. The thesis shows that all rights generate a variety of duties, both positive and negative, and that an adequate theory of rights has to be able to accommodate the inevitability of conflicts of rights at the level of their enforcement. Consequently, this study argues there is no reason to give either class of right primary importance, as both first and second generation human rights are essential to the agency and dignity of a human being, and they are thus interdependent. Furthermore, the thesis shows that human rights can be balanced at the level of the obligations which they generate without compromising the deontological nature of such rights. This thesis argues that a theory of rights which is rooted in the liberal democratic notion of rights, such as that characterised by the choice theory of rights, is inadequate. It therefore argues that a benefit theory of rights must be adopted in order to accommodate conflicts of rights when they arise. The thesis argues that as such conflicts of rights are" most common in cases involving the assertion of social and economic rights, this balancing of rights is of special significance for the enforcement of second generation rights. Furthermore, this thesis argues for a theory of minimal interdependence of first and second generation rights, in order to accommodate the notion of first and second generation rights of equal status and importance, as well as to prevent an inflation of rights claims which would compromise the balancing of rights. It is argued that a reordering of values is necessary to take account of material well-being, as well as civil freedom, as both of these generate fundamental rights of equal status and importance.
- Full Text:
- Date Issued: 1998
Identity and transformation within the Playhouse Dance Company, 1993-1997
- Ballantyne, Tammy Marguerite
- Authors: Ballantyne, Tammy Marguerite
- Date: 1998
- Subjects: Playhouse dance company , Dance -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2131 , http://hdl.handle.net/10962/d1002363 , Playhouse dance company , Dance -- South Africa
- Description: This thesis examines the principles and policies underlying the need for transformation within the Playhouse Dance Company (PDC) in Durban and the actualities of implementing these visions and procedures. It is proposed that artistic structures, ideals and processes cannot remain impervious to the climate of change. Alterations in the political arena demand radical permutations within arts councils and their concept of repertoire, educational programmes and training. Transformation is linked to the problem of identity and it is suggested that the company is in the midst of a journey towards "becoming" rather than "being". Chapter One comprises an overview of changing trends in the arts globally and the impact on South Mrican art forms and processes. There is also an examination of the past, the establishment of arts councils and the colonial heritage of the dance companies within these councils. The formative years of the NAP AC Dance Company and the strategies formulated by former artistic directors have, it is suggested, hampered the transformation process. Chapter Two focuses on the PDC's endeavours to transform between the years 1993 and 1997. Lack of funding, conservative public tastes and training processes are. all' issues confronting management, choreographers, educators and performers in attempting to provide a clear direction towards transformation. The company walk a tightrope as they struggle to balance the heritage of their artistic past while giving birth to a new heritage for the future. Chapter Three discusses two areas that reveal measurable attempts at transformation. Hawkins offers re-inventions of the classics which encourages innovation, and Siwela Sonke was conceived to draw on dance forms located in Kwazulu-Natal in the search for a South Mrican dance aesthetic. Chapter Four investigates whether transformative visions are becoming a reality and suggests how the company could extend the process further. This chapter concludes with .. ideas about the nature of culture and how this informs,the exercise of transformation. This thesis proposes that transformation within the PDC is occurring even though it has its shortcomings. The main thrust of the research is to investigate, identifY and document factors that are contributing to current dance trends in Durban.
