Pharmacological studies of Foeniculum Vulgare (Mill.) and Lippia Javanica (Burm.F.) spreng. used as spices in Nkonkobe Municipality of the Eastern Cape Province, South Africa
- Asowata-Ayodele, Abiola Mojisola
- Authors: Asowata-Ayodele, Abiola Mojisola
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Fennel -- Utilization -- South Africa -- Eastern Cape Ethnopharmacology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2777 , vital:28085
- Description: Spices are of great importance in the indigenous culinary and traditional medicine systems of the people of Nkonkobe Municipality of the Eastern Cape, South Africa. The present investigation evaluated the ethnopharmacological potentials of two indigenous South African spices- Foeniculum vulgare and Lippia javanica. The pharmacological investigations on these two plant species include ultra-morphology, nutrient and mineral analysis, evaluation of the essential oil, phytochemical and antioxidant assays, antimicrobial, anti-inflammatory as well as anti-urolithiatic assay of the acetone and aqueous extracts of the two plants. The species were selected for study as the most cited plants after an ethnobotanical survey conducted on the indigenous knowledge of plants used as spices and medicine in Nkonkobe Municipality, Eastern Cape of South Africa. Among the plants cited Foeniculum vulgare(Apiaceae) and Lippia javanica (Verbenaceae) stood out as the most commonly used spices. Others were members of the families; Solanaceae, Apiaceae, Amaryllidaceae, Amaranthaceae and Lamiaceae. Ultra-morphological studies conducted on the leaves of the two selected plants using scanning electron microscope revealed the presence of non-glandular and glandular trichomes, stomata and crystals. The leaf surfaces of these herbs may serve as secretory sites where aromatic secondary metabolites are produced. Analyses of the proximate, mineral, vitamin and anti-nutrients contents of these two spices showed that both species are good sources of these phytochemicals and may be used to enrich the human diet. Lippia javanica possesses lower lipid (0.50 percent), fibre (5 percent) and carbohydrate (64.96 percent) contents than Foeniculum vulgare. On the other hand, protein (20.54 percent), ash (11.60 percent) and moisture content (11.69 percent) were higher in Foeniculum vulgare than in Lippia javanica. Foeniculum vulgare showed higher N (3286 mg/100g), Mg (386.7 mg/100g), K (3187 mg/100g) and Na (1383 mg/100g) content while Lippia javanica was higher in Ca (1833 mg/100g), Zn (4.7 mg/100g), Cu (0.9 mg/100g) and Fe (78.4 mg/100g). Vitamins Aand E were also higher in Lippia javanica (1.31 mg/100g; 2.52 mg/100g) while Foeniculum vulgare (0.45 mg/100g) had higher vitamin C content. No significant differences were observed in the phytate, oxalate and tannin contents of the two spices, but saponin and cyanide were significantly lower in Lippia javanica (268.5 mg/100g; 8.45 mg/100g) than in Foeniculum vulgare (1855 mg/100g; 10.5 mg/100g) Evaluation of the essential oil component, cytotoxicity and antimicrobial activities of both fresh and dried leaves of Lippia javanica and Foeniculum vulgare revealed that the dried samples yielded more oil and also contain more chemical than the fresh samples of both plants. The overall antimicrobial activity evaluated using susceptibility and microdilution assays revealed that the oils of F. vulgare and L. javanica exhibited high antifungal and antibacterial activity, compared to the reference drugs. In addition, essential oil from fresh leaves of both spices was less toxic compared to the oil from the dried leaves. Polyphenolic evaluation of the aqueous and acetone extracts of the plants revealed that the acetone extract had higher phenol, flavanol, flavonoid and proanthocyanidin contents than the aqueous extracts. The total phenolic content of acetone and aqueous extracts were 4.49 ± 0.411 mg/g and 3.73 ± 0.498 mg/g tannic acid equivalent (TAE) respectively for Lippia javanica. The same trend was also observed in Foeniculum vulgare with total phenolic content of acetone and aqueous extracts were 4.22 ± 0.325 mg/g and 4.17 ± 0.651 mg/g tannic acid equivalent (TAE) respectively. Further assessment of the antioxidant activity of the solvent extracts revealed that both plants exhibited promising free radical scavenging potentials against 1,1 diphenyl-2-picrylhydrazyl (DPPH), 2, 2’-azino-bis(3- ethylbenzthiazoline-6-sulfonic acid (ABTS), reducing power, lipid peroxidation, nitric oxide, phosphomolybdate and hydrogen peroxide. Antimicrobial activities of the acetone and aqueous extracts of the two plants revealed moderate antibacterial and antifungal activities. They inhibited the growth of Microsporium canis and Trichophyton rubrum that were not susceptible to the standard antifungal drug used as control.
- Full Text:
- Date Issued: 2016
- Authors: Asowata-Ayodele, Abiola Mojisola
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Fennel -- Utilization -- South Africa -- Eastern Cape Ethnopharmacology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2777 , vital:28085
- Description: Spices are of great importance in the indigenous culinary and traditional medicine systems of the people of Nkonkobe Municipality of the Eastern Cape, South Africa. The present investigation evaluated the ethnopharmacological potentials of two indigenous South African spices- Foeniculum vulgare and Lippia javanica. The pharmacological investigations on these two plant species include ultra-morphology, nutrient and mineral analysis, evaluation of the essential oil, phytochemical and antioxidant assays, antimicrobial, anti-inflammatory as well as anti-urolithiatic assay of the acetone and aqueous extracts of the two plants. The species were selected for study as the most cited plants after an ethnobotanical survey conducted on the indigenous knowledge of plants used as spices and medicine in Nkonkobe Municipality, Eastern Cape of South Africa. Among the plants cited Foeniculum vulgare(Apiaceae) and Lippia javanica (Verbenaceae) stood out as the most commonly used spices. Others were members of the families; Solanaceae, Apiaceae, Amaryllidaceae, Amaranthaceae and Lamiaceae. Ultra-morphological studies conducted on the leaves of the two selected plants using scanning electron microscope revealed the presence of non-glandular and glandular trichomes, stomata and crystals. The leaf surfaces of these herbs may serve as secretory sites where aromatic secondary metabolites are produced. Analyses of the proximate, mineral, vitamin and anti-nutrients contents of these two spices showed that both species are good sources of these phytochemicals and may be used to enrich the human diet. Lippia javanica possesses lower lipid (0.50 percent), fibre (5 percent) and carbohydrate (64.96 percent) contents than Foeniculum vulgare. On the other hand, protein (20.54 percent), ash (11.60 percent) and moisture content (11.69 percent) were higher in Foeniculum vulgare than in Lippia javanica. Foeniculum vulgare showed higher N (3286 mg/100g), Mg (386.7 mg/100g), K (3187 mg/100g) and Na (1383 mg/100g) content while Lippia javanica was higher in Ca (1833 mg/100g), Zn (4.7 mg/100g), Cu (0.9 mg/100g) and Fe (78.4 mg/100g). Vitamins Aand E were also higher in Lippia javanica (1.31 mg/100g; 2.52 mg/100g) while Foeniculum vulgare (0.45 mg/100g) had higher vitamin C content. No significant differences were observed in the phytate, oxalate and tannin contents of the two spices, but saponin and cyanide were significantly lower in Lippia javanica (268.5 mg/100g; 8.45 mg/100g) than in Foeniculum vulgare (1855 mg/100g; 10.5 mg/100g) Evaluation of the essential oil component, cytotoxicity and antimicrobial activities of both fresh and dried leaves of Lippia javanica and Foeniculum vulgare revealed that the dried samples yielded more oil and also contain more chemical than the fresh samples of both plants. The overall antimicrobial activity evaluated using susceptibility and microdilution assays revealed that the oils of F. vulgare and L. javanica exhibited high antifungal and antibacterial activity, compared to the reference drugs. In addition, essential oil from fresh leaves of both spices was less toxic compared to the oil from the dried leaves. Polyphenolic evaluation of the aqueous and acetone extracts of the plants revealed that the acetone extract had higher phenol, flavanol, flavonoid and proanthocyanidin contents than the aqueous extracts. The total phenolic content of acetone and aqueous extracts were 4.49 ± 0.411 mg/g and 3.73 ± 0.498 mg/g tannic acid equivalent (TAE) respectively for Lippia javanica. The same trend was also observed in Foeniculum vulgare with total phenolic content of acetone and aqueous extracts were 4.22 ± 0.325 mg/g and 4.17 ± 0.651 mg/g tannic acid equivalent (TAE) respectively. Further assessment of the antioxidant activity of the solvent extracts revealed that both plants exhibited promising free radical scavenging potentials against 1,1 diphenyl-2-picrylhydrazyl (DPPH), 2, 2’-azino-bis(3- ethylbenzthiazoline-6-sulfonic acid (ABTS), reducing power, lipid peroxidation, nitric oxide, phosphomolybdate and hydrogen peroxide. Antimicrobial activities of the acetone and aqueous extracts of the two plants revealed moderate antibacterial and antifungal activities. They inhibited the growth of Microsporium canis and Trichophyton rubrum that were not susceptible to the standard antifungal drug used as control.
- Full Text:
- Date Issued: 2016
Geospatial technologies and indigenous Knowledge Systems:
- Authors: Aswani, Shankar
- Date: 2016
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/145448 , vital:38439 , ISBN 9781315181523 , https://www.taylorfrancis.com/books/e/9781315181523/chapters/10.1201/9781315181523-18
- Description: During the twentieth and twenty-first centuries, pressure on coastal ecosystems has amplified and resulted in the widespread degradation of adjacent marine and terrestrial habitats globally (Burke et al., 2001). The ecosystem services provided by coastal habitats, including coastal protection and food procurement, have been heavily compromised by anthropogenic disturbance such as overfishing, pollution, sedimentation and alteration of coastal vegetation (Costanza et al., 1997; Agardy et al., 2009). In the context of small islands, this continued degradation in tandem with the ongoing effects of climate change is putting the livelihoods of coastal peoples at risk (e.g. Bell et al., 2009). While international efforts at curtailing these negative trends are ongoing, many researchers are working directly with coastal local/ indigenous communities to seek more effective management of coastal terrestrial and marine resources. Among various approaches, researchers are increasingly incorporating local knowledge systems for designing resource management and conservation plans (e.g. Gadgil et al., 1993).
