Izaci namaqhalo esiXhosa: Xhosa idioms and proverbs referring to plants
- Cocks, Michelle L, Dold, Anthony P
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141326 , vital:37962 , https://hdl.handle.net/10520/EJC112940
- Description: Converging with the ecological extinction crisis, the planet has been experiencing a severe erosion of the diversity of human cultures and languages, reducing the pool of knowledge, behaviors and values from which individual communities and humanity at large can draw to respond to social and environmental stresses.
- Full Text:
- Date Issued: 2006
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141326 , vital:37962 , https://hdl.handle.net/10520/EJC112940
- Description: Converging with the ecological extinction crisis, the planet has been experiencing a severe erosion of the diversity of human cultures and languages, reducing the pool of knowledge, behaviors and values from which individual communities and humanity at large can draw to respond to social and environmental stresses.
- Full Text:
- Date Issued: 2006
JM Coetzee's Disgrace and the Task of the Imagination:
- Authors: Marais, Mike
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144126 , vital:38313 , DOI: 10.2979/JML.2006.29.2.75
- Description: In an early review of Disgrace, Jane Taylor first relates this novel's treatment of violence in post-apartheid South Africa to the European Enlightenment's legacy of the autonomy of the human subject (25), in terms of which each individual is conceived of as a living consciousness separated totally from every other consciousness, and then discusses J.M. Coetzee's postulation of the sympathetic imagination as a potential corrective to the violence attendant on monadic individuality. Taylor makes the telling point that, in the eighteenth century, the notions of sensibility, sympathy, and compassion, which the novel repeatedly invokes, were self-consciously developed as an ethical response to the instrumentalist logic of autonomous individuality and, in this regard, she cites Adam Smith's observation in The Theory of Moral Sentiments that "By the imagination we place ourselves in his situation, we conceive ourselves enduring all the same torments, we enter as it were into his body, and become in some measure the same person with him, and thence form some idea of his sensation" (qtd. in Taylor 25).
- Full Text:
- Date Issued: 2006
- Authors: Marais, Mike
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144126 , vital:38313 , DOI: 10.2979/JML.2006.29.2.75
- Description: In an early review of Disgrace, Jane Taylor first relates this novel's treatment of violence in post-apartheid South Africa to the European Enlightenment's legacy of the autonomy of the human subject (25), in terms of which each individual is conceived of as a living consciousness separated totally from every other consciousness, and then discusses J.M. Coetzee's postulation of the sympathetic imagination as a potential corrective to the violence attendant on monadic individuality. Taylor makes the telling point that, in the eighteenth century, the notions of sensibility, sympathy, and compassion, which the novel repeatedly invokes, were self-consciously developed as an ethical response to the instrumentalist logic of autonomous individuality and, in this regard, she cites Adam Smith's observation in The Theory of Moral Sentiments that "By the imagination we place ourselves in his situation, we conceive ourselves enduring all the same torments, we enter as it were into his body, and become in some measure the same person with him, and thence form some idea of his sensation" (qtd. in Taylor 25).
- Full Text:
- Date Issued: 2006
Joking around in Zimbabwe, undoing and redoing participation
- Authors: Price, Leigh
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373715 , vital:66716 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122750"
- Description: In Zimbabwe, I teach a participatory course on environmental education to trainers. The course is an adaptation of a course designed by Rhodes University, South Africa. It gives participants a background in educational theories and has a strong theoretical component built around a focus on practice. During the time that the course was being delivered to non-industry participants, the theoretical component of the course was whole-heartedly embraced. We assumed that calling the course ‘participatory’ presupposed the need for this theory because within the theory were the tools for emancipation. And participation, we believed, had an emancipatory mandate. However, when we decided to redevelop the course for industry, we were uncomfortably surprised by the request from a majority of industry participants to reduce the theory and concentrate solely on skills-based training. This paper documents how this discomfort resulted in my adjusting my view of participation.
- Full Text:
- Date Issued: 2006
- Authors: Price, Leigh
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373715 , vital:66716 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122750"
- Description: In Zimbabwe, I teach a participatory course on environmental education to trainers. The course is an adaptation of a course designed by Rhodes University, South Africa. It gives participants a background in educational theories and has a strong theoretical component built around a focus on practice. During the time that the course was being delivered to non-industry participants, the theoretical component of the course was whole-heartedly embraced. We assumed that calling the course ‘participatory’ presupposed the need for this theory because within the theory were the tools for emancipation. And participation, we believed, had an emancipatory mandate. However, when we decided to redevelop the course for industry, we were uncomfortably surprised by the request from a majority of industry participants to reduce the theory and concentrate solely on skills-based training. This paper documents how this discomfort resulted in my adjusting my view of participation.