- Full Text:
- Date Issued: 1998
- Authors: Ballantyne, Tammy Marguerite
- Date: 1998
- Subjects: Playhouse dance company , Dance -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2131 , http://hdl.handle.net/10962/d1002363 , Playhouse dance company , Dance -- South Africa
- Description: This thesis examines the principles and policies underlying the need for transformation within the Playhouse Dance Company (PDC) in Durban and the actualities of implementing these visions and procedures. It is proposed that artistic structures, ideals and processes cannot remain impervious to the climate of change. Alterations in the political arena demand radical permutations within arts councils and their concept of repertoire, educational programmes and training. Transformation is linked to the problem of identity and it is suggested that the company is in the midst of a journey towards "becoming" rather than "being". Chapter One comprises an overview of changing trends in the arts globally and the impact on South Mrican art forms and processes. There is also an examination of the past, the establishment of arts councils and the colonial heritage of the dance companies within these councils. The formative years of the NAP AC Dance Company and the strategies formulated by former artistic directors have, it is suggested, hampered the transformation process. Chapter Two focuses on the PDC's endeavours to transform between the years 1993 and 1997. Lack of funding, conservative public tastes and training processes are. all' issues confronting management, choreographers, educators and performers in attempting to provide a clear direction towards transformation. The company walk a tightrope as they struggle to balance the heritage of their artistic past while giving birth to a new heritage for the future. Chapter Three discusses two areas that reveal measurable attempts at transformation. Hawkins offers re-inventions of the classics which encourages innovation, and Siwela Sonke was conceived to draw on dance forms located in Kwazulu-Natal in the search for a South Mrican dance aesthetic. Chapter Four investigates whether transformative visions are becoming a reality and suggests how the company could extend the process further. This chapter concludes with .. ideas about the nature of culture and how this informs,the exercise of transformation. This thesis proposes that transformation within the PDC is occurring even though it has its shortcomings. The main thrust of the research is to investigate, identifY and document factors that are contributing to current dance trends in Durban.
- Full Text:
- Date Issued: 1998
Ikatara
- Sponono, Composer not specified, Dargie, Dave
- Authors: Sponono , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342337 , vital:62881 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340a-01
- Description: Ngqoko music ensemble accompanied by inkinge bowed bow
- Full Text: false
- Date Issued: 1998
- Authors: Sponono , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342337 , vital:62881 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340a-01
- Description: Ngqoko music ensemble accompanied by inkinge bowed bow
- Full Text: false
- Date Issued: 1998
Improvement of fertility and hatchability of artificially incubated ostrich eggs in the little Karoo
- Van Schalkwyk, Salmon Jacobus
- Authors: Van Schalkwyk, Salmon Jacobus
- Date: 1998
- Subjects: Ostrich farming -- South Africa , Eggs -- Hatchability , Eggs -- Incubation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5713 , http://hdl.handle.net/10962/d1005399
- Description: Ostriches are an important commercial species in South Africa and are becoming increasingly so in other parts of the world. Fertility and hatchability of artificially incubated ostrich eggs, however, is generally regarded as low compared to other poultry species and to ostriches in the wild. Investigation into specific farming practices at present indicated scope for an overall improvement in productivity through a sound breeding strategy. This thesis investigated factors that affect egg production, fertility, and hatchability of artificially incubated eggs in the Little Karoo region of South Africa. Specific breeding pair combinations accounted for the major variations in egg weight, hatchability, chick production and offspring weight at slaughter age. An appreciable proportion of variation in reproductive traits was attributable to the repeatable nature of breeding pair performance from year to year, even from first breeding attempts, suggesting that selection of good breeding stock can be made from an early age. Artificially incubated eggs showed improved hatchability when eggs were collected two to three hours after lay rather than the following morning. Storing position of eggs did not significantly effect hatchability when eggs were stored for a maximum of one week. The critical zero temperature for ostrich eggs, below which no embryonical development takes place, was found to be ± 25°C and cooling eggs to temperatures below 20°C for complete cessation of embryonic development during storage resulted in better hatchabilities compared to eggs stored at 25°C room temperature. Hatchability decreased when incubator temperatures were raised from 36 to 37.3°C. Large temperature fluctuations and gradients, which encompass detrimental temperatures, persist within forced draught wooden incubators of the type most commonly in use in the Little Karoo region. The highest temperatures occurred at the top of these incubators and will consequently have a negative impact on hatchability. The ontogeny of ostrich egg metabolism showed an exponential increase during the first 70% of incubation followed by a decline to 75% of the peak value between days 31 and 38 of incubation. From peak levels of embryonic development it was calculated that single stage incubators needs an airflow of 54.4 1/egg.hour to maintain oxygen levels just below 21% and carbon dioxide levels below 0.5%. Lower embryonic mortalities were observed when eggs were turned twenty-four times/day in an electronic incubator compared to hand turning twice a day. Eggs rotated through increasing angles between 60 and 90° resulted in a linear improvement in hatchability. In incubators where turning angles were fixed at 60°, lower hatchabilities were overcome by incubating eggs for 2 - 3 weeks in a horizontal position before placing them vertically. No specific farming practice could be singled out as the main cause of low fertility or hatchability but rather a combination of certain practices applied wrongly.
- Full Text:
- Date Issued: 1998
Improvement of fertility and hatchability of artificially incubated ostrich eggs in the little Karoo
- Authors: Van Schalkwyk, Salmon Jacobus
- Date: 1998
- Subjects: Ostrich farming -- South Africa , Eggs -- Hatchability , Eggs -- Incubation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5713 , http://hdl.handle.net/10962/d1005399
- Description: Ostriches are an important commercial species in South Africa and are becoming increasingly so in other parts of the world. Fertility and hatchability of artificially incubated ostrich eggs, however, is generally regarded as low compared to other poultry species and to ostriches in the wild. Investigation into specific farming practices at present indicated scope for an overall improvement in productivity through a sound breeding strategy. This thesis investigated factors that affect egg production, fertility, and hatchability of artificially incubated eggs in the Little Karoo region of South Africa. Specific breeding pair combinations accounted for the major variations in egg weight, hatchability, chick production and offspring weight at slaughter age. An appreciable proportion of variation in reproductive traits was attributable to the repeatable nature of breeding pair performance from year to year, even from first breeding attempts, suggesting that selection of good breeding stock can be made from an early age. Artificially incubated eggs showed improved hatchability when eggs were collected two to three hours after lay rather than the following morning. Storing position of eggs did not significantly effect hatchability when eggs were stored for a maximum of one week. The critical zero temperature for ostrich eggs, below which no embryonical development takes place, was found to be ± 25°C and cooling eggs to temperatures below 20°C for complete cessation of embryonic development during storage resulted in better hatchabilities compared to eggs stored at 25°C room temperature. Hatchability decreased when incubator temperatures were raised from 36 to 37.3°C. Large temperature fluctuations and gradients, which encompass detrimental temperatures, persist within forced draught wooden incubators of the type most commonly in use in the Little Karoo region. The highest temperatures occurred at the top of these incubators and will consequently have a negative impact on hatchability. The ontogeny of ostrich egg metabolism showed an exponential increase during the first 70% of incubation followed by a decline to 75% of the peak value between days 31 and 38 of incubation. From peak levels of embryonic development it was calculated that single stage incubators needs an airflow of 54.4 1/egg.hour to maintain oxygen levels just below 21% and carbon dioxide levels below 0.5%. Lower embryonic mortalities were observed when eggs were turned twenty-four times/day in an electronic incubator compared to hand turning twice a day. Eggs rotated through increasing angles between 60 and 90° resulted in a linear improvement in hatchability. In incubators where turning angles were fixed at 60°, lower hatchabilities were overcome by incubating eggs for 2 - 3 weeks in a horizontal position before placing them vertically. No specific farming practice could be singled out as the main cause of low fertility or hatchability but rather a combination of certain practices applied wrongly.