- Full Text:
- Date Issued: 2016
- Authors: Aswani, Shankar
- Date: 2016
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/145448 , vital:38439 , ISBN 9781315181523 , https://www.taylorfrancis.com/books/e/9781315181523/chapters/10.1201/9781315181523-18
- Description: During the twentieth and twenty-first centuries, pressure on coastal ecosystems has amplified and resulted in the widespread degradation of adjacent marine and terrestrial habitats globally (Burke et al., 2001). The ecosystem services provided by coastal habitats, including coastal protection and food procurement, have been heavily compromised by anthropogenic disturbance such as overfishing, pollution, sedimentation and alteration of coastal vegetation (Costanza et al., 1997; Agardy et al., 2009). In the context of small islands, this continued degradation in tandem with the ongoing effects of climate change is putting the livelihoods of coastal peoples at risk (e.g. Bell et al., 2009). While international efforts at curtailing these negative trends are ongoing, many researchers are working directly with coastal local/ indigenous communities to seek more effective management of coastal terrestrial and marine resources. Among various approaches, researchers are increasingly incorporating local knowledge systems for designing resource management and conservation plans (e.g. Gadgil et al., 1993).
- Full Text:
- Date Issued: 2016
Thermoluminescence of annealed synthetic quartz
- Atang, Elizabeth Fende Midiki
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
A Review of Arterial Stiffness and HIV Infection in Adult Africans
- Awotedu, Kofoworola Olajire, Iputo, Jehu
- Authors: Awotedu, Kofoworola Olajire , Iputo, Jehu
- Date: 09-06-2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/3484 , vital:43615 , https://www.hilarispublisher.com/open-access/a-review-of-arterial-stiffness-and-hiv-infection-in-adult-africans-2167-1095-1000221.pdf
- Description: Aim: To review the impact of the human immunodeficiency virus and antiretroviral therapy on the vasculature. Objectives: This review seeks to identify the burden which the human immunodeficiency virus and antiretroviral therapy have on the vasculature. Method: Medline/PubMed and Google scholar were searched. There were over 100 publications reviewed. Some people who worked in similar fields were also contacted. The present review summarized current understanding of Human immunodeficiency virus, antiretroviral therapy and effect on the vasculature such as arterial stiffness. Atherosclerosis, endothelial dysfunction, the strengths and weaknesses of current testing strategies, and their potential applications in clinical research and patient care. The association of inflammatory biomarkers, blood pressure and ageing with arterial stiffness were also reviewed. Conclusion: Available literature shows that HIV and antiretroviral agents have a great impact on the vasculature and its progression.
- Full Text:
- Date Issued: 09-06-2016
- Authors: Awotedu, Kofoworola Olajire , Iputo, Jehu
- Date: 09-06-2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/3484 , vital:43615 , https://www.hilarispublisher.com/open-access/a-review-of-arterial-stiffness-and-hiv-infection-in-adult-africans-2167-1095-1000221.pdf
- Description: Aim: To review the impact of the human immunodeficiency virus and antiretroviral therapy on the vasculature. Objectives: This review seeks to identify the burden which the human immunodeficiency virus and antiretroviral therapy have on the vasculature. Method: Medline/PubMed and Google scholar were searched. There were over 100 publications reviewed. Some people who worked in similar fields were also contacted. The present review summarized current understanding of Human immunodeficiency virus, antiretroviral therapy and effect on the vasculature such as arterial stiffness. Atherosclerosis, endothelial dysfunction, the strengths and weaknesses of current testing strategies, and their potential applications in clinical research and patient care. The association of inflammatory biomarkers, blood pressure and ageing with arterial stiffness were also reviewed. Conclusion: Available literature shows that HIV and antiretroviral agents have a great impact on the vasculature and its progression.
- Full Text:
- Date Issued: 09-06-2016
The effectiveness of the concrete / semi-concrete / abstract (CSA) appoach and drill- practice on grade 10 learners' ability to simplify addition and subtraction algebraic fractions
- Authors: Awuah, Bernard Prince
- Date: 2016
- Subjects: Algebra, Abstract
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5105 , vital:29076
- Description: This study was conducted in one of the education districts in the Eastern Cape Province of South Africa. The purpose was to analyse the effectiveness of the concrete/semi-concrete/abstract (CSA) approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The following two objectives were set. First, to identify the learners’ challenges in studying addition and subtraction of algebraic fractions in grade 10; and second to analyse the effectiveness of the CSA approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. Both threshold concepts and troublesome knowledge, Polya’s problem-solving techniques, CSA Approach theory and Drill-practice theory were all pertinent as a theoretical framework for the study. Positivism research paradigm was adopted for the study and it afforded the researcher opportunity to employ quantitative research approach. Based on the research question of this study, an experimental design was chosen as a suitable descriptive design. Purposive sampling method was used to select three schools which involved 135 grade 10 mathematics learners. Stratified random sampling method was thereafter employed to select 45 learners from each school for the study. The learners were grouped in each school as top, average and weak based on their performance in Algebra in term one. Pre-questionnaire and post-questionnaire were used to obtain data regarding challenges learners experience in simplifying addition and subtraction of algebraic fractions. Ethical clearance from the relevant school and university authorities were obtained. On the first two days, the researcher briefed the school authorities and learners and explained to them the purpose and details of the study. Day three was used to administer the pre-questionnaire test, thereafter, the next ten days were used to teach addition and subtraction of both numeric and algebraic fractions with same and different numerators and denominators. The next two days were used for revision and the last day was used to administer the postquestionnaire test out 25 marks. The respondent rate was 98.5%. The data collected were analysed by using SPSS version 16.10. Both descriptive and inferential statistics were used to analyse the data. The pre-questionnaire scores revealed that majority of the learners’ perceived fractions as two separate entities and as a result add or subtract numerator to numerator and denominator to denominator. It was also discovered that learners had a challenge in finding LCM of algebraic fractions. A t-Test for independent means was used to test the following hypotheses at 𝛼 = 0.05: 𝐇𝟎: The CSA approach and drill-practice intervention has no significant effect on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions; 𝐇𝟏: The CSA approach and drill-practice will significantly enhance Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The t-Test revealed a p-value of 0.139 which was statistically significant at 𝛼 = 0.05. Therefore, the researcher rejected the null hypothesis and concluded that the CSA approach and drill-practice have significantly enhanced the Grade 10 learners’ ability to simplify algebraic fractions.
- Full Text:
- Date Issued: 2016
- Authors: Awuah, Bernard Prince
- Date: 2016
- Subjects: Algebra, Abstract
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5105 , vital:29076
- Description: This study was conducted in one of the education districts in the Eastern Cape Province of South Africa. The purpose was to analyse the effectiveness of the concrete/semi-concrete/abstract (CSA) approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The following two objectives were set. First, to identify the learners’ challenges in studying addition and subtraction of algebraic fractions in grade 10; and second to analyse the effectiveness of the CSA approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. Both threshold concepts and troublesome knowledge, Polya’s problem-solving techniques, CSA Approach theory and Drill-practice theory were all pertinent as a theoretical framework for the study. Positivism research paradigm was adopted for the study and it afforded the researcher opportunity to employ quantitative research approach. Based on the research question of this study, an experimental design was chosen as a suitable descriptive design. Purposive sampling method was used to select three schools which involved 135 grade 10 mathematics learners. Stratified random sampling method was thereafter employed to select 45 learners from each school for the study. The learners were grouped in each school as top, average and weak based on their performance in Algebra in term one. Pre-questionnaire and post-questionnaire were used to obtain data regarding challenges learners experience in simplifying addition and subtraction of algebraic fractions. Ethical clearance from the relevant school and university authorities were obtained. On the first two days, the researcher briefed the school authorities and learners and explained to them the purpose and details of the study. Day three was used to administer the pre-questionnaire test, thereafter, the next ten days were used to teach addition and subtraction of both numeric and algebraic fractions with same and different numerators and denominators. The next two days were used for revision and the last day was used to administer the postquestionnaire test out 25 marks. The respondent rate was 98.5%. The data collected were analysed by using SPSS version 16.10. Both descriptive and inferential statistics were used to analyse the data. The pre-questionnaire scores revealed that majority of the learners’ perceived fractions as two separate entities and as a result add or subtract numerator to numerator and denominator to denominator. It was also discovered that learners had a challenge in finding LCM of algebraic fractions. A t-Test for independent means was used to test the following hypotheses at 𝛼 = 0.05: 𝐇𝟎: The CSA approach and drill-practice intervention has no significant effect on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions; 𝐇𝟏: The CSA approach and drill-practice will significantly enhance Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The t-Test revealed a p-value of 0.139 which was statistically significant at 𝛼 = 0.05. Therefore, the researcher rejected the null hypothesis and concluded that the CSA approach and drill-practice have significantly enhanced the Grade 10 learners’ ability to simplify algebraic fractions.
