Synthesis, photophysical and photochemical studies on long chain zinc phthalocyanine derivatives
- Ogunsipe, Abimbola, Durmus, Mahmut, Atilla, Devrim, Gürek, Ayşe Gül, Ahsen, Vefa, Nyokong, Tebello
- Authors: Ogunsipe, Abimbola , Durmus, Mahmut , Atilla, Devrim , Gürek, Ayşe Gül , Ahsen, Vefa , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266019 , vital:53910 , xlink:href="https://doi.org/10.1016/j.synthmet.2008.06.007"
- Description: The synthesis and characterization of 2,9,16,23-chloro-3,10,17,24-triethyleneoxysulphanylphthalocyaninato zinc(II) (CTESZnPc) is described. The photophysics and photochemistry of CTESZnPc and those of tetrakis(triethyleneoxysulphanyl)zinc phthalocyanine (TTESZnPc) and octakis(triethyleneoxysulphanyl)zinc phthalocyanine (OTESZnPc), are presented and compared with those of unsubstituted zinc phthalocyanine (ZnPc). The presence of triethyleneoxysulphanyl substituents on the ZnPc ring gave rise to higher values of singlet oxygen (ΦΔ) and photodegradation (ΦPd) quantum yields in DMF. However, TTESZnPc, OTESZnPc and CTESZnPc are less fluorescent than ZnPc, judging from their fluorescence quantum yield (ΦF) values. Fluorescence was lower in toluene than in DMF due to aggregation in the former solvent. Triplet quantum yield (ΦT) values were found to increase with the presence of substituents on the ZnPc ring, while triplet lifetimes (τT) were found to vary linearly with the logarithms of solvent viscosities. The fluorescences of the substituted ZnPc complexes were effectively quenched by benzoquinone (BQ), and the quenching data analyzed by the Stern–Volmer equation. The Stern–Volmer constants and the diffusion-controlled bimolecular rate constants were calculated.
- Full Text:
- Date Issued: 2008
- Authors: Ogunsipe, Abimbola , Durmus, Mahmut , Atilla, Devrim , Gürek, Ayşe Gül , Ahsen, Vefa , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/266019 , vital:53910 , xlink:href="https://doi.org/10.1016/j.synthmet.2008.06.007"
- Description: The synthesis and characterization of 2,9,16,23-chloro-3,10,17,24-triethyleneoxysulphanylphthalocyaninato zinc(II) (CTESZnPc) is described. The photophysics and photochemistry of CTESZnPc and those of tetrakis(triethyleneoxysulphanyl)zinc phthalocyanine (TTESZnPc) and octakis(triethyleneoxysulphanyl)zinc phthalocyanine (OTESZnPc), are presented and compared with those of unsubstituted zinc phthalocyanine (ZnPc). The presence of triethyleneoxysulphanyl substituents on the ZnPc ring gave rise to higher values of singlet oxygen (ΦΔ) and photodegradation (ΦPd) quantum yields in DMF. However, TTESZnPc, OTESZnPc and CTESZnPc are less fluorescent than ZnPc, judging from their fluorescence quantum yield (ΦF) values. Fluorescence was lower in toluene than in DMF due to aggregation in the former solvent. Triplet quantum yield (ΦT) values were found to increase with the presence of substituents on the ZnPc ring, while triplet lifetimes (τT) were found to vary linearly with the logarithms of solvent viscosities. The fluorescences of the substituted ZnPc complexes were effectively quenched by benzoquinone (BQ), and the quenching data analyzed by the Stern–Volmer equation. The Stern–Volmer constants and the diffusion-controlled bimolecular rate constants were calculated.
- Full Text:
- Date Issued: 2008
Temporal and spatial variability in stable isotope ratios of SPM link to local hydrography and longer term SPM averages suggest heavy dependence of mussels on nearshore production
- Hill, Jaclyn M, McQuaid, Christopher D, Kaehler, Sven
- Authors: Hill, Jaclyn M , McQuaid, Christopher D , Kaehler, Sven
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:6969 , http://hdl.handle.net/10962/d1012034
- Description: Temporal changes in hydrography affect suspended particulate matter (SPM) composition and distribution in coastal systems, potentially influencing the diets of suspension feeders. Temporal variation in SPM and in the diet of the mussel Perna perna, were investigated using stable isotope analysis. The δ13C and δ15 N ratios of SPM, mussels and macroalgae were determined monthly, with SPM samples collected along a 10 km onshore–offshore transect, over 14 months at Kenton-on-Sea, on the south coast of South Africa. Clear nearshore (0 km) to offshore (10 km) carbon depletion gradients were seen in SPM during all months and extended for 50 km offshore on one occasion. Carbon enrichment of coastal SPM in winter (June–August 2004 and May 2005) indicated temporal changes in the nearshore detrital pool, presumably reflecting changes in macroalgal detritus, linked to local changes in coastal hydrography and algal seasonality. Nitrogen patterns were less clear, with SPM enrichment seen between July and October 2004 from 0 to 10 km. Nearshore SPM demonstrated cyclical patterns in carbon over 24-h periods that correlated closely with tidal cycles and mussel carbon signatures, sampled monthly, demonstrated fluctuations that could not be correlated to seasonal or monthly changes in SPM. Macroalgae showed extreme variability in isotopic signatures, with no discernable patterns. IsoSource mixing models indicated over 50% reliance of mussel tissue on nearshore carbon, highlighting the importance of nearshore SPM in mussel diet. Overall, carbon variation in SPM at both large and small temporal scales can be related to hydrographic processes, but is masked in mussels by long-term isotope integration.
- Full Text:
- Date Issued: 2008
- Authors: Hill, Jaclyn M , McQuaid, Christopher D , Kaehler, Sven
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:6969 , http://hdl.handle.net/10962/d1012034
- Description: Temporal changes in hydrography affect suspended particulate matter (SPM) composition and distribution in coastal systems, potentially influencing the diets of suspension feeders. Temporal variation in SPM and in the diet of the mussel Perna perna, were investigated using stable isotope analysis. The δ13C and δ15 N ratios of SPM, mussels and macroalgae were determined monthly, with SPM samples collected along a 10 km onshore–offshore transect, over 14 months at Kenton-on-Sea, on the south coast of South Africa. Clear nearshore (0 km) to offshore (10 km) carbon depletion gradients were seen in SPM during all months and extended for 50 km offshore on one occasion. Carbon enrichment of coastal SPM in winter (June–August 2004 and May 2005) indicated temporal changes in the nearshore detrital pool, presumably reflecting changes in macroalgal detritus, linked to local changes in coastal hydrography and algal seasonality. Nitrogen patterns were less clear, with SPM enrichment seen between July and October 2004 from 0 to 10 km. Nearshore SPM demonstrated cyclical patterns in carbon over 24-h periods that correlated closely with tidal cycles and mussel carbon signatures, sampled monthly, demonstrated fluctuations that could not be correlated to seasonal or monthly changes in SPM. Macroalgae showed extreme variability in isotopic signatures, with no discernable patterns. IsoSource mixing models indicated over 50% reliance of mussel tissue on nearshore carbon, highlighting the importance of nearshore SPM in mussel diet. Overall, carbon variation in SPM at both large and small temporal scales can be related to hydrographic processes, but is masked in mussels by long-term isotope integration.
- Full Text:
- Date Issued: 2008
The African reception of global media:
- Strelitz, Larry N, Boshoff, Priscilla A
- Authors: Strelitz, Larry N , Boshoff, Priscilla A
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143527 , vital:38254 , ISBN 9781473971752 , https://books.google.co.za/books?id=pfRcCwAAQBAJanddq=The+African+Reception+of+Global+Mediaandlr=andsource=gbs_navlinks_s
- Description: This chapter engages debates concerning the impact of global media on local youth audiences in Africa. Recognizing the profound rootedness of media consumption in everyday life, the chapter specifically examines the way selected South African youth audiences, differentially embedded in their particular economic and ideological formations, use local and global media texts as part of their ongoing attempts to make sense of their lives.
- Full Text:
- Date Issued: 2008
- Authors: Strelitz, Larry N , Boshoff, Priscilla A
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143527 , vital:38254 , ISBN 9781473971752 , https://books.google.co.za/books?id=pfRcCwAAQBAJanddq=The+African+Reception+of+Global+Mediaandlr=andsource=gbs_navlinks_s
- Description: This chapter engages debates concerning the impact of global media on local youth audiences in Africa. Recognizing the profound rootedness of media consumption in everyday life, the chapter specifically examines the way selected South African youth audiences, differentially embedded in their particular economic and ideological formations, use local and global media texts as part of their ongoing attempts to make sense of their lives.
- Full Text:
- Date Issued: 2008
The Cultural Use of the Wild Olive Tree by the amaXhosa People in the Eastern Cape Province of South Africa:
- Cocks, Michelle L, Dold, Anthony P
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141314 , vital:37961 , DOI: 10.1558/jsrnc.v2i3.292
- Description: The cultural meanings of harvested plants have for the most part been ignored in academic research on non-timber forest products (NTFPs) in southern Africa. Historically scientists have tended to ignore the complex relationships between nature and culture. Given the country's unique political and economic past and the current search for sustainable use of natural resources, a focus on the convergence of natural science and cultural diversity is important at this time. Empirical data on cultural practices is being collected in order to develop fresh and relevant insights into the complex relationships between culture and bítKÜversity. The purpose of this paper is to demonstrate that the concept of culture needs to be brought into our understanding of the role of NTFPs. We dtxrument the use and value of a specific tree, Olea europaea L. subsp. africana (Mill.) P,S. Green, called Umiicjuma in the Xhosa language, for cultural purposes, by both rural and urban households.
- Full Text:
- Date Issued: 2008
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141314 , vital:37961 , DOI: 10.1558/jsrnc.v2i3.292
- Description: The cultural meanings of harvested plants have for the most part been ignored in academic research on non-timber forest products (NTFPs) in southern Africa. Historically scientists have tended to ignore the complex relationships between nature and culture. Given the country's unique political and economic past and the current search for sustainable use of natural resources, a focus on the convergence of natural science and cultural diversity is important at this time. Empirical data on cultural practices is being collected in order to develop fresh and relevant insights into the complex relationships between culture and bítKÜversity. The purpose of this paper is to demonstrate that the concept of culture needs to be brought into our understanding of the role of NTFPs. We dtxrument the use and value of a specific tree, Olea europaea L. subsp. africana (Mill.) P,S. Green, called Umiicjuma in the Xhosa language, for cultural purposes, by both rural and urban households.
- Full Text:
- Date Issued: 2008
The impact of aid dependence on social development: the case of Zimbabwe
- Authors: Nyatoro, Tinashe
- Date: 2008
- Subjects: Economic assistance , Zimbabwe
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26649 , vital:65735
- Description: The purpose of this study was to look at how a foreign aid dependent economy is vulnerable to external manipulations. This study came up with the conclusion that foreign capital dependence is detrimental to long-term social, economic, and sustainable development of developing countries. The study also noted how foreign aid is used as a foreign policy instrument by western countries to influence the behaviour of the developing countries. The study noted that Zimbabwe is an aid dependent country hence its vulnerability to external manipulation. This has been demonstrated by capital flight from Zimbabwe since 1997. Multilateral Financial Institutions, the European Union, United States of America and other bilateral donors withdrew their financial support to the country due to policy disagreements with the Zimbabwean government. This incidence of donors withdrawing their financial support to Zimbabwe raises fundamental questions as to whether the African state is autonomous or is it possible for the African state to delink itself from the current global international market and at what costs? What has come out very clearly from this study is that a dependent state has no autonomy to decide on its domestic and foreign policies without considering the interests of its donors, and hence its vulnerability to external manipulations. , Thesis (MSoc) -- Faculty of Management and Commerce, 2008
- Full Text:
- Date Issued: 2008
- Authors: Nyatoro, Tinashe
- Date: 2008
- Subjects: Economic assistance , Zimbabwe
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26649 , vital:65735
- Description: The purpose of this study was to look at how a foreign aid dependent economy is vulnerable to external manipulations. This study came up with the conclusion that foreign capital dependence is detrimental to long-term social, economic, and sustainable development of developing countries. The study also noted how foreign aid is used as a foreign policy instrument by western countries to influence the behaviour of the developing countries. The study noted that Zimbabwe is an aid dependent country hence its vulnerability to external manipulation. This has been demonstrated by capital flight from Zimbabwe since 1997. Multilateral Financial Institutions, the European Union, United States of America and other bilateral donors withdrew their financial support to the country due to policy disagreements with the Zimbabwean government. This incidence of donors withdrawing their financial support to Zimbabwe raises fundamental questions as to whether the African state is autonomous or is it possible for the African state to delink itself from the current global international market and at what costs? What has come out very clearly from this study is that a dependent state has no autonomy to decide on its domestic and foreign policies without considering the interests of its donors, and hence its vulnerability to external manipulations. , Thesis (MSoc) -- Faculty of Management and Commerce, 2008
- Full Text:
- Date Issued: 2008
The oppression of isiXhosa literature and the irony of transformation
- Authors: Kaschula, Russell H
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:6334 , http://hdl.handle.net/10962/d1012398 , https://orcid.org/0000-0002-5481-6748
- Description: his article will contend that the natural development of isiXhosa orature and literature, as with all South African indigenous literatures, ended with the arrival of European missionaries in 1799. The apartheid policy then exacerbated the destructive approaches to indigenous languages already in operation as it designated separate language boards for language development. These boards operated in the 'homelands' and were generally conservative, corrupt and oppressive. The manuscripts they recommended to publishers were for the most part only those that could be prescribed in schools. This resulted in the publishing of material that was parochial, apolitical and neutral in style. Often the material prescribed was written by the board members themselves. For instance, Lennox Sebe, erstwhile President of the Ciskei, produced an isiXhosa book entitled Ucamngco, for prescription, though it seems to contain little original material. Laurence Wright has shown that the opposite was true for English literature written by black South Africans and published internationally in the 1970s, at the height of apartheid (2004, 47). He describes, for instance, how one of the manuscript readers of Peteni's seminal novel, Hill of Fools (1976), rejected it as irrelevant and unsuitable for publication precisely because it made no reference to South Africa's turbulent politics. Throughout this period, however, only apolitical novels were published in the indigenous languages.
- Full Text:
- Date Issued: 2008
- Authors: Kaschula, Russell H
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:6334 , http://hdl.handle.net/10962/d1012398 , https://orcid.org/0000-0002-5481-6748
- Description: his article will contend that the natural development of isiXhosa orature and literature, as with all South African indigenous literatures, ended with the arrival of European missionaries in 1799. The apartheid policy then exacerbated the destructive approaches to indigenous languages already in operation as it designated separate language boards for language development. These boards operated in the 'homelands' and were generally conservative, corrupt and oppressive. The manuscripts they recommended to publishers were for the most part only those that could be prescribed in schools. This resulted in the publishing of material that was parochial, apolitical and neutral in style. Often the material prescribed was written by the board members themselves. For instance, Lennox Sebe, erstwhile President of the Ciskei, produced an isiXhosa book entitled Ucamngco, for prescription, though it seems to contain little original material. Laurence Wright has shown that the opposite was true for English literature written by black South Africans and published internationally in the 1970s, at the height of apartheid (2004, 47). He describes, for instance, how one of the manuscript readers of Peteni's seminal novel, Hill of Fools (1976), rejected it as irrelevant and unsuitable for publication precisely because it made no reference to South Africa's turbulent politics. Throughout this period, however, only apolitical novels were published in the indigenous languages.
- Full Text:
- Date Issued: 2008
The photophysical studies of a mixture of CdTe quantum dots and negatively charged zinc phthalocyanines
- Moeno, Sharon, Nyokong, Tebello
- Authors: Moeno, Sharon , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268663 , vital:54220 , xlink:href="https://doi.org/10.1016/j.poly.2008.03.007"
- Description: Fluorescence resonance energy transfer (FRET) studies were carried out with quantum dots capped with thioglycolic acid (TGA) and 2-mercaptoethanol (2-ME) and negatively charged phthalocyanines {Zn tetracarboxy (ZnTCPc), Zn octacarboxy (ZnOCPc) and Zn tetrasulfo (ZnTSPc) phthalocyinines} in a 0.1 NaOH:EtOH (50:50) solvent mixture. The best overlap between emission spectra of the donor (QDs) and the absorption spectra of the acceptor (ZnPc derivatives) was observed for TGA capped QDs, very little overlap was obtained for 2-ME QDs. ZnTSPc gave the highest FRET efficiency (0.3), with ZnOCPc and ZnTCPc giving a FRET efficiency of 0.2. The ΦT values of the MPcs generally decreased in the presence of the QD whereas the triplet lifetimes (τT) of the ZnPc derivatives were higher in the presence of QDs.
- Full Text:
- Date Issued: 2008
- Authors: Moeno, Sharon , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268663 , vital:54220 , xlink:href="https://doi.org/10.1016/j.poly.2008.03.007"
- Description: Fluorescence resonance energy transfer (FRET) studies were carried out with quantum dots capped with thioglycolic acid (TGA) and 2-mercaptoethanol (2-ME) and negatively charged phthalocyanines {Zn tetracarboxy (ZnTCPc), Zn octacarboxy (ZnOCPc) and Zn tetrasulfo (ZnTSPc) phthalocyinines} in a 0.1 NaOH:EtOH (50:50) solvent mixture. The best overlap between emission spectra of the donor (QDs) and the absorption spectra of the acceptor (ZnPc derivatives) was observed for TGA capped QDs, very little overlap was obtained for 2-ME QDs. ZnTSPc gave the highest FRET efficiency (0.3), with ZnOCPc and ZnTCPc giving a FRET efficiency of 0.2. The ΦT values of the MPcs generally decreased in the presence of the QD whereas the triplet lifetimes (τT) of the ZnPc derivatives were higher in the presence of QDs.
- Full Text:
- Date Issued: 2008
The Postcolonial heart of African philosophy
- Authors: Tabensky, Pedro
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/305762 , vital:58610 , xlink:href="https://hdl.handle.net/10520/EJC96056"
- Description: This piece is one of among a handful that seek in the first instance to reveal the origin of African philosophy as an academic discipline, the source of its unity and distinctiveness. The discipline of African philosophy originates in tragedy, out of pain, confusion and rage stemming from colonial destruction; destruction that is responsible for what Fanon calls the ‘negro neurosis’ caused by what Biko would describe as the unbearable fusion of colonised and coloniser. I argue that the birth of African philosophy as an academic discipline is largely responsible for its character and, crucially, for its distinctive creative possibilities.
- Full Text:
- Date Issued: 2008
- Authors: Tabensky, Pedro
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/305762 , vital:58610 , xlink:href="https://hdl.handle.net/10520/EJC96056"
- Description: This piece is one of among a handful that seek in the first instance to reveal the origin of African philosophy as an academic discipline, the source of its unity and distinctiveness. The discipline of African philosophy originates in tragedy, out of pain, confusion and rage stemming from colonial destruction; destruction that is responsible for what Fanon calls the ‘negro neurosis’ caused by what Biko would describe as the unbearable fusion of colonised and coloniser. I argue that the birth of African philosophy as an academic discipline is largely responsible for its character and, crucially, for its distinctive creative possibilities.
- Full Text:
- Date Issued: 2008
The role of the privileged in responding to poverty: perspectives emerging from the post-development debate
- Authors: Matthews, Sally
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142476 , vital:38083 , DOI: 10.1080/01436590802201022
- Description: The debate between post-development theorists and their critics has raised several important questions, one of them being the question of how relatively privileged people may respond meaningfully to poverty while not perpetuating the flaws of past development practice. In this article I build upon the ideas of several contributors to the post-development debate in order to suggest three ways in which we who are relatively privileged may play a role in struggles against poverty. I argue that we can work to rethink the concepts informing development practice; that we may find ways to give our support to popular initiatives, and that there are aspects of our own societies which we may change in solidarity with the struggles of distant others.
- Full Text:
- Date Issued: 2008
- Authors: Matthews, Sally
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142476 , vital:38083 , DOI: 10.1080/01436590802201022
- Description: The debate between post-development theorists and their critics has raised several important questions, one of them being the question of how relatively privileged people may respond meaningfully to poverty while not perpetuating the flaws of past development practice. In this article I build upon the ideas of several contributors to the post-development debate in order to suggest three ways in which we who are relatively privileged may play a role in struggles against poverty. I argue that we can work to rethink the concepts informing development practice; that we may find ways to give our support to popular initiatives, and that there are aspects of our own societies which we may change in solidarity with the struggles of distant others.
- Full Text:
- Date Issued: 2008
The Sacred Door and other Stories: Cameroon Folktales of the Beba (Makuchi)
- Authors: Kaschula, Russell H
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175177 , vital:42550 , https://doi.org/10.17159/2309-9070/tvl.v.45i2.4743
- Description: In The Sacred Door and Other Stories: Cameroon Folktales of the Beba, Makuchi has collected thirty-three folktales of the Beba people. These stories are presented in English only. The book contains a foreword by well-known oral literature scholar, Isidore Okpewho and a preface by the author. In the foreword, Okpewho states that:“Tales like these need to be retold again and again, because the lessons they yield belong not merely to a long-forgotten historical or so-called primitive past but very much to the present times in which we live”(xi). The book therefore represents a sense of continuity between past and present. Although the tales may no longer be told in the same way that they were many years ago, the messages contained in the tales remain as relevant today as they did in the past.
- Full Text:
- Date Issued: 2008
- Authors: Kaschula, Russell H
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175177 , vital:42550 , https://doi.org/10.17159/2309-9070/tvl.v.45i2.4743
- Description: In The Sacred Door and Other Stories: Cameroon Folktales of the Beba, Makuchi has collected thirty-three folktales of the Beba people. These stories are presented in English only. The book contains a foreword by well-known oral literature scholar, Isidore Okpewho and a preface by the author. In the foreword, Okpewho states that:“Tales like these need to be retold again and again, because the lessons they yield belong not merely to a long-forgotten historical or so-called primitive past but very much to the present times in which we live”(xi). The book therefore represents a sense of continuity between past and present. Although the tales may no longer be told in the same way that they were many years ago, the messages contained in the tales remain as relevant today as they did in the past.
- Full Text:
- Date Issued: 2008
The trajectory, dynamics, determinants and nature of institutional change in post-1994 South African higher education
- Authors: Badat, Saleem
- Date: 2008
- Language: English
- Type: Conference paper , text
- Identifier: vital:7120 , http://hdl.handle.net/10962/d1006568
- Description: Introduction: The institutional change agenda in post-1994 South African higher education has been extensive in its objects, ambitious in its goals, and far-reaching in nature. Given its scope, it is not possible here to critically analyse change in all its dimensions or in all arenas. Instead, this paper confines itself to analysing the trajectory, dynamics, outcomes and determinants of institutional change in South African higher education since 1994, and concludes with observations on the nature of change. , Higher Education Close Up 4 : University of Cape Town, Breakwater Conference Centre, 26-28 June 2008
- Full Text:
- Date Issued: 2008
- Authors: Badat, Saleem
- Date: 2008
- Language: English
- Type: Conference paper , text
- Identifier: vital:7120 , http://hdl.handle.net/10962/d1006568
- Description: Introduction: The institutional change agenda in post-1994 South African higher education has been extensive in its objects, ambitious in its goals, and far-reaching in nature. Given its scope, it is not possible here to critically analyse change in all its dimensions or in all arenas. Instead, this paper confines itself to analysing the trajectory, dynamics, outcomes and determinants of institutional change in South African higher education since 1994, and concludes with observations on the nature of change. , Higher Education Close Up 4 : University of Cape Town, Breakwater Conference Centre, 26-28 June 2008
- Full Text:
- Date Issued: 2008
Towards revised physically based parameter estimation methods for the Pitman monthly rainfall-runoff model
- Kapangaziwiri, Evison, Hughes, Denis A
- Authors: Kapangaziwiri, Evison , Hughes, Denis A
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:7088 , http://hdl.handle.net/10962/d1012417
- Description: This paper presents a preliminary stage in the development of an alternative parameterisation procedure for the Pitman monthly rainfall runoff model which enjoys popular use in water resource assessment in Southern Africa. The estimation procedures are based on the premise that it is possible to use physical basin properties directly in the quantification of the soil moisture accounting, runoff, and recharge and infiltration parameters. The results for selected basins show that the revised parameters are at least as good as current regionalised sets or give satisfactory results in areas where no regionalised parameters exist.
- Full Text:
- Date Issued: 2008
- Authors: Kapangaziwiri, Evison , Hughes, Denis A
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:7088 , http://hdl.handle.net/10962/d1012417
- Description: This paper presents a preliminary stage in the development of an alternative parameterisation procedure for the Pitman monthly rainfall runoff model which enjoys popular use in water resource assessment in Southern Africa. The estimation procedures are based on the premise that it is possible to use physical basin properties directly in the quantification of the soil moisture accounting, runoff, and recharge and infiltration parameters. The results for selected basins show that the revised parameters are at least as good as current regionalised sets or give satisfactory results in areas where no regionalised parameters exist.
- Full Text:
- Date Issued: 2008
Tracing and erasure in Kathryn Smith's Psychogeographies: the washing away of wrongs
- Authors: de Jager, Maureen
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147413 , vital:38634 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC31057
- Description: Kathryn Smith's Psychogeographies: The Washing Away of Wrongs is a series of twelve prints comprising photographs and handwritten text, wherein she records her 'pilgrimage' to the former homes of British serial killer Dennis Nilsen. As such, it utilises photographic and autographic traces to 'track' the elusive traces left by Nilsen. Given the lapse of two decades between Nilsen's arrest and Smith's visit, the traces of Nilsen's 'wrongs' seem all but erased by the banal façade of suburban living which has continued on, regardless. In taking this as a starting point, the following article considers the motif of absence that characterises Smith's work as intrinsic to traces per se.
- Full Text:
- Date Issued: 2008
- Authors: de Jager, Maureen
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147413 , vital:38634 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC31057
- Description: Kathryn Smith's Psychogeographies: The Washing Away of Wrongs is a series of twelve prints comprising photographs and handwritten text, wherein she records her 'pilgrimage' to the former homes of British serial killer Dennis Nilsen. As such, it utilises photographic and autographic traces to 'track' the elusive traces left by Nilsen. Given the lapse of two decades between Nilsen's arrest and Smith's visit, the traces of Nilsen's 'wrongs' seem all but erased by the banal façade of suburban living which has continued on, regardless. In taking this as a starting point, the following article considers the motif of absence that characterises Smith's work as intrinsic to traces per se.
- Full Text:
- Date Issued: 2008
Tuning the redox properties of Co-N4 macrocyclic complexes for the catalytic electrooxidation of glucose
- Villagra, Evelyn, Bedioui, Fethi, Nyokong, Tebello, Canales, J Carlos, Sancy, Mamie, Páez, Maritza A, Costamagna, Juan, Zagal, Jose H
- Authors: Villagra, Evelyn , Bedioui, Fethi , Nyokong, Tebello , Canales, J Carlos , Sancy, Mamie , Páez, Maritza A , Costamagna, Juan , Zagal, Jose H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268675 , vital:54221 , xlink:href="https://doi.org/10.1016/j.electacta.2008.02.006"
- Description: Graphite electrodes modified with four different cobalt N4 macrocyclics, namely Co tetrapentapyridinophthalocyanine, (CoTPenPyrPc), Co tetrapyridinoporphyrazine (CoTPyPz), Co octa(hydroxyethylthio)phthalocyanine (CoOEHTPc) and Co tetranitrophthalocyanine (CoTNPc) exhibit catalytic activity for the oxidation of glucose in alkaline media. The purpose of this work is to establish correlations between the catalytic activity of these complexes and their redox potential. The activity of the different modified electrodes was tested by linear voltammetry under hydrodynamic conditions using the rotating disk technique. Tafel plots constructed from mass-transport corrected currents give slopes ranging from 0.080 to 0.160 V/decade for the different catalysts which suggests that a first one-electron step is rate controlling with the symmetry of the energy barrier depending on the nature of the ligand of the Co complex. A plot of log I versus the Co(II)/(I) formal potential gives a volcano curve that also includes catalysts studied previously. This illustrates the concept that the formal potential of the catalyst needs to be tuned to a certain value for achieving maximum activity. A theoretical interpretation of these results is given in terms of Langmuir isotherms for the adsorption of glucose on the Co sites of the surface-confined metal complexes.
- Full Text:
- Date Issued: 2008
- Authors: Villagra, Evelyn , Bedioui, Fethi , Nyokong, Tebello , Canales, J Carlos , Sancy, Mamie , Páez, Maritza A , Costamagna, Juan , Zagal, Jose H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268675 , vital:54221 , xlink:href="https://doi.org/10.1016/j.electacta.2008.02.006"
- Description: Graphite electrodes modified with four different cobalt N4 macrocyclics, namely Co tetrapentapyridinophthalocyanine, (CoTPenPyrPc), Co tetrapyridinoporphyrazine (CoTPyPz), Co octa(hydroxyethylthio)phthalocyanine (CoOEHTPc) and Co tetranitrophthalocyanine (CoTNPc) exhibit catalytic activity for the oxidation of glucose in alkaline media. The purpose of this work is to establish correlations between the catalytic activity of these complexes and their redox potential. The activity of the different modified electrodes was tested by linear voltammetry under hydrodynamic conditions using the rotating disk technique. Tafel plots constructed from mass-transport corrected currents give slopes ranging from 0.080 to 0.160 V/decade for the different catalysts which suggests that a first one-electron step is rate controlling with the symmetry of the energy barrier depending on the nature of the ligand of the Co complex. A plot of log I versus the Co(II)/(I) formal potential gives a volcano curve that also includes catalysts studied previously. This illustrates the concept that the formal potential of the catalyst needs to be tuned to a certain value for achieving maximum activity. A theoretical interpretation of these results is given in terms of Langmuir isotherms for the adsorption of glucose on the Co sites of the surface-confined metal complexes.
- Full Text:
- Date Issued: 2008
Underlying mechanisms affecting institutionalisation of environmental education courses in Southern Africa
- Authors: Lupele, Justin
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386926 , vital:68188 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122773"
- Description: This paper discusses the underlying causal mechanisms that enabled or constrained institutionalisation of environmental education in 12 institutions in eight countries in southern Africa. The study was carried out in the context of the Southern Africa Development Community Regional Environmental Education Support Programme’s Course Development Network (CDN). This paper reports on part of the author's doctoral study and draws on critical realism as the ontological lens. Data analysis was done by means of a retroductive mode of inference, as articulated by Danermark, Ekström, Jakosben and Karlsson (2002). The paper demonstrates that there are a number of underlying causal mechanisms, which may enable or constrain institutionalisation of environmental education. They include factors at play at both national and institutional level; namely, responsiveness to national and institutional needs, recognition and ownership, accreditation and certification, institutional culture and politics, short course support structure and support from colleagues. As part of the discussions of the results of the study, I have advanced some retroductive theories that suggest causal mechanisms beyond the empirical data based on the participants’ experiences and events in the CDN.
- Full Text:
- Date Issued: 2008
- Authors: Lupele, Justin
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386926 , vital:68188 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122773"
- Description: This paper discusses the underlying causal mechanisms that enabled or constrained institutionalisation of environmental education in 12 institutions in eight countries in southern Africa. The study was carried out in the context of the Southern Africa Development Community Regional Environmental Education Support Programme’s Course Development Network (CDN). This paper reports on part of the author's doctoral study and draws on critical realism as the ontological lens. Data analysis was done by means of a retroductive mode of inference, as articulated by Danermark, Ekström, Jakosben and Karlsson (2002). The paper demonstrates that there are a number of underlying causal mechanisms, which may enable or constrain institutionalisation of environmental education. They include factors at play at both national and institutional level; namely, responsiveness to national and institutional needs, recognition and ownership, accreditation and certification, institutional culture and politics, short course support structure and support from colleagues. As part of the discussions of the results of the study, I have advanced some retroductive theories that suggest causal mechanisms beyond the empirical data based on the participants’ experiences and events in the CDN.
- Full Text:
- Date Issued: 2008
Viewpoint: reading conference recommendations in a wider context of social change
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67411 , vital:29085 , https://www.ajol.info/index.php/sajee/article/view/122783
- Description: publisher version , This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67411 , vital:29085 , https://www.ajol.info/index.php/sajee/article/view/122783
- Description: publisher version , This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
Volcano correlations for the reactivity of surface-confined cobalt N4-macrocyclics for the electrocatalytic oxidation of 2-mercaptoacetate
- Claußen, Jan A, Ochoa, Gonzalo, Páez, Maritza, Costamagno, Juan, Gulppi, Miguel, Nyokong, Tebello, Bedioui, Fethi, Zagal, José H
- Authors: Claußen, Jan A , Ochoa, Gonzalo , Páez, Maritza , Costamagno, Juan , Gulppi, Miguel , Nyokong, Tebello , Bedioui, Fethi , Zagal, José H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268688 , vital:54222 , xlink:href="https://doi.org/10.1007/s10008-007-0336-y"
- Description: We have investigated the electrocatalytic activity of several substituted and unsubstituted cobalt–phthalocyanines of substituted tetraphenyl porphyrins and of vitamin B12, for the electro-oxidation of 2-mercaptoacetate, with the complexes pre-adsorbed on a pyrolytic graphite electrode. Several N4-macrocyclic were used to have a wide variety of Co(II)/(I) formal potentials. The electrocatalytic activity, measured as current at constant potential, increases with the Co(II)/(I) redox potential for porphyrins as Co–pentafluorotetraphenylporphyrin larger than Co–tetrasulfonatotetraphenylporphyrin larger than Co-2,2′,2″,2‴tetra-aminotetraphenylporphyrin and decreases for cobalt phthalocyanines as Co-3,4-octaethylhexyloxyphthalocyanine > Co–octamethoxyphthalocyanine > Co–tetranitrophthalocyanine Co–tetraaminophthalocyanine > Co–unsubstituted phthalocyanine > Co–tetrasulfonatophthalocyanine > Co–perfluorinated phthalocyanine. Vitamin B12 exhibits the maximum activity. A correlation of log I (at constant potential) versus the Co(II)/(I) formal potential of the catalysts gives a volcano curve. This clearly shows that the search for better catalysts for this reaction point to those N4-macrocyclic complexes with Co(II)/(I) formal potentials close to −0.84 V versus SCE, which correspond to an optimum situation for the interaction of the thiol with the active site.
- Full Text:
- Date Issued: 2008
- Authors: Claußen, Jan A , Ochoa, Gonzalo , Páez, Maritza , Costamagno, Juan , Gulppi, Miguel , Nyokong, Tebello , Bedioui, Fethi , Zagal, José H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268688 , vital:54222 , xlink:href="https://doi.org/10.1007/s10008-007-0336-y"
- Description: We have investigated the electrocatalytic activity of several substituted and unsubstituted cobalt–phthalocyanines of substituted tetraphenyl porphyrins and of vitamin B12, for the electro-oxidation of 2-mercaptoacetate, with the complexes pre-adsorbed on a pyrolytic graphite electrode. Several N4-macrocyclic were used to have a wide variety of Co(II)/(I) formal potentials. The electrocatalytic activity, measured as current at constant potential, increases with the Co(II)/(I) redox potential for porphyrins as Co–pentafluorotetraphenylporphyrin larger than Co–tetrasulfonatotetraphenylporphyrin larger than Co-2,2′,2″,2‴tetra-aminotetraphenylporphyrin and decreases for cobalt phthalocyanines as Co-3,4-octaethylhexyloxyphthalocyanine > Co–octamethoxyphthalocyanine > Co–tetranitrophthalocyanine Co–tetraaminophthalocyanine > Co–unsubstituted phthalocyanine > Co–tetrasulfonatophthalocyanine > Co–perfluorinated phthalocyanine. Vitamin B12 exhibits the maximum activity. A correlation of log I (at constant potential) versus the Co(II)/(I) formal potential of the catalysts gives a volcano curve. This clearly shows that the search for better catalysts for this reaction point to those N4-macrocyclic complexes with Co(II)/(I) formal potentials close to −0.84 V versus SCE, which correspond to an optimum situation for the interaction of the thiol with the active site.
- Full Text:
- Date Issued: 2008
WET-Origins: controls on the distribution and dynamics of wetlands in South Africa
- Ellery, William F N, Grenfell, Michael C, Grenfell, Suzanne E, Kotze, Donovan C, McCarthy, Terence, Tooth, Stephen, Grundling, Piet-Louis, Beckedahl, Heinz, Le Maitre, David C, Ramsay, Lisa F
- Authors: Ellery, William F N , Grenfell, Michael C , Grenfell, Suzanne E , Kotze, Donovan C , McCarthy, Terence , Tooth, Stephen , Grundling, Piet-Louis , Beckedahl, Heinz , Le Maitre, David C , Ramsay, Lisa F
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/176598 , vital:40091 , ISBN 978-77005-633-6 , https://www.wrc.org.za/mdocs-posts/wetland-management-series-wet-origins-controls-on-the-distribution-and-dynamics-of-wetlands-in-south-africa/
- Description: The need for wetland rehabilitation in South Africa is compelling: loss and degradation of wetlands have been great and national policy and legislation provide clear direction and support for rehabilitation. However, rehabilitating wetlands is often complex because wetlands and their links with people are complex (e.g. through the ways that people use wetlands and the different benefits that people receive from the ecosystem services that wetlands supply).
- Full Text:
- Date Issued: 2008
- Authors: Ellery, William F N , Grenfell, Michael C , Grenfell, Suzanne E , Kotze, Donovan C , McCarthy, Terence , Tooth, Stephen , Grundling, Piet-Louis , Beckedahl, Heinz , Le Maitre, David C , Ramsay, Lisa F
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/176598 , vital:40091 , ISBN 978-77005-633-6 , https://www.wrc.org.za/mdocs-posts/wetland-management-series-wet-origins-controls-on-the-distribution-and-dynamics-of-wetlands-in-south-africa/
- Description: The need for wetland rehabilitation in South Africa is compelling: loss and degradation of wetlands have been great and national policy and legislation provide clear direction and support for rehabilitation. However, rehabilitating wetlands is often complex because wetlands and their links with people are complex (e.g. through the ways that people use wetlands and the different benefits that people receive from the ecosystem services that wetlands supply).
- Full Text:
- Date Issued: 2008
What future subordinates will value in their leaders
- Cox, A, Amos, Trevor L, Baxter, Jeremy
- Authors: Cox, A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270992 , vital:54499 , xlink:href="https://hdl.handle.net/10520/EJC51031"
- Description: Leaders should not randomly choose a leadership style. To be effective, leaders need to ensure that their leadership style is congruent with what subordinates value. The focus of this study is on what the future South African graduate workforce will value in a leader. The female and male respondents in this study emphasise similar leadership values, indicating that there is no distinct set of competencies that will be valued separately by males and females. The same was found for respondents of different cultures, namely African, Coloured, Indian, White and other. With respect to both gender and culture, the respondents emphasise a mixture of African and Western leadership values. This supports the idea that to be effective in South Africa, leaders need to understand the prevailing national cultural values before simply applying ''foreign'' leadership models and theories based upon cultural values found in the West. This research finds that irrespective of gender and culture in the South African workplace, to be effective, leaders need to be loyal and inspirational, have vision and integrity and must be open and honest with their subordinates. Leaders should avoid being autocratic, strict, religious, ritualistic and traditional. They should also avoid using consensus and perceived external control.
- Full Text:
- Date Issued: 2008
- Authors: Cox, A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270992 , vital:54499 , xlink:href="https://hdl.handle.net/10520/EJC51031"
- Description: Leaders should not randomly choose a leadership style. To be effective, leaders need to ensure that their leadership style is congruent with what subordinates value. The focus of this study is on what the future South African graduate workforce will value in a leader. The female and male respondents in this study emphasise similar leadership values, indicating that there is no distinct set of competencies that will be valued separately by males and females. The same was found for respondents of different cultures, namely African, Coloured, Indian, White and other. With respect to both gender and culture, the respondents emphasise a mixture of African and Western leadership values. This supports the idea that to be effective in South Africa, leaders need to understand the prevailing national cultural values before simply applying ''foreign'' leadership models and theories based upon cultural values found in the West. This research finds that irrespective of gender and culture in the South African workplace, to be effective, leaders need to be loyal and inspirational, have vision and integrity and must be open and honest with their subordinates. Leaders should avoid being autocratic, strict, religious, ritualistic and traditional. They should also avoid using consensus and perceived external control.
- Full Text:
- Date Issued: 2008
When commercial can also be community:
- Authors: du Toit, Peter , Rau, Asta
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159322 , vital:40287 , https://hdl.handle.net/10520/EJC140094
- Description: Questions of ownership, control and profit distribution are widely used to distinguish between commercial and community media ventures, but an over-reliance on such distinctions may eclipse other important considerations in a way that impacts negatively on media diversity.
- Full Text:
- Date Issued: 2008
- Authors: du Toit, Peter , Rau, Asta
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159322 , vital:40287 , https://hdl.handle.net/10520/EJC140094
- Description: Questions of ownership, control and profit distribution are widely used to distinguish between commercial and community media ventures, but an over-reliance on such distinctions may eclipse other important considerations in a way that impacts negatively on media diversity.
- Full Text:
- Date Issued: 2008