Institutions and economic research: a case of location externalities on agricultural resource allocation in the Kat River basin, South Africa. A Rejoinder
- Mbatha, Cyril N, Antrobus, Geoffrey G
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143002 , vital:38184 , https://0-doi.org.wam.seals.ac.za/10.1080/03031853.2013.798069
- Description: In Mbatha and Antrobus (2008), an argument was put forward against an importation or adoption of universal models or general theorems to explain locally prevailing socio-economic conditions and predict outcomes in varied geographical contexts such as in the Kat River basin. In response to this argument a comment in this edition argues that our “results are caused by, metaphorically speaking, comparing apples and oranges. If, however, all of the relevant information is taken into account, a simple economic model may suffice to depict the situation within the KRV.” Here we illustrate that the comment comes from a misreading of basic details in the original discussion and in its construction and presentation of an alternative model of the KRV conditions the comment reiterates our original argument that general models and theorems are likely to fail to explain local intricacies primarily because they are not founded on local historical institutions.
- Full Text:
- Date Issued: 2013
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143002 , vital:38184 , https://0-doi.org.wam.seals.ac.za/10.1080/03031853.2013.798069
- Description: In Mbatha and Antrobus (2008), an argument was put forward against an importation or adoption of universal models or general theorems to explain locally prevailing socio-economic conditions and predict outcomes in varied geographical contexts such as in the Kat River basin. In response to this argument a comment in this edition argues that our “results are caused by, metaphorically speaking, comparing apples and oranges. If, however, all of the relevant information is taken into account, a simple economic model may suffice to depict the situation within the KRV.” Here we illustrate that the comment comes from a misreading of basic details in the original discussion and in its construction and presentation of an alternative model of the KRV conditions the comment reiterates our original argument that general models and theorems are likely to fail to explain local intricacies primarily because they are not founded on local historical institutions.
- Full Text:
- Date Issued: 2013
Is classical biological control a 20th century" old science" paradigm that is losing its way?
- Sheppard, Andy, Werner, K, Hill, Martin P, McEvoy, Peter, Fowler, Simon, Hill, Richard
- Authors: Sheppard, Andy , Werner, K , Hill, Martin P , McEvoy, Peter , Fowler, Simon , Hill, Richard
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/425434 , vital:72239 , xlink:href="https://www.fs.usda.gov/research/treesearch/44754"
- Description: For years most countries accepted the benefits of biological control as given, leading to facilitated inside lanes through the regulatory maze. "Successes" led to many passionate disciples over science rationalists. Biocontrol targets continue to be selected on assumptions of good value with little direct evidence. Even when successful, biocontrol has rarely delivered environmental benefits that have been measured. Money flow is still healthy, but is arguably being directed against less impactful targets. Lack of science rigour exposes the field to attacks from an increasing number of critics as values change. A global change driven counter-revolution is underway on the dichotomy of hate between natives and aliens. Will climate change undermine even currently successful biocontrol outcomes? Meanwhile negative direct and indirect impacts of biological continue to fuel dissent. Nowhere is this issue hotter than in Hawaii where "invaders" have massively increased biodiversity, make up nearly all the biomass and create whole new ecosystems. This workshop will entertain a panel discussion around the future for classical biological control of weeds. Does it need to change its paradigm in response to changing societal values, if so can it reinvent itself?
- Full Text:
- Date Issued: 2013
- Authors: Sheppard, Andy , Werner, K , Hill, Martin P , McEvoy, Peter , Fowler, Simon , Hill, Richard
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/425434 , vital:72239 , xlink:href="https://www.fs.usda.gov/research/treesearch/44754"
- Description: For years most countries accepted the benefits of biological control as given, leading to facilitated inside lanes through the regulatory maze. "Successes" led to many passionate disciples over science rationalists. Biocontrol targets continue to be selected on assumptions of good value with little direct evidence. Even when successful, biocontrol has rarely delivered environmental benefits that have been measured. Money flow is still healthy, but is arguably being directed against less impactful targets. Lack of science rigour exposes the field to attacks from an increasing number of critics as values change. A global change driven counter-revolution is underway on the dichotomy of hate between natives and aliens. Will climate change undermine even currently successful biocontrol outcomes? Meanwhile negative direct and indirect impacts of biological continue to fuel dissent. Nowhere is this issue hotter than in Hawaii where "invaders" have massively increased biodiversity, make up nearly all the biomass and create whole new ecosystems. This workshop will entertain a panel discussion around the future for classical biological control of weeds. Does it need to change its paradigm in response to changing societal values, if so can it reinvent itself?
- Full Text:
- Date Issued: 2013
Is Fairtrade in commercial farms justifiable?: its impact on commercial and small-scale producers in South Africa
- Jari, Bridget, Snowball, Jeanette D, Fraser, Gavin C G
- Authors: Jari, Bridget , Snowball, Jeanette D , Fraser, Gavin C G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69408 , vital:29519 , https://doi.org/10.1080/03031853.2013.847036
- Description: Fairtrade initially was limited to improving the lives of small-scale and peasant farmers, but later on it embraced commercial farmers, which attracted criticism. While there are a number of justifications for the Fairtrade organization's decision, there are authors who feel that meaningful “fair trade” cannot be achieved with the inclusion of commercial farms. This paper investigates the impact of Fairtrade on commercial farms and small-scale farmer cooperatives in South Africa. Fairtrade on South African commercial farms embraces a number of policy concerns related to land reform, BEE and sustainable development. The results of the study show that when commercial farms are included in the Fairtrade model, communities in which these farmers live benefit from developmental projects. In addition, in some instances, farm workers gain shares in the commercial farms, and benefit from the farm owners’ knowledge and capital.
- Full Text:
- Date Issued: 2013
- Authors: Jari, Bridget , Snowball, Jeanette D , Fraser, Gavin C G
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69408 , vital:29519 , https://doi.org/10.1080/03031853.2013.847036
- Description: Fairtrade initially was limited to improving the lives of small-scale and peasant farmers, but later on it embraced commercial farmers, which attracted criticism. While there are a number of justifications for the Fairtrade organization's decision, there are authors who feel that meaningful “fair trade” cannot be achieved with the inclusion of commercial farms. This paper investigates the impact of Fairtrade on commercial farms and small-scale farmer cooperatives in South Africa. Fairtrade on South African commercial farms embraces a number of policy concerns related to land reform, BEE and sustainable development. The results of the study show that when commercial farms are included in the Fairtrade model, communities in which these farmers live benefit from developmental projects. In addition, in some instances, farm workers gain shares in the commercial farms, and benefit from the farm owners’ knowledge and capital.
- Full Text:
- Date Issued: 2013
IsiXhosa lexicography: past, present and future
- Authors: Nkomo, Dion , Wababa, Zola
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67526 , vital:29108 , http://dx.doi.org/10.5788/23-1-1219
- Description: Publisher version , This article presents a panoramic and critical overview of isiXhosa lexicography and its impact on the intellectualisation of this indigenous South African language. The history of isi¬Xhosa lexicography dates back more than two centuries. However, there still exists a need for dic¬tionaries that serve the language-speaking community as practical tools for addressing diverse communication and learning-oriented needs in the current language policy dispensation. The Isi¬Xhosa National Lexicography Unit (XNLU) is currently working on dictionary projects that attempt to address this situation while at the same time not losing sight of the mandate that the Pan South African National Language Board (PanSALB) placed on all the National Lexicography Units (NLUs). For this to happen, the article argues that the NLU needs to put lexicographic prac¬tice into its historical perspective, i.e. conceiving dictionary projects in the light of existing diction¬aries and lexicographic traditions in the language. Over and above that, there is a need to take into account the recent developments in lexicographic research, adopt co-operative lexicographic prac¬tice and develop a dictionary culture among the isiXhosa-speaking community.
- Full Text:
- Date Issued: 2013
- Authors: Nkomo, Dion , Wababa, Zola
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67526 , vital:29108 , http://dx.doi.org/10.5788/23-1-1219
- Description: Publisher version , This article presents a panoramic and critical overview of isiXhosa lexicography and its impact on the intellectualisation of this indigenous South African language. The history of isi¬Xhosa lexicography dates back more than two centuries. However, there still exists a need for dic¬tionaries that serve the language-speaking community as practical tools for addressing diverse communication and learning-oriented needs in the current language policy dispensation. The Isi¬Xhosa National Lexicography Unit (XNLU) is currently working on dictionary projects that attempt to address this situation while at the same time not losing sight of the mandate that the Pan South African National Language Board (PanSALB) placed on all the National Lexicography Units (NLUs). For this to happen, the article argues that the NLU needs to put lexicographic prac¬tice into its historical perspective, i.e. conceiving dictionary projects in the light of existing diction¬aries and lexicographic traditions in the language. Over and above that, there is a need to take into account the recent developments in lexicographic research, adopt co-operative lexicographic prac¬tice and develop a dictionary culture among the isiXhosa-speaking community.
- Full Text:
- Date Issued: 2013
Karoo volcanic and intrusive rocks: Lesotho and Eastern Cape
- Authors: Marsh, Julian S
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144890 , vital:38388
- Description: The Karoo Igneous Province is one of the classic Mesozoic continental flood basalt provinces. At present erosion levels it comprises numerous eroded remnants of an extensive, thick volcanic sequence (largely lava flows) and a well-exposed subvolcanic intrusive complex of dykes and sheets which are particularly abundant in the underlying Karoo sedimentary strata.
- Full Text:
- Date Issued: 2013
- Authors: Marsh, Julian S
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144890 , vital:38388
- Description: The Karoo Igneous Province is one of the classic Mesozoic continental flood basalt provinces. At present erosion levels it comprises numerous eroded remnants of an extensive, thick volcanic sequence (largely lava flows) and a well-exposed subvolcanic intrusive complex of dykes and sheets which are particularly abundant in the underlying Karoo sedimentary strata.