- Full Text:
- Date Issued: 2016
A framework for grain commodity trading decision support in South Africa
- Authors: Ayankoya, Kayode Anthony
- Date: 2016
- Subjects: Grain trade -- South Africa Commodity exchanges -- South Africa Food industry and trade -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/11437 , vital:26925
- Description: In several countries around the world, grain commodities are traded as assets on stock exchanges. This indicate that the market and effectively the prices of the grain commodities in such countries, are controlled by several local and international economic, political and social factors that are rapidly changing. As a result, the prices of some grain commodities are volatile and trading in such commodities are prone to price-related risks. There are different trading strategies for minimising price-related risks and maximising profits. But empirical research suggests that making the right decision for effective grain commodities trading has been a difficult task for stakeholders due to high volatility of grain commodities prices. Studies have shown that this is more challenging among grain commodities farmers because of their lack of skills and the time to sift through and make sense of the datasets on the plethora of factors that influence the grain commodities market. This thesis focused on providing an answer for the main research problem that grain farmers in South Africa do not take full advantage of all the available strategies for trading their grain commodities because of the complexities associated with monitoring the large datasets that influence the grain commodities market. The main objective set by this study is to design a framework that can be followed to collect, integrate and analyse datasets that influence trading decisions of grain farmers in South Africa about grain commodities. This study takes advantage of the developments in Big Data and Data Science to achieve the set objective using the Design Science Research (DSR) methodology. The prediction of future prices of grain commodities for the different trading strategies was identified as an important factor for making better decisions when trading grain commodities and the key factors that influence the prices were identified. This was followed by a critical review of the literature to determine how the concepts of Big Data and Data Science can be leveraged for an effective grain commodities trading decision support. This resulted in a proposed framework for grain commodities trading. The proposed framework suggested an investigation of the factors that influence the prices of grain commodities as the basis for acquiring the relevant datasets. The proposed framework suggested the adoption of the Big Data approach in acquiring, preparing and integrating relevant datasets from several sources. Furthermore, it was suggested that algorithmic models for predicting grain commodities prices can be developed on top of the data layer of the proposed framework to provide real-time decision support. The proposed framework suggests the need for a carefully designed visualisation of the result and the collected data that promotes user experience. Lastly, the proposed framework included a technology consideration component to support the Big Data and Data Science approach of the framework. To demonstrate that the proposed framework addressed the main problem of this research, datasets from several sources on trading white maize in South Africa and the factors that influence market were streamed, integrated and analysed. Backpropagation Neural Network algorithm was used for modelling the prices of white maize for spot and futures trading strategies were predicted. There are other modelling techniques such as the Box-Jenkins statistical time series analysis methodology. But, Neural Networks was identified as more suitable for time series data with complex patterns and relationships. A demonstration system was setup to provide effective decision support by using near real-time data to provide a dynamic predictive analytics for the spot and December futures contract prices of white maize in South Africa. Comparative analysis of predictions made using the model from the proposed framework to actual data indicated a significant degree of accuracy. A further evaluation was carried out by asking experienced traders to make predictions for the spot and December futures contract prices of white maize. The result of the exercise indicated that the predictions from the developed model were much closer to the actual prices. This indicated that the proposed framework is technically capable and generally useful. It also shows that the proposed framework can be used to provide decision support about trading grain commodities to stakeholders with lesser skills, experience and resources. The practical contribution of this thesis is that relevant datasets from several sources can be streamed into an integrated data source in real-time, which can be used as input for a real-time learning algorithmic model for predicting grain commodities prices. This will make it possible for a predictive analytics that responds to market volatility thereby providing an effective decision support for grain commodities trading. Another practical contribution of this thesis is a proposed framework that can be followed for developing a Decision Support System for trading in grain commodities. This thesis made theoretical contributions by building on the information processing theory and the decision making theory. The theoretical contribution of this thesis consists of the identification of Big Data approach, tools and techniques for eradicating uncertainty and equivocality in grain commodities trading decision making process.
- Full Text:
- Date Issued: 2016
- Authors: Ayankoya, Kayode Anthony
- Date: 2016
- Subjects: Grain trade -- South Africa Commodity exchanges -- South Africa Food industry and trade -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/11437 , vital:26925
- Description: In several countries around the world, grain commodities are traded as assets on stock exchanges. This indicate that the market and effectively the prices of the grain commodities in such countries, are controlled by several local and international economic, political and social factors that are rapidly changing. As a result, the prices of some grain commodities are volatile and trading in such commodities are prone to price-related risks. There are different trading strategies for minimising price-related risks and maximising profits. But empirical research suggests that making the right decision for effective grain commodities trading has been a difficult task for stakeholders due to high volatility of grain commodities prices. Studies have shown that this is more challenging among grain commodities farmers because of their lack of skills and the time to sift through and make sense of the datasets on the plethora of factors that influence the grain commodities market. This thesis focused on providing an answer for the main research problem that grain farmers in South Africa do not take full advantage of all the available strategies for trading their grain commodities because of the complexities associated with monitoring the large datasets that influence the grain commodities market. The main objective set by this study is to design a framework that can be followed to collect, integrate and analyse datasets that influence trading decisions of grain farmers in South Africa about grain commodities. This study takes advantage of the developments in Big Data and Data Science to achieve the set objective using the Design Science Research (DSR) methodology. The prediction of future prices of grain commodities for the different trading strategies was identified as an important factor for making better decisions when trading grain commodities and the key factors that influence the prices were identified. This was followed by a critical review of the literature to determine how the concepts of Big Data and Data Science can be leveraged for an effective grain commodities trading decision support. This resulted in a proposed framework for grain commodities trading. The proposed framework suggested an investigation of the factors that influence the prices of grain commodities as the basis for acquiring the relevant datasets. The proposed framework suggested the adoption of the Big Data approach in acquiring, preparing and integrating relevant datasets from several sources. Furthermore, it was suggested that algorithmic models for predicting grain commodities prices can be developed on top of the data layer of the proposed framework to provide real-time decision support. The proposed framework suggests the need for a carefully designed visualisation of the result and the collected data that promotes user experience. Lastly, the proposed framework included a technology consideration component to support the Big Data and Data Science approach of the framework. To demonstrate that the proposed framework addressed the main problem of this research, datasets from several sources on trading white maize in South Africa and the factors that influence market were streamed, integrated and analysed. Backpropagation Neural Network algorithm was used for modelling the prices of white maize for spot and futures trading strategies were predicted. There are other modelling techniques such as the Box-Jenkins statistical time series analysis methodology. But, Neural Networks was identified as more suitable for time series data with complex patterns and relationships. A demonstration system was setup to provide effective decision support by using near real-time data to provide a dynamic predictive analytics for the spot and December futures contract prices of white maize in South Africa. Comparative analysis of predictions made using the model from the proposed framework to actual data indicated a significant degree of accuracy. A further evaluation was carried out by asking experienced traders to make predictions for the spot and December futures contract prices of white maize. The result of the exercise indicated that the predictions from the developed model were much closer to the actual prices. This indicated that the proposed framework is technically capable and generally useful. It also shows that the proposed framework can be used to provide decision support about trading grain commodities to stakeholders with lesser skills, experience and resources. The practical contribution of this thesis is that relevant datasets from several sources can be streamed into an integrated data source in real-time, which can be used as input for a real-time learning algorithmic model for predicting grain commodities prices. This will make it possible for a predictive analytics that responds to market volatility thereby providing an effective decision support for grain commodities trading. Another practical contribution of this thesis is a proposed framework that can be followed for developing a Decision Support System for trading in grain commodities. This thesis made theoretical contributions by building on the information processing theory and the decision making theory. The theoretical contribution of this thesis consists of the identification of Big Data approach, tools and techniques for eradicating uncertainty and equivocality in grain commodities trading decision making process.
- Full Text:
- Date Issued: 2016
Construction project manager health and safety interventions towards improving workers' performance
- Authors: Ayessaki, Winn-Yam Houdou
- Date: 2016
- Subjects: Construction industry -- Management -- Health aspects Construction workers -- Health aspects -- South Africa Construction workers -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12275 , vital:27050
- Description: Optimum construction worker (CW) performance is required to achieve project delivery within project parameters. It is not always the case as CWs are regularly exposed to hazards, involved in accidents, their productivity is poor, they suffer from ill health, suffer from work-related musculoskeletal disorders (WMSDs) and contractors lack resources to allocate towards H&S. However, the lack or the absence of health and safety (H&S) measures, which the aforementioned depend on, has a negative impact on workers’ performance. Two descriptive surveys were conducted among professional construction project managers (CPMs) registered with the South African Council for Project and Construction Management Professions (SACPCMP) and general contractors (GCs) registered with the East Cape Master Builders Association (ECMBA). Interviews were also conducted with CPMs registered with the SACPCMP residing in the Nelson Mandela Bay metropolitan area. The salient findings include: • Accidents, which occur on construction sites, impact workers’ performance; • Inadequate H&S implementation affects both CW skills and motivation, which in turn affects their performance; • Poor constructability is relevant to H&S and CWs’ skills; • Provision and maintenance of welfare facilities are commonly inadequate and affect workers’ performance, and • Projects do not benefit from the adequate financial provision for H&S. It was concluded that exposure to hazards, poor site conditions, inadequate provision of welfare facilities, WMSDs, and insufficient financial provision for H&S affect workers’ performance by either incapacitating or demotivating them. Recommendations include : CPMs should make better use of their influence on clients; they should improve communication channels between project stakeholders; legislators need to raise awareness regarding H&S and worker welfare, and training and education institutions need to empower workers and professionals with H&S knowledge.
- Full Text:
- Date Issued: 2016
- Authors: Ayessaki, Winn-Yam Houdou
- Date: 2016
- Subjects: Construction industry -- Management -- Health aspects Construction workers -- Health aspects -- South Africa Construction workers -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12275 , vital:27050
- Description: Optimum construction worker (CW) performance is required to achieve project delivery within project parameters. It is not always the case as CWs are regularly exposed to hazards, involved in accidents, their productivity is poor, they suffer from ill health, suffer from work-related musculoskeletal disorders (WMSDs) and contractors lack resources to allocate towards H&S. However, the lack or the absence of health and safety (H&S) measures, which the aforementioned depend on, has a negative impact on workers’ performance. Two descriptive surveys were conducted among professional construction project managers (CPMs) registered with the South African Council for Project and Construction Management Professions (SACPCMP) and general contractors (GCs) registered with the East Cape Master Builders Association (ECMBA). Interviews were also conducted with CPMs registered with the SACPCMP residing in the Nelson Mandela Bay metropolitan area. The salient findings include: • Accidents, which occur on construction sites, impact workers’ performance; • Inadequate H&S implementation affects both CW skills and motivation, which in turn affects their performance; • Poor constructability is relevant to H&S and CWs’ skills; • Provision and maintenance of welfare facilities are commonly inadequate and affect workers’ performance, and • Projects do not benefit from the adequate financial provision for H&S. It was concluded that exposure to hazards, poor site conditions, inadequate provision of welfare facilities, WMSDs, and insufficient financial provision for H&S affect workers’ performance by either incapacitating or demotivating them. Recommendations include : CPMs should make better use of their influence on clients; they should improve communication channels between project stakeholders; legislators need to raise awareness regarding H&S and worker welfare, and training and education institutions need to empower workers and professionals with H&S knowledge.
- Full Text:
- Date Issued: 2016
Perspectives of Post Graduate Certificate in Education (PGCE) students on the effectiveness of school based mentoring
- Authors: Baartman, Nomakhaya
- Date: 2016
- Subjects: Mentoring in education -- South Africa -- Eastern Cape Teachers -- In-service training -- South Africa -- Eastern Cape Student teachers -- Supervision of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/5641 , vital:29354
- Description: Effective mentoring is essential for the development of student-teachers. A sequential explanatory mixed method study was conducted in order to analyse the perspectives of Post Graduate Certificate of Education (PGCE) students on the effectiveness of school based mentoring. Thirty-six (36) PGCE students from a higher education institution in the Eastern Cape participated in this study. Firstly, quantitative questionnaires were used to gather data from all the participants followed by qualitative semi–structured interviews from a purposive sample of five (5) participants in order to enrich the study. This study analysed PGCE students’ perspectives of mentor teacher practices. In doing so the study evoked Hudson and Peards’ Five Factor Mentoring Model. This model includes Personal Attributes, Systems Requirements, Pedagogical Knowledge, Modelling and Feedback. From the findings, PGCE students reported that Teaching Practice (TP) is a stressful period full of anxieties, excitement and fears, hence they need to be guided and supported by knowledgeable and specialist teachers (mentors). Mentors play a significant role in supporting and guiding student-teachers during TP. From the analysis of PGCE students’ perspectives, the research suggested that those who were supported and guided by their mentors experienced positive mentoring during TP. Those who experienced negative mentoring reported limited time for mentoring and unavailability of the mentors as the causes. They further expressed that they wished mentors were understanding, good models who treated them as teacher candidates not as students and gave them constructive feedback. Finally, they indicated that the partnership between host schools and the university needs to be improved.
- Full Text:
- Date Issued: 2016
- Authors: Baartman, Nomakhaya
- Date: 2016
- Subjects: Mentoring in education -- South Africa -- Eastern Cape Teachers -- In-service training -- South Africa -- Eastern Cape Student teachers -- Supervision of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/5641 , vital:29354
- Description: Effective mentoring is essential for the development of student-teachers. A sequential explanatory mixed method study was conducted in order to analyse the perspectives of Post Graduate Certificate of Education (PGCE) students on the effectiveness of school based mentoring. Thirty-six (36) PGCE students from a higher education institution in the Eastern Cape participated in this study. Firstly, quantitative questionnaires were used to gather data from all the participants followed by qualitative semi–structured interviews from a purposive sample of five (5) participants in order to enrich the study. This study analysed PGCE students’ perspectives of mentor teacher practices. In doing so the study evoked Hudson and Peards’ Five Factor Mentoring Model. This model includes Personal Attributes, Systems Requirements, Pedagogical Knowledge, Modelling and Feedback. From the findings, PGCE students reported that Teaching Practice (TP) is a stressful period full of anxieties, excitement and fears, hence they need to be guided and supported by knowledgeable and specialist teachers (mentors). Mentors play a significant role in supporting and guiding student-teachers during TP. From the analysis of PGCE students’ perspectives, the research suggested that those who were supported and guided by their mentors experienced positive mentoring during TP. Those who experienced negative mentoring reported limited time for mentoring and unavailability of the mentors as the causes. They further expressed that they wished mentors were understanding, good models who treated them as teacher candidates not as students and gave them constructive feedback. Finally, they indicated that the partnership between host schools and the university needs to be improved.
- Full Text:
- Date Issued: 2016
The physical activity and health-related fitness of female students at a South African university
- Authors: Baatjes, Tashrique
- Date: 2016
- Subjects: Physical fitness for women Physical education and training Women college students -- Health and hygiene Health behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/5575 , vital:20909
- Description: Physical inactivity and resultant chronic diseases of lifestyle (CDLs) are becoming a global epidemic as secular modernization and the sedentary lifestyles it brings with it become universal. The importance of physical activity (PA) in reducing morbidity and mortality from CDLs and related conditions has been well established. Since it is generally significant that the onset of many CDLs lies in childhood through to adolescence, preventative strategies should start as early in life as possible. Currently, university students are failing to engage in the levels of PA recommended for better health outcomes over the short and long term. To make matters worse, there is increasing evidence of a decrease in PA during the transitional phase from adolescence to adulthood. This study aimed to determine the physical activity (PA) levels, sedentary behaviour and health-related fitness (HRF) characteristics of female university students. In addition, the participants‘ perceived barriers to PA were investigated. The study was exploratory-descriptive and employed a quantitative research design. Five hundred and thirty-one full-time female students, between the ages of 18 and 46, studying at Nelson Mandela Metropolitan University‘s (NMMU) South, North, Second Avenue and Missionvale campuses participated in the study. The participants (n=531) completed an online survey which determined their PA levels, sedentary behaviours and perceived barriers to PA participation. A health-related fitness (HRF) assessment was also administered to 68 participants who completed the online survey. Their height, weight, and waist and hip circumferences were measured, as well as their cardiovascular fitness (CF). The majority (88 percent) of the participants reported low and minimal levels of PA, and 44 percent were either overweight or obese. The participants had a low-risk waist-to-hip ratio (WHR) (M=0.70). The majority of the population (94 percent) had poor cardiovascular fitness (CF). A high prevalence of sitting time was recorded among the participants: on average 855 minutes (14 hours) on a usual weekday and 720 minutes (12 hours) on a usual weekend day. Students reported the greatest length of sitting time at work/attending lectures/studying. Cross tabulations and Chi2 tests indicated no significant relationships among PA and HRF (BMI, WHR and CF) and sedentary behaviour and HRF. The ANOVA and t-test results for PA, sedentary behaviour and HRF related to various demographic variables, found small (0.19 < d < 0.50) and medium (0.49 < d < 0.80) significant differences by race (d=0.43; d=0.52), home language (d=0.41; d=0.44) and living arrangement (d=0.38; d=0.28). No significant relationship was found to exist between age, year of study and faculty of registration and sedentary behaviour or HRF. The participants listed: Not enough time; too expensive to exercise; and, no friends who can exercise with me as the most important barriers to participation in PA. Academic obligations (3.08 mean) was found to be the most important barrier to PA.
- Full Text:
- Date Issued: 2016
- Authors: Baatjes, Tashrique
- Date: 2016
- Subjects: Physical fitness for women Physical education and training Women college students -- Health and hygiene Health behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/5575 , vital:20909
- Description: Physical inactivity and resultant chronic diseases of lifestyle (CDLs) are becoming a global epidemic as secular modernization and the sedentary lifestyles it brings with it become universal. The importance of physical activity (PA) in reducing morbidity and mortality from CDLs and related conditions has been well established. Since it is generally significant that the onset of many CDLs lies in childhood through to adolescence, preventative strategies should start as early in life as possible. Currently, university students are failing to engage in the levels of PA recommended for better health outcomes over the short and long term. To make matters worse, there is increasing evidence of a decrease in PA during the transitional phase from adolescence to adulthood. This study aimed to determine the physical activity (PA) levels, sedentary behaviour and health-related fitness (HRF) characteristics of female university students. In addition, the participants‘ perceived barriers to PA were investigated. The study was exploratory-descriptive and employed a quantitative research design. Five hundred and thirty-one full-time female students, between the ages of 18 and 46, studying at Nelson Mandela Metropolitan University‘s (NMMU) South, North, Second Avenue and Missionvale campuses participated in the study. The participants (n=531) completed an online survey which determined their PA levels, sedentary behaviours and perceived barriers to PA participation. A health-related fitness (HRF) assessment was also administered to 68 participants who completed the online survey. Their height, weight, and waist and hip circumferences were measured, as well as their cardiovascular fitness (CF). The majority (88 percent) of the participants reported low and minimal levels of PA, and 44 percent were either overweight or obese. The participants had a low-risk waist-to-hip ratio (WHR) (M=0.70). The majority of the population (94 percent) had poor cardiovascular fitness (CF). A high prevalence of sitting time was recorded among the participants: on average 855 minutes (14 hours) on a usual weekday and 720 minutes (12 hours) on a usual weekend day. Students reported the greatest length of sitting time at work/attending lectures/studying. Cross tabulations and Chi2 tests indicated no significant relationships among PA and HRF (BMI, WHR and CF) and sedentary behaviour and HRF. The ANOVA and t-test results for PA, sedentary behaviour and HRF related to various demographic variables, found small (0.19 < d < 0.50) and medium (0.49 < d < 0.80) significant differences by race (d=0.43; d=0.52), home language (d=0.41; d=0.44) and living arrangement (d=0.38; d=0.28). No significant relationship was found to exist between age, year of study and faculty of registration and sedentary behaviour or HRF. The participants listed: Not enough time; too expensive to exercise; and, no friends who can exercise with me as the most important barriers to participation in PA. Academic obligations (3.08 mean) was found to be the most important barrier to PA.
