Adoption and risk of mobile financial services: a case of some selected municipalities in Eastern Cape Province
- Authors: Aderibigbe, Ifeoluwa A.I
- Date: