"Complexes of carbohydrates with magnesium-ions" : "the isolation of an oligosaccharide containing L-galactose from the polysaccharide of Aeodes orbitosa" : "horizontal cellulose colum chromatography of sugars"
- Authors: Van der Linde, Michael John
- Date: 1974
- Subjects: Magenesium , Ions , Carbohydrates , Oligosaccharides , Polysaccharides , Chromatographic analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4504 , http://hdl.handle.net/10962/d1013282
- Description: Sugar complexes with anions and cations are reviewed. Evidence is presented for the formation of a complex of stoichiometry 1:1 in aqueous solution between methyl-α-Dglucopyranoside and magnesium perchlorate. The complex may be detected by the method of continuous variations. Measurements of changes in the proton chemical shifts of the glucoside in dauterium oxide, indicate that the complex is probably formed between the vicinal hydroxyl groups at C-2 and C-3 of the pyranoside ring and the hydrated cation. At elevation temperatures there is evidence for the presence of a complex of stoichiometry 2:1. Experiments conducted on cellulose indicate the possible formation of cellulose - magnesium-ion complexes . These complexes provide an explanation for the "protective action" of mEgnesium compounds on the cellulose portion of pulp during alkali-oxygen bleaching.
- Full Text:
- Date Issued: 1974
- Authors: Van der Linde, Michael John
- Date: 1974
- Subjects: Magenesium , Ions , Carbohydrates , Oligosaccharides , Polysaccharides , Chromatographic analysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4504 , http://hdl.handle.net/10962/d1013282
- Description: Sugar complexes with anions and cations are reviewed. Evidence is presented for the formation of a complex of stoichiometry 1:1 in aqueous solution between methyl-α-Dglucopyranoside and magnesium perchlorate. The complex may be detected by the method of continuous variations. Measurements of changes in the proton chemical shifts of the glucoside in dauterium oxide, indicate that the complex is probably formed between the vicinal hydroxyl groups at C-2 and C-3 of the pyranoside ring and the hydrated cation. At elevation temperatures there is evidence for the presence of a complex of stoichiometry 2:1. Experiments conducted on cellulose indicate the possible formation of cellulose - magnesium-ion complexes . These complexes provide an explanation for the "protective action" of mEgnesium compounds on the cellulose portion of pulp during alkali-oxygen bleaching.
- Full Text:
- Date Issued: 1974
"But what story?": a narrative-discursive analysis of "white" Afrikaners' accounts of male involvement in parenthood decision-making
- Authors: Morison, Tracy
- Date: 2011
- Subjects: Family planning -- South Africa -- Psychological aspects Family size Birth intervals Men -- South Africa -- Attitudes Men -- South Africa -- Psychology Couples -- South Africa -- Psychology Afrikaners -- Attitudes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3025 , http://hdl.handle.net/10962/d1002534
- Description: Despite the increased focus on men in reproductive research, little is known about male involvement in the initial decision/s regarding parenthood (i.e., to become a parent or not) and the subsequent decision-making that may ensue (e.g., choices about timing or spacing of births). In particular, the parenthood decision-making of “White”, heterosexual men from the middle class has been understudied, as indicated in the existing literature. In South Africa, this oversight has been exacerbated by the tendency for researchers to concentrate on “problematic” men, to the exclusion of the “boring, normal case”. I argue that this silence in the literature is a result of the taken for granted nature of parenthood in the “normal” heterosexual life course. In this study, I have turned the spotlight onto the norm of “Whiteness” and heterosexuality by studying those who have previously been overlooked by researchers. I focus on “White” Afrikaans men’s involvement in parenthood decision-making. My aim was to explore how constructions of gender inform male involvement in decision-making, especially within the South African context where social transformation has challenged traditional conceptions of male selfhood giving rise to new and contested masculine identities and new discourses of manhood and fatherhood. In an effort to ensure that women’s voices are not marginalised in the research, as is often the case in studies of men and masculinity, I conducted in-depth, semi-structured interviews about male involvement in decision-making with both “White” Afrikaans women and men. There were 23 participants in total, who all identified as heterosexual and middle-class. The participants were divided into two age cohorts (21 – 30 years and >40 years), which were then differentiated according to gender, reproductive status, and relationship status. Treating the interviews as jointly produced narratives, I analysed them by means of a performativity/performance lens. This dual analytic lens focuses on how particular narrative performances are simultaneously shaped by the interview setting and the broader discursive context. The lens was fashioned by synthesising Butler’s theory of performativity with Taylor’s narrative-discursive method. This synthesis (1) allows for Butler’s notion of “performativity” to be supplemented with that of “performance”; (2) provides a concrete analytical strategy in the form of positioning analysis; and (3) draws attention to both the micro politics of the interview conversation and the operation of power on the macro level, including the possibility of making “gender trouble”. The findings of the study suggest that the participants experienced difficulty narrating about male involvement in parenthood decision-making, owing to the taken for granted nature of parenthood for heterosexual adults. This was evident in participants’ sidelining of issues of “deciding” and “planning” and their alternate construal of childbearing as a non-choice, which, significantly served to bolster hetero-patriarchal norms. A central rhetorical tool for accomplishing these purposes was found in the construction of the “sacralised” child. In discursively manoeuvring around the central problematic, the participants ultimately produced a “silence” in the data that repeats the one in the research literature.
