Showing items 61 - 80 of 113

Your selections:

The impact of institutional cultures on student’s wellbeing among postgraduate students: the case of Nelson Mandela University in South Africa

  • Authors: Lebelo, Mpho
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54450 , vital:46549
  • Description: Increasingly, students across the world in various tertiary institutions are faced with many challenges ranging from financial difficulties, accommodation, academic exclusion and many other challenges. Subsequently, the students’ academic performance suffers due to these challenges. This thesis therefore aims to focus on the perspectives of the post-graduate students at the Nelson Mandela University regarding the notion of wellbeing. This thesis attempts to uses a sociological indigenous perspective of wellbeing of “impilo” in describing well-being. Therefore, the thesis uses wellness as a conceptual framework to understand the challenges faced by postgraduate students at Nelson Mandela University. The thesis was conducted in Port Elizabeth, at Nelson Mandela University campus of Summerstrand focusing on post-graduate students in faculty of humanities. A qualitative research design and qualitative digital ethnographic research methodology was chosen as suitable for answering the research question. Data was collected using semi-structured interviews and transcribed verbatim. Data analysis included identifying consistent themes around notions of well-being and experiences of changing university culture in the responses. The thesis main findings reveal the impact of how the changing university institutional culture impacts post-graduate student’s wellbeing. The research found that students are affected by institutional cultures and this is narrated through their experience of university life and their reflections on #MustFall movements. The participants have detailed how the cultures in the university have a greater impact on the well-being on student because the university is more than just a place of learning but their home. The participants also detailed new colloquial ways of describing well-being using the term “inerves” and “umgowo” are general ways of describing their well-being. The dissertation has contributed to the limited body of knowledge in the context of post-graduate students experience and conception of well-being in the South African higher education. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
  • Full Text:
  • Date Issued: 2021-12

The impact of transformed landscapes on the resource selection and occupancy of specialized browsing species in a lowland fynbos and renosterveld ecosystem

  • Authors: Swanepoel, Hermanus Izak Johannes
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54132 , vital:46308
  • Description: Human activities have dramatically transformed the natural environment over the last century. In most cases these activities have resulted in the destruction and fragmentation of habitats. However, in some areas the transformation of landscapes through agriculture have created novel habitats which could benefit some species. The effect of these transformed landscapes on the resource selection and occupancy of antelope species in different vegetation types such as fynbos and renosterveld are still understudied. In order to investigate this,we conducted a study in the Overberg region of the Western Cape, South Africa. We studied theoccupancy and habitat useof five specialist browsing species (Tragelaphus scriptus sylvaticus(bushbuck), Rhaphicerus melanotis(cape grysbok), Sylvicapra grimmia(common duiker), Palea Capreolus(grey rhebok) and Rhaphicerus campestris(steenbok)) within a transformed landscape. We collected speciesdetection/ non-detectionand presence/ absence data using camera traps and road strip counts.Usinga single season, single species occupancy framework as a surrogate for habitat usewedeterminedhow transformed landscapes affected their occupancy. Using aniche factor analysis and resource selection functions wedetermine how transformed landscapes affected the resource selectionof these species. Our results from the resource selection analysis indicated that steenbok, grey rhebok, andcommon duiker included crops such as wheat and planted pastures in their resource selection while also including natural vegetation. Cape grysbok and bushbuck selected predominantly for natural vegetation areas such as critical biodiversity areas and ecological support areas while also including some crops in their resource selection. Our results from the occupancy analysis indicatedthat steenbok, grey rhebok and common duiker had a higher occupancy in the transformed landscape than in the natural landscape. Bushbuck and Cape grysbok showed little to no difference in their occupancy between land use types. The insight provided by our results will allow practitioners to maximise the potentialof these mosaic landscape in the Overberg for mammal conservation.The study also provides a baseline from which further research and monitoring programs can be developed to further understand the dynamics of this landscape. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
  • Full Text:
  • Date Issued: 2021-12

The importance of public officials’ knowledge and understanding of the constitutional principles of public administration

  • Authors: Zameko, Zamuxolo
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54596 , vital:46732
  • Description: Public officials in South Africa have been accused of lacking accountability, transparency, corruption, inefficiencies, unethical practices and a general unmotivated approach to service delivery. Section 195 of the 1996 constitution emphasises the need for public officials to be efficient, effective and not to be partial in their execution of duty. On that basis the research sought to investigate whether the public officials can improve on their performance if they are exposed to and are knowledgeable of the constitution. The study utilized a qualitative research method and a document analysis in which documents which served as sources of information were selected based on their relevance to the subject area of Public Administration. The documents selected were legal instruments used to enforce the operations of public officials including the Constitution of South Africa (1996), Batho Pele, White Paper on the Transformation of the Public Service, 1995; Promotion of Access to Information (Act no 2 of 2000 and Promotion of Equality & Prevention of Unfair Discrimination (Ac no 4 of 2000) Findings of the research indicate that key skills of the public officials like effective communication, change management, conflict resolution, decision-making, negotiation and accountability can be enhanced if they are knowledgeable of their constitutional mandate. The Public Service board should among others emphasize on constitutional principles training of all its employees upon recruitment such that they are aware of the public expectations. Continuous on the job training should also be offered to public officials so that their operations are always adjusted to the prevailing environmental and technological conditions. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
  • Full Text:
  • Date Issued: 2021-12