- Full Text:
- Date Issued: 2016
Influence of the macro-economic environment on the construction sector's contribution to the South African economy, 1984 to 2011
- Authors: Babalola, Adewumi Joseph
- Date: 2016
- Subjects: Construction industry -- Economic aspects Economic development Environmental economics
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/5618 , vital:20916
- Description: The construction sector serves as the engine of growth to the South Africa economy because of its catalytic role in the growth and development of the country. This study focuses mainly on the influence of the macro-economic environment on the contribution of the private sector to construction in the South Africa economy from 1984 to 2011. Government construction work is considered to be an injection into the economy; in this regard, state construction is regarded as public investment in the economy; and therefore, it is anti-cyclic (Keynes, 1936). The aim of this study has been to develop an econometric model for predicting the influence of the macroeconomic environment on the contribution of the private sector to the construction sector in the South Africa economy. The research design adopted in this study was an “ex-post facto” type, otherwise known as a causal-comparative design. The data were extracted from the published sources of the South African National Statistics, namely SARB, Stats SA and Quantec SA. The estimation technique used in this study was the ARDL model using quarterly data from 1984 to 2011. This is because in the construction sector, the influence of the independent variables is always felt over time – rather than all at once. The results of this study show that there is a long run causal relationship between inflation rate, interest rate, real exchange rate, GDP and gdp in the construction sector. The descriptive statistical analysis shows that there is a negative relationship between variables inflation rate and interest rate and the private sector spending in construction. However, economic growth as well as growth in the construction sector has a positive relationship with the private sector spending in construction. Likewise, the real exchange rate and labour productivity in construction have a negative relationship with the private sector’s spending in construction and they are statistically insignificant. The variance decomposition analysis show that the private sector spending in construction explains about 75 per cent of it variations, followed by inflation rate that explains 21 per cent on the average; while the remaining variations, comprising about 4 per cent, were shared among the other independent variables, such as GDP, GDP in construction, the interest rate and the real exchange rate. It was discovered that only the inflation rate does Granger-cause the private sector spending in construction. From the finding it can be concluded that inflation rate is a significant explanatory variable in explaining the variation in the dependent variable during period under review. Policy recommendations are as follows: firstly, the monetary authorities in South Africa should embark on sound policies that would bring about low prices of the construction materials. This would ensure growth and development in the construction sector; secondly, a stimulating development plan that would encourage private sector investment in properties and infrastructural development must be instituted; thirdly, an alternative policy to the present inflation targeting is recommended that would bring about low inflation, high growth, low unemployment and stable exchange rate; fourthly, the present policy on interest rate must be reviewed to allow for more participation in construction projects by the private sectors of the economy; fifthly, due to the fact that fluctuation in the crude oil prices in the international market is one of the major factors causing high inflation rate in South Africa, government must source local alternative products that would bring down prices of construction materials.
- Full Text:
- Date Issued: 2016
- Authors: Babalola, Adewumi Joseph
- Date: 2016
- Subjects: Construction industry -- Economic aspects Economic development Environmental economics
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/5618 , vital:20916
- Description: The construction sector serves as the engine of growth to the South Africa economy because of its catalytic role in the growth and development of the country. This study focuses mainly on the influence of the macro-economic environment on the contribution of the private sector to construction in the South Africa economy from 1984 to 2011. Government construction work is considered to be an injection into the economy; in this regard, state construction is regarded as public investment in the economy; and therefore, it is anti-cyclic (Keynes, 1936). The aim of this study has been to develop an econometric model for predicting the influence of the macroeconomic environment on the contribution of the private sector to the construction sector in the South Africa economy. The research design adopted in this study was an “ex-post facto” type, otherwise known as a causal-comparative design. The data were extracted from the published sources of the South African National Statistics, namely SARB, Stats SA and Quantec SA. The estimation technique used in this study was the ARDL model using quarterly data from 1984 to 2011. This is because in the construction sector, the influence of the independent variables is always felt over time – rather than all at once. The results of this study show that there is a long run causal relationship between inflation rate, interest rate, real exchange rate, GDP and gdp in the construction sector. The descriptive statistical analysis shows that there is a negative relationship between variables inflation rate and interest rate and the private sector spending in construction. However, economic growth as well as growth in the construction sector has a positive relationship with the private sector spending in construction. Likewise, the real exchange rate and labour productivity in construction have a negative relationship with the private sector’s spending in construction and they are statistically insignificant. The variance decomposition analysis show that the private sector spending in construction explains about 75 per cent of it variations, followed by inflation rate that explains 21 per cent on the average; while the remaining variations, comprising about 4 per cent, were shared among the other independent variables, such as GDP, GDP in construction, the interest rate and the real exchange rate. It was discovered that only the inflation rate does Granger-cause the private sector spending in construction. From the finding it can be concluded that inflation rate is a significant explanatory variable in explaining the variation in the dependent variable during period under review. Policy recommendations are as follows: firstly, the monetary authorities in South Africa should embark on sound policies that would bring about low prices of the construction materials. This would ensure growth and development in the construction sector; secondly, a stimulating development plan that would encourage private sector investment in properties and infrastructural development must be instituted; thirdly, an alternative policy to the present inflation targeting is recommended that would bring about low inflation, high growth, low unemployment and stable exchange rate; fourthly, the present policy on interest rate must be reviewed to allow for more participation in construction projects by the private sectors of the economy; fifthly, due to the fact that fluctuation in the crude oil prices in the international market is one of the major factors causing high inflation rate in South Africa, government must source local alternative products that would bring down prices of construction materials.
- Full Text:
- Date Issued: 2016
SASO and Black Consciousness, and the shift to congress politics
- Authors: Badat, Saleem
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/59755 , vital:27645 , http://witspress.co.za/catalogue/students-must-rise/
- Description: Students Must Rise 98 Chapter 8 SASO and Black Consciousness, and the shift to congress politics I n 1960, demonstrators protesting against pass laws were killed and injured by police at Sharpeville. Soon afterwards, the apartheid government declared a state of emergency. Over 11 000 political activists were detained, and repressive new laws, police raids, arrests, bannings, and torture were used to crush political opposition to apartheid. The African National Congress (ANC) and Pan Africanist Congress (PAC) were banned, and many leaders of the ANC and PAC were arrested and imprisoned , and hundreds fled into exile. For many white South Africans, the rest of the 1960s were a time of economic boom, political calm, prosperity, and rising living standards. Some blacks took the opportunity to accumulate wealth, power, and privilege through the Bantustans that the apartheid government established as part of its separate development programme. For most blacks, it was a period of great economic exploitation, extensive political and social control, fear, and demoralisation. It was difficult to see how there could be any political challenge to white minority rule. Anti-apartheid organisations faced immediate repression. They also had to overcome black people’s fear and demoralisation, which stood in the way of mobilising opposition against apartheid. The emergence of the South African Students’ Organisation and Black Consciousness Despite many problems, the South African Students’ Organisation (SASO) was formed as an exclusively black university and college student organisation in 1968. It escaped immediate state repression, and developed a following among students at the Saleem Badat SASO and Black Consciousness, and the shift to congress politics 99 universities reserved for blacks. Thereafter, the ideology of Black Consciousness (BC) was developed and other BC organisations were formed, resulting in the BC movement. SASO saw its challenge as the ‘assertion, manifestation and development of a sense of awareness politically, socially and economically among the black community’.1 It emphasised black ‘group cohesion and solidarity’ as ‘important facets of Black Consciousness’, the need for ‘the totality of involvement of the oppressed people’, and for BC ‘to be spread to reach all sections of the black community’.2 SASO began community development, literacy, education, media, culture, and sports projects, which aimed to help black communities to determine and realise their own needs. They were seen as a means to win the trust of people and to educate and mobilise them.3 Projects instilled the idea of self-reliance, seen as important for achieving freedom, in members and communities. SASO created a favourable political climate for various organisations to emerge.
- Full Text: false
- Date Issued: 2016
- Authors: Badat, Saleem
- Date: 2016
- Language: English
- Type: book chapter , text
- Identifier: http://hdl.handle.net/10962/59755 , vital:27645 , http://witspress.co.za/catalogue/students-must-rise/
- Description: Students Must Rise 98 Chapter 8 SASO and Black Consciousness, and the shift to congress politics I n 1960, demonstrators protesting against pass laws were killed and injured by police at Sharpeville. Soon afterwards, the apartheid government declared a state of emergency. Over 11 000 political activists were detained, and repressive new laws, police raids, arrests, bannings, and torture were used to crush political opposition to apartheid. The African National Congress (ANC) and Pan Africanist Congress (PAC) were banned, and many leaders of the ANC and PAC were arrested and imprisoned , and hundreds fled into exile. For many white South Africans, the rest of the 1960s were a time of economic boom, political calm, prosperity, and rising living standards. Some blacks took the opportunity to accumulate wealth, power, and privilege through the Bantustans that the apartheid government established as part of its separate development programme. For most blacks, it was a period of great economic exploitation, extensive political and social control, fear, and demoralisation. It was difficult to see how there could be any political challenge to white minority rule. Anti-apartheid organisations faced immediate repression. They also had to overcome black people’s fear and demoralisation, which stood in the way of mobilising opposition against apartheid. The emergence of the South African Students’ Organisation and Black Consciousness Despite many problems, the South African Students’ Organisation (SASO) was formed as an exclusively black university and college student organisation in 1968. It escaped immediate state repression, and developed a following among students at the Saleem Badat SASO and Black Consciousness, and the shift to congress politics 99 universities reserved for blacks. Thereafter, the ideology of Black Consciousness (BC) was developed and other BC organisations were formed, resulting in the BC movement. SASO saw its challenge as the ‘assertion, manifestation and development of a sense of awareness politically, socially and economically among the black community’.1 It emphasised black ‘group cohesion and solidarity’ as ‘important facets of Black Consciousness’, the need for ‘the totality of involvement of the oppressed people’, and for BC ‘to be spread to reach all sections of the black community’.2 SASO began community development, literacy, education, media, culture, and sports projects, which aimed to help black communities to determine and realise their own needs. They were seen as a means to win the trust of people and to educate and mobilise them.3 Projects instilled the idea of self-reliance, seen as important for achieving freedom, in members and communities. SASO created a favourable political climate for various organisations to emerge.