- Full Text:
- Date Issued: 2013
Knockdown of Hop downregulates RhoC expression, and decreases pseudopodia formation and migration in cancer cell lines:
- Willmer, Tarryn, Contu, Lara, Blatch, Gregory L, Edkins, Adrienne L
- Authors: Willmer, Tarryn , Contu, Lara , Blatch, Gregory L , Edkins, Adrienne L
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165196 , vital:41217 , DOI: 10.1016/j.canlet.2012.09.021
- Description: The Hsp90/Hsp70 organising protein (Hop) is a co-chaperone that mediates the interaction of Hsp90 and Hsp70 molecular chaperones during assembly of Hsp90 complexes in cells. Formation of Hsp90 complexes is a key intermediate step in the maturation and homeostasis of oncoproteins and several hormone receptors. In this paper, we demonstrate that knockdown of Hop decreased migration of Hs578T and MDA-MB-231 breast cancer cells. Hop was identified in isolated pseudopodia fractions; it colocalised with actin in lamellipodia, and co-sedimented with purified actin in vitro. Knockdown of Hop caused a decrease in the level of RhoC GTPase, and significantly inhibited pseudopodia formation in Hs578T cells. Our data suggest that Hop regulates directional cell migration by multiple unknown mechanisms.
- Full Text:
- Date Issued: 2013
- Authors: Willmer, Tarryn , Contu, Lara , Blatch, Gregory L , Edkins, Adrienne L
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165196 , vital:41217 , DOI: 10.1016/j.canlet.2012.09.021
- Description: The Hsp90/Hsp70 organising protein (Hop) is a co-chaperone that mediates the interaction of Hsp90 and Hsp70 molecular chaperones during assembly of Hsp90 complexes in cells. Formation of Hsp90 complexes is a key intermediate step in the maturation and homeostasis of oncoproteins and several hormone receptors. In this paper, we demonstrate that knockdown of Hop decreased migration of Hs578T and MDA-MB-231 breast cancer cells. Hop was identified in isolated pseudopodia fractions; it colocalised with actin in lamellipodia, and co-sedimented with purified actin in vitro. Knockdown of Hop caused a decrease in the level of RhoC GTPase, and significantly inhibited pseudopodia formation in Hs578T cells. Our data suggest that Hop regulates directional cell migration by multiple unknown mechanisms.
- Full Text:
- Date Issued: 2013
Land claims and the pursuit of co-management on four protected areas in South Africa
- Cundill, Georgina, Thondhlana, Gladman, Sisitka, Lawrence, Shackleton, Sheona, Blorea, M
- Authors: Cundill, Georgina , Thondhlana, Gladman , Sisitka, Lawrence , Shackleton, Sheona , Blorea, M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391223 , vital:68632 , xlink:href="https://doi.org/10.1016/j.landusepol.2013.05.016"
- Description: Successful land claims on protected areas by previously disenfranchised communities often result in co-management agreements between claimant communities and state conservation agencies. South Africa, in particular, has pursued co-management as the desired outcome of land claims on its protected areas. We review four cases of co-management on protected areas in South Africa, and reflect on the appropriateness of the pursuit of co-management as the preferred outcome of land claims. Despite promises of pro-poor, democratically informed management, the practical experience of co-management has seen the continuation of the status quo in terms of conservation, with very few material benefits for claimant communities and limited sharing of responsibilities and decision-making functions. The findings underscore two deep challenges facing co-management in cases of land claims worldwide. First, during land claims negotiations in cases involving protected areas, the state cannot be expected to represent the best interests of its citizens (the land claimants), while simultaneously seeking to meet national and international obligations for protected area coverage. Second, the concept of democratic co-management may sit uncomfortably beside the realities of managing loss-making protected areas with ever-shrinking conservation budgets. Where co-management agreements have already been signed, ensuring that new landowners do indeed have a say in management should form the driving focus for co-management practice going forward.
- Full Text:
- Date Issued: 2013
- Authors: Cundill, Georgina , Thondhlana, Gladman , Sisitka, Lawrence , Shackleton, Sheona , Blorea, M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391223 , vital:68632 , xlink:href="https://doi.org/10.1016/j.landusepol.2013.05.016"
- Description: Successful land claims on protected areas by previously disenfranchised communities often result in co-management agreements between claimant communities and state conservation agencies. South Africa, in particular, has pursued co-management as the desired outcome of land claims on its protected areas. We review four cases of co-management on protected areas in South Africa, and reflect on the appropriateness of the pursuit of co-management as the preferred outcome of land claims. Despite promises of pro-poor, democratically informed management, the practical experience of co-management has seen the continuation of the status quo in terms of conservation, with very few material benefits for claimant communities and limited sharing of responsibilities and decision-making functions. The findings underscore two deep challenges facing co-management in cases of land claims worldwide. First, during land claims negotiations in cases involving protected areas, the state cannot be expected to represent the best interests of its citizens (the land claimants), while simultaneously seeking to meet national and international obligations for protected area coverage. Second, the concept of democratic co-management may sit uncomfortably beside the realities of managing loss-making protected areas with ever-shrinking conservation budgets. Where co-management agreements have already been signed, ensuring that new landowners do indeed have a say in management should form the driving focus for co-management practice going forward.
- Full Text:
- Date Issued: 2013
Lechwe Trust Collection:
- Authors: Simbao, Ruth K
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147547 , vital:38648 , https://doi.org/10.1162/afar.2005.38.3.78
- Description: The caustic humor of The Arts Delegate (2000), by the cartoonist popularly known in Zambia as" Yuss," captures a dynamic readily found in the Zambian art world.
- Full Text:
- Date Issued: 2013
- Authors: Simbao, Ruth K
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147547 , vital:38648 , https://doi.org/10.1162/afar.2005.38.3.78
- Description: The caustic humor of The Arts Delegate (2000), by the cartoonist popularly known in Zambia as" Yuss," captures a dynamic readily found in the Zambian art world.
- Full Text:
- Date Issued: 2013
Local setting influences the quantity of household food waste in mid-sized South African towns
- Chakona, Gamuchirai, Shackleton, Charlie M
- Authors: Chakona, Gamuchirai , Shackleton, Charlie M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67289 , vital:29067 , https://doi.org/10.1371/journal.pone.0189407
- Description: publisher version , From Introduction: The world faces a food security challenge with approximately 868 million people undernourished and about two billion people suffering from the negative health consequences of micronutrient deficiencies [1]. Yet, at least one-third of food produced for human consumption is lost or wasted along the food chain between farm and fork [2–7]. Food waste refers to wholesome edible material intended for human consumption, arising at any point in the food supply chain that is instead discarded, lost, degraded or consumed by pests [8]. Food loss is defined as the decrease in food quantity or quality which makes it unfit for human consumption [9]. According to the European Commission [10], food waste is composed of raw or cooked food materials such as vegetable peelings, meat trimmings and spoiled or excess ingredients or prepared food as well as bones, carcasses and organs. However, food waste can be measured only for edible products that are directed to human consumption [6]. Food losses take place at production, postharvest and processing stages in the food supply chain and the food losses that occur at the end of the food chain (retail and final consumption) are called “food waste” [11]. In our study food waste refers to food losses that occur at the end of the food chain (final consumption at household or consumer level) which include edible products that are directed to human consumption and are discarded when not consumed for various reasons. It is related to consumers’ behaviour [6,11] and it includes food loss before, during or after meal preparation in the household. , The research was funded by VW foundation under the Livelihoods Urbanisation and Natural Resources in Africa (LUNA) project through Freiburg University, Germany. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of this manuscript
- Full Text:
- Date Issued: 2013
- Authors: Chakona, Gamuchirai , Shackleton, Charlie M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67289 , vital:29067 , https://doi.org/10.1371/journal.pone.0189407
- Description: publisher version , From Introduction: The world faces a food security challenge with approximately 868 million people undernourished and about two billion people suffering from the negative health consequences of micronutrient deficiencies [1]. Yet, at least one-third of food produced for human consumption is lost or wasted along the food chain between farm and fork [2–7]. Food waste refers to wholesome edible material intended for human consumption, arising at any point in the food supply chain that is instead discarded, lost, degraded or consumed by pests [8]. Food loss is defined as the decrease in food quantity or quality which makes it unfit for human consumption [9]. According to the European Commission [10], food waste is composed of raw or cooked food materials such as vegetable peelings, meat trimmings and spoiled or excess ingredients or prepared food as well as bones, carcasses and organs. However, food waste can be measured only for edible products that are directed to human consumption [6]. Food losses take place at production, postharvest and processing stages in the food supply chain and the food losses that occur at the end of the food chain (retail and final consumption) are called “food waste” [11]. In our study food waste refers to food losses that occur at the end of the food chain (final consumption at household or consumer level) which include edible products that are directed to human consumption and are discarded when not consumed for various reasons. It is related to consumers’ behaviour [6,11] and it includes food loss before, during or after meal preparation in the household. , The research was funded by VW foundation under the Livelihoods Urbanisation and Natural Resources in Africa (LUNA) project through Freiburg University, Germany. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of this manuscript
- Full Text:
- Date Issued: 2013
Making meaning of citizenship: how ‘born frees’ use media in South Africa's democratic evolution
- Malila, Vanessa, Oeofsen, Marietjie, Garman, Anthea
- Authors: Malila, Vanessa , Oeofsen, Marietjie , Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159790 , vital:40344 , DOI: 10.1080/02500167.2013.852598
- Description: By examining young people's habits of using the media in relation to citizenship, this article responds to calls that the starting point for research into citizenship and democracy should be the perspectives of citizens themselves. Drawing on both quantitative and qualitative research with young South Africans (the ‘born free’ generation), the study sought to gain insight into how young people use media to make sense of notions of citizenship and participatory democracy in ways that are relevant and reliable to their everyday lives.
- Full Text:
- Date Issued: 2013
- Authors: Malila, Vanessa , Oeofsen, Marietjie , Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159790 , vital:40344 , DOI: 10.1080/02500167.2013.852598
- Description: By examining young people's habits of using the media in relation to citizenship, this article responds to calls that the starting point for research into citizenship and democracy should be the perspectives of citizens themselves. Drawing on both quantitative and qualitative research with young South Africans (the ‘born free’ generation), the study sought to gain insight into how young people use media to make sense of notions of citizenship and participatory democracy in ways that are relevant and reliable to their everyday lives.