The synthesis of anastrazole intermediates using continuous flow systems

  • Authors: Tanyi, Sam Tambi
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54116 , vital:46304
  • Description: In this study, the continuous flow synthesis of anastrozole intermediates were investigated using mesitylene as starting material. Anastrozole is an important drug used for the treatment of breast cancer. In the first step, mesitylene was brominated using N-bromosuccinimide to obtain 3,5-bis(bromomethyl)toluene. Selectivity became an issue due to the formation of two by-products; namely 1,3,5-tris(bromomethyl) benzene (the tribrominated by-product) and 1-(bromomethyl)-3,5-dimethylbenzene (the monobrominated by-product). Since the reaction parameters can be more precisely controlled in flow chemistry systems, we were able to optimize the formation the desired product 3,5-bis(bromomethyl)toluene. The reaction was initially optimized ina 15μLChemtrix glass micro reactor resulting in 100%conversion with 95%selectivity towards the desired product 3,5-bis(bromomethyl)toluenein 15 seconds, with a throughput of 0.006 g/h. The reaction was then scaled up in a 1.7 mLLTF reactor, equally yielding 100%conversion with 95%selectivityin 4minutes, with a throughput of2.01g/h. The bromination of mesitylene was also attempted in a homemade photochemical reactor consisting of a 3.02 polytetrafluoroethylene coil reactor and BLE-6T365 UV lamp. In this photochemical reactor, although 100%conversionwas again obtained only75%selectivity was achieved in 20minutes, with a throughput of 0.025g/h. This drop in selectivity was attributed to poorer mixing in the larger polytetrafluoroethylene coil reactor and possibly insufficient light penetration. The next step, involving the cyanation of 3,5-bis(bromomethyl)toluene to obtain 2,2'-(5-methyl-1,3-phenylene) diacetonitrilegave 100%conversion in 1 minute at 190 °C in a 1.7 mLLTFreactor, with a throughput of 5.2g/h. The subsequent methylation of 3,5-bis(cyanomethyl)toluene to obtain3,5-bis(1-cyano-1-methylethyl) toluene was investigated using a1mLpolytetrafluoroethylenecoil reactor, ultimatelyachieving99%conversionat40 °Cin 8minutes, with a throughput of 0.045g/h. Next, the bromination of3,5-bis(1-cyano-1-methylethyl)toluene using N-bromosuccinimideto yield 2,2'-(5-bromomethyl-1,3-phenylene)di(2-methyl propionitrile) gave 100%conversion at 120 °C in 4 minutes, with a throughput of 0.35g/h. Lastly, the multistep synthesis of 3,5-bis(cyanomethyl)toluene was done in two integrated 1.7 mLLTF reactors, using the predetermined optimum conditions to achieve 94%conversion towards 3,5-bis(cyanomethyl)toluene with a total r , Thesis (MSc) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
  • Full Text:
  • Date Issued: 2021-12

The synthesis, empirical and theoretical studies of various (N→B) diarylborinate esters

  • Authors: Manana, Pholani Sakhile
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10948/53869 , vital:46027
  • Description: A series of core-functionalized borinic acids was synthesized from Grignard reagents and tributylborate and reacted with ethanolamine, amino acids, 2-pyridylmethanol as well as 2-(ethyl amino ethanol). Among the borinic acids synthesized were the ones bearing: para-(2, 15, 16, 22, 27)-methyl, (3, 20, 25)-chloro, (4, 23, 26)-fluoro, (5)-methoxy; meta-(7, 17)-methyl, (9)-fluoro; ortho-(6)-methyl, (8)-chloro, (10, 18, 19)-methoxy substituents on their respective aromatic systems. All compounds obtained by condensation of the borinic acids with the aforementioned nitrogen-containing substrates were characterized structurally by means of diffraction studies based on single crystals and found to constitute chelate esters/amides featuring covalent B-O and dative N→B bonds. The chelate compounds researched in this study could be classified into four families and represent the compounds: ethanol amine: (1) 2,2-diphenyl-1,3,2-oxazaborolidines, (2) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (3) 2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (4) 2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (5) 2,2-bis(p-methoxyphenyl)-1,3,2-oxazaborolidines, (6) 2,2-bis(o-tolyl)-1,3,2-oxazaborolidines, (7) 2,2-bis(m-tolyl)-1,3,2-oxazaborolidines, (8) 2,2-bis(o-chlorophenyl)-1,3,2-oxazaborolidines, (9) 2,2-bis(m-fluorophenyl)-1,3,2-oxazaborolidines, (10) 2,2-bis(o-methoxyphenyl)-1,3,2-oxazaborolidines. α-amino acids : (14) 4-methyl-2,2-diphenyl-1,3,2-oxazaborolidin-5-ones, (15) 2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (16) 4-methyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidin-5-ones, (17) 4-isopropyl-2,2-bis(m-tolyl)-1,3,2-oxazaborolidin-5-ones, (18) 4-methyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (19) 4-acetamidyl-2,2-bis(o-methoxyphenyl)-1,3,2- oxazaborolidin-5-ones, (20) 4-phenylethane-2,2-bis(p-chlorophenyl)-1,3,2 oxazaborolidin-5-ones. 2-pyridylmethanol: (21) 1,3-hydroxypyridyl-2,2-diphenyl 1,3,2-oxazaborolidines, (22) 1,3-hydroxypyridyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines, (23) 1,3-hydroxypyridyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines 2-(ethyl amino ethanol): (24) 3-ethyl-2,2-diphenyl-1,3,2-oxazaborolidines, (25) 3-ethyl-2,2-bis(p-chlorophenyl)-1,3,2-oxazaborolidines, (26) 3-ethyl-2,2-bis(p-fluorophenyl)-1,3,2-oxazaborolidines, (27) 3-ethyl-2,2-bis(p-tolyl)-1,3,2-oxazaborolidines. Apart from structural studies in the solid state, the compounds were also characterized by means of multinuclear NMR spectroscopy (1H, 11B, 13C) as well as UV/vis and FTIR. The typical 11B resonances were found in the range of (4-10 ppm). A series of characteristic metrical parameters for the compounds in the solid state as well as typical NMR shifts for the chelate target molecules was established that allowed for the determination of the coordination induced shift. The carbon atom bonded to the oxygen atom shifted upfield, while the carbon atom bonded to the nitrogen atom shifted downfield. Factors mentioned in the literature that has an influence on the hydrolytic stability on the heterocyclic borinate motif have been taken into consideration and verified for the systems researched in this study. The substitution at the nitrogen atom with one ethyl group caused the greatest increases in the N→B bond length (27) 1.714 Å, due to the increase in the nitrogen Lewis basicity, making it the least hydrolytically stable, these include compounds (24-26). Furthermore, DFT calculations were performed by employing Becke’s three parameter hybrid exchange functional with Lee–Yang–Parr functional (B3LYP) method using the Gaussian 16 program package (Rev. B01) employing the basis set 6-311++G(d,p), to corroborate and correlate the experimental findings, which gave a general R-squared value of 0.9978 for calculated vs experimental 13C chemical shifts. Thermal properties are recorded for select compounds, indicating the ΔH and the melting points. , Thesis (PhD) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
  • Full Text:
  • Date Issued: 2021-12