- Full Text:
- Date Issued: 2006
Labouring to love: romantic love and power in the construction of middle-class femininity
- Vincent, Louise, McEwen, Caryn
- Authors: Vincent, Louise , McEwen, Caryn
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141783 , vital:38004 , DOI: 10.1177/097152150501300102
- Description: South Africa is 10 years into its new democratic order. An aspect of the country's political transformation has been an official political commitment to gender trans-formation. While great strides have been made towards greater gender equality at the institutional and legal level of society, the present article suggests that highly unequal power relations between men and women continue to be perpetuated in unexpected ways among those whom we would most expect to be capable of resistance. This paper is about how subtle yet deeply embedded ideologies and practices within heterosexual relationships serve to keep highly educated, apparently empowered and liberated women ‘in their place’, ensuring that they do not fulfil their potential. Traditionally women were socialised into assuming their positions in the home as caregivers and unpaid household labourers. The hope of feminism was that education, economic empowerment and an ideology of ‘can do’ independence would liberate women. However, for many women, it is in the most intimate aspects of their lives—in their sexual relationships with men—that this hope continues to be thwarted.
- Full Text:
- Date Issued: 2006
- Authors: Vincent, Louise , McEwen, Caryn
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141783 , vital:38004 , DOI: 10.1177/097152150501300102
- Description: South Africa is 10 years into its new democratic order. An aspect of the country's political transformation has been an official political commitment to gender trans-formation. While great strides have been made towards greater gender equality at the institutional and legal level of society, the present article suggests that highly unequal power relations between men and women continue to be perpetuated in unexpected ways among those whom we would most expect to be capable of resistance. This paper is about how subtle yet deeply embedded ideologies and practices within heterosexual relationships serve to keep highly educated, apparently empowered and liberated women ‘in their place’, ensuring that they do not fulfil their potential. Traditionally women were socialised into assuming their positions in the home as caregivers and unpaid household labourers. The hope of feminism was that education, economic empowerment and an ideology of ‘can do’ independence would liberate women. However, for many women, it is in the most intimate aspects of their lives—in their sexual relationships with men—that this hope continues to be thwarted.
- Full Text:
- Date Issued: 2006
Managing South Africa's trawl bycatch
- Walmsley, Sarah A, Leslie, Rob W, Sauer, Warwick H H
- Authors: Walmsley, Sarah A , Leslie, Rob W , Sauer, Warwick H H
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124954 , vital:35713 , https://doi.10.1093/icesjms/fsl022
- Description: Over the past few decades, it has become widely recognized that the management strategies of world fisheries must ensure sustainability of bycatch as well as of target species. South Africa implemented a pilot observer programme from 1995 to 2000 to collect data on the levels and patterns of bycatch and discards in the demersal trawl fishery. Here, the results of that programme are used in conjunction with information on bycatch value and compliance to assess the issues and problems regarding bycatch and discarding in the fishery. In general, bycatch components can be placed into one of three categories (discarded bycatch, retained bycatch, and processing waste), each of which present different management problems and require different management approaches. The results were used to formulate a bycatch management plan for the demersal trawl fishery in South Africa. Given the need to continue monitoring bycatch, the performance of the pilot observer programme is reviewed, and the levels of sampling effort required for a national programme are discussed.
- Full Text:
- Date Issued: 2006
- Authors: Walmsley, Sarah A , Leslie, Rob W , Sauer, Warwick H H
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124954 , vital:35713 , https://doi.10.1093/icesjms/fsl022
- Description: Over the past few decades, it has become widely recognized that the management strategies of world fisheries must ensure sustainability of bycatch as well as of target species. South Africa implemented a pilot observer programme from 1995 to 2000 to collect data on the levels and patterns of bycatch and discards in the demersal trawl fishery. Here, the results of that programme are used in conjunction with information on bycatch value and compliance to assess the issues and problems regarding bycatch and discarding in the fishery. In general, bycatch components can be placed into one of three categories (discarded bycatch, retained bycatch, and processing waste), each of which present different management problems and require different management approaches. The results were used to formulate a bycatch management plan for the demersal trawl fishery in South Africa. Given the need to continue monitoring bycatch, the performance of the pilot observer programme is reviewed, and the levels of sampling effort required for a national programme are discussed.
- Full Text:
- Date Issued: 2006
Methinks he doth protest too much - recovering unjustified payments made under duress and protest
- Authors: Glover, Graham B
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70744 , vital:29724 , https://hdl.handle.net/10520/EJC55014
- Description: The private law doctrine of duress, although mostly discussed in the context of the law of contract in South Africa, is also relevant in the law of unjustified enrichment. Where an unjustified payment or transfer of some kind has been induced by duress, in a situation where there is no contractual relationship between the parties, the aggrieved party will be entitled to reclaim the payment or transfer. The principles of enrichment law will apply in such cases.