- Full Text:
- Date Issued: 2013
Marxisms past and present
- Helliker, Kirk D, Vale, Peter C J
- Authors: Helliker, Kirk D , Vale, Peter C J
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71263 , vital:29825 , https://doi.org/10.1177/0725513612470532
- Description: Marxism was central to the understanding of South Africa’s struggle for freedom. This article provides a critical analysis of Marxist literature on South Africa since the 1970s, drawing out its relevance for contemporary analyses of the post-apartheid state and for radical politics today. It suggests that while the literature offered important insights into the character of the apartheid state, it failed to provide a critical appraisal of the state per se. Moreover, the capturing of state power by the liberation movement was not grounded in an understanding of the oppressive character of the state-form. The undermining of mainstream Marxism under neo-liberalizing conditions in post-apartheid South Africa has opened up the prospects for anti-statist radical libertarian thinking (including autonomist Marxism), and this thinking is consistent with the practices of certain autonomist popular politics currently emerging. Social theorizing on South Africa has had a complex relationship with Marxism. This article is interested in drawing on this experience in an effort to understand its implications for the ‘new’ South Africa where, 20 years after apartheid’s formal ending, social transformation remains caught in the logic not of Marxism but neo-liberalizing capitalism.
- Full Text: false
- Date Issued: 2013
- Authors: Helliker, Kirk D , Vale, Peter C J
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71263 , vital:29825 , https://doi.org/10.1177/0725513612470532
- Description: Marxism was central to the understanding of South Africa’s struggle for freedom. This article provides a critical analysis of Marxist literature on South Africa since the 1970s, drawing out its relevance for contemporary analyses of the post-apartheid state and for radical politics today. It suggests that while the literature offered important insights into the character of the apartheid state, it failed to provide a critical appraisal of the state per se. Moreover, the capturing of state power by the liberation movement was not grounded in an understanding of the oppressive character of the state-form. The undermining of mainstream Marxism under neo-liberalizing conditions in post-apartheid South Africa has opened up the prospects for anti-statist radical libertarian thinking (including autonomist Marxism), and this thinking is consistent with the practices of certain autonomist popular politics currently emerging. Social theorizing on South Africa has had a complex relationship with Marxism. This article is interested in drawing on this experience in an effort to understand its implications for the ‘new’ South Africa where, 20 years after apartheid’s formal ending, social transformation remains caught in the logic not of Marxism but neo-liberalizing capitalism.
- Full Text: false
- Date Issued: 2013
MCD spectroscopy and TD-DFT calculations of a naphthalene-ring-bridged coplanar binuclear phthalocyanine dimer
- Mack, John, Liang, Xu, Dubinina, Tatiana V, Tomilova, Larisa G, Nyokong, Tebello, Kobayashi, Nagao
- Authors: Mack, John , Liang, Xu , Dubinina, Tatiana V , Tomilova, Larisa G , Nyokong, Tebello , Kobayashi, Nagao
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232511 , vital:49998 , xlink:href="https://doi.org/10.1142/S1088424613500259"
- Description: Magnetic circular dichroism (MCD) spectroscopy and TD-DFT calculations are used to analyze the electronic structure and optical properties of an alkyl-substituted naphthalene-ring-bridged coplanar binuclear phthalocyanine dimer. An analysis of the MCD spectrum of the naphthalene-ring-bridged dimer relative to those of benzene-bridged compounds reported previously, demonstrates that there is a significantly weaker interaction between the two phthalocyanine rings. TD-DFT results obtained using the B3LYP functional with 6–31G basis sets were found to be problematic. Closer agreement with the experimental data is obtained when the CAM-B3LYP functional is used instead. The naphthalene-ring-bridged compound is found to be unsuitable for use as a photosensitizer for the formation of singlet oxygen, because the ΦT values are negligible.
- Full Text:
- Date Issued: 2013
- Authors: Mack, John , Liang, Xu , Dubinina, Tatiana V , Tomilova, Larisa G , Nyokong, Tebello , Kobayashi, Nagao
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232511 , vital:49998 , xlink:href="https://doi.org/10.1142/S1088424613500259"
- Description: Magnetic circular dichroism (MCD) spectroscopy and TD-DFT calculations are used to analyze the electronic structure and optical properties of an alkyl-substituted naphthalene-ring-bridged coplanar binuclear phthalocyanine dimer. An analysis of the MCD spectrum of the naphthalene-ring-bridged dimer relative to those of benzene-bridged compounds reported previously, demonstrates that there is a significantly weaker interaction between the two phthalocyanine rings. TD-DFT results obtained using the B3LYP functional with 6–31G basis sets were found to be problematic. Closer agreement with the experimental data is obtained when the CAM-B3LYP functional is used instead. The naphthalene-ring-bridged compound is found to be unsuitable for use as a photosensitizer for the formation of singlet oxygen, because the ΦT values are negligible.