The use of ambient seismic noise to investigate internal changes in a tailings storage facility and to image the subsurface geology in the Cradock area of the Eastern Cape

  • Authors: Kunjwa, Thulisile
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/53642 , vital:45690
  • Description: Passive seismic interferometry is a process by which ambient noise data recorded at different seismic stations can be cross-correlated to estimate Green's functions. In the past, both surface waves and body waves have successfully been extracted by cross-correlation of ambient noise data on both regional and global scales. Recent advancements in ambient seismic noise techniques have the potential to provide new methods for subsurface imaging and monitoring. The ambient noise data processing procedure divides into four principal phases: (1) single station data preparation, (2) cross-correlation and temporal stacking, (3) measurement of dispersion curves and (4) inversion of dispersion curves to obtain 1-D shear wave profiles and computation of 2-D shear wave velocity cross-section. The purpose of this study is to investigate whether ambient seismic noise can be used to image and detect internal changes within a mine tailings dam wall and to image the subsurface geology of part of the Eastern Cape Karoo near Cradock. In the first experiment, the investigation consisted of continuous ambient noise data recordings over a period of 3 days with 20 three-component short period geophones. The geophones were deployed over a survey wall of roughly 100 m in length at the Harmony Gold mine tailings dam in Welkom. In the second experiment, the investigation consisted of data recordings over a period of 35 days. The geophones were deployed in Cradock. The first phase of the data processing procedure included de-trending, de-meaning and band-pass filtering the data. This was done to ensure that any long period trends associated with instrument glitches are removed from the data. A spectrogram was then computed to view the spectrum of frequencies in the signal and to check if the filter that was designed was able to cut off the unwanted frequencies. The horizontal and vertical components of the ambient noise data were cross-correlated and picked between sensor pairs to create surface wave dispersion curves. Subsequently, the dispersion curves were inverted to estimate the shear wave velocity of the dam wall and subsurface as a function of depth. The computed cross sections of shear wave velocity indicated a low-velocity zone between 2 and 10 m below the surface on the dam wall, this suggested that the phreatic surface is much closer to surface in this area. In the second experiment, the interpolated shear wave velocity profiles indicated that there is a layer of low velocity zone between depths 250 to 300 m below the surface. The cross-correlations were also used to compute group velocity maps from periods 1.5 seconds to 30 seconds. The group velocity maps showed various high and low velocity anomalies. The high velocity zones observed on the eastern section of the map were interpreted as evidence of dolerite intrusions. The low velocity zones observed in the western and southern sections of the map interpreted as Karoo sediments that belong to the Adelaide Subgroup which is dominated by mudstones. , Thesis (MSc) -- Faculty of Science, Department of Geosciences (Geology and Geography), 2021
  • Full Text:
  • Date Issued: 2021-12

The use of photography to visualise abstracted narratives of emotions associated with trauma