- Full Text: false
- Date Issued: 2016
The tax benefits available to investors in immovable property in South Africa
- Authors: Baines, Daniel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/4026 , vital:20589
- Description: The object of this thesis is to provide guidelines relating to the tax benefits that are available to investors in immovable property in South Africa. This was done by analysing the various sections of the Income Tax Act, as well as case law and South African Revenue Service guidelines that interpret these sections, which provide for expenditure which may be deducted by taxpayers from their income when conducting the trade of letting immovable property in order to reduce their overall tax liability. The thesis also includes a chapter dealing with the four different types of vehicles that taxpayers may use when investing in property. It was found that there are significant tax benefits available to investors in immovable property through the general deductions provided in terms of section 11(a) of the Act, as well as the specific deductions that the legislature has promulgated for investors in immovable property. It was also found that each of the four vehicles has its own advantages and that a taxpayer’s personal circumstances will dictate which of the vehicles will best suit his or her needs.
- Full Text:
- Date Issued: 2016
- Authors: Baines, Daniel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/4026 , vital:20589
- Description: The object of this thesis is to provide guidelines relating to the tax benefits that are available to investors in immovable property in South Africa. This was done by analysing the various sections of the Income Tax Act, as well as case law and South African Revenue Service guidelines that interpret these sections, which provide for expenditure which may be deducted by taxpayers from their income when conducting the trade of letting immovable property in order to reduce their overall tax liability. The thesis also includes a chapter dealing with the four different types of vehicles that taxpayers may use when investing in property. It was found that there are significant tax benefits available to investors in immovable property through the general deductions provided in terms of section 11(a) of the Act, as well as the specific deductions that the legislature has promulgated for investors in immovable property. It was also found that each of the four vehicles has its own advantages and that a taxpayer’s personal circumstances will dictate which of the vehicles will best suit his or her needs.
- Full Text:
- Date Issued: 2016
Between"culture" and "Cruelty"narratives of widows on land dispossession in Gqadu administrative area, Mbashe Municipality , Eastern Cape
- Authors: Baleka, Zola
- Date: 2016
- Subjects: Widows -- South Africa -- Eastern Cape Land tenure -- South Africa -- Eastern Cape Right of property -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5083 , vital:29057
- Description: This study highlights the cultural underpinnings of specific indulgences pertaining to land ownership with reference to widowhood in the rural Eastern Cape. The study does this by examining the narratives of widows about their experiences of land dispossession in Nqadu Administrative Area. Nqadu Administrative Area is a rural community in Mbhashe Local Municipality in the Eastern Cape Province of South Africa. The study focuses on widows’ experiences relating to the cultural practices of the community regarding land ownership. A qualitative, case study design was adopted. To uncover the widows’ narratives, the study utilised in-depth interviews and focus group discussions, with a sample of 50 widows. Further empirical data were obtained from four members of the municipal Land Committees, two Ward Councillors, four Traditional Leaders and two officials from the Eastern Cape Department of Rural Development and Agrarian Reform, using in-depth and key informant interviews. The study found that widows were vulnerable to land ownership violations and dispossessions, and that these violations were perpetrated by community members, particularly relatives of deceased husbands. Low levels of education and fear of antagonising clan relatives played a vital role in preventing widows from fighting for their legal rights. The failure of widows to fight for their rights increased their chances of being heavily exposed to dispossession of their land rights. Cultural practices within the communities catalysed abusive practices against widows, particularly against those whose marriage was not ‘recognised’ due to various stated reasons. The study also revealed that widows who had married as second wives and those who did not bear children experienced egregious abuses. Another finding was that men from Nqadu Administrative Area were given priority during the allocation of land, based on cultural and traditional practices, and were given land of their own choice depending on availability. The study thus highlights the impact of cultural practices and the ways in which these became instruments of gender abuse, despite the existence of laws designed to prevent specific social cruelties.
- Full Text:
- Date Issued: 2016
- Authors: Baleka, Zola
- Date: 2016
- Subjects: Widows -- South Africa -- Eastern Cape Land tenure -- South Africa -- Eastern Cape Right of property -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5083 , vital:29057
- Description: This study highlights the cultural underpinnings of specific indulgences pertaining to land ownership with reference to widowhood in the rural Eastern Cape. The study does this by examining the narratives of widows about their experiences of land dispossession in Nqadu Administrative Area. Nqadu Administrative Area is a rural community in Mbhashe Local Municipality in the Eastern Cape Province of South Africa. The study focuses on widows’ experiences relating to the cultural practices of the community regarding land ownership. A qualitative, case study design was adopted. To uncover the widows’ narratives, the study utilised in-depth interviews and focus group discussions, with a sample of 50 widows. Further empirical data were obtained from four members of the municipal Land Committees, two Ward Councillors, four Traditional Leaders and two officials from the Eastern Cape Department of Rural Development and Agrarian Reform, using in-depth and key informant interviews. The study found that widows were vulnerable to land ownership violations and dispossessions, and that these violations were perpetrated by community members, particularly relatives of deceased husbands. Low levels of education and fear of antagonising clan relatives played a vital role in preventing widows from fighting for their legal rights. The failure of widows to fight for their rights increased their chances of being heavily exposed to dispossession of their land rights. Cultural practices within the communities catalysed abusive practices against widows, particularly against those whose marriage was not ‘recognised’ due to various stated reasons. The study also revealed that widows who had married as second wives and those who did not bear children experienced egregious abuses. Another finding was that men from Nqadu Administrative Area were given priority during the allocation of land, based on cultural and traditional practices, and were given land of their own choice depending on availability. The study thus highlights the impact of cultural practices and the ways in which these became instruments of gender abuse, despite the existence of laws designed to prevent specific social cruelties.
- Full Text:
- Date Issued: 2016
Uhlalutyo ngokwesithako sobunzululwazi nkcubeko-ntlalo yaseAfrika kwinoveli yesiXhosa: Inkululeko isentabeni
- Authors: Bali, Nolundi Monica
- Date: 2016
- Subjects: Xhosa literature -- History and criticism
- Language: Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/9077 , vital:26462
- Description: Kule ngxoxo kuqwalaswele indlela amasiko nezithethe asetyenziswe ngayo kwincwadi kaSaule, ethi, Inkululeko isentabeni. Le ngxoxo ijolise ekuncomeni indlela lo kaSaule awasebenzise ngayo amasiko kunye nezithethe zakwaNtu ukwakha isizwe esimnyama. Konke oku kudandalazisa ukubaluleka kokusetyenziswa kwawo ukwakha isizwe. Injongo yolu phando kukuphendla indlela umtshato, isithembu, ulwaluko, imbeleko, intonjane, ukufa, ukukhapha, ukubuyisa nokungenwa ezaziqhutywa ngayo nezizathu zoko. Le ngxoxo iza kuphonononga ixhaswe ngezithako eziziimbono zeengcali zohlalutyo kwintlalo kaNtu. Ingxoxo le yahlulwe yazizahluko ezintandathu. Isahluko sokuqala sivula ngentshayelelo, ze sidandalazise intsusamabandla yolu phando, kushukuxwe imbangeli yophando, ze kwenziwe uphengululo lweencwadi zeengcali kwisithako sobuNzululwazi Nkcubeko-Ntlalo. Isahluko sesibini, siqwalasela ukuxabiseka kolwendo ngokwengcinga yesiNtu kwincwadi kaSaule. Indlela isiko lokuthwala lalisenziwa ngalo mandulo xa kuthelekiswa kweyangoku, nemiceli-mngeni elijamelene nalo eli siko. Isahluko sesithathu, sijongene nesithembu, iimeko ezazinyanzelisa ukuthathwa komfazi wesibini nangaphezulu nemiceli-mngeni ekhoyo kwesi sithethe. Isahluko sesine, singolwaluko ngemihla yamandulo size sithelekiswe nale mihla siphila kuyo. Iingxaki ezikhoyo kweli siko ezibangelwa kukungakhathali kwengcibi, namakhankatha. Esesihlanu, isahluko singamasiko nezithethe, iindlela ezazisaya kusetyenziswa mandulo kuthelekiswa nezeli xesha lokhanyo ekwenzeni la masiko nezi zithethe. Isahluko sesithandathu, sesokuphetha, siyintyilazwi yeengxoxo ezikolu hlalutyo, kuxilongwa ubuzaza besithako sobunzululwazi nkcubeko-ntlalo.
- Full Text:
- Date Issued: 2016
- Authors: Bali, Nolundi Monica
- Date: 2016
- Subjects: Xhosa literature -- History and criticism
- Language: Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/9077 , vital:26462
- Description: Kule ngxoxo kuqwalaswele indlela amasiko nezithethe asetyenziswe ngayo kwincwadi kaSaule, ethi, Inkululeko isentabeni. Le ngxoxo ijolise ekuncomeni indlela lo kaSaule awasebenzise ngayo amasiko kunye nezithethe zakwaNtu ukwakha isizwe esimnyama. Konke oku kudandalazisa ukubaluleka kokusetyenziswa kwawo ukwakha isizwe. Injongo yolu phando kukuphendla indlela umtshato, isithembu, ulwaluko, imbeleko, intonjane, ukufa, ukukhapha, ukubuyisa nokungenwa ezaziqhutywa ngayo nezizathu zoko. Le ngxoxo iza kuphonononga ixhaswe ngezithako eziziimbono zeengcali zohlalutyo kwintlalo kaNtu. Ingxoxo le yahlulwe yazizahluko ezintandathu. Isahluko sokuqala sivula ngentshayelelo, ze sidandalazise intsusamabandla yolu phando, kushukuxwe imbangeli yophando, ze kwenziwe uphengululo lweencwadi zeengcali kwisithako sobuNzululwazi Nkcubeko-Ntlalo. Isahluko sesibini, siqwalasela ukuxabiseka kolwendo ngokwengcinga yesiNtu kwincwadi kaSaule. Indlela isiko lokuthwala lalisenziwa ngalo mandulo xa kuthelekiswa kweyangoku, nemiceli-mngeni elijamelene nalo eli siko. Isahluko sesithathu, sijongene nesithembu, iimeko ezazinyanzelisa ukuthathwa komfazi wesibini nangaphezulu nemiceli-mngeni ekhoyo kwesi sithethe. Isahluko sesine, singolwaluko ngemihla yamandulo size sithelekiswe nale mihla siphila kuyo. Iingxaki ezikhoyo kweli siko ezibangelwa kukungakhathali kwengcibi, namakhankatha. Esesihlanu, isahluko singamasiko nezithethe, iindlela ezazisaya kusetyenziswa mandulo kuthelekiswa nezeli xesha lokhanyo ekwenzeni la masiko nezi zithethe. Isahluko sesithandathu, sesokuphetha, siyintyilazwi yeengxoxo ezikolu hlalutyo, kuxilongwa ubuzaza besithako sobunzululwazi nkcubeko-ntlalo.