- Full Text:
- Date Issued: 2013
Media, citizenship and the politics of belonging in contemporary South Africa:
- Milton, Viola C, Wasserman, Herman, Garman, Anthea
- Authors: Milton, Viola C , Wasserman, Herman , Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159802 , vital:40345 , DOI: 10.1080/02500167.2013.864447
- Description: Drawing on a wide range of theoretical and empirical studies, the articles in this special issue examine issues of citizenship and belonging in South Africa. Questions of belonging and citizenship are neither novel, nor particular to South Africa – they have been high on the intellectual (and popular) agenda internationally since at least the early 1990s. Yet South Africa's history of artificially separating and defining its citizens in the racial regimes of colonialism and apartheid still reverberates today, as is reflected in the continued inequalities marring South African society
- Full Text:
- Date Issued: 2013
- Authors: Milton, Viola C , Wasserman, Herman , Garman, Anthea
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159802 , vital:40345 , DOI: 10.1080/02500167.2013.864447
- Description: Drawing on a wide range of theoretical and empirical studies, the articles in this special issue examine issues of citizenship and belonging in South Africa. Questions of belonging and citizenship are neither novel, nor particular to South Africa – they have been high on the intellectual (and popular) agenda internationally since at least the early 1990s. Yet South Africa's history of artificially separating and defining its citizens in the racial regimes of colonialism and apartheid still reverberates today, as is reflected in the continued inequalities marring South African society
- Full Text:
- Date Issued: 2013
Metal nanoparticles caused death of metastatic MDA-MB-231 breast cancer cells:
- Adeyemi, Oluyomi, Edkins, Adrienne L, Whiteley, Christopher
- Authors: Adeyemi, Oluyomi , Edkins, Adrienne L , Whiteley, Christopher
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164797 , vital:41173 , DOI: 10.1016/j.toxlet.2013.05.599
- Description: Available data on the toxicity of nanoparticles is a subject of controversy. The interaction of nanoparticles with biological systems including living cells has become one of the most urgent areas of collaborative research in materials science and biology. This is due to the fact that toxicity of nanomaterials are ill defined in terms of cause–effect relationships.
- Full Text:
- Date Issued: 2013
- Authors: Adeyemi, Oluyomi , Edkins, Adrienne L , Whiteley, Christopher
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164797 , vital:41173 , DOI: 10.1016/j.toxlet.2013.05.599
- Description: Available data on the toxicity of nanoparticles is a subject of controversy. The interaction of nanoparticles with biological systems including living cells has become one of the most urgent areas of collaborative research in materials science and biology. This is due to the fact that toxicity of nanomaterials are ill defined in terms of cause–effect relationships.
- Full Text:
- Date Issued: 2013
Mg/Triethylammonium Formate: A Useful System for Reductive Dimerization of Araldehydes into Pinacols;Nitroarenes into Azoarenes and Azoarenes into Hydrazoarenes
- Pamar, M Geeter, Govender, P, Muthusamy, K, Krause, Rui W M
- Authors: Pamar, M Geeter , Govender, P , Muthusamy, K , Krause, Rui W M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125107 , vital:35729 , https://doi.org/10.13005/ojc/290316
- Description: Studies are reported which describes the effectiveness of triethylammonium formate in the presence of magnesium for the efficient intermolecular pinacol coupling using MeOH as solvent. Various aromatic carbonyls underwent smooth reductive coupling to give the corresponding 1,2-diols. A series of azo compounds were obtained by the reductive coupling of nitroaromatics while azo compounds were reduced to the corresponding hydrazoarenes by this system. There was no adverse effect on the other reducible and hydrogenolysable groups such as ether linkage, hydroxy and halogens. The reactions are clean, high yielding and inexpensive. All the reactions proceeded smoothly at ambient temperature.
- Full Text:
- Date Issued: 2013
- Authors: Pamar, M Geeter , Govender, P , Muthusamy, K , Krause, Rui W M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125107 , vital:35729 , https://doi.org/10.13005/ojc/290316
- Description: Studies are reported which describes the effectiveness of triethylammonium formate in the presence of magnesium for the efficient intermolecular pinacol coupling using MeOH as solvent. Various aromatic carbonyls underwent smooth reductive coupling to give the corresponding 1,2-diols. A series of azo compounds were obtained by the reductive coupling of nitroaromatics while azo compounds were reduced to the corresponding hydrazoarenes by this system. There was no adverse effect on the other reducible and hydrogenolysable groups such as ether linkage, hydroxy and halogens. The reactions are clean, high yielding and inexpensive. All the reactions proceeded smoothly at ambient temperature.
- Full Text:
- Date Issued: 2013
Microbial agents for control of aquatic weeds and their role in integrated management
- Authors: Ray, P , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423550 , vital:72071 , xlink:href="https://www.cabidigitallibrary.org/doi/abs/10.1079/PAVSNNR20128014"
- Description: Aquatic ecosystems throughout the world are threatened by the presence of invasive aquatic plants, both floating and submerged. Some of the aquatic species, such as water hyacinth (Eichhornia crassipes [Mart.] Solms), alligator weed, Alternanthera philoxeroides (Mart.), giant salvinia, Salvinia molesta D.S. Mitchell and water lettuce (Pistia stratiotes L.), Griseb. despite being relatively minor problems in their native range, have become major invaders of aquatic habitats in other parts of the world after having escaped from their natural enemies. Unchecked growth of aquatic vegetation is generally undesirable and reduces the value of the water resource. Despite adopting all control options including manual, mechanical, chemical and classical biological, the problem persists. The current weed management is oriented towards finding approaches that are effective in controlling the weed and reducing environmental contamination from herbicides. Plant pathogens have been gaining increasing attention and interest among those concerned with developing environmentally friendly, effective and compatible approaches for integrated management of the noxious weeds. This paper discusses some of the major microbial agents associated with aquatic weeds and their increasing role in integrated weed management.