- Full Text: false
- Date Issued: 2006
- Authors: Glover, Graham B
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70744 , vital:29724 , https://hdl.handle.net/10520/EJC55014
- Description: The private law doctrine of duress, although mostly discussed in the context of the law of contract in South Africa, is also relevant in the law of unjustified enrichment. Where an unjustified payment or transfer of some kind has been induced by duress, in a situation where there is no contractual relationship between the parties, the aggrieved party will be entitled to reclaim the payment or transfer. The principles of enrichment law will apply in such cases.
- Full Text: false
- Date Issued: 2006
Mlanjeni's war charms: Ikhubalo likaMlanjeni
- Cocks, Michelle L, Dold, Anthony P
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141349 , vital:37964 , https://hdl.handle.net/10520/EJC112911
- Description: Most South Africans are familiar with lucky charms such as the four leaved clover of European origin, the Hamsa Hand (Arabic) or Hamesh Hand (Hebrew), the Hindu lucky elephant representing Ganesha, son of Siva, or the African ikhubalo. Amakhubalo refer to charms, often of plant origin, that have magical powers to ward off danger or to bring good luck. Charm plants are used almost everywhere in the Eastern Cape to ensure health, luck and success in sporting events, business, courtship, legal proceedings, safety against accidents and crime and protection against jealousy and sorcery.
- Full Text:
- Date Issued: 2006
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141349 , vital:37964 , https://hdl.handle.net/10520/EJC112911
- Description: Most South Africans are familiar with lucky charms such as the four leaved clover of European origin, the Hamsa Hand (Arabic) or Hamesh Hand (Hebrew), the Hindu lucky elephant representing Ganesha, son of Siva, or the African ikhubalo. Amakhubalo refer to charms, often of plant origin, that have magical powers to ward off danger or to bring good luck. Charm plants are used almost everywhere in the Eastern Cape to ensure health, luck and success in sporting events, business, courtship, legal proceedings, safety against accidents and crime and protection against jealousy and sorcery.
- Full Text:
- Date Issued: 2006
Of no account?: South Africa's electoral system (non) debate
- Authors: Vincent, Louise
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141657 , vital:37994 , DOI: 10.1080/02589000500513796
- Description: Accountability can be summarised simply as ‘answerability’ (James and Hadland 2002:1) and is a vital cornerstone of representative democracy. Without accountability, an electorate, once having put into power a particular representative, has no recourse to explanations, justifications or reviews of how that person has performed and whether or not they have fulfilled the promises which secured their election in the first place. In a representative democracy mechanisms of accountability are necessarily multiple and must include both formal and informal dimensions. The electoral system is but one of these. Other key lynchpins in the accountability engine include the role of opposition parties, the committee system, the media, civil society, the courts, and what in South Africa are referred to, on the basis of the 1996 Constitution, as the ‘Chapter Nine Institutions’: the Public Protector, Human Rights Commission, Commission for the Promotion and Protection of the Rights of Cultural, Religious and Linguistic Communities, Commission for Gender Equality, Auditor-General, and the Electoral Commission.
- Full Text:
- Date Issued: 2006
- Authors: Vincent, Louise
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141657 , vital:37994 , DOI: 10.1080/02589000500513796
- Description: Accountability can be summarised simply as ‘answerability’ (James and Hadland 2002:1) and is a vital cornerstone of representative democracy. Without accountability, an electorate, once having put into power a particular representative, has no recourse to explanations, justifications or reviews of how that person has performed and whether or not they have fulfilled the promises which secured their election in the first place. In a representative democracy mechanisms of accountability are necessarily multiple and must include both formal and informal dimensions. The electoral system is but one of these. Other key lynchpins in the accountability engine include the role of opposition parties, the committee system, the media, civil society, the courts, and what in South Africa are referred to, on the basis of the 1996 Constitution, as the ‘Chapter Nine Institutions’: the Public Protector, Human Rights Commission, Commission for the Promotion and Protection of the Rights of Cultural, Religious and Linguistic Communities, Commission for Gender Equality, Auditor-General, and the Electoral Commission.