- Full Text:
- Date Issued: 1998
In search of the culture of links : the use of myth and ritual in the work of Peter Brook
- Authors: Du Plessis, Tanya Lenore
- Date: 1998
- Subjects: Brook, Peter -- Criticism and interpretation , Myth in literature , Mahābhārata -- Adaptations , Ritual in literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2136 , http://hdl.handle.net/10962/d1002368 , Brook, Peter -- Criticism and interpretation , Myth in literature , Mahābhārata -- Adaptations , Ritual in literature
- Description: This thesis examines the use of elements of myth and ritual in the work of Peter Brook, focusing primarily on The Mahabharata ( 1986 ). The argument proposes that Brook uses myth and ritual as an integral part of his search for the culture of links .. This thesis examines the precise functioning of myth and ritual in Brook's theatre, and places his work in relation to the concepts of interculturalism and postmodernism. In so doing, The Mahabharata is seen as a valid and important step in Brook's search for the culture of links. Chapter One formulates broad-based concepts of myth and ritual, and examines their function in society and culture, as well as their role in theatre. Chapter Two offers a brief discussion of the use of elements of myth and ritual in Brook's productions, beginning with King Lear (1962), and ending with 0rghast (1971). The discussion illustrates the multiple functions which myth and ritual serve in Brook's work. Chapter Three examines the trend of interculturalism, placing Brook's work within this franlework. Attention is given to the moral and political issues implicit in interculturalism. The chapter highlights the need for intercultural theatre to be evaluated in terms of artistic criteria, rather than on anthropological or political grounds. Finally, there is a discussion of the work of other intercultural theatre practitioners. Chapter Four examines Brook's Mahabharata. A detailed discussion of the authenticity and visual presentation of Brook's interpretation shows how Brook mediates between the Indian epic and a Western audience An examination of the critical response offers insights into the dangers of insensitive cross-cultural contact.. Chapter Five offers a critical summary of the argument. Brook's search for the culture of links has led him to use elements of myths and rituals of non-Western cultures. In so doing, Brook seeks to bring their living quality to his work, and to forge links between the peoples and cultures of the world.
- Full Text:
- Date Issued: 1998
- Authors: Du Plessis, Tanya Lenore
- Date: 1998
- Subjects: Brook, Peter -- Criticism and interpretation , Myth in literature , Mahābhārata -- Adaptations , Ritual in literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2136 , http://hdl.handle.net/10962/d1002368 , Brook, Peter -- Criticism and interpretation , Myth in literature , Mahābhārata -- Adaptations , Ritual in literature
- Description: This thesis examines the use of elements of myth and ritual in the work of Peter Brook, focusing primarily on The Mahabharata ( 1986 ). The argument proposes that Brook uses myth and ritual as an integral part of his search for the culture of links .. This thesis examines the precise functioning of myth and ritual in Brook's theatre, and places his work in relation to the concepts of interculturalism and postmodernism. In so doing, The Mahabharata is seen as a valid and important step in Brook's search for the culture of links. Chapter One formulates broad-based concepts of myth and ritual, and examines their function in society and culture, as well as their role in theatre. Chapter Two offers a brief discussion of the use of elements of myth and ritual in Brook's productions, beginning with King Lear (1962), and ending with 0rghast (1971). The discussion illustrates the multiple functions which myth and ritual serve in Brook's work. Chapter Three examines the trend of interculturalism, placing Brook's work within this franlework. Attention is given to the moral and political issues implicit in interculturalism. The chapter highlights the need for intercultural theatre to be evaluated in terms of artistic criteria, rather than on anthropological or political grounds. Finally, there is a discussion of the work of other intercultural theatre practitioners. Chapter Four examines Brook's Mahabharata. A detailed discussion of the authenticity and visual presentation of Brook's interpretation shows how Brook mediates between the Indian epic and a Western audience An examination of the critical response offers insights into the dangers of insensitive cross-cultural contact.. Chapter Five offers a critical summary of the argument. Brook's search for the culture of links has led him to use elements of myths and rituals of non-Western cultures. In so doing, Brook seeks to bring their living quality to his work, and to forge links between the peoples and cultures of the world.
- Full Text:
- Date Issued: 1998
In vitro permeation of progesterone from a gel through the shed skin of three different snake species
- Haigh, John M, Beyssac, E, Chanet, L, Aiache, J M
- Authors: Haigh, John M , Beyssac, E , Chanet, L , Aiache, J M
- Date: 1998
- Language: English
- Type: Article
- Identifier: vital:6366 , http://hdl.handle.net/10962/d1006066
- Description: The in vitro diffusion of progesterone from a gel formulation using the European Pharmacopoeia method for transdermal dosage forms is described. The membranes used were the dorsal and ventral portions of the shed skin of three different species of snake. Considerable differences are apparent between the dorsal and ventral sites and between the different species of snake. The dorsal area shows better permeability for progesterone and the permeability order for the different species is python>cobra>viper. These differences may be due to the thickness of the skin and the hinge:scale ratio. The results indicate that shed snake skin is not a model membrane for human skin.