- Full Text:
- Date Issued: 2013
- Authors: Ray, P , Hill, Martin P
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423550 , vital:72071 , xlink:href="https://www.cabidigitallibrary.org/doi/abs/10.1079/PAVSNNR20128014"
- Description: Aquatic ecosystems throughout the world are threatened by the presence of invasive aquatic plants, both floating and submerged. Some of the aquatic species, such as water hyacinth (Eichhornia crassipes [Mart.] Solms), alligator weed, Alternanthera philoxeroides (Mart.), giant salvinia, Salvinia molesta D.S. Mitchell and water lettuce (Pistia stratiotes L.), Griseb. despite being relatively minor problems in their native range, have become major invaders of aquatic habitats in other parts of the world after having escaped from their natural enemies. Unchecked growth of aquatic vegetation is generally undesirable and reduces the value of the water resource. Despite adopting all control options including manual, mechanical, chemical and classical biological, the problem persists. The current weed management is oriented towards finding approaches that are effective in controlling the weed and reducing environmental contamination from herbicides. Plant pathogens have been gaining increasing attention and interest among those concerned with developing environmentally friendly, effective and compatible approaches for integrated management of the noxious weeds. This paper discusses some of the major microbial agents associated with aquatic weeds and their increasing role in integrated weed management.
- Full Text:
- Date Issued: 2013
Modeling Complex Networked Audio Devices
- Eales, Andrew, Foss, Richard
- Authors: Eales, Andrew , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427012 , vital:72408 , https://www.aes.org/e-lib/browse.cfm?elib=16706
- Description: The lack of a universally accepted standard control protocol, as well as a lack of interoperability among existing protocols, limits how audio software can support a wide range of networked devices. To address this issue, the authors propose an abstract standard audio device model that is independent of any particular technology. This standard device model supports service discovery and enumeration, while also specifying device parts, the representation of parameter addresses, and the visual appearance of controls. The discussion explores the model in the context of a self-configuring discovery and control environment. Within this environment, controllers do not “pull” descriptions from a device; but rather, devices “push” full-service implementations to controllers.
- Full Text:
- Date Issued: 2013
- Authors: Eales, Andrew , Foss, Richard
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427012 , vital:72408 , https://www.aes.org/e-lib/browse.cfm?elib=16706
- Description: The lack of a universally accepted standard control protocol, as well as a lack of interoperability among existing protocols, limits how audio software can support a wide range of networked devices. To address this issue, the authors propose an abstract standard audio device model that is independent of any particular technology. This standard device model supports service discovery and enumeration, while also specifying device parts, the representation of parameter addresses, and the visual appearance of controls. The discussion explores the model in the context of a self-configuring discovery and control environment. Within this environment, controllers do not “pull” descriptions from a device; but rather, devices “push” full-service implementations to controllers.
- Full Text:
- Date Issued: 2013
Morphological and genetic characterization of a South African Plutella xylostella granulovirus (plxy GV) isolate
- Abdulkadir, Fatima, Marsberg, Tamryn, Knox, Caroline M, Hill, Martin P, Moore, Sean D
- Authors: Abdulkadir, Fatima , Marsberg, Tamryn , Knox, Caroline M , Hill, Martin P , Moore, Sean D
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406117 , vital:70240 , xlink:href="https://hdl.handle.net/10520/EJC132828"
- Description: Plutella xylostella (L.) (Lepidoptera: Plutellidae), also known as diamondback moth, is a destructive insect pest of cruciferous crops (Talekar and Shelton 1993; Shelton 2004). The pest occurs wherever its host plants are cultivated and the global annual cost of damage and control is estimated to be US$4-5 billion (Zalucki et al. 2012). The extensive use of synthetic pesticides for control combined with the high fecundity of P. xylostella has resulted in the pest developing resistance to nearly all classes of insecticides (Grzywacz et al. 2009). Moreover, these chemicals have negative environmental implications and may affect non-target species, some of which are natural enemies of the pest.
- Full Text:
- Date Issued: 2013
- Authors: Abdulkadir, Fatima , Marsberg, Tamryn , Knox, Caroline M , Hill, Martin P , Moore, Sean D
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/406117 , vital:70240 , xlink:href="https://hdl.handle.net/10520/EJC132828"
- Description: Plutella xylostella (L.) (Lepidoptera: Plutellidae), also known as diamondback moth, is a destructive insect pest of cruciferous crops (Talekar and Shelton 1993; Shelton 2004). The pest occurs wherever its host plants are cultivated and the global annual cost of damage and control is estimated to be US$4-5 billion (Zalucki et al. 2012). The extensive use of synthetic pesticides for control combined with the high fecundity of P. xylostella has resulted in the pest developing resistance to nearly all classes of insecticides (Grzywacz et al. 2009). Moreover, these chemicals have negative environmental implications and may affect non-target species, some of which are natural enemies of the pest.
