A review of the geology of primary tin deposits with emphasis on the factors that control grade and tonnage
- Authors: Archer, Paul D
- Date: 1981
- Subjects: Tin ores , Granite , Geology , Tonnage
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4912 , http://hdl.handle.net/10962/d1001572
- Description: "The purpose of this dissertation is ... to review the economic geology of primary tin deposits and the geological factors that control grade and tonnage . The work concludes with a discussian of the implications of these geological controls on evaluation"-- Introd., p. 1
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- Date Issued: 1981
An investigation into the potential immunogenicity of various extracts of the South African bont tick Amblyomma hebraeum
- Authors: Adamson, Deborah Jane
- Date: 1993
- Subjects: Amblyomma -- South Africa , Ticks -- South Africa , Ticks -- Control -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4127 , http://hdl.handle.net/10962/d1015640
- Description: Rabbits and goats were inoculated with crude, membrane-associated and soluble components extracted from unengorged adult females and nymphs of the bont tick Amblyomma hebraeum. Inoculation provided some protection against nymphal infestation, however it had little effect on adult feeding. Histological examination of adults fed on inoculated hosts showed evidence of gut damage. Skin provocation testing with tick extracts elicited a Type I immediate hypersensitivity which was influenced by antihistamine. A delayed skin reaction was also evident. Whether this was attributable to Type III Arthus reaction or Type IV cell-mediated hypersensitivity was not determined. A comparative histological study of sites of tick extract injection, on inoculated and naive hosts, demonstrated the role of eosinophils in the hosts response to tick feeding. Serological examination revealed elevated anti-A hebraeum lgG titres following inoculation. These titres were found to decrease in the ten weeks after inoculation, despite the hosts being repeatedly infested with A hebraeum. Although the IgG titres of naive control hosts increased after each tick infestation, they failed to reach the titres achieved through inoculation. Western blot analysis of serum from inoculated hosts recognized most of the A. hebraeum proteins against which it was screened.
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- Date Issued: 1993
Assessing the vulnerability of resource-poor households to disasters associated with climate variability using remote sensing and GIS techniques in the Nkonkobe Local Municipality, Eastern Cape Province, South Africa
- Authors: Chari, Martin Munashe
- Date: 2016
- Subjects: Climatic changes -- Forecasting Natural resources -- Remote sensing Droughts -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2425 , vital:27837
- Description: The main objective of the study was to assess the extent to which resource-poor households in selected villages of Nkonkobe Local Municipality in the Eastern Cape Province of South Africa are vulnerable to drought by using an improvised remote sensing and Geographic Information System (GIS)-based mapping approach. The research methodology was comprised of 1) assessment of vulnerability levels and 2) the calculation of established drought assessment indices comprising the Normalized Difference Vegetation Index (NDVI) and the Normalized Difference Water Index (NDWI) from wet-season Landsat images covering a period of 29 years from 1985 to 2014 in order to objectively determine the temporal recurrence of drought in Nkonkobe Local Municipality. Vulnerability of households to drought was determined by using a multi-step GIS-based mapping approach in which 3 components comprising exposure, sensitivity and adaptive capacity were simultaneously analysed and averaged to determine the magnitude of vulnerability. Thereafter, the Analytical Hierarchy Process (AHP) was used to establish weighted contributions of these components to vulnerability. The weights applied to the AHP were obtained from the 2012 - 2017 Nkonkobe Integrated Development Plan (IDP) and perceptions that were solicited from key informants who were judged to be knowledgeable about the subject. A Kruskal-Wallis H test on demographic data for water access revealed that the demographic results are independent of choice of data acquired from different data providers (χ2(2) = 1.26, p = 0.533, with a mean ranked population scores of 7.4 for ECSECC, 6.8 for Quantec and 9.8 for StatsSA). Simple linear regression analysis revealed strong positive correlations between NDWI and NDVI ((r = 0.99609375, R2 = 1, for 1985), 1995 (r = 0.99609375, R2 = 1 for 1995), (r = 0.99609375, R2 = 1 for 2005) and (r = 0.99609375, R2 = 1 for 2014). The regression analysis proved that vegetation condition depends on surface water arising from rainfall. The results indicate that the whole of Nkonkobe Local Municipality is susceptible to drought with villages in south eastern part being most vulnerable to droughts due to high sensitivity and low adaptive capacity.
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- Date Issued: 2016
Electrochemical studies of gold bioaccumulation by yeast cell wall components
- Authors: Lack, Barbara Anne
- Date: 1999
- Subjects: Hydrometallurgy , Electrochemical analysis , Gold ores , Gold
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4311 , http://hdl.handle.net/10962/d1004969 , Hydrometallurgy , Electrochemical analysis , Gold ores , Gold
- Description: Gold, amongst other group 11 metals, was almost certainly one of the first three metals known to man. In addition to the economic importance of the metal, gold has a wide variety of applications in the medical, electrocatalytical and micro-electronics fields. However, the determination of gold ions in solution, with accuracy, precision, sensitivity and selectivity is still an interesting and much debated topic in analytical chemistry. A system whereby gold ions have been successfully detected employing an electrochemical technique, known as stripping voltammetry, has been developed. The electrochemical method was chosen over other available techniques for the sensitivity, particularly at low concentrations, and selectivity properties; notably in the presence of other metal ions. Under acidic conditions, the electrochemical technique was applied and the presence of gold(III), at a concentration of 2.53 x 10⁻⁵ mol dm⁻³ in a mine waste water sample, was detected. Biomass, in particular yeast and algal types, have been successfully employed in extracting low concentrations of gold ions from industrial effluents. The manipulation of the biological facility for mineral interaction, biohydrometallurgy, may yield numerous potential new technologies. South Africa in particular would benefit from this area of research, since the country is a major ore and metal refining country and if the output and the efficiency of the mines could be improved, even by a small percentage, the financial rewards would be vast. In this study, the application of adsorptive cathodic stripping voltammetry (AdCSV) of gold(III) in the presence of various Saccharomyces cerevisiae cell wall components, was investigated to determine which, if any, were involved specifically in the chemical binding of the gold ions. The chitin and mannan extracts showed the most promise with detection limits of 1.10 x 10⁻⁶ mol dm⁻³ and 9 x 10⁻⁹ mol dm⁻³, respectively; employing the AdCSV technique. A modification of the stripping voltammetry technique, Osteryoung square wave stripping voltammetry (OSWSV), provided the lowest detection limit, for gold(IIl) in the presence of mannan, of 1.70 x 10⁻¹¹ mol dm⁻³ ; utilising a modified carbon paste electrode. The detection of gold(III) has been shown to be dependent on the type of electrode employed, the electrolyte solution and the presence of interfering agents. The effect of copper(II) and silver(I) on the detection of the gold(III) in solution was investigated; whilst the silver(I) has shown no detrimental effects on gold (III) detection systems, copper(II) has indicated the possibility of forming an inter-metallic compound with the gold(III). However, mannan has shown to selectively and preferentially bind the gold(III) in the presence of a ten-fold excess of copper(II). Nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, as well as computer modelling techniques were employed to further investIgate the mannan-gold(III) interaction and proposed complex formed. The NMR, IR and computer modelling data are in agreement with the electrochemical data on proposing a mannan-gold(III) complex. The co-ordination site was established to be in the vicinity of the H-I and H-2 protons and the gold(III) adopts a square-planar geometry upon co-ordination. The benefits of the research are useful from a biological perspective (i. e. as more is known about the binding sites, microbiologists/biochemists may work on the optimisation of parameters for these sites or work could be furthered into the enhanced expression of the sites) and an industrial one. In addition to the' two major benefits, an improved understanding of gold and its chemistry would be achieved, which is advantageous for other fields of research as well.
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- Date Issued: 1999
Investigation into the extended capabilities of the new DPS-4D ionosonde
- Authors: Ssessanga, Nicholas
- Date: 2011
- Subjects: Ionosondes , Ionosphere , Ionosphere -- Observations -- South Africa -- Hermanus (Cape of Good Hope) , Ionosphere -- Research -- South Africa -- Hermanus (Cape of Good Hope)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5472 , http://hdl.handle.net/10962/d1005257 , Ionosondes , Ionosphere , Ionosphere -- Observations -- South Africa -- Hermanus (Cape of Good Hope) , Ionosphere -- Research -- South Africa -- Hermanus (Cape of Good Hope)
- Description: The DPS-4D is the latest version of digital ionosonde developed by the UMLCAR (University of Massachusetts in Lowell Center for Atmospheric Research) in 2008. This new ionosonde has advances in both the hardware and software which allows for the promised advanced capabilities. The aim of this thesis was to present results from an experiment undertaken using the Hermanus DPS-4D (34.4°S 19.2°E, South Africa), the first of this version to be installed globally, to answer a science question outside of the normally expected capabilities of an ionosonde. The science question posed focused on the ability of the DPS-4D to provide information on day-time Pc3 pulsations evident in the ionosphere. Day-time Pc3 ULF waves propagating down through the ionosphere cause oscillations in the Doppler shift of High Frequency (HF) radio transmissions that are correlated with the magnetic pulsations recorded on the ground. Evidence is presented which shows that no correlation exists between the ground magnetic pulsation data and DPS-4D ionospheric data. The conclusion was reached that although the DPS-4D is more advanced in its eld of technology than its predecessors it may not be used to observe Pc3 pulsations.
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- Date Issued: 2011
Seasonal physiological and behavioural responses of a small bird in a hot, arid habitat
- Authors: Pattinson, Nicholas Bruce
- Date: 2017
- Subjects: Birds -- Behavior Birds -- Physiology , Birds -- Ecophysiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/19728 , vital:28948
- Description: The role that climate plays in the ecology of organisms is perhaps the most pronounced where the earth’s environments are most extreme. In arid-zones, organisms have to deal with large seasonal shifts and/or extremes in temperature and/or moisture levels. As a result, arid-zone species are sensitive to climatic changes. I assessed the physiological and behavioural adjustments of an arid-zone endemic passerine, the rufous-eared warbler (Malcorus pectoralis), to seasonal changes in the Karoo semi-desert of South Africa. Respirometry measurements in the field showed that the warblers’ basal metabolic rate was lower and set point body temperature (Tb) was higher in summer compared to winter. At high air temperatures (Ta) evaporative water loss (EWL) rate was significantly lower in summer compared to winter, while Tb showed a clear pattern of heterothermy that was similar in both seasons. Compared to winter, the warblers in summer were able to remain calm, and tolerate higher Ta’s, before their Tb’s increased to potentially detrimental levels. Behavioural observations showed that free-living warblers exhibited significant temperature-dependence in their behaviour; they increased panting behaviour, and reduced activity levels, time spent preening, and foraging effort at high Ta’s in summer. The warblers also displayed a considerable decrease in foraging success, and a shift in microsite use, at high Ta’s in summer. I hypothesise that the flexible responses the rufous-eared warblers show are aimed at increasing their heat tolerance in summer, and help them balance their energy and water demands in an arid environment that exhibits wide seasonality in Ta, in addition to high summer Ta. My findings emphasise the importance of identifying, as well as understanding, the associated costs of physiological and behavioural responses to environmental variables. This information is valuable in terms of predicting biologically meaningful responses (and hence, vulnerability) of arid-zone avian communities to climactic shifts.
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- Date Issued: 2017
The development of an improved coded-pulse, vertical-incidence ionosonde
- Authors: Cretchley, Brian Brind
- Date: 1979
- Subjects: Ionosondes Ionospheric sounds Computer simulation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5436 , http://hdl.handle.net/10962/d1001989
- Description: This thesis describes the theoretical development of a new ionospheric sounding system. The different types of ionosonde, their prime objectives, and their relative merits and demerits are discussed. The various types of code and their correlation functions are described. The essential requirements of the new system are listed, and suitable codes are found for it. Computer calculations and mathematical derivations demonstrate the (theoretical) suitability of these codes under all conditions. Essentials of the mode of operation of the system and details of its design are specified, and computer simulations are used to examine relevant aspects of its operation. Finally, since the construction of the system is not complete and results cannot therefore be presented, the present state of construction of the system is described
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- Date Issued: 1979