- Full Text:
- Date Issued: 1998
- Authors: Haigh, John M , Beyssac, E , Chanet, L , Aiache, J M
- Date: 1998
- Language: English
- Type: Article
- Identifier: vital:6366 , http://hdl.handle.net/10962/d1006066
- Description: The in vitro diffusion of progesterone from a gel formulation using the European Pharmacopoeia method for transdermal dosage forms is described. The membranes used were the dorsal and ventral portions of the shed skin of three different species of snake. Considerable differences are apparent between the dorsal and ventral sites and between the different species of snake. The dorsal area shows better permeability for progesterone and the permeability order for the different species is python>cobra>viper. These differences may be due to the thickness of the skin and the hinge:scale ratio. The results indicate that shed snake skin is not a model membrane for human skin.
- Full Text:
- Date Issued: 1998
In vitro release of amoxycillin from lipophilic suppositories
- Webster, Jessica A, Dowse, Roslind, Walker, Roderick B
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184377 , vital:44213 , xlink:href="https://doi.org/10.3109/03639049809085636"
- Description: The in vitro release characteristics of amoxycillin from different lipophilic suppository bases were investigated using the USP rotating basket method. Suppositories containing 250 mg amoxycillin were prepared in theobroma oil and in the semisynthetic bases Witepsol W35, Suppocire A32, Novata BD, and Novata 299. Both freshly prepared and 1-month-old suppositories were tested. Analysis of amoxycillin was performed using a validated high-performance liquid chromatographic (HPLC) technique. Release profiles differed significantly between bases, with the greatest amount of amoxycillin being released from both newly made and 1-month-old Novata BD bases (87.57 ± 8.18 and 99.66 ± 6.63%, respectively), and the lowest amount released from the newly manufactured theobroma suppositories (8.82 ± 0.75%) and the 1-month-old Suppocire A32 suppositories (7.78 ± 0.27%).
- Full Text:
- Date Issued: 1998
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184377 , vital:44213 , xlink:href="https://doi.org/10.3109/03639049809085636"
- Description: The in vitro release characteristics of amoxycillin from different lipophilic suppository bases were investigated using the USP rotating basket method. Suppositories containing 250 mg amoxycillin were prepared in theobroma oil and in the semisynthetic bases Witepsol W35, Suppocire A32, Novata BD, and Novata 299. Both freshly prepared and 1-month-old suppositories were tested. Analysis of amoxycillin was performed using a validated high-performance liquid chromatographic (HPLC) technique. Release profiles differed significantly between bases, with the greatest amount of amoxycillin being released from both newly made and 1-month-old Novata BD bases (87.57 ± 8.18 and 99.66 ± 6.63%, respectively), and the lowest amount released from the newly manufactured theobroma suppositories (8.82 ± 0.75%) and the 1-month-old Suppocire A32 suppositories (7.78 ± 0.27%).
- Full Text:
- Date Issued: 1998
Interaction of nitric oxide with cobalt (II) phthalocyanine
- Vilakazi, Sibulelo L, Nyokong, Tebello
- Authors: Vilakazi, Sibulelo L , Nyokong, Tebello
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293579 , vital:57100 , xlink:href="https://doi.org/10.1016/S0277-5387(98)00244-7"
- Description: The coordination of nitric oxide (NO) to cobalt(II) phthalocyanine (CoPc) in dimethyl sulphoxide (DMSO) has been studied. CoPc coordinates with NO in a 1:1 ratio, forming a CoPc(NO) species. The IR band observed at 1680 cm−1 is assigned to the coordinated NO. In the presence of excess NO, pseudo first order kinetics were followed. The observed rate constant, kf, was determined to be 15.0±0.3 dm−3 mol−1 s−1 and the equilibrium constant was K=5.4±0.4×104dm3 mol−1. Solution or adsorbed CoPc catalyses the reduction of NO. The products of reduction include NH3 and NH2OH.