- Full Text:
- Date Issued: 2013
Movement patterns and habitat selection of invasive African sharptooth catfish
- Kadye, Wilbert T, Booth, Anthony J
- Authors: Kadye, Wilbert T , Booth, Anthony J
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125276 , vital:35767 , http://dx.doi.10.1111/j.1469-7998.2012.00960.x
- Description: Information on the movement behaviour and habitat use by non-native invasive African catfish Clarias gariepinus is crucial in understanding and possibly mitigating its potential impacts. The aim of this study was to examine catfish movement and habitat selection within an invaded impoundment in the Eastern Cape, South Africa. Acoustic telemetry data for 10 tagged catfish were analyzed to identify spatial patterns in home ranges and seasonal changes in habitat associations. Long-distance movements were observed for most catfish from common central release point, whereas short-distance movements defined their home ranges and utilization distributions that were categorized as localized within single or multiple habitats. Habitat selection was non-random with most catfish utilizing the shallow river mouth and upper section of the reservoir that were dominated by a rocky substratum interspersed with submerged trees. These localities were likely to be preferred for spawning and/or feeding. Utilization of these habitats by catfish is likely to be associated with probable impact due to predation and interference competition for feeding and breeding grounds with other species. Although most catfish maintained their home ranges throughout the study, seasonal shifts in habitat use, which was reflected by the utilization of deep and silt-dominated habitats, were also observed for some catfish. Non-random habitat use and homing behaviour within single and multiple habitats by non-native sharptooth catfish suggests that its impact within the invaded habitats may be associated with particular habitats both at broad spatial and temporal scales. Protection of habitats from catfish invasion should be considered as a management option to conserve native biota.
- Full Text:
- Date Issued: 2013
- Authors: Kadye, Wilbert T , Booth, Anthony J
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125276 , vital:35767 , http://dx.doi.10.1111/j.1469-7998.2012.00960.x
- Description: Information on the movement behaviour and habitat use by non-native invasive African catfish Clarias gariepinus is crucial in understanding and possibly mitigating its potential impacts. The aim of this study was to examine catfish movement and habitat selection within an invaded impoundment in the Eastern Cape, South Africa. Acoustic telemetry data for 10 tagged catfish were analyzed to identify spatial patterns in home ranges and seasonal changes in habitat associations. Long-distance movements were observed for most catfish from common central release point, whereas short-distance movements defined their home ranges and utilization distributions that were categorized as localized within single or multiple habitats. Habitat selection was non-random with most catfish utilizing the shallow river mouth and upper section of the reservoir that were dominated by a rocky substratum interspersed with submerged trees. These localities were likely to be preferred for spawning and/or feeding. Utilization of these habitats by catfish is likely to be associated with probable impact due to predation and interference competition for feeding and breeding grounds with other species. Although most catfish maintained their home ranges throughout the study, seasonal shifts in habitat use, which was reflected by the utilization of deep and silt-dominated habitats, were also observed for some catfish. Non-random habitat use and homing behaviour within single and multiple habitats by non-native sharptooth catfish suggests that its impact within the invaded habitats may be associated with particular habitats both at broad spatial and temporal scales. Protection of habitats from catfish invasion should be considered as a management option to conserve native biota.
- Full Text:
- Date Issued: 2013
Nanoconjugates of CdTe@ ZnS quantum dots with cobalt tetraamino-phthalocyanine
- Adegoke, Oluwasesan, Antunes, Edith M, Nyokong, Tebello
- Authors: Adegoke, Oluwasesan , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242049 , vital:50996 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.02.010"
- Description: The covalent linking of thiol-capped CdTe@ZnS QDs with cobalt tetraamino-phthalocyanine (CoTAPc) has been successfully carried out. Several techniques such as time-resolved fluorescence measurements, thermal gravimetric analysis,transmissionelectronmicroscopy andspectrophotometric techniques were employed to characterize the nanoconjugates. Covalent binding of the QDs with CoTAPc resulted in the fluorescence quenching of the former. In the presence of varying concentrations of superoxide anion (O2 •−), the fluorescence of the QDs in the conjugate was gradually enhanced and the detection limits obtained were 2.1 and 2.4 nM for the smaller and larger QDs, respectively. Based on the excellent selectivity displayed by the nanoconjugates towards O2 •− over other biologically active species, a potential nanosensor was developed.
- Full Text:
- Date Issued: 2013
- Authors: Adegoke, Oluwasesan , Antunes, Edith M , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242049 , vital:50996 , xlink:href="https://doi.org/10.1016/j.jphotochem.2013.02.010"
- Description: The covalent linking of thiol-capped CdTe@ZnS QDs with cobalt tetraamino-phthalocyanine (CoTAPc) has been successfully carried out. Several techniques such as time-resolved fluorescence measurements, thermal gravimetric analysis,transmissionelectronmicroscopy andspectrophotometric techniques were employed to characterize the nanoconjugates. Covalent binding of the QDs with CoTAPc resulted in the fluorescence quenching of the former. In the presence of varying concentrations of superoxide anion (O2 •−), the fluorescence of the QDs in the conjugate was gradually enhanced and the detection limits obtained were 2.1 and 2.4 nM for the smaller and larger QDs, respectively. Based on the excellent selectivity displayed by the nanoconjugates towards O2 •− over other biologically active species, a potential nanosensor was developed.
- Full Text:
- Date Issued: 2013