  • Authors: Warner, Lauren
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54585 , vital:46726
  • Description: The purpose of this qualitative research study is to comment on the use of photography to visualise abstracted narratives of the emotions associated with trauma. This is a practicebased study developed on the interweaving of theoretical and practical output. The practical output produced a photographic body of work which argues in favour of an abstracted narrative for the visualisation of trauma by engaging with visualised emotions associated with trauma. The theoretical output of the study relates to three visual themes: firstly, the direct or actual moment of trauma; secondly, the triggering of the traumatic experience and lastly, the abstracted narrative of emotions associated with trauma. Photographing a traumatic event freezes a moment in which the subjects are continually engaging in the traumatic experience. Sontag (2003: 93) asserts that this type of direct photographic representation should be discouraged for fear of aestheticising pain and desensitising the viewer to horror. The study aims not to visualise actual traumatic events, but rather to engage with abstracted narratives of emotions associated with trauma experienced or felt, both directly and indirectly. This is achieved by firstly, providing a context on how the role of photography dealing with trauma has evolved to move beyond the depiction of an actual traumatic experience. Secondly, Gillian Rose’s (2016) Visual Methodologies Framework is introduced and photographers Roger Ballen’s Cut Loose (2015) and Jo Ractliffe’s 1999 work entitled Vlakplaas: 2 June 1999 (Drive-by Shooting) analysed as visual expressions of trauma. Similarly, photographers Robert Frank’s 1978 work entitled Sick of goodby’s and Manuela Thames’s 2019 work entitled Trauma are analysed to reflect on the use of abstracted narratives as they comment on personal traumatic experiences. Lastly, the body of work produced in the practice-based output of the study, Public Places: Private Spaces, are analysed as a vehicle through which emotions are associated with trauma. These traumatic experiences are visually expressed using abstracted images in triptych narratives. This study contributes to the current body of knowledge by critically addressing ways of thinking about the visualisation of trauma. This provides insight into the topic of trauma and the various ways in which it could be visualised without depicting the actual trauma (with the potential of continuously wounding or replaying trauma) and instead engaging with the visualised traumatic experience as an abstracted narrative within a South African context. , Thesis (MA) -- Faculty of Humanities, School of Visual and Performing Arts, 2021
  • Full Text:
  • Date Issued: 2021-12

Ureaplasma species in the placenta and histopathology associated with preterm birth

  • Authors: Sprong, Kaitlin Elizabeth
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54128 , vital:46310
  • Description: The Eastern Cape province is known for its high perinatal morbidity and mortality rate. Studies from other countries indicate that Ureaplasma spp. have been associated with clinical chorioamnionitis, spontaneous preterm labor and preterm premature rupture of the fetal membranes. The prevalence of Ureaplasma urealyticum, Ureaplasma parvumand Mycoplasma hominisin the placenta and its role in preterm birth is unknown in South Africa. Objectives The objectives of this study were to: (i) analyze placental histology, maternal and neonatal outcomes and clinical presentation of preterm birth, (ii) detect Ureaplasma spp. and M. hominisin the placenta from cases of preterm birth, (iii) determine antibiotic susceptibility profiles of Ureaplasma spp. isolates and investigate mechanisms of antibiotic resistance, (iv) characterize the microbial diversity in the placenta using 16S rRNA next generation sequencing and(v) review pathologies to ascertain whether there is any association between Ureaplasma spp. in the placenta and adverse maternal, obstetric and neonatal outcomes. iiiABSTRACTBackground The Eastern Cape province is known for its high perinatal morbidity and mortality rate. Studies from other countries indicate that Ureaplasmaspp. have been associated with clinical chorioamnionitis, spontaneous preterm labor and preterm premature rupture of the fetal membranes. The prevalenceof Ureaplasmaurealyticum,UreaplasmaparvumandMycoplasmahominisin the placenta andits role in preterm birth is unknown in South Africa. Objectives The objectives of this study were to: (i) analyze placental histology, maternal and neonatal outcomes and clinical presentation of preterm birth, (ii) detect Ureaplasmaspp. and M. hominisin the placenta from cases of preterm birth, (iii) determine antibiotic susceptibility profiles of Ureaplasmaspp. isolates and investigate mechanisms of antibiotic resistance, (iv) characterize the microbial diversity in the placenta using 16S rRNA next generation sequencing and(v) review pathologies to ascertain whether there is any association between Ureaplasmaspp. inthe placenta and adverse maternal, obstetric and neonatal outcomes. MethodsPlacentas were collected from patients presenting with preterm birth (n=100; 28-34 weeks gestational age) and term birth (n=20; >38 weeks) regardless of the APGAR score. Placentas were submitted for histopathology and used for detection of Ureaplasmaspp. by culture (U9 broth, MycoDuo kits;BioRad) and PCR (DNA was extracted from culture and homogenized placental tissue). Antibiotic susceptibility profiles of Ureaplasmaspp isolates were determined by the SIR Antibiogram kit (BioRad) and microbroth dilution method. Molecular mechanisms of resistance were ascertained by PCR amplification of target genes. Placentas were sent to National Health Laboratory Servicesfor routine histopathology. Next generation sequencing was performed on 16S rRNA amplicons from placental DNA for analysis of microbial diversity. , Thesis (PhD) -- Faculty of Science, Journalsim and Media Studies, 2021
  • Full Text:
  • Date Issued: 2021-12

Youth development: a case study of vision4 mentorship programme for teenage girls in Port Elizabeth

  • Authors: Gqabe, Ongeziwe Sharon
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54343 , vital:46477
  • Description: Investment in youth development for a country like South Africa, where social issues such as unemployment, lack of quality education, high levels of school dropouts, difficulty in accessing post-secondary education and training are of high prevalence is crucial. There are different strategies that key players in youth development such as the government, private sector and NGOs can implement in advancing the youth. This study sought to examine one of these strategies which is mentorship. Consequently, the purpose of this study was to scrutinize the essential role that a mentorship program can play in progressing youth development. The objectives of this study are as follows: to investigate the key challenges facing the teenage girls that participated on the Vision4 Mentorship Program; to investigate the effectiveness of the strategy of using mentorship programs as a tool in achieving youth development in Motherwell, Port Elizabeth and to come up with the recommendations with the view of addressing some of the problems faced by the youth in Motherwell, Port Elizabeth. The research methodology used in this study include among others, individual interviews of participants that has been previously gone through the Vision4 Mentorship Program. Furthermore, relevant scholarly published work has been consulted to supplement the interviews. Mentorship has been used as a conceptual framework to understand the impact of mentoring to the young girls at Vision4 Mentorship Program. , Thesis (MA) -- Faculty of Humanities, Department of Sociology and Anthropology, 2021
  • Full Text:
  • Date Issued: 2021-12

Youth sub-cultures: the case of izikhothane amongst youth in Port Elizabeth townships

  • Authors: Laqwela, Bayanda B
  • Date: 2021-12
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54694 , vital:47442
  • Description: The studies on youth subcultures have always attracted scholars and media, both locally and internationally. Specifically, in South Africa, we have witnessed subcultural youth formations, such as amapantsula1 , umswenko2 , the smarteez, zef, emmos and so forth. In the past few years, we saw the rise of a certain subcultural youth formation, popularly known as izikhothane3 , in South African townships. Owing to an escalation in izikhothane, this study was undertaken among the youth in Port Elizabeth townships. The study sought to explore and describe the significance of izikhothane membership and the rituals that are performed during their meetings. The qualitative approach was used for the study and semi-structured interviews, focus groups and observations were employed as data collection tools. The study used the explorative, descriptive and contextual design. The population for the study was the youth who are involved in the youth subculture of izikhothane in Port Elizabeth townships. The themes, which answered the questions, were identified as follows: the definition of isikhothane according to izikhothane, pulling or attraction factors, izikhothane rituals, the significance of isikhothane membership, the stopping age and the perceptions of community members about izikhothane. One of the main findings of this study is the age at which the youth join izikhothane. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
  • Full Text:
  • Date Issued: 2021-12

A framework to measure employee engagement at Stefanutti Stocks RPM Business Unit

  • Authors: Maher, Theresa
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/53315 , vital:45142
  • Description: Work gratification and expectancies are of the utmost importance to the skilled workforce in the South African construction industry. The price paid for a demotivated workforce in this industry is very high and it leads to friction in the workplace, displeasing work outcomes and time delays. Furthermore it leads to increased incidences of theft,absenteeism and outputs that arebelow standard in terms of productivityand thequality of the work.In order to motivate the workforce in the construction industry,a day-by-day, step-by-step,hands-on approachmust be used. The aforesaid aids site managers to manage effectively and this in turn leads to an increase in production by way of enhanced productivity. Research shows that a correlationbetweenmotivation, excelling at work, improved productivity and fulfilment and expectancyexist. The reason why individuals act in a specific manner and choose not to act in a certain way can be directly linked totheirmotivation and engagement.As a member ofthe construction industry in South Africa, Stefanutti Stocks isseen as one of the leading construction groups. Employing more than 12 000 workers it has the ability to provide a wide variety of different scale projects for a host of clients in varied markets. The division concentrated on in this study is the Roads, Pipelines and Mining Services (RPM)Business Unit. The MD of the RPM Business Unit when starting at the company a few years ago came to the conclusion that in order for the RPM Business Unit to function optimally certain business inconsistencies regarding employee engagement needed to be addressed. Based on this he decided to use a consulting firm, AIM,to establish what the exact concernswere and what interventions wererequired to deal with them. ivInterventions facilitatedby AIM includedManagement Training Programmes and Workshops as well as one-on-one coaching sessions with selected individuals.The methodology used in this study was to measurethe current level of employee engagement subsequent toengagement interventionsconcludedby AIM.The approach used was the use of surveys distributed through AIM in conjunction with the RPM Business Unit’sHR Department. The surveys were distributed via Survey Monkey Software owned by the RPM Business Unit of Stefanutti Stocks. , Thesis (MBA) -- Faculty of Business and Economic Sciences, NMMU Business School, 2021
  • Full Text:
  • Date Issued: 2021-04

A study of the airflow on the windward slope of a transverse dune in the Alexandria coastal dunefield

  • Authors: Burkinshaw, Jennifer Ruth
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/52734 , vital:43883
  • Description: Our understanding of the evolution of dune morphology has been hampered by a lack of empirical observations of airflow behaviour over dune forms. Sand dunes intrude into the atmospheric boundary layer and convergence of streamlines results in an acceleration of airflow up the windward slopes of dunes. This study examines the airflow structure and corresponding bedform development on the windward slope of a 7 m high transverse dune on the edge of the Alexandria coastal dunefield, Algoa Bay, South Africa. The Alexandria dunefield is subjected to a trimodal wind regime, consisting of the dominant south-westerly which blows all year round, summer easterlies and winter northwesterlies. The morphology of the study dune, Dune13, is controlled by the easterlies and north-westerlies, and reverses seasonally with respect to these two winds. Seven section lines 30 m apart and normal to the dune crest were surveyed regularly over the period of a year to monitor the reversal process. Three detailed topographic surveys were also done during this period. Airflow behaviour was monitored during the year. Wind speed profiles on the windward slope of the dune were measured using 4 to 5 vertical arrays of anemometers positioned from the base of the dune to the crest on a 1 selected section line. Usually 4 to 5 anemometers were deployed in each vertical array, from a height of 6 to 10 cm above the surface, up to a height of 150 cm above the surface. Initially 8 microanemometers were available; ultimately 28 anemometers were run simultaneously. An independent weather station at an elevation of 6 m recorded the unaccelerated flow. Local gradient measurements and erosion and deposition rates were recorded along selected section lines. Strong summer easterly winds (14 m/sec at 1.4 m above the dune crest) were measured on a dune slope in the process of being transformed from a slipface to a stoss slope. The following winter, light north-westerly winds (typically B m/sec at 1.6 m above the dune crest) were measured on the new windward slope already reversed by the prevailing winter wind. Airflow data confirm the compression of airflow against the windward slope resulting in a non-logarithmic wind speed profile. Compression results in an increased shear velocity within 30 cm of the dune surface, and the dune slope is eroded. Higher up in the wind speed profile, shear velocity decreases to 0.1 m/sec. It is not known at what height the wind speed profile recovers from the intrusion of the dune into the boundary layer. High values of shear velocity (1.6 m/sec) above the rounded crestal area of the dune record the recovery of the wind speed profile from flow divergence, which is a response to the rapid reduction of dune gradient and is accompanied by deposition of sand in this region. 2 The erosion pin data act as a simple and sensitive test for changes in gradient, reflecting the dune's response to changes in the airflow regime. The shape of the dune plays a major role in determining the extent of the compression and the distribution of shear velocity up the slope. Increased shear velocity is experienced on that part of the slope which is nonaerodynamic with respect to the prevailing wind. Under unidirectional conditions, feedback between flow and form results ultimately in a slope with a curvature such that shear velocity increases systematically upslope. The survey data and erosion pin data record the reversal process as the dune achieves a new steady state during each wind season. The existence of a non-logarithmic wind speed profile makes it difficult to know what relevant measure of shear velocity is to be used in sand transport equations. Future work should include wind speed measurements within 10 cm of the surface. An ideal study modelling aeolian bedform development would utilise wind tunnel measurements, combined with field measurements such as obtained in this study, for comparison with numerical modelling. The study needs to be extended to 3-dimensional airflow measurements. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2021
  • Full Text:
  • Date Issued: 2021-04

An anthropological enquiry on the perceptions of adults on female sterilisation: a case of Gunguluza township

  • Authors: Mbanjwa, Mpho
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54859 , vital:48085
  • Description: The purpose of the study was to make an enquiry on the perceptions on female sterilisation adult participants, residing in Gunguluza Township, Uitenhage had. A qualitative research approach was used to collect the responses of 10 participants. These included eight women, one man and one traditional healer registered within the Traditional Healers Association of South Africa. The interviews had been semistructured with open-ended questions pre-set to help the researcher guide the conversation. Conversation analysis was the technique used to transform the information into research data that would attempt to answer the research question. The question this research attempted to answer was to form an understanding of how information and education resources provided by both Western and Traditional sources, including their availability and accessibility with regards to female sterilisation, as a form of contraception, have been understood, received and interpreted by adults residing in the research area of Gunguluza township. Gunguluza forms part of the area formally known as the Kwanobuhle 10 and Kwanobuhle 11 respectively. Some limitations, including limiting resources that resulted in only 10 participants being interviewed. The results had shown that participants had shown interest in acquiring more knowledge about female sterilisation and other reproductive health issues, in order to make informed decisions about their bodies, with contraceptive choice and use in particular. Most felt the need to engage with their partners about the choice of sterilisation largely due to the support they would need. With regard to traditional health as an alternative or interchangeable method of contraception, participants had very little knowledge of, with some expressing some importance and relevance in acquiring such knowledge, in a modern context. These findings came with sets of recommendations which placed an emphasis on the building of indigenous knowledge and its inclusion in formal spaces for open engagement and discussion. Traditional knowledge needed to be transferred from an oral to being documented into literature for future preservation and to eliminate any distortion. There was a gap for formal western medicine to collaborate or accommodate traditional medicine. The study made use of female sterilisation as a conceptual framework, with time and more future research could build and produce new theoretical understandings of the concept, from an Afrocentric context in particular. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
  • Full Text:
  • Date Issued: 2021-04

An anthropological investigation on academic performance of grade 12 learners: selected schools in King William’s Town, Eastern Cape

  • Authors: Stuart, Sinaed
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54816 , vital:47910
  • Description: The Eastern Cape is one of the poorest provinces in South Africa. The level of poverty, and lack of basic resources has given way to inadequacies in many of the services available to communities. From improper infrastructure, to a flawed or lacking public education system. Past and future research into the inadequacies and inequity that exists in the public education system need to act as a catalyst to policy changes, and intervention implementations to solve the issues that continue to persist. This study focuses on the factors that influence the academic performance of learners in matric in King Williams Town. The importance of this research is to investigate the issues that negatively impact on the performance of Grade 12 learners at Breidbach High School. Further, the importance of this study is to share the findings of the research with community members as well as the Department of Basic Education with the view and hope that they will address these issues. The research question is: What are the factors influencing academic performance of Grade 12 learners at Breidbach High School in Breidbach outside King Williams Town? The research objectives are as follows: to investigate and highlight factors associated with poor academic performance in the participating high school at Breidbach in King Williams Town, to contribute within the anthropology of education, adding to an already existing body of knowledge, with specific reference to the participating high school in King William’s Town and to come up with the recommendations with the view of addressing some of the challenges faced by the participating high school in King Williams Town. The study followed a qualitative approach which included various techniques and ethical compliance was adhered to. For the proposed study, the researcher will use ‘academic performance’ as a guideline for the conceptual framework. , Thesis (MA) -- Faculty of Humanities, Department of Sociology and Anthropology, 2021
  • Full Text:
  • Date Issued: 2021-04

An investigation into the effects of nano-carbons on the negative electrode morphology of lead acid batteries under high rate partial state of capacity cycling

  • Authors: Bolo, Lukanyo
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/53324 , vital:45132
  • Description: New technological developments in the field of Hybrid Electric Vehicles (HEV’s), vehicle stop-start applications and electrical power utility devices have brought about new demands on the use of energy storage devices such as the Pb-acid battery. These applications require a new understanding and research into the material chemistry of the battery where it has to functionin a Partial State of Capacity Cycling (PSoCC) or High Rate Partial State of Capacity Cycling (HRPSoCC)duty. The Pb-acid battery is well known for its use in the automotive industry where it had worked for decades as a typical Starter, Lighting and Ignition (SLI) power source. However, the conventional Pb-acid battery is not suitable for the new types of vehicle demands and applications. When the Pb-lead acid battery is subjected to PSoCC conditions, very quickly excessive amount of non-conducting PbSO4crystals are formed on the negative plates of the battery that then drastically reduce its useful life in application. Over the years, researchers have shown that the small addition of certain carbon types to the negative plate active material (NAM) during battery manufacturing can reduce the sulfation effect thereby increasing its use the modern vehicle applications. This study investigated industrial manufactured cells that contained up to 0.5 % by weight two types of carbons in the NAM. These were compared to standard built cells in terms of their standard achievable capacities at various rates, their Cold Cranking Ability (CCA), their Dynamic Charge Acceptance (DCA) and a simplified PSoCC test. The carbons were classified as an activated carbon and a carbon nano-fiber and were included as a dry weight additive during the standard paste manufacturing process of the negative plate. Cells were built with a 9-plate configuration using standard expanded grid positive plates with a nominal rated capacity of 36 Ah. The cells were formed and subjected to a number of electrochemical tests, of which selected negative plates were then studied using Scanning Electron Microscopy (SEM) and Electrochemical in-situ Atomic Force Microscopy (EC-AFM). The microscopic study was then used to try and relate the observed material characteristics of the NAM with the carbons to the electrochemical results observed when testing a built cell. , Thesis (MA) --Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
  • Full Text:
  • Date Issued: 2021-04

Ecosexual digital war machines: minoritarian environmental desires in the age of new media

  • Authors: Weideman, Lisa
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10948/54828 , vital:47915
  • Description: Today the (Transnational) State Apparatuses of neoliberal capitalism, ranging from educational institutions to mass media and financial institutions, have effectively created and channelled desires towards consumerism, predicated on resource-extractive practices, within the context of what Gilles Deleuze calls societies of control. This control has also intensified in the digital era, particularly through Internet-based technologies which provide increasingly efficient platforms for the escalation of commodification – ironically, despite the reality of ecological crisis being precipitated by the related extractive practices to the point where it now threatens the continued existence of life on earth. , Thesis (MA) -- Faculty of Humanities, School of Language, Media and Communication, 2021
  • Full Text: false
  • Date Issued: 2021-04

Enhancing the provision of social housing through public-private partnerships in Buffalo City Metropolitan Municipality

  • Authors: Sobuza, Duduzile
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54806 , vital:47905
  • Description: The purpose of this study was to establish the extent to which the provision of social housing can be enhanced through public-private partnerships (PPPs) in the Buffalo City Municipality. A total quality management approach was used as a foundation to understand the application of PPPs in social housing delivery in the Buffalo City Municipality. The study was desktop research to understand the role of PPPs in the provision of social housing. The findings of the study revealed that PPPs provide additional capital for social housing development. The study highlighted that PPPs play a crucial role in providing alternative management and implementation skills as well as offering greater efficiency in the utilisation of financial resources in the delivery of social housing. The findings of the study further revealed that PPPs accelerate social housing delivery through the provision of additional sources of finance where the government is unable to increase public debt to meet investment needs. The study also identified a plethora of constraints that can hinder the adoption of PPP initiatives in social housing delivery. These include capacity constraints, financial constraints, lack of access to land and an unfavourable policy environment. Subsequently, the study advanced a set of recommendations in this regard that includes the creation of transparent and competitive procurement processes, government support in terms of financial incentives, review of the regulatory framework to improve access to land and the regulation of financial services institutions for access to affordable housing credit. , Thesis (MA) -- Faculty of Humanities, Department of Public Management and Leadership , 2021
  • Full Text:
  • Date Issued: 2021-04

Optimising the uptake of [𝐈𝐫𝐂𝐥𝟔]𝟐− by a diammonium resin: HCl effect and resin performance

  • Authors: Ngayeka, Mbokazi Zizipho
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54089 , vital:46284
  • Description: The separation of [IrCl6]2- from [RhCl5(H2O)]2- by silica microparticles functionalized with 1,10-diamindecane (C10) and quaternized with 4-nitrobenzylchloride (NO2Benz) in various hydrochloric acid mediums was investigated by continuous column studies. The sorbent materials were synthesized using three different routes: Synthesis route 1 (NaI catalyzed synthesis of diammonium functionalized silica microparticles), Synthesis Route 2 (via silylazation of silica followed by functionalization) and Synthesis Route 3 (silane-based sorbent material). The functionalized sorbent materials were characterized by NMR, Microanalysis, SEM-EDS, FT-IR, TGA and BET surface area. The separation efficiency of the quaternary diammonium cations was investigated under dynamic flow adsorption conditions. Preliminary ICP-OES runs were done, at 6 M HCl, to assess which synthesis route gave the best performing sorbent material. [IrCl6]2- selectivity of the sorbent materials was achieved by washing with an HCl solution to remove unadsorbed metal species, then stripping off the [RhCl5(H2O)]2- with 0.05 M of sodium chlorate and the iridium species was eluted with a 20% HCl solution. From the preliminary ICP-OES, loading capacities were calculated, and it was observed that the three sorbent materials from synthesis route 2 (13.89 mg/g for (4) SSC10NO2Benz-A, 1.44 mg/g for (5) SSC10NO2Benz-HoA, and 1.0859 mg/g for (6) SSC10NO2Benz-DoA) showed the highest uptake of [IrCl6]2- and route 1 (1.89 mg/g for (1) SSC10NO2Benz-A, 1.25 mg/g for (2) SSC10NO2Benz-HoA and 0.99 mg/g for (3) SSC10NO2Benz-DoA ) and Route 3 (0.55 mg/g for (7) SC10-AI and 0.755 mg/g for (8) SC10-ACl) materials did not perform efficiently enough, thus were not used further for the HCl study. Within synthesis route 2, three sorbent materials were evaluated, which had varying quantities of the cation: SSC10NO2Benz-A (having a quantity previously used in our research and denoted A), SSC10NO2Benz-HoA (having a quantity Half of A) and SSC10NO2Benz-DoA (having a quantity double of A). SSC10NO2Benz-A showed the highest loading capacity than SSC10NO2Benz-HoA and SSC10NO2Benz-DoA; HCl studies were carried out using SSC10NO2Benz-A. HCl solution having different concentrations (5, 5.5 , 6 , 6.6 and 6.8 M) were used to prepare the metal solutions. This was done to assess which HCl concentration gave the best metal solution containing high amounts of [IrCl6]2- and [RhCl5(H2O)]2-, which would result in a more efficient separation. An auto titrator was used to standardize the HCl concentrations, and the metal ion chloride species solutions were determined by UV-Vis, and their concentrations were confirmed with ICP-OES. Column sorption of iridium and rhodium on SSC10NO2Benz-A using these HCl solutions was carried out, and loading capacities of [IrCl6]2- were obtained. The loading capacities of the 5 M, 5.5 M, 6 M, 6,6 M and 6.8 M HCl solutions for [IrCl6]2- were 2.64, 4.01, 13.89, 18.15 and 7.23 mg/g, respectively. The optimum separation conditions were thus determined by investigating effective parameters such as the method of synthesis, silica to cation ratio, HCl concentration and flow rate. This thesis presents quaternary diammonium sorbent materials that could be applied in feed solutions from ore processing for iridium recovery. , Thesis (MSc) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2021
  • Full Text:
  • Date Issued: 2021-04

Rheology behaviour of slurries as a function of particle size and ion concentration

  • Authors: Kondlo, Princess Kholiwe
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/53333 , vital:45141
  • Description: In this work, the rheological properties of alumina slurries milled to different particle sizes were investigated. Viscosity increases as the particle size decreases. When increasing amounts of calcium hydroxide, strontium hydroxide or barium hydroxide are added, the viscosity first goes down and then goes up. This can be explained in terms of changes in pH and changes in ionic strength impacting on the surface potential of the particles in suspension. Adding the same concentration of different cations results in different viscosities, with the order being (from high to low viscosity) Ba>Sr>Ca. Effects of partial dissolution of and structural changes to the alumina particles at high pH cannot be excluded. In order to better understanding the different effects, it was attempted to measure the zeta potential of the slurries at different pH values. This resulted in highly positive zeta potential values over the complete pH range, without the observationof an iso-electric point. This does not fit to the observed changes in rheology and contrasts withliterature data. One explanation would be that the measurement system used is unsuitable to yield correct zeta potential values for the materials under investigation. , Thesis (MSc) -- Faculty of Science, Department of Chemistry, 2021
  • Full Text:
  • Date Issued: 2021-04

The relationship between the performance management development system and compensation: the case of the City of Cape Town Municipality

  • Authors: Ramaru, Murendeni Praise
  • Date: 2021-04
  • Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
  • Language: English
  • Type: Master's theses , text
  • Identifier: http://hdl.handle.net/10948/54836 , vital:47926
  • Description: This research was directed towards the current state of the relationship between the Performance Management Development System and compensation in the City of Cape Town Municipality. The research approach adopted in this study was a qualitative method. Desktop analysis and case study design were used as secondary data collection tools. Since the democratization of South Africa in 1994, the focus has been directed towards the maximising of economic growth and development. The road to development has been challenging since the inception of democracy. Organisations are operating in a dynamic and highly competitive environment which requires adjustments and development of strategies to remain relevant. Compensation is one of the ways different organisations have adopted as a strategy for attracting and retaining suitable employees as well as maintaining performance management. The essence of a well-functioning performance management development system has played a critical role in providing an effective system in the public service. The main objective of compensation is to ensure an organisation has the right resources necessary to motivate employees’ performance needed to achieve the organisational strategy. The study found that a compensation strategy leads to increased employees’ performance. The findings indicated that there is a positive connection between the compensation strategy and the performance of the employees. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
  • Full Text:
  • Date Issued: 2021-04
  • Disclaimer
  • Privacy
  • Copyright
  • Contact