The development of a morphometric model for the estimation of mean annual sediment yield in ungauged catchments of South African river systems
- Authors: Roberts, Peter J T
- Date: 1975
- Subjects: Sedimentation and deposition -- South Africa -- Mathematical models
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4876 , http://hdl.handle.net/10962/d1013062
- Description: Hydrologists are regularly faced with the unenviable task of having to predict the magnitude and frequency of phenomena such as floods and droughts; and rates of erosion. If long records are available for analysis the hydrologist is able to base his predictions on the premise that the pattern of variation that has been observed in the past will persist in the future. The confidence that can be placed in any estimate consequently depends to a large extent on the length of time over which the phenomena have been measured at the problem site. Unfortunately the availability of adequate records tends to be the exception rather than the rule and in areas where there is inadequate data, it is necessary to resort to the hazardous procedure of transferring information from the gauged to the ungauged catchments. The transfer of information is accomplished by using empirical methods based on regionalised parameters, but the uncertainties involved together with the economic implications that could arise from a poor estimate, prompt the hydrologist to use as many methods as possible. The need for empirical methods of estimating mean annual sediment yield in ungauged catchments was first appreciated by the author when he was involved in the estimation of design floods and sediment accumulation at sites for proposed reservoirs. Empirical methods of estimating sediment yield are frequently used in an engineering context, but little attention has been given to the catchment surface from which the sediment supply is derived. It is perhaps in this often neglected field of research that the physical geographer can make a contribution. The principal aim of the thesis, more fully discussed in Chapter I, was the development of a morphometric model which could be used to estimate mean annual sediment yield in ungauged catchments in South Africa. The data used in the development of the model were drawn from the catchments, described in Appendix A, that cover a wide range of climate and topography. A description of the approaches adopted by other researchers for the development of empirical models of estimating sediment yield which forms the background to the model has been included as Appendix B. The model was first developed in an elementary form as the focus of a research project which was documented in the form of three reports of research in progress (Roberts, 1973 a, b and c). Analysis of the pattern of variation of suspended sediment yield provided a better understanding of factors affecting sediment yield and supported the selection of the prediction variable (Horton's P ratio) which was used in the model. The concepts of network topology were utilised to gain insight into the environmental factors controlling both the P ratio and sediment yield. Reasons for the high correlation between the P ratio and sediment yield are suggested but it is felt that further research should be focused on this aspect. In order not to break the continuity and development of the steps taken in the derivation of the model details of the calculations are collected in Appendices C, D and E. While many of the figures and tables presented in the thesis appeared in technical notes prepared entirely by the author for the Department of Water Affairs, the views expressed in the thesis do not in any way, either explicitly or by implication, represent any official view or policy of the Department of Water Affairs.
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- Date Issued: 1975
The study of hydroxyoximes and hydroxamic acids supported on macroporous resins and their use in the rapid seperation of metals
- Authors: Hemmes, Marlene
- Date: 1979
- Subjects: Chromatographic analysis , Separation (Technology) , Metal ions , Solvent extraction , Extraction (Chemistry) , Oximes , Metals -- Analysis
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4453 , http://hdl.handle.net/10962/d1009512
- Description: Introduction: The macroporous Amberlite XAD resins were coated with LIX-64N and examined for the rate of uptake of copper . XAD-7 was by far the best support and gave a satisfactory rate of uptake up to loadings of 60% (w/w). The specific surface area of XAD-7 was measured by the adsorption of methylene blue from aqueous solution. The area of the wetted resin was five times less than that of the dry resin. LIX-65N was purified and the anti isomer characterised using spectroscopic techniques . The rate of uptake of copper was not improved by use of purified LIX-65N or by addition of LIX-63. XAD-7 coated with LIX-65N was used in columns. Elution curves for copper showed negligible tailing, and rapid separations of copper from iron (111), nickel, cobalt and magnesium by selective absorption were achieved. Copper was concentrated from very dilute solution at a flow rate of 50 ml min -1 ,and a 99% recovery was obtained. The method was applied to the rapid determination of copper in brass and bronze. A series of long-chain hydroxamic acids were synthesised and tested for suitability as stationary phase on XAD-7. Oleohydroxamic acid and naphthenohydroxamic acid were the most promising. The r ate of uptake of copper was reduced by the use of nonylphenol or amyl alcohol as a diluent. The capacities for copper of the hydroxamic acids were less when supported on XAD-7 than when used as liquid ionexchangers. The distribution coefficients of cobalt, nickel, zinc, lead, vanadium, uranium, iron (111) and copper were measured as a function of pH. XAD-7 coated with oleohydroxamic acid was used in columns for the rapid separation of iron (111) from copper and of copper from nickel, cobalt, lead and zinc. Copper was concentrated from very dilute solution at a flow rate of 45 ml min -1 and a 100,8% recovery was obtained. Copper was successfully separated from nickel by selective elution. The elution curves obtained show negligible tailing. The resin loaded with oleohydroxamic acid lost capacity due to chemical instability. Naphthenohydroxamic acid supported on XAD-7 was not suitable for use in columns, because it was physically unstable.
- Full Text:
- Date Issued: 1979
Cleavage of the precursor coat protein of black beetle virus strain w17 in rabbit reticulocyte lysate
- Authors: Blackhurst, Diane Mary
- Date: 1988
- Subjects: Beetles , Insects -- Viruses
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3880 , http://hdl.handle.net/10962/d1001614
- Description: Black beetle virus (BBV) is a bipartite single-stranded RNA virus belonging to the family Nodaviridae. Its host range has been found to be limited to insects. RNA 1, the larger of the two RNA molecules, with a MW of 1,15 x 10⁶ and the smaller RNA 2 with a MW of 0,46 x 10⁶, are both packaged in the same virus particle. The two RNA molecules are translated separately, with RNA 1 coding for protein A of MW 105 x 10³ and RNA 2 coding for protein α of MW 47 x 10³. Protein α is the major capsid protein precursor, which during in vivo maturation is cleaved to form the coat protein β of MW 43 x 10³, and protein γ of MW 5 x 10³. Cell-free translation of BBV (strain W17) mRNA was carried out in rabbit reticulocyte lysates. Protein α was detectable between 0 and 30 minutes after RNA addition. A protein 'β', which was found to co-electrophorese on polyacrylamide gels with authentic β and which was immunoprecipitated by anti-BBV antiserum, was detectable after 30 minutes. Results of this work show that the formation of 'β' could be prevented by the addition of RNase to the lysate, indicating that intact RNA is necessary for α to β cleavage. Arresting protein synthesis by the addition of cycloheximide to the lysate mix did not inhibit the cleavage. The formation of β could also be prevented by cooling the lysate mix to 1°C. Cleavage of α to β still occurred when RNA 2, without the presence of RNA 1, was translated. Therefore the cleavage is not dependent on a translation product of RNA 1. Sedimentation of lysate on sucrose density gradients showed that α to β cleavage was not accompanied by assembly of BBV RNA and protein lnto a viral substructure as has been shown to occur with some viruses, for example certain picornaviruses. Serial dilution of lysate containing α showed that the level of β decreased with increasing dilution, indicating that the cleavage is not mediated by autocatalysis, but by some other unknown factor. Although much work has been carried out on black beetle virus, no work has been published to date concerning α to β cleavage as an indication of assembly in rabbit reticulocyte lysates. Results of these cell-free translation experiments thus indicate that BBV coat protein precursor α, in association with its messenger RNA 2, undergoes a maturation cleavage in the lysate to produce BBV coat protein β. In addition, this cleavage seems to occur without assembly into any intermediate viral structure
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- Date Issued: 1988
A possible mechanism for enzymic depilation of skins
- Authors: Brady, Dean
- Date: 1989
- Subjects: Chemistry, Technical , Tanning
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3877 , http://hdl.handle.net/10962/d1001611
- Description: Streptomyces fradiae is a bacterium which has been previously found to produce extracellular enzymes which are capable of wool degradation and skin depilation. Streptomyces fradiae 3739 and other strains of Streptomyces were found in this study to be able to degrade a keratin source (wool) to a considerable degree. However according to the evidence of SEM micrographs presented here the highly keratinised spindle cells of the paracortex are fairly resistant to protease attack, and it is the cementation material which binds these cells together which is initially degraded by the proteases. A large degree of correlation was found with the strains of Streptomyces studied, between the ability of the individual strains to degrade wool and the ability of their extracellular proteases to reduce the depilation load of sheepskins. With further analysis S. fradiae 3739 was found to produce at least one amylase and four or more proteases. The proteases as a group had maximal proteolytic activity in the 8.0-9.0 pH unit range, and were considerably thermostabilised by the inclusion of calcium ions into the reaction solution. The protease group was found to cause depilation of merino sheepskins. For comparative purposes a protease produced by a strain of Proteus vulgaris isolated from a staling hide with hair slip (natural depilation) was studied. The protease activity was maximal in the alkaline region between 8.0-9.0 pH units. Tbe protease appeared to be a single enzyme with a molecular mass of approximately 44 000 daltons. The protease was maximally active at 40°C, although it was only thermostable to 30°C. The enzyme was ineffectual as a depilant except when the skin was pre-treated with a strong alkali, preferably including sodium sulphite in the protease preparation. One of the most important differences between the extracellular proteases of S. fradiae and P. vulgaris was that the former were greater in variety and caused a greater decrease in the depilation load of sheepskins than the latter. Further research with mixtures of commercial proteases provided evidence that a synergistic depilatory effect occurs when proteases of complementary bond specificities are used in conjunction in enzymic depilatory preparations. Some form of strong alkali treatment of skins was found to be necessary to produce leather of the prerequisite quality when the skin was depilated by proteases, otherwise the skin was found to be depleted and stiff. Calcium hydroxide alone was found to be inadequate for this task, probably owing to the fact that it is less alkaline than the lime-sulphide mixture. The calcium hydroxide (lime) must therefore be used in conjunction with sodium hydroxide (which makes the solution as alkaline as that of the lime-sulphide solution) to produce leather comparable to that produced by the lime sulphide treatment. A combination of the information provided by the present research and that gleaned from the relevent literature allows for the construction of a model to represent the possible mechanism of enzymic depilation of skins, in which depilation is caused by the disruption of the basement membrane at the dermal-epidermal junction by the degradation of its constituent molecular components by general proteases, resulting in the removal of the epidermis and its associated wool or hair
- Full Text:
- Date Issued: 1989
Environmentally friendly dyeing and finishing
- Authors: Dayla, Mackraj
- Date: 2013
- Subjects: Dyes and dyeing -- Knit goods -- South Africa , Textile finishing -- South Africa , Bleaching industry -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10454 , http://hdl.handle.net/10948/d1020776
- Description: The textile industry in South Africa is a significant contributor to the chemical load that public wastewater treatment plants have to process, and the discharge of toxic substances, especially to the aquatic environment. In order to address this issue at factory level, the processes at a textile plant, JMV Textiles were chosen for investigation into the possibilities of minimization of discharges of harmful substances into the environment. The study followed the principles of cleaner production, and the processes that were investigated and revised were: The conventional peroxide bleaching process employed a peroxide stabilizer that did not biodegrade easily. The bleaching process was changed, so that the prevailing conditions in the fabric and dyebath facilitated bleaching without the addition of peroxide stabilizer, and also reduced the alkali and energy requirements. Polyester‐viscose fabric was pretreated by bleaching with hydrogen peroxide, which seemed to be unnecessarily rigorous, because polyester and viscose, unlike natural fibres, are relatively clean and have good whiteness in comparison with natural fibres. The proposed alternate pretreatment was a scour with detergent and alkali. The pretreatment for all polyester‐cotton fabrics was also a hydrogen peroxide bleach. Due to the ability of medium and dark shades to mask the natural tint of cotton fibres, a simpler alternate pretreatment, consisting of an alkaline scour with sequestering agent, was trialled. An unacceptable proportion of the dyeings on polyester was rejected for dye‐stains and dye‐marks. A possible solution exploited the properties of using the finishing auxiliary chemical to alleviate dye‐stains and dye‐marks during the dyeing stage, instead of using the chemical after dyeing. The highly toxic carrier that was used to facilitate level dyeing of polyester fibres that had unacceptable variation in their dyeing properties, was replaced by a less toxic carrier. The formulation for dyeing polyester was simplified to eliminate the auxiliary chemicals that were not essential to the dyeing process. Pale reactive dyed shades on cellulose and polyester‐cellulose were washed off only with hot water instead of detergent. The revised procedures consequential to the study, offered significant environmental benefits by reducing the concentration and volume of effluent produced, substituting a highly toxic carrier with a less toxic one and saving energy and water. Implementation of the suggested changes also offered financial benefits. The management of the factory, however, accepted and implemented some changes, but wanted further investigations for others and a phased approach to the other suggested changes.
- Full Text:
- Date Issued: 2013
Determining and analysing the emergent behaviour from context-aware devices
- Authors: Bandason, Vivian
- Date: 2017
- Subjects: Context-aware computing Mobile computing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/7907 , vital:30805
- Description: With the continued miniaturization of technology and the incorporation of Moore’s law, smartphones are more powerful. These mobile devices contain technologies that add other functionalities to them. Technologies such as sensors constantly provide information to the device. The constant stream of information from these sensors often leads to information overload of relevant and irrelevant information. To work towards solving this problem context-aware computing was introduced. Our major concern is that context information in context aware computing is not completely being utilized. The aggregation of context information could unlock more possibilities. This research seeks to aggregate the context of multiple devices such that, through analysis, some emergent behaviour can be observed. In this research context information from the sensors of devices is collected using an Android application and a central Server. The context information is used for pattern analysis. A pattern analysis algorithm is designed and used to observe patterns throughout the data set. It shows patterns that are similar within the dataset. In the case that the pattern observed has no similar pattern or few similar patterns this behaviour can be stated as emergent in the dataset. Further study of this emergent behaviour can be performed were a classifier can be used to give the exact activities that were being performed at that time. The research found this was possible and has many uses. One of these is in disaster prevention were the behaviour of a group of individuals may be monitored to observe any random changes such as masses running at the same time. This could be used as a first warning to natural disasters.
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- Date Issued: 2017
Synthesis and characterization of CdSe quantum dots for solar cell application
- Authors: Makinana, Sinovuyo
- Date: 2017
- Subjects: Quantum dots Quantum dots -- Optical properties Renewable energy sources
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5994 , vital:29466
- Description: This study shows a detailed report on the morphological, structural and optical properties of CdSe QDs synthesised by the hot injection method. Cadmium acetate dihydrate and Se powder were used as cadmium and selenide precursors, respectively. Various QD sizes were achieved by synthesizing in temperature range of 150ºC, 175ºC, 200ºC, 225ºC, 250ºC, 275ºC and 300ºC, respectively. The as synthesized QDs by the hot injection method were cross-examined for their morphological, structural and optical using HRTEM, FTIR, XRD, RS, and UV-Vis spectroscopy techniques respectively. FTIR analysis has revealed vibrations at 738, 738, 738, 738, 735, 735 and 733 cm-1 for the QDs synthesized at various temperatures of 150, 175, 200, 225, 250, 275, and 300℃, respectively. The presence of the above mentioned peaks confirms the presence of Cd-Se bond in our samples. XRD analysis of CdSe QDs revealed diffraction peaks at 2 angles of 16.66 , 25.20 , 34.77 , 40.9 , 45.39 and 49.1 for 150 17.4 , 25.22 , 34.85 , 41.7 , 44.45 and 47.5 for the QDs synthesized at various temperatures of 175 17.07 , 25.19 , 34.85 , 41.34 , 44.41 and 48.86 for 200 ; 16.34 , 25.20 , 34.76 , 40.6 , 44.74 and 49.48 for 225 ; 17.44 , 25.17 , 34.19 , 41.7 , 44.45 , 49.24 for 250 ; 16.70 , 25.16 , 34.85 , 40.32 , 45.1 and 49.1 7 for 275 ;and 17.35 , 25.18 , 35.13 , 41.63 , 45.7 , 49.48 for 300 . These XRD peaks relate to crystal planes of (100), (002), (102), (220), (103) and (112) which belong to hexagonal Wurtzite CdSe crystal structure. Additionally XRD analysis has revealed a general peak shift to higher 2 values was observed for CdSe QDs. HRTEM analysis showed that the synthesised CdSe QDs have a spherical shape and are monodispersed. Moreover, HRTEM analysis has revealed CdSe QDs modal crystallite size of 1.79 nm, 1.81 nm, 2.06 nm, 2.08 nm, 2.11 nm, 3.10 nm and 3.12 nm for the QDs synthesized at various temperatures of 150ºC, 175ºC, 200ºC, 225ºC, 250ºC, 275ºC and 300ºC, respectively. HRTEM results were in mutual agreement with XRD results. Additionally, the SAED images showed intense electron diffraction rings, which confirmed that the as-synthesised CdSe QDs have a Wurtzite crystal structure. RS analysis showed that CdSe QDs have LO and 2LO vibrational modes which are characteristic peaks for CdSe. The presence of these peaks in Raman spectra further supports our previous observation from XRD analysis and HRTEM analysis that the synthesized CdSe QDs have a Wurtzite crystal structure. The effect of synthesis temperature Raman peak shift, FHWH and peak intensity has been cross examined in this work, Moreover, the effect of increasing temperature on the peak shift, FWHM and peak intensity is discussed in detail below. UV-Vis analysis revealed an absorbance of CdSe QDs in higher wavelengths as temperature was increased. Furthermore, the Yu et al 2003 relation was used to calculate QD size and band gap energy of CdSe QDs. The results showed that QD size increases with increasing synthesis temperature, which is in agreement with HRTEM and XRD results.
- Full Text:
- Date Issued: 2017
Assessment of indigenous forest degradation and deforestation along the wild coast, near Port St John’s, Eastern Cape Province, South Africa
- Authors: Katende, Lukyamuzi Lucky Fulgentius
- Date: 2018
- Subjects: Deforestation -- South Africa -- Eastern Cape , Forest degradation -- South Africa -- Eastern Cape Forest management -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/30649 , vital:31006
- Description: Indigenous forests along the Wild Coast of the Eastern Cape Province have experienced both degradation and deforestation over the past decades. In early 2000, steps were taken to rehabilitate some of the degraded areas. Nevertheless, there is no monitoring mechanism in place, so little is known about the extent of degradation and impact of the rehabilitation efforts. The present study assesses the extent to which deforestation and degradation of the indigenous forests have occurred, and evaluates rehabilitation efforts in the study area around Port Saint John’s. Forest degradation was defined as the decrease in forest cover density while deforestation was defined as an increase in the trend of light forests and/ or a decrease in dense forests. The details for this study were obtained from multi – temporal remotely sensed data for a period between 1982 and 2013 (31 years). Multi-temporal Landsat satellite imagery for 1982, 1986, 1989, 2002, 2009 and 2013 was acquired and analysed. On the basis of prior knowledge of the area, the supervised classification approach was used. The Maximum likelihood supervised classification technique was used to extract information from satellite data. The classified images were filtered using a majority filtering procedure to reduce noise. Google Earth (Astrium) ancillary images were used to refine the classification based on expert rules. The derived changes in the degraded and rehabilitated areas were further validated through field visits. The overall image classification accuracy generated from Landsat image data ranged from 80% to 90%. It was noted that the area of dense forest almost doubled between 1986 and 1989, coinciding with a 59% decrease in the light forest. Subsequently, dense forests increased by 14,820 ha while light forests decreased by 16,690 ha between 1989 and 2002. The subsequent reduction in light forest coverage is explained by the establishment of the Participatory Forest Management (PFMA) approach by Department of Water Affairs and Forestry (DWAF) which reversed the degradation trend. However, specific degradation hotspots were identified, particularly where new settlements have been established. The emergence of the non-vegetated area increased gradually from 7% in 1986 to 23.4% in 2013. Notably, dense forest was observed to have experienced higher rates of forest degradation and deforestation than the light forest. The highest number patches were 4 recorded between 2002 and 1998, followed by between 2010 and 2013 and lastly 1986. Based on spatial connectedness of patches, the year 1986 had the highest landscape connectedness of forest vegetation (CONAT = 35.3) followed by 2002 and 1996 while the year 2010 and 2013 had the lowest landscape contiguity. Over the study period, the distribution of patches clearly shows that forest degradation and deforestation rates were lower in the years 1986, 1998 and tremendously increased in the later period of between 2010 and 2013. However, as a result of rehabilitation efforts, dense forest was seen to steadily gain more land than light forest. Finer details of degradation trends could not be easily picked from the images used in the study, given their spatial resolution limitations. That notwithstanding, the trends identified are good for overview decisions. The study has also established that de-agraianisation, forest restoration and rehabilitation greatly contributed to increased forest cover. Therefore, with more use of GIS by forest managers, and imagery of the high resolution being readily available, forests will in future be easily monitored using remote sensing.
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- Date Issued: 2018
Functional conversion of commercial buildings in South Africa
- Authors: Kuliti, Gerald
- Date: 2020
- Subjects: Commercial buildings -- South Africa , Buildings -- Conservation and restoration Buildings -- Maintenance and repair
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/46075 , vital:39485
- Description: In the major cities of South Africa, there is a prevalence of originally built commercial buildings that are being converted into residential apartments or other industrial economic spaces. These secondary users refurbish the original structures to accommodate their new specialised requirements and this mostly happens after the buildings have been lying vacant for a long period of time. The study by Y.Long et al. (2011) narrates the changes in land use, identification of driving forces and the mapping of areas that are experiencing intense land use transformation. Properties that were developed for a focused particular use, were found to have been redeveloped within a few years for other functions. Subjects that were included in the sample were selected to meet specific criteria. The stakeholders had to meet the following criteria to be included in the sample: They were registered professionals in the built environment such as: Architecture, Engineering (civil, electrical, mechanical and structural), Quantity Surveying, Town Planning, Construction Management and Estate management The method that was used to collect data was self-completion questionnaire that was given out by electronic mail. After the data was collected, it was organised and analysed. For the analysis of closed-ended questions, an online programme called QuestionPro, was used, data was analysed by using descriptive statistics and frequency tables were drawn and from these, the data was presented in pie diagrams and bar graphs. While it is necessary to expand the horizons of the ever-growing global population, it is imperative that all stakeholders in the building industry work together to find sustainable solutions to residential and industrial development.
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- Date Issued: 2020