- Full Text:
- Date Issued: 1998
- Authors: Vilakazi, Sibulelo L , Nyokong, Tebello
- Date: 1998
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293579 , vital:57100 , xlink:href="https://doi.org/10.1016/S0277-5387(98)00244-7"
- Description: The coordination of nitric oxide (NO) to cobalt(II) phthalocyanine (CoPc) in dimethyl sulphoxide (DMSO) has been studied. CoPc coordinates with NO in a 1:1 ratio, forming a CoPc(NO) species. The IR band observed at 1680 cm−1 is assigned to the coordinated NO. In the presence of excess NO, pseudo first order kinetics were followed. The observed rate constant, kf, was determined to be 15.0±0.3 dm−3 mol−1 s−1 and the equilibrium constant was K=5.4±0.4×104dm3 mol−1. Solution or adsorbed CoPc catalyses the reduction of NO. The products of reduction include NH3 and NH2OH.
- Full Text:
- Date Issued: 1998
Iyaka yaka
- Dywili, Nofinishi, Composer not specified, Dargie, Dave
- Authors: Dywili, Nofinishi , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342562 , vital:62905 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340b-05
- Description: Ngqoko music ensemble accompanied by uhadi
- Full Text: false
- Date Issued: 1998
- Authors: Dywili, Nofinishi , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342562 , vital:62905 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340b-05
- Description: Ngqoko music ensemble accompanied by uhadi
- Full Text: false
- Date Issued: 1998
Kalambaw
- Kenza Batoma Diallo (author, composer, lead singer), Aliou Traore (violin), Benogo Diakite (ngoni, kangnan), Kabin Kaba Diakite (guitar, bass, yabara), Halima Sangare (chorus), Souleymane Dembele (balafon), Kalibou Diarra (djembe), MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Authors: Kenza Batoma Diallo (author, composer, lead singer) , Aliou Traore (violin) , Benogo Diakite (ngoni, kangnan) , Kabin Kaba Diakite (guitar, bass, yabara) , Halima Sangare (chorus) , Souleymane Dembele (balafon) , Kalibou Diarra (djembe) , MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Date: 1998
- Subjects: Popular music , Folk music , Africa Mali Bamako f-ml
- Language: Fulani
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129749 , vital:36327 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC32-06
- Description: Traditional Malian music from the south, performed on traditional instruments, ngoni, kangnan, yabara, balafon, djembe and a violin
- Full Text: false
- Date Issued: 1998
- Authors: Kenza Batoma Diallo (author, composer, lead singer) , Aliou Traore (violin) , Benogo Diakite (ngoni, kangnan) , Kabin Kaba Diakite (guitar, bass, yabara) , Halima Sangare (chorus) , Souleymane Dembele (balafon) , Kalibou Diarra (djembe) , MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Date: 1998
- Subjects: Popular music , Folk music , Africa Mali Bamako f-ml
- Language: Fulani
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129749 , vital:36327 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC32-06
- Description: Traditional Malian music from the south, performed on traditional instruments, ngoni, kangnan, yabara, balafon, djembe and a violin
- Full Text: false
- Date Issued: 1998
Kodiavision Show
- MC-Zotto (lead, vocal, rap, ragga), Lamso (rap, composition), Poupson (rap), Bouttas (ragga), David (rap, sing), Dene, Izebere (chorus), MALI K7 S.A.
- Authors: MC-Zotto (lead, vocal, rap, ragga) , Lamso (rap, composition) , Poupson (rap) , Bouttas (ragga) , David (rap, sing) , Dene, Izebere (chorus) , MALI K7 S.A.
- Date: 1998
- Subjects: Popular music , Popular music--Mali--1991-2000 , Rap (Music) , Africa Mali Bamako f-ml
- Language: English , French , Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128595 , vital:36126 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC12-06
- Description: Rap songs about contempory issues, unity and peace
- Full Text: false
- Date Issued: 1998
- Authors: MC-Zotto (lead, vocal, rap, ragga) , Lamso (rap, composition) , Poupson (rap) , Bouttas (ragga) , David (rap, sing) , Dene, Izebere (chorus) , MALI K7 S.A.