- Full Text:
- Date Issued: 2006
Orthopaedic grade ultra–high molecular weight polyethylene: some features of the main thermoluminescence glow curve
- Authors: Chithambo, Makaiko L
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125499 , vital:35789 , https://doi.10.1093/rpd/nci661
- Description: Thermoluminescence (TL) characteristics of orthopaedic–grade ultra–high molecular weight polyethylene have been investigated between 20 and 200_C. The TL at 1_C s_1 consists of two glow curves, a weaker intensity peak at 115_C and the main peak at 70_C, studied in this work. TL intensity increases with beta irradiation but with a dose–response influenced by heating rate. On the other hand, the peak maximum is affected by both irradiation and repeated use of a sample. The glow curve shifts to higher temperatures with increase in heating rate but only slightly so with change in beta irradiation dose, properties suggestive of first-order kinetics. Kinetic analysis for activation energy and order of kinetics, based on the discrete trap model, produce somewhat conflicting results. Whereas qualitative analysis of peak symmetry show that first-order kinetics apply, geometrical analysis of the peak shape suggests that the order of kinetics might be other than first-order. Values of activation energy evaluated using the initial rise method were found to be dose dependent and for a given beta dose are in agreement with calculations from peak shape and initial rise methods but less so with results from variable heating rate method.
- Full Text:
- Date Issued: 2006
- Authors: Chithambo, Makaiko L
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125499 , vital:35789 , https://doi.10.1093/rpd/nci661
- Description: Thermoluminescence (TL) characteristics of orthopaedic–grade ultra–high molecular weight polyethylene have been investigated between 20 and 200_C. The TL at 1_C s_1 consists of two glow curves, a weaker intensity peak at 115_C and the main peak at 70_C, studied in this work. TL intensity increases with beta irradiation but with a dose–response influenced by heating rate. On the other hand, the peak maximum is affected by both irradiation and repeated use of a sample. The glow curve shifts to higher temperatures with increase in heating rate but only slightly so with change in beta irradiation dose, properties suggestive of first-order kinetics. Kinetic analysis for activation energy and order of kinetics, based on the discrete trap model, produce somewhat conflicting results. Whereas qualitative analysis of peak symmetry show that first-order kinetics apply, geometrical analysis of the peak shape suggests that the order of kinetics might be other than first-order. Values of activation energy evaluated using the initial rise method were found to be dose dependent and for a given beta dose are in agreement with calculations from peak shape and initial rise methods but less so with results from variable heating rate method.
- Full Text:
- Date Issued: 2006
Participating in the UN Decade of Education for Sustainability: voices in a southern African consultation process
- Authors: Lotz-Sisitka, Heila
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67367 , vital:29081 , https://www.ajol.info/index.php/sajee/article/view/122720
- Description: publisher version , This paper documents the outcomes of the consultation process on participating in the UNDESD which was led by the SADC Regional Environmental Education Programme in 2005/2006, assisted by the Rhodes University Environmental Education and Sustainability Unit and Environment Africa. The goals of the consultation process were to explore interpretations and meaning-making around the global discourse of ESD in a southern African context. Findings from the consultation process provide useful baseline information on the status of debate on sustainable development in educational circles; participation and partnerships; insights into environmental and sustainability education (ESD) practice and mechanisms needed for supporting this practice. The paper ends by outlining a research agenda for ESD in southern Africa, as discussed during the consultation process.
- Full Text:
- Date Issued: 2006
- Authors: Lotz-Sisitka, Heila
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67367 , vital:29081 , https://www.ajol.info/index.php/sajee/article/view/122720
- Description: publisher version , This paper documents the outcomes of the consultation process on participating in the UNDESD which was led by the SADC Regional Environmental Education Programme in 2005/2006, assisted by the Rhodes University Environmental Education and Sustainability Unit and Environment Africa. The goals of the consultation process were to explore interpretations and meaning-making around the global discourse of ESD in a southern African context. Findings from the consultation process provide useful baseline information on the status of debate on sustainable development in educational circles; participation and partnerships; insights into environmental and sustainability education (ESD) practice and mechanisms needed for supporting this practice. The paper ends by outlining a research agenda for ESD in southern Africa, as discussed during the consultation process.
- Full Text:
- Date Issued: 2006
Predictor variables for moggel (Labeo umbratus) biomass and production in small South African reservoirs
- Potts, Warren M, Booth, Anthony J, Hecht, Thomas, Andrew, Timothy G
- Authors: Potts, Warren M , Booth, Anthony J , Hecht, Thomas , Andrew, Timothy G
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125763 , vital:35815 , https://doi.10.2989/16085910609503877
- Description: South Africa has approximately 3 100 registered reservoirs, ranging in size from 1–1 000 hectares, with a surface area totalling 84 439 hectares (SADC Surface Water Body Database, unpublished data). Within southern and eastern Africa, Lindqvist (1994) estimated the number of small reservoirs to be between 50 000 and 100 000. Given Bernacsek’s (1986) estimate of the total fishery potential of small reservoirs in Africa at between 1 and 2.3 million tons, this number of reservoirs clearly could provide fishery opportunities for rural communities.
