- Title
- Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions
- Creator
- Jiang, Yu
- Creator
- Li, Minzhi
- Creator
- Liang, Xu
- Creator
- Mack, John
- Creator
- Wildervanck, Martijn
- Creator
- Nyokong, Tebello
- Creator
- Qin, Mingfeng
- Creator
- Zhu, Weihua
- Subject
- Dalton Transactions (2015), 44, 18237-18246, doi:10.1039/c5dt03256c
- Date
- 2015-10-07
- Type
- Article
- Identifier
- vital:7282
- Identifier
- http://hdl.handle.net/10962/d1020322
- Description
- A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions.
- Description
- Original publication is available at http://dx.doi.org/10.1039/C5DT03256C
- Format
- 10 p.
- Format
- Publisher
- Royal Society of Chemistry
- Language
- English
- Relation
- Jiang, Y., Li, M., Liang, X., Mack, J., Wildervanck, M., Nyokong, T., Qin, M. & Zhu, W. 2015. Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions. Dalton Transactions, 44(41):18237-18246. Available: http://dx.doi.org/10.1039/C5DT03256C.
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Mack, John (Associate Prof)
RU Centre for Nanotechnology Innovation
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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