- Full Text:
- Date Issued: 2011
- Authors: Morison, Tracy
- Date: 2011
- Subjects: Family planning -- South Africa -- Psychological aspects Family size Birth intervals Men -- South Africa -- Attitudes Men -- South Africa -- Psychology Couples -- South Africa -- Psychology Afrikaners -- Attitudes
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3025 , http://hdl.handle.net/10962/d1002534
- Description: Despite the increased focus on men in reproductive research, little is known about male involvement in the initial decision/s regarding parenthood (i.e., to become a parent or not) and the subsequent decision-making that may ensue (e.g., choices about timing or spacing of births). In particular, the parenthood decision-making of “White”, heterosexual men from the middle class has been understudied, as indicated in the existing literature. In South Africa, this oversight has been exacerbated by the tendency for researchers to concentrate on “problematic” men, to the exclusion of the “boring, normal case”. I argue that this silence in the literature is a result of the taken for granted nature of parenthood in the “normal” heterosexual life course. In this study, I have turned the spotlight onto the norm of “Whiteness” and heterosexuality by studying those who have previously been overlooked by researchers. I focus on “White” Afrikaans men’s involvement in parenthood decision-making. My aim was to explore how constructions of gender inform male involvement in decision-making, especially within the South African context where social transformation has challenged traditional conceptions of male selfhood giving rise to new and contested masculine identities and new discourses of manhood and fatherhood. In an effort to ensure that women’s voices are not marginalised in the research, as is often the case in studies of men and masculinity, I conducted in-depth, semi-structured interviews about male involvement in decision-making with both “White” Afrikaans women and men. There were 23 participants in total, who all identified as heterosexual and middle-class. The participants were divided into two age cohorts (21 – 30 years and >40 years), which were then differentiated according to gender, reproductive status, and relationship status. Treating the interviews as jointly produced narratives, I analysed them by means of a performativity/performance lens. This dual analytic lens focuses on how particular narrative performances are simultaneously shaped by the interview setting and the broader discursive context. The lens was fashioned by synthesising Butler’s theory of performativity with Taylor’s narrative-discursive method. This synthesis (1) allows for Butler’s notion of “performativity” to be supplemented with that of “performance”; (2) provides a concrete analytical strategy in the form of positioning analysis; and (3) draws attention to both the micro politics of the interview conversation and the operation of power on the macro level, including the possibility of making “gender trouble”. The findings of the study suggest that the participants experienced difficulty narrating about male involvement in parenthood decision-making, owing to the taken for granted nature of parenthood for heterosexual adults. This was evident in participants’ sidelining of issues of “deciding” and “planning” and their alternate construal of childbearing as a non-choice, which, significantly served to bolster hetero-patriarchal norms. A central rhetorical tool for accomplishing these purposes was found in the construction of the “sacralised” child. In discursively manoeuvring around the central problematic, the participants ultimately produced a “silence” in the data that repeats the one in the research literature.
- Full Text:
- Date Issued: 2011
"Abject dictatorship of the flesh" : corporeality in the fiction of Patrick White
- Authors: Grogan, Bridget Meredith
- Date: 2013
- Subjects: White, Patrick, 1912-1990 -- Criticism and interpretation Human body in literature Dualism in literature Human body -- Social aspects Body image -- Social aspects Australian fiction -- 20th century -- History and criticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2166 , http://hdl.handle.net/10962/d1001554
- Description: Thesis embargoed for an indefinite period - full text not available
- Full Text: false
- Date Issued: 2013
- Authors: Grogan, Bridget Meredith
- Date: 2013
- Subjects: White, Patrick, 1912-1990 -- Criticism and interpretation Human body in literature Dualism in literature Human body -- Social aspects Body image -- Social aspects Australian fiction -- 20th century -- History and criticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2166 , http://hdl.handle.net/10962/d1001554
- Description: Thesis embargoed for an indefinite period - full text not available
- Full Text: false
- Date Issued: 2013
"A lean-led-evaluation" of infrastructure development improvement programme in South Africa
- Authors: Monyane, Thabiso Godfrey
- Date: 2019
- Subjects: Construction industry -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44535 , vital:38131
- Description: A doctoral study was embarked upon with the intentions of addressing cost management problems encountered on Infrastructure Delivery Projects in South Africa. Given that poor cost performance constitute hindrance to the realization of project goals, it is imperative to eliminate it from project delivery. The prevalence of cost overrun in public sector projects is a call to all stakeholders to address cost management issues in the construction industry. The predominance of cost overruns in public sector construction projects in South Africa has been observed. With the decline of the current economic conditions in South Africa, project performance is a great concern that needs attention. In addition, ineffective initiatives to curb the abuse of the procurement processes are directly affecting the outcomes of construction projects, and if these status quo remains, the sector will continue to have a bad image and continued waste of taxpayers’ money will not cease until the public sector remove non-value adding activities in their operations. Study adopted a mixed methods designed that collected both textual and statistical data. Semistructured interviews were undertaken to determine the outcomes of current project management practices in South Africa. In terms of performance of projects, the status quo paints a disconsolate picture. Findings reveal protracted processes, and the use of unqualified and inexperienced contribute to poor performance of public sector projects. Poor performance continues to dominate the construction sector, especially in the public sector. Interviews data were contrasted with evidence from project-related documents. Based on the data, the study produces a vignette of existing cost management frameworks applied to such projects. Encompassing various stages of the project delivery lifecycle, this vignette will enable an identification of the challenges afflicting cost management on projects. Accordingly, this study identified Lean opportunities from existing cost management practices. Such opportunities will enable identification of effective cost management during project delivery. There appears a need for collaborative cost management practices. Lean tools mentioned for improvement include the 5Whys, the big room, target value design, and the integration of design and construction. A collaborative cost management framework was developed through relevant theories to improve the cost management process of public sector projects.
- Full Text:
- Date Issued: 2019
- Authors: Monyane, Thabiso Godfrey
- Date: 2019
- Subjects: Construction industry -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44535 , vital:38131
- Description: A doctoral study was embarked upon with the intentions of addressing cost management problems encountered on Infrastructure Delivery Projects in South Africa. Given that poor cost performance constitute hindrance to the realization of project goals, it is imperative to eliminate it from project delivery. The prevalence of cost overrun in public sector projects is a call to all stakeholders to address cost management issues in the construction industry. The predominance of cost overruns in public sector construction projects in South Africa has been observed. With the decline of the current economic conditions in South Africa, project performance is a great concern that needs attention. In addition, ineffective initiatives to curb the abuse of the procurement processes are directly affecting the outcomes of construction projects, and if these status quo remains, the sector will continue to have a bad image and continued waste of taxpayers’ money will not cease until the public sector remove non-value adding activities in their operations. Study adopted a mixed methods designed that collected both textual and statistical data. Semistructured interviews were undertaken to determine the outcomes of current project management practices in South Africa. In terms of performance of projects, the status quo paints a disconsolate picture. Findings reveal protracted processes, and the use of unqualified and inexperienced contribute to poor performance of public sector projects. Poor performance continues to dominate the construction sector, especially in the public sector. Interviews data were contrasted with evidence from project-related documents. Based on the data, the study produces a vignette of existing cost management frameworks applied to such projects. Encompassing various stages of the project delivery lifecycle, this vignette will enable an identification of the challenges afflicting cost management on projects. Accordingly, this study identified Lean opportunities from existing cost management practices. Such opportunities will enable identification of effective cost management during project delivery. There appears a need for collaborative cost management practices. Lean tools mentioned for improvement include the 5Whys, the big room, target value design, and the integration of design and construction. A collaborative cost management framework was developed through relevant theories to improve the cost management process of public sector projects.
- Full Text:
- Date Issued: 2019
"A complex and delicate web" : a comparative study of selected speculative novels by Margaret Atwood, Ursula K. Le Guin, Doris Lessing and Marge Piercy
- Authors: Glover, Jayne Ashleigh
- Date: 2008
- Subjects: Atwood, Margaret Eleanor, 1939- -- Criticism and interpretation Le Guin, Ursula K., 1929- -- Criticism and interpretation Lessing, Doris May, 1919- -- Criticism and interpretation Piercy, Marge Piercy, Marge -- Criticism and interpretation Utopias in literature Dystopias in literature Science fiction, English -- History and criticism Fantasy fiction -- History and criticism Fantasy literature -- History and criticism Women authors -- 20th Century Women authors -- 21st Century English fiction -- 20th Century English fiction -- 21st Century
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2199 , http://hdl.handle.net/10962/d1002241
- Description: This thesis examines selected speculative novels by Margaret Atwood, Ursula K. Le Guin, Doris Lessing and Marge Piercy. It argues that a specifiable ecological ethic can be traced in their work – an ethic which is explored by them through the tensions between utopian and dystopian discourses. The first part of the thesis begins by theorising the concept of an ecological ethic of respect for the Other through current ecological philosophies, such as those developed by Val Plumwood. Thereafter, it contextualises the novels within the broader field of science fiction, and speculative fiction in particular, arguing that the shift from a critical utopian to a critical dystopian style evinces their changing treatment of this ecological ethic within their work. The remainder of the thesis is divided into two parts, each providing close readings of chosen novels in the light of this argument. Part Two provides a reading of Le Guin’s early Hainish novels, The Left Hand of Darkness, The Word for World is Forest and The Dispossessed, followed by an examination of Piercy’s Woman on the Edge of Time, Lessing’s The Marriages Between Zones Three, Four and Five, and Atwood’s The Handmaid’s Tale. The third, and final, part of the thesis consists of individual chapters analysing the later speculative novels of each author. Piercy’s He, She and It, Le Guin’s The Telling, and Atwood’s Oryx and Crake are all scrutinised, as are Lessing’s two recent ‘Ifrik’ novels. This thesis shows, then, that speculative fiction is able to realise through fiction many of the ideals of ecological thinkers. Furthermore, the increasing dystopianism of these novels reflects the greater urgency with which the problem of Othering needs to be addressed in the light of the present global ecological crisis.
- Full Text:
- Date Issued: 2008
- Authors: Glover, Jayne Ashleigh
- Date: 2008
- Subjects: Atwood, Margaret Eleanor, 1939- -- Criticism and interpretation Le Guin, Ursula K., 1929- -- Criticism and interpretation Lessing, Doris May, 1919- -- Criticism and interpretation Piercy, Marge Piercy, Marge -- Criticism and interpretation Utopias in literature Dystopias in literature Science fiction, English -- History and criticism Fantasy fiction -- History and criticism Fantasy literature -- History and criticism Women authors -- 20th Century Women authors -- 21st Century English fiction -- 20th Century English fiction -- 21st Century
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2199 , http://hdl.handle.net/10962/d1002241
- Description: This thesis examines selected speculative novels by Margaret Atwood, Ursula K. Le Guin, Doris Lessing and Marge Piercy. It argues that a specifiable ecological ethic can be traced in their work – an ethic which is explored by them through the tensions between utopian and dystopian discourses. The first part of the thesis begins by theorising the concept of an ecological ethic of respect for the Other through current ecological philosophies, such as those developed by Val Plumwood. Thereafter, it contextualises the novels within the broader field of science fiction, and speculative fiction in particular, arguing that the shift from a critical utopian to a critical dystopian style evinces their changing treatment of this ecological ethic within their work. The remainder of the thesis is divided into two parts, each providing close readings of chosen novels in the light of this argument. Part Two provides a reading of Le Guin’s early Hainish novels, The Left Hand of Darkness, The Word for World is Forest and The Dispossessed, followed by an examination of Piercy’s Woman on the Edge of Time, Lessing’s The Marriages Between Zones Three, Four and Five, and Atwood’s The Handmaid’s Tale. The third, and final, part of the thesis consists of individual chapters analysing the later speculative novels of each author. Piercy’s He, She and It, Le Guin’s The Telling, and Atwood’s Oryx and Crake are all scrutinised, as are Lessing’s two recent ‘Ifrik’ novels. This thesis shows, then, that speculative fiction is able to realise through fiction many of the ideals of ecological thinkers. Furthermore, the increasing dystopianism of these novels reflects the greater urgency with which the problem of Othering needs to be addressed in the light of the present global ecological crisis.
- Full Text:
- Date Issued: 2008