- Full Text:
- Date Issued: 2006
- Authors: Potts, Warren M , Booth, Anthony J , Hecht, Thomas , Andrew, Timothy G
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125763 , vital:35815 , https://doi.10.2989/16085910609503877
- Description: South Africa has approximately 3 100 registered reservoirs, ranging in size from 1–1 000 hectares, with a surface area totalling 84 439 hectares (SADC Surface Water Body Database, unpublished data). Within southern and eastern Africa, Lindqvist (1994) estimated the number of small reservoirs to be between 50 000 and 100 000. Given Bernacsek’s (1986) estimate of the total fishery potential of small reservoirs in Africa at between 1 and 2.3 million tons, this number of reservoirs clearly could provide fishery opportunities for rural communities.
- Full Text:
- Date Issued: 2006
Preliminary observations of tag shedding, tag reporting, tag wounds, and tag biofouling for raggedtooth sharks (Carcharias taurus) tagged off the east coast of South Africa
- Dicken, Matthew Laurence, Booth, Anthony J, Smale, Malcolm John
- Authors: Dicken, Matthew Laurence , Booth, Anthony J , Smale, Malcolm John
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125774 , vital:35816 , https://doi.10.1016/j.icesjms.2006.06.009
- Description: Mark-recapture models do not distinguish how ‘‘deaths’’ accrue to marked animals in the population. If animals lose their tags, then recaptures will be fewer than expected and estimates of survival will be underestimated (Arnason and Mills, 1981; McDonald et al., 2003). Similarly, if the non-reporting rate is unknown and assumed to be negligible, as is the case in some tagging studies (e.g. Cliff et al., 1996, for white sharks Carcharodon carcharias), the probability of capture can be underestimated. The effects of both these problems, inherent in cooperative tagging programmes, lead to too few tagged fish being recovered, with a positive bias on the estimation of population size. These effects are most pronounced when capture probability is low and fewer tags are available for recapture (McDonald et al., 2003).
- Full Text:
- Date Issued: 2006
- Authors: Dicken, Matthew Laurence , Booth, Anthony J , Smale, Malcolm John
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125774 , vital:35816 , https://doi.10.1016/j.icesjms.2006.06.009
- Description: Mark-recapture models do not distinguish how ‘‘deaths’’ accrue to marked animals in the population. If animals lose their tags, then recaptures will be fewer than expected and estimates of survival will be underestimated (Arnason and Mills, 1981; McDonald et al., 2003). Similarly, if the non-reporting rate is unknown and assumed to be negligible, as is the case in some tagging studies (e.g. Cliff et al., 1996, for white sharks Carcharodon carcharias), the probability of capture can be underestimated. The effects of both these problems, inherent in cooperative tagging programmes, lead to too few tagged fish being recovered, with a positive bias on the estimation of population size. These effects are most pronounced when capture probability is low and fewer tags are available for recapture (McDonald et al., 2003).
- Full Text:
- Date Issued: 2006
Self-assembled monolayers (SAMs) of cobalt tetracarboxylic acidchloride phthalocyanine covalently attached onto a preformed mercaptoethanol SAM
- Mashazi, Philani N, Ozoemena, Kenneth I, Maree, David M, Nyokong, Tebello
- Authors: Mashazi, Philani N , Ozoemena, Kenneth I , Maree, David M , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283792 , vital:55989 , xlink:href="https://doi.org/10.1016/j.electacta.2005.10.004"
- Description: A feasible method of fabricating phthalocyanine sensor was developed by covalent attachment of cobalt tetracarboxylic acidchloride phthalocyanine (CoTCACIPc) onto a preformed 2-mercaptoethanol (2-ME) self-assembled monolayer (SAM) modified gold electrode (designated as CoTCACIPc-2-ME-SAM). The surface concentration of the CoTCACIPc was found to be 4.58 × 10−10 mol/cm2. The sensor gave a linear response to L-cysteine over the concentration range 0.28–20 μM with a detection limit of 5 × 10−7 M and best response time of 2 s.
- Full Text:
- Date Issued: 2006
- Authors: Mashazi, Philani N , Ozoemena, Kenneth I , Maree, David M , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283792 , vital:55989 , xlink:href="https://doi.org/10.1016/j.electacta.2005.10.004"
- Description: A feasible method of fabricating phthalocyanine sensor was developed by covalent attachment of cobalt tetracarboxylic acidchloride phthalocyanine (CoTCACIPc) onto a preformed 2-mercaptoethanol (2-ME) self-assembled monolayer (SAM) modified gold electrode (designated as CoTCACIPc-2-ME-SAM). The surface concentration of the CoTCACIPc was found to be 4.58 × 10−10 mol/cm2. The sensor gave a linear response to L-cysteine over the concentration range 0.28–20 μM with a detection limit of 5 × 10−7 M and best response time of 2 s.