- Date: 1998
- Subjects: Popular music , Popular music--Mali--1991-2000 , Rap (Music) , Africa Mali Bamako f-ml
- Language: English , French , Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128595 , vital:36126 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC12-06
- Description: Rap songs about contempory issues, unity and peace
- Full Text: false
- Date Issued: 1998
Kome ne
- Habib Koite (lead singer, guitar, chorus, lyrics, composer), Baba Sissoko (n'goni, balafon), Abdoul W. Berthe (bass guitar, kamale n'goni), Souleymane Ann (drums, calebasse, chorus), Boubacar Sidibe (guitar, chorus, harmonica), Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble), Coutre-Jour, Putumayo World Music
- Authors: Habib Koite (lead singer, guitar, chorus, lyrics, composer) , Baba Sissoko (n'goni, balafon) , Abdoul W. Berthe (bass guitar, kamale n'goni) , Souleymane Ann (drums, calebasse, chorus) , Boubacar Sidibe (guitar, chorus, harmonica) , Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble) , Coutre-Jour, Putumayo World Music
- Date: 1998
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131302 , vital:36557 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC51-02
- Description: Relaxed intimate vocal style accompanied by talking drum, guitar, bass, drum set, harmonica violon, calabash and balafon
- Full Text: false
- Date Issued: 1998
- Authors: Habib Koite (lead singer, guitar, chorus, lyrics, composer) , Baba Sissoko (n'goni, balafon) , Abdoul W. Berthe (bass guitar, kamale n'goni) , Souleymane Ann (drums, calebasse, chorus) , Boubacar Sidibe (guitar, chorus, harmonica) , Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble) , Coutre-Jour, Putumayo World Music
- Date: 1998
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131302 , vital:36557 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC51-02
- Description: Relaxed intimate vocal style accompanied by talking drum, guitar, bass, drum set, harmonica violon, calabash and balafon
- Full Text: false
- Date Issued: 1998
Kumbin
- Habib Koite (lead singer, guitar, chorus, lyrics, composer), Baba Sissoko (n'goni, balafon), Abdoul W. Berthe (bass guitar, kamale n'goni), Souleymane Ann (drums, calebasse, chorus), Boubacar Sidibe (guitar, chorus, harmonica), Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble), Coutre-Jour, Putumayo World Music
- Authors: Habib Koite (lead singer, guitar, chorus, lyrics, composer) , Baba Sissoko (n'goni, balafon) , Abdoul W. Berthe (bass guitar, kamale n'goni) , Souleymane Ann (drums, calebasse, chorus) , Boubacar Sidibe (guitar, chorus, harmonica) , Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble) , Coutre-Jour, Putumayo World Music
- Date: 1998
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: English
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131341 , vital:36561 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC51-06
- Description: Relaxed intimate vocal style accompanied by talking drum, guitar, bass, drum set, harmonica violon, calabash and balafon
- Full Text: false
- Date Issued: 1998
- Authors: Habib Koite (lead singer, guitar, chorus, lyrics, composer) , Baba Sissoko (n'goni, balafon) , Abdoul W. Berthe (bass guitar, kamale n'goni) , Souleymane Ann (drums, calebasse, chorus) , Boubacar Sidibe (guitar, chorus, harmonica) , Fanga Diawara, Mahame Cisse, Alhousseini Dicko (violon peuls, Malian instrument ensemble) , Coutre-Jour, Putumayo World Music
- Date: 1998
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: English
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131341 , vital:36561 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC51-06
- Description: Relaxed intimate vocal style accompanied by talking drum, guitar, bass, drum set, harmonica violon, calabash and balafon
- Full Text: false
- Date Issued: 1998
Latshon' Ilanga
- Dywili, Nofinishi, Composer not specified, Dargie, Dave
- Authors: Dywili, Nofinishi , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342488 , vital:62897 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340b-02
- Description: Ngqoko music ensemble accompanied by uhadi
- Full Text: false
- Date Issued: 1998
- Authors: Dywili, Nofinishi , Composer not specified , Dargie, Dave
- Date: 1998
- Subjects: Folk music , Sacred music , Field recordings , Africa, Sub-Saharan , Africa South Africa Ngqoko sa
- Language: IsiXhosa
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/342488 , vital:62897 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DDC340b-02
- Description: Ngqoko music ensemble accompanied by uhadi
- Full Text: false
- Date Issued: 1998