- Full Text:
- Date Issued: 2016
Biological activity of extracellular and intracellular polysaccharides from Pleurotus tuber-regium hybrid and mutant strains
- Bamigboye, Comfort Olukemi, Oloke, Julius Kola, Dames, Joanna Felicity
- Authors: Bamigboye, Comfort Olukemi , Oloke, Julius Kola , Dames, Joanna Felicity
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69056 , vital:29376 , http://pubs.sciepub.com/jfnr/4/7/2/
- Description: Publisher version , Pleurotus tuber-regium (Fr.) Singer (1951) is a unique sclerotium-forming edible and medicinal mushroom. Interestingly, both the sclerotium and mushroom are edible and are often used for curing various ailments. Previous studies have focused on the antimicrobial and antioxidant activity of the extracellular polysaccharide (EPS) from wild P. tuber-regium. There has been no report on the intracellular polysaccharide (IPS) of the wild mycelia, likewise there is very meager information on the improvement of the perceived potentials of P. tuber-regium. This research study analysed the EPS and IPS fractions of P. tuber-regium hybrid and mutant strains. The antimicrobial potential of the IPS and EPS fractions, their scavenging activity on 1, 1-diphenyl–2picryhydrazyl (DPPH) and Hydroxyl radicals were also determined. Both IPS and EPS fractions of P. tuber-regium hybrids and mutants showed increased DPPH and hydroxyl scavenging activity over the wild P. tuber-regium with an EC50 mostly 1 mg/ml. The antimicrobial activity of the IPS from a mutant strain had an IC50 of 15.6 mg/ml compared to the wild type (18.75 mg /ml). This study showed that selected mutant and hybrids of P. tuber-regium had increased radical scavenging activity indicating potentially increased biological activity that could offer increased benefit as a neutraceutical.
- Full Text: false
- Date Issued: 2016
- Authors: Bamigboye, Comfort Olukemi , Oloke, Julius Kola , Dames, Joanna Felicity
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69056 , vital:29376 , http://pubs.sciepub.com/jfnr/4/7/2/
- Description: Publisher version , Pleurotus tuber-regium (Fr.) Singer (1951) is a unique sclerotium-forming edible and medicinal mushroom. Interestingly, both the sclerotium and mushroom are edible and are often used for curing various ailments. Previous studies have focused on the antimicrobial and antioxidant activity of the extracellular polysaccharide (EPS) from wild P. tuber-regium. There has been no report on the intracellular polysaccharide (IPS) of the wild mycelia, likewise there is very meager information on the improvement of the perceived potentials of P. tuber-regium. This research study analysed the EPS and IPS fractions of P. tuber-regium hybrid and mutant strains. The antimicrobial potential of the IPS and EPS fractions, their scavenging activity on 1, 1-diphenyl–2picryhydrazyl (DPPH) and Hydroxyl radicals were also determined. Both IPS and EPS fractions of P. tuber-regium hybrids and mutants showed increased DPPH and hydroxyl scavenging activity over the wild P. tuber-regium with an EC50 mostly 1 mg/ml. The antimicrobial activity of the IPS from a mutant strain had an IC50 of 15.6 mg/ml compared to the wild type (18.75 mg /ml). This study showed that selected mutant and hybrids of P. tuber-regium had increased radical scavenging activity indicating potentially increased biological activity that could offer increased benefit as a neutraceutical.
- Full Text: false
- Date Issued: 2016
Implementation of classroom action research in Zimbabwean teacher education colleges: implications for teacher education curriculum
- Authors: Banda, Wilson
- Date: 2016
- Subjects: Action research in education , Education -- Research , Curriculum planning
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/10604 , vital:35632
- Description: It was the purpose of this study to interrogate the implementation of classroom action research (CAR) in identified Zimbabwean teachers’ colleges to provide the basis for future policy directions and related day-to-day CAR practice. The study leaned on the progressive educationists’ stance that teaching is an intricate profession that has more to it than mere technical skills. Teaching is viewed as a lifelong profession that requires pre-service teachers to be capacitated with CAR skills and competencies to ensure that they systematically, intentionally and critically consider a myriad of learner related psychosocial factors in their tour of duty. In that way teachers are made to appreciate why they should teach the way they teach, without necessarily turning them into some kind of public intellectuals, philosophers or theorists. The study utilised the mixed methods research approach in tune with the adopted pragmatism paradigm. The research paradigm draws on the strengths of both empirical data and the theoretical sentiments drawn from the respondents. The study used the concurrent triangulation design, rooted in the post-positivist research paradigm that integrates concurrent procedures in the collection, analysis and interpretation of research data. It was guided by three theoretical frameworks, namely, the experiential learning theory, the curriculum implementation framework and the living educational theory. The theories have a strong bearing on reflective practice and they acknowledge the subjectivity of truth. The study’s purposive sample comprised of sixty-four teacher educators and seventy-six preservice teachers. Several research instruments were utilised to solicit the requisite CAR implementation quantitative and qualitative data. These were questionnaires, interview schedules, focus group discussions and documents. The Statistical Packages for Social Sciences were used to summarise the solicited data through graphical representations and related frequency tables depicting descriptive statistics such as range, mean and mode. Qualitative data were analysed using content analysis through emerging themes, iv related to the sub-research questions. The study established that although the bulk of the teacher educators had the requisite professional qualifications, maturity and experiential background, more curricular and organisational reconstruction was required to improve on the status quo. For instance, solicited data demonstrated that the lecturers’ appetite for educational research was low. Furthermore, the teacher educators’ CAR skills and competencies were compromised by the research component’s inadequate contact time. In addition, it was instituted that the teachers’ colleges produced student teachers who lacked sound grasp of the CAR process. The mediocrity was attributed to a series of teacher educator and student teacher factors which were exacerbated by several other organisational and administrative impediments. Overall, the study concluded that teacher educators were incapacitated to effectively deliver CAR, owing partly to the nature of teacher educator preparation they got and the watered down professional induction. It further revealed that it was wrong to assume that all lecturers had operational capacity to effectively teach and supervise CAR projects. Furthermore, the study recommended that the teacher educators’ capacity in CAR needs enhancement. Identified CAR implementation strategies need further reconstruction and enforcement.
- Full Text:
- Date Issued: 2016
- Authors: Banda, Wilson
- Date: 2016
- Subjects: Action research in education , Education -- Research , Curriculum planning
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/10604 , vital:35632
- Description: It was the purpose of this study to interrogate the implementation of classroom action research (CAR) in identified Zimbabwean teachers’ colleges to provide the basis for future policy directions and related day-to-day CAR practice. The study leaned on the progressive educationists’ stance that teaching is an intricate profession that has more to it than mere technical skills. Teaching is viewed as a lifelong profession that requires pre-service teachers to be capacitated with CAR skills and competencies to ensure that they systematically, intentionally and critically consider a myriad of learner related psychosocial factors in their tour of duty. In that way teachers are made to appreciate why they should teach the way they teach, without necessarily turning them into some kind of public intellectuals, philosophers or theorists. The study utilised the mixed methods research approach in tune with the adopted pragmatism paradigm. The research paradigm draws on the strengths of both empirical data and the theoretical sentiments drawn from the respondents. The study used the concurrent triangulation design, rooted in the post-positivist research paradigm that integrates concurrent procedures in the collection, analysis and interpretation of research data. It was guided by three theoretical frameworks, namely, the experiential learning theory, the curriculum implementation framework and the living educational theory. The theories have a strong bearing on reflective practice and they acknowledge the subjectivity of truth. The study’s purposive sample comprised of sixty-four teacher educators and seventy-six preservice teachers. Several research instruments were utilised to solicit the requisite CAR implementation quantitative and qualitative data. These were questionnaires, interview schedules, focus group discussions and documents. The Statistical Packages for Social Sciences were used to summarise the solicited data through graphical representations and related frequency tables depicting descriptive statistics such as range, mean and mode. Qualitative data were analysed using content analysis through emerging themes, iv related to the sub-research questions. The study established that although the bulk of the teacher educators had the requisite professional qualifications, maturity and experiential background, more curricular and organisational reconstruction was required to improve on the status quo. For instance, solicited data demonstrated that the lecturers’ appetite for educational research was low. Furthermore, the teacher educators’ CAR skills and competencies were compromised by the research component’s inadequate contact time. In addition, it was instituted that the teachers’ colleges produced student teachers who lacked sound grasp of the CAR process. The mediocrity was attributed to a series of teacher educator and student teacher factors which were exacerbated by several other organisational and administrative impediments. Overall, the study concluded that teacher educators were incapacitated to effectively deliver CAR, owing partly to the nature of teacher educator preparation they got and the watered down professional induction. It further revealed that it was wrong to assume that all lecturers had operational capacity to effectively teach and supervise CAR projects. Furthermore, the study recommended that the teacher educators’ capacity in CAR needs enhancement. Identified CAR implementation strategies need further reconstruction and enforcement.