- Full Text:
- Date Issued: 2006
Self-assembled monolayers and electropolymerized thin films of phthalocyanines as molecular materials for electroanalysis
- Nyokong, Tebello, Bedioui, Fethi
- Authors: Nyokong, Tebello , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283826 , vital:55994 , xlink:href="https://doi.org/10.1142/S1088424606000454"
- Description: In this review, we report on the newly developed area of research devoted to the formation of self-assembled monolayers of metallophthalocyanines by focusing on some significant examples dedicated to electroanalytical applications. We also summarize recent examples on the use of electropolymerized metallophthalocyanine films in electroanalysis. In both cases, activation and detection of thiols are the main targeted applications.
- Full Text:
- Date Issued: 2006
- Authors: Nyokong, Tebello , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283826 , vital:55994 , xlink:href="https://doi.org/10.1142/S1088424606000454"
- Description: In this review, we report on the newly developed area of research devoted to the formation of self-assembled monolayers of metallophthalocyanines by focusing on some significant examples dedicated to electroanalytical applications. We also summarize recent examples on the use of electropolymerized metallophthalocyanine films in electroanalysis. In both cases, activation and detection of thiols are the main targeted applications.
- Full Text:
- Date Issued: 2006
Self-assembled monolayers and electropolymerized thin films of phthalocyanines as molecular materials for electroanalysis
- Nyokong, Tebello, Bedioui, Fethi
- Authors: Nyokong, Tebello , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283851 , vital:55996 , xlink:href="https://doi.org/10.1142/S1088424606000454"
- Description: In this review, we report on the newly developed area of research devoted to the formation of self-assembled monolayers of metallophthalocyanines by focusing on some significant examples dedicated to electroanalytical applications. We also summarize recent examples on the use of electropolymerized metallophthalocyanine films in electroanalysis. In both cases, activation and detection of thiols are the main targeted applications.
- Full Text:
- Date Issued: 2006
- Authors: Nyokong, Tebello , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283851 , vital:55996 , xlink:href="https://doi.org/10.1142/S1088424606000454"
- Description: In this review, we report on the newly developed area of research devoted to the formation of self-assembled monolayers of metallophthalocyanines by focusing on some significant examples dedicated to electroanalytical applications. We also summarize recent examples on the use of electropolymerized metallophthalocyanine films in electroanalysis. In both cases, activation and detection of thiols are the main targeted applications.
- Full Text:
- Date Issued: 2006
Situated environmental learning in Southern Africa at the start of the UN decade of education for sustainable development
- O'Donoghue, Rob, Lotz-Sisitka, Heila
- Authors: O'Donoghue, Rob , Lotz-Sisitka, Heila
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183059 , vital:43908 , xlink:href="https://doi.org/10.1017/S0814062600001737"
- Description: Within the globalising trajectory of modernism, conservation, then environmental (EE) and now sustainability education (ESD) have each emerged as developing responses to risk produced by and in the modern state. Through adopting a long term process perspective, this paper narrates the emergence of situated learning perspectives and a developing re-orientation of EE at the start of the United Nations Decade of Education for Sustainable Development (UNDESD). We identified the need to examine ESD practice in responses to recent ESD consultations in 14 southern African countries, where a rhetorical marking was noted in discussions on ESD practices, particularly with regard to changing teaching and learning processes. The paper narrates how an interplay of review, research and practical engagement activities have all contributed to an extended critical review of learning interactions in environmental education in an attempt to provide useful perspective for educational activities within the UNDESD. We found that EE and ESD initiatives only acquired more substantive meaning and coherent orientation when examined within ongoing inquiries into situated learning, agency and risk reduction in contexts of poverty, vulnerability and risk, the key concern to us in this paper and the primary focus of the WEHAB (Water, Energy, Health, Agriculture and Biodiversity) sustainable development agenda in the region.
- Full Text:
- Date Issued: 2006
- Authors: O'Donoghue, Rob , Lotz-Sisitka, Heila
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183059 , vital:43908 , xlink:href="https://doi.org/10.1017/S0814062600001737"
- Description: Within the globalising trajectory of modernism, conservation, then environmental (EE) and now sustainability education (ESD) have each emerged as developing responses to risk produced by and in the modern state. Through adopting a long term process perspective, this paper narrates the emergence of situated learning perspectives and a developing re-orientation of EE at the start of the United Nations Decade of Education for Sustainable Development (UNDESD). We identified the need to examine ESD practice in responses to recent ESD consultations in 14 southern African countries, where a rhetorical marking was noted in discussions on ESD practices, particularly with regard to changing teaching and learning processes. The paper narrates how an interplay of review, research and practical engagement activities have all contributed to an extended critical review of learning interactions in environmental education in an attempt to provide useful perspective for educational activities within the UNDESD. We found that EE and ESD initiatives only acquired more substantive meaning and coherent orientation when examined within ongoing inquiries into situated learning, agency and risk reduction in contexts of poverty, vulnerability and risk, the key concern to us in this paper and the primary focus of the WEHAB (Water, Energy, Health, Agriculture and Biodiversity) sustainable development agenda in the region.
- Full Text:
- Date Issued: 2006
Spotlight on research: 50 years of Pharmaceutical Sciences Research Excellence Faculty of Pharmacy Rhodes University
- Authors: Walker, Roderick B
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184243 , vital:44193 , xlink:href="https://hdl.handle.net/10520/EJC81478"
- Description: This year, the Faculty of Pharmacy at Rhodes University is celebrating its 50th Anniversary. Over 2000 BPharm, 33 BSc honours, 65 MSc and 27 PhD degrees have been conferred since the Faculty’s inception. The diverse research activities and dedicated academic staff have ensured that the Faculty of Pharmacy has high visibility with respect to research outputs, as is evidenced by the appointment of various members of staff to national and international research, regulatory and professional committees, as well as to serving on the editorial boards of a number of international journals. In addition, staff regularly publish in international and local peer-reviewed journals and present their research findings at international and local conferences.
- Full Text:
- Date Issued: 2006
- Authors: Walker, Roderick B
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184243 , vital:44193 , xlink:href="https://hdl.handle.net/10520/EJC81478"
- Description: This year, the Faculty of Pharmacy at Rhodes University is celebrating its 50th Anniversary. Over 2000 BPharm, 33 BSc honours, 65 MSc and 27 PhD degrees have been conferred since the Faculty’s inception. The diverse research activities and dedicated academic staff have ensured that the Faculty of Pharmacy has high visibility with respect to research outputs, as is evidenced by the appointment of various members of staff to national and international research, regulatory and professional committees, as well as to serving on the editorial boards of a number of international journals. In addition, staff regularly publish in international and local peer-reviewed journals and present their research findings at international and local conferences.
- Full Text:
- Date Issued: 2006
Synthesis and electrochemical characterisation of α-and β-tetra-substituted oxo (phthalocyaninato) titanium (IV) complexes
- Tau, Prudence, Nyokong, Tebello
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283869 , vital:55998 , xlink:href="https://doi.org/10.1016/j.poly.2005.11.025"
- Description: The synthesis, spectroscopic and electrochemical characterisation of the following oxotitanium tetra-substituted phthalocyanines are reported: 1,(4)-(tetraphenoxyphthalocyaninato)titanium(IV) oxide (5a); 1,(4)-(tetra-tert-butylphenoxyphthalocyaninato)titanium(IV) oxide (5b); 2,(3)-(tetraphenoxyphthalocyaninato)titanium(IV) oxide (6a) and 2,(3)-(tetra-tert-butylphenoxyphthalocyaninato)titanium(IV) oxide (6b). Complexes 5a and 5b are substituted at the non-peripheral (α) positions, whereas complexes 6a and 6b are substituted at the peripheral (β) positions. Cyclic voltammograms of all four complexes are similar, with three reversible reduction couples and three quasi-reversible to irreversible oxidations. The first two reductions are two-electron processes, confirmed by spectroelectrochemistry to be due to TiIVPc−2/TiIIPc−3 and TiIIPc−2/TiIPc−3 redox processes. Spectroelectrochemistry showed that upon oxidation, the molecule decomposes. Oxidation is expected to occur at the ring. Chronocoulometry confirmed two electron transfer at the first and second reduction steps; and a one electron transfer at the third reduction.
- Full Text:
- Date Issued: 2006
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283869 , vital:55998 , xlink:href="https://doi.org/10.1016/j.poly.2005.11.025"
- Description: The synthesis, spectroscopic and electrochemical characterisation of the following oxotitanium tetra-substituted phthalocyanines are reported: 1,(4)-(tetraphenoxyphthalocyaninato)titanium(IV) oxide (5a); 1,(4)-(tetra-tert-butylphenoxyphthalocyaninato)titanium(IV) oxide (5b); 2,(3)-(tetraphenoxyphthalocyaninato)titanium(IV) oxide (6a) and 2,(3)-(tetra-tert-butylphenoxyphthalocyaninato)titanium(IV) oxide (6b). Complexes 5a and 5b are substituted at the non-peripheral (α) positions, whereas complexes 6a and 6b are substituted at the peripheral (β) positions. Cyclic voltammograms of all four complexes are similar, with three reversible reduction couples and three quasi-reversible to irreversible oxidations. The first two reductions are two-electron processes, confirmed by spectroelectrochemistry to be due to TiIVPc−2/TiIIPc−3 and TiIIPc−2/TiIPc−3 redox processes. Spectroelectrochemistry showed that upon oxidation, the molecule decomposes. Oxidation is expected to occur at the ring. Chronocoulometry confirmed two electron transfer at the first and second reduction steps; and a one electron transfer at the third reduction.
- Full Text:
- Date Issued: 2006
Synthesis and photophysical properties of octa-substituted phthalocyaninato oxotitanium (IV) derivatives
- Tau, Prudence, Nyokong, Tebello
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283881 , vital:55999 , xlink:href="https://doi.org/10.1142/S1088424606000399"
- Description: The synthesis, spectral and photophysical properties including fluorescence quenching of the following octa-substituted oxotitanium phthalocyanines are reported: 2,3,9,10,16,17,23,24-octaphenoxyphthalocyaninato titanium(IV) oxide, 2,3,9,10,16,17,23,24-[octakis(4-t-butylphenoxyphthalocyaninato)]titanium(IV) oxide, 2,3,9,10,16,17,23,24-{octakis[(4-benzyloxy)phenoxy]phthalocyaninato}titanium(IV) oxide and 2,3,9,10,16,17,23,24-octaphenylthiophthalocyaninato titanium(IV) oxide. The complexes are characterized by 1H NMR, IR and UV-vis spectroscopies. Their photophysical properties are presented where moderate fluorescence quantum yields (0.14-0.19) and lifetimes were determined. Varied triplet quantum yields were obtained and the triplet lifetimes (40-100 μs) were short.
- Full Text:
- Date Issued: 2006
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283881 , vital:55999 , xlink:href="https://doi.org/10.1142/S1088424606000399"
- Description: The synthesis, spectral and photophysical properties including fluorescence quenching of the following octa-substituted oxotitanium phthalocyanines are reported: 2,3,9,10,16,17,23,24-octaphenoxyphthalocyaninato titanium(IV) oxide, 2,3,9,10,16,17,23,24-[octakis(4-t-butylphenoxyphthalocyaninato)]titanium(IV) oxide, 2,3,9,10,16,17,23,24-{octakis[(4-benzyloxy)phenoxy]phthalocyaninato}titanium(IV) oxide and 2,3,9,10,16,17,23,24-octaphenylthiophthalocyaninato titanium(IV) oxide. The complexes are characterized by 1H NMR, IR and UV-vis spectroscopies. Their photophysical properties are presented where moderate fluorescence quantum yields (0.14-0.19) and lifetimes were determined. Varied triplet quantum yields were obtained and the triplet lifetimes (40-100 μs) were short.
- Full Text:
- Date Issued: 2006
Teacher education for Mathematical Literacy: a modelling approach
- Brown, Bruce J L, Schäfer, Marc
- Authors: Brown, Bruce J L , Schäfer, Marc
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141040 , vital:37939 , DOI: 10.4102/pythagoras.v0i64.98
- Description: This paper reports on a study of the extent to which question design affects the solution strategies adopted by children when solving linear number pattern generalisation tasks presented in pictorial and numeric contexts. The research tool comprised a series of 22 pencil-and-paper exercises based on linear generalisation tasks set in both numeric and two-dimensional pictorial contexts. The responses to these linear generalisation questions were classified by means of stage descriptors as well as stage modifiers. The method or strategy adopted was analysed and classified into one of seven categories. In addition, a meta-analysis focused on the formula derived for the nth term in conjunction with its justification. The results of this study strongly support the notion that question design can play a critical role in influencing learners' choice of strategy and level of attainment when solving pattern generalisation tasks. An understanding of the importance of appropriate question design has direct pedagogical application within the context of the mathematics classroom.
- Full Text:
- Date Issued: 2006
- Authors: Brown, Bruce J L , Schäfer, Marc
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141040 , vital:37939 , DOI: 10.4102/pythagoras.v0i64.98
- Description: This paper reports on a study of the extent to which question design affects the solution strategies adopted by children when solving linear number pattern generalisation tasks presented in pictorial and numeric contexts. The research tool comprised a series of 22 pencil-and-paper exercises based on linear generalisation tasks set in both numeric and two-dimensional pictorial contexts. The responses to these linear generalisation questions were classified by means of stage descriptors as well as stage modifiers. The method or strategy adopted was analysed and classified into one of seven categories. In addition, a meta-analysis focused on the formula derived for the nth term in conjunction with its justification. The results of this study strongly support the notion that question design can play a critical role in influencing learners' choice of strategy and level of attainment when solving pattern generalisation tasks. An understanding of the importance of appropriate question design has direct pedagogical application within the context of the mathematics classroom.
- Full Text:
- Date Issued: 2006