- Full Text:
- Date Issued: 2016
Nonlinear optical response of a low symmetry phthalocyanine in the presence of gold nanoparticles when in solution or embedded in poly acrylic acid polymer thin films
- Bankole, Owolabi M, Nyokong, Tebello
- Authors: Bankole, Owolabi M , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188719 , vital:44779 , xlink:href="https://doi.org/10.1016/j.jphotochem.2015.12.014"
- Description: In this article, we explored the photophysical and nonlinear optical (NLO) characterizations of low symmetry phthalocyanine (ZnPc-NH2) covalently linked to MPA-capped AuNPs (ZnPc-NH2-AuNPs) and poly acrylic acid (ZnPc-NH2-PAA). Nonlinear optical (NLO) properties of the samples were evaluated using Z-scan technique at 532 nm and 10 ns pulsed duration. We observed enhanced photophysical and nonlinear optical behaviour for the ZnPc-NH2 in presence of AuNPs. By virtue of the magnitude of absorption coefficients and other NLO optical parameters estimated in this work, ZnPc-NH2-AuNPs was found to exhibit improved nonlinear optical response compared to the ZnPc-NH2 and ZnPc-NH2-PAA. Both ZnPc-NH2-AuNPs and ZnPc-NH2 doped in PAA possess strong nonlinear absorption coefficients and very low limiting thresholds than when measured in solution.
- Full Text:
- Date Issued: 2016
- Authors: Bankole, Owolabi M , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188719 , vital:44779 , xlink:href="https://doi.org/10.1016/j.jphotochem.2015.12.014"
- Description: In this article, we explored the photophysical and nonlinear optical (NLO) characterizations of low symmetry phthalocyanine (ZnPc-NH2) covalently linked to MPA-capped AuNPs (ZnPc-NH2-AuNPs) and poly acrylic acid (ZnPc-NH2-PAA). Nonlinear optical (NLO) properties of the samples were evaluated using Z-scan technique at 532 nm and 10 ns pulsed duration. We observed enhanced photophysical and nonlinear optical behaviour for the ZnPc-NH2 in presence of AuNPs. By virtue of the magnitude of absorption coefficients and other NLO optical parameters estimated in this work, ZnPc-NH2-AuNPs was found to exhibit improved nonlinear optical response compared to the ZnPc-NH2 and ZnPc-NH2-PAA. Both ZnPc-NH2-AuNPs and ZnPc-NH2 doped in PAA possess strong nonlinear absorption coefficients and very low limiting thresholds than when measured in solution.
- Full Text:
- Date Issued: 2016
Comparative studies on photophysical and optical limiting characterizations of low symmetry phthalocyanine linked to Fe 3 O 4–Ag core–shell or hybrid nanoparticles
- Bankole, Owolabi M, Nyokong, Tebello
- Authors: Bankole, Owolabi M , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188788 , vital:44785 , xlink:href="https://doi.org/10.1039/C6NJ01511E"
- Description: Photophysical and nonlinear optical (NLO) behaviours of low symmetry zinc phthalocyanine (1) linked to Fe3O4/Ag core–shell (represented as Fe/Ag) or Fe3O4–Ag hybrid (represented as FeAg) nanoparticles were investigated in DMSO. Triplet quantum yields and NLO parameters of phthalocyanine improved due to the combined effects of magnetic–metallic nanoparticles. A direct relationship between the increased triplet excited state absorptions by already excited molecules and reverse saturable absorption (RSA) was established as the predominant mechanism responsible for nonlinearity of the samples. Our findings show that, at the same approximate concentrations and conditions, 1-FeAg enhanced the OL potentials of 1 more than 1-Fe/Ag.
- Full Text:
- Date Issued: 2016
- Authors: Bankole, Owolabi M , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188788 , vital:44785 , xlink:href="https://doi.org/10.1039/C6NJ01511E"
- Description: Photophysical and nonlinear optical (NLO) behaviours of low symmetry zinc phthalocyanine (1) linked to Fe3O4/Ag core–shell (represented as Fe/Ag) or Fe3O4–Ag hybrid (represented as FeAg) nanoparticles were investigated in DMSO. Triplet quantum yields and NLO parameters of phthalocyanine improved due to the combined effects of magnetic–metallic nanoparticles. A direct relationship between the increased triplet excited state absorptions by already excited molecules and reverse saturable absorption (RSA) was established as the predominant mechanism responsible for nonlinearity of the samples. Our findings show that, at the same approximate concentrations and conditions, 1-FeAg enhanced the OL potentials of 1 more than 1-Fe/Ag.
- Full Text:
- Date Issued: 2016
Nonlinear optical behavior of alkyne terminated phthalocyanines in solution and when embedded in polysulfone as thin films: effects of aggregation
- Bankole, Owolabi M, Yilmaz, Yusuf, Nyokong, Tebello
- Authors: Bankole, Owolabi M , Yilmaz, Yusuf , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189110 , vital:44817 , xlink:href="https://doi.org/10.1016/j.optmat.2015.11.041"
- Description: We report here for the first time, on the comparative studies of the photophysical and optical limiting behavior of our two novel phthalocyanines namely 2(3), 9(10), 16(17), 23(24)-tetrakis-(4-(5-methylhex-1-yn-3-yloxy)) phthalocyanines 2, and 2(3), 9(10), 16(17), 23(24)-tetrakis-(4-(5-methylhex-1-yn-3-yloxy)) phthalocyaninato zinc (II) (3) in solution and thin films. Nonlinear optical (NLO) properties of the samples in solution and contained in polysulfone (PSU) thin films were evaluated using Z-scan technique at 532 nm and 10 ns pulsed duration. Effects of aggregation and disaggregation on the NLO performance of metal-free phthalocyanine are reported in detail. Our findings showed that the prepared Pcs show larger nonlinear absorption coefficient and lower limiting thresholds when embedded in polysulfone films compared to in solutions. The values of nonlinear susceptibility and hyperpolarizability recorded for 3-PSU in this work are respectively, ∼2.09 × 10−8 esu and ∼1.02 × 10−26 esu. These values are among the largest values reported for phthalocyanines and other macrocycles doped on polymer matrices.
- Full Text:
- Date Issued: 2016
- Authors: Bankole, Owolabi M , Yilmaz, Yusuf , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189110 , vital:44817 , xlink:href="https://doi.org/10.1016/j.optmat.2015.11.041"
- Description: We report here for the first time, on the comparative studies of the photophysical and optical limiting behavior of our two novel phthalocyanines namely 2(3), 9(10), 16(17), 23(24)-tetrakis-(4-(5-methylhex-1-yn-3-yloxy)) phthalocyanines 2, and 2(3), 9(10), 16(17), 23(24)-tetrakis-(4-(5-methylhex-1-yn-3-yloxy)) phthalocyaninato zinc (II) (3) in solution and thin films. Nonlinear optical (NLO) properties of the samples in solution and contained in polysulfone (PSU) thin films were evaluated using Z-scan technique at 532 nm and 10 ns pulsed duration. Effects of aggregation and disaggregation on the NLO performance of metal-free phthalocyanine are reported in detail. Our findings showed that the prepared Pcs show larger nonlinear absorption coefficient and lower limiting thresholds when embedded in polysulfone films compared to in solutions. The values of nonlinear susceptibility and hyperpolarizability recorded for 3-PSU in this work are respectively, ∼2.09 × 10−8 esu and ∼1.02 × 10−26 esu. These values are among the largest values reported for phthalocyanines and other macrocycles doped on polymer matrices.
- Full Text:
- Date Issued: 2016
Enhanced nonlinear optical responses of zinc diaminopyrimidin-2-ylthio phthalocyanine conjugated to AgxAuy alloy nanoparticles
- Bankole, Owolabi M, Osifeko, Olawale, Nyokong, Tebello
- Authors: Bankole, Owolabi M , Osifeko, Olawale , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240382 , vital:50829 , xlink:href="https://doi.org/10.1016/j.jphotochem.2016.06.025"
- Description: In this article, the photophysical and nonlinear optical (NLO) characterizations of diaminopyrimidin-2-ylthio phthalocyaninatozinc (II) (2) before and after conjugation to AgxAuy nano-alloys are discussed. Phthalocyanines-AgxAuy (2-AgxAuy) composites showed enhanced triplet state and nonlinear optical behaviour when compared to free phthalocyanine. Optical limiting (OL) responses of the samples were evaluated using Z-scan technique at 532 nm and 10 ns in dimethyl sulfoxide. Reverse saturable absorption (RSA), which is a direct consequence of triplet absorption of already excited molecules was observed as the dominant mechanism responsible for nonlinearity of the samples. By virtue of the magnitude of absorption coefficients and other NLO optical parameters estimated in this work, 2-AgxAuy composites were found to exhibit stronger optical limiting responses than unconjugated phthalocyanine. The large third-order susceptibilities of the composites make them suitable materials for attenuating modern laser radiations, and also found useful in various optical applications.
- Full Text:
- Date Issued: 2016
- Authors: Bankole, Owolabi M , Osifeko, Olawale , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240382 , vital:50829 , xlink:href="https://doi.org/10.1016/j.jphotochem.2016.06.025"
- Description: In this article, the photophysical and nonlinear optical (NLO) characterizations of diaminopyrimidin-2-ylthio phthalocyaninatozinc (II) (2) before and after conjugation to AgxAuy nano-alloys are discussed. Phthalocyanines-AgxAuy (2-AgxAuy) composites showed enhanced triplet state and nonlinear optical behaviour when compared to free phthalocyanine. Optical limiting (OL) responses of the samples were evaluated using Z-scan technique at 532 nm and 10 ns in dimethyl sulfoxide. Reverse saturable absorption (RSA), which is a direct consequence of triplet absorption of already excited molecules was observed as the dominant mechanism responsible for nonlinearity of the samples. By virtue of the magnitude of absorption coefficients and other NLO optical parameters estimated in this work, 2-AgxAuy composites were found to exhibit stronger optical limiting responses than unconjugated phthalocyanine. The large third-order susceptibilities of the composites make them suitable materials for attenuating modern laser radiations, and also found useful in various optical applications.
- Full Text:
- Date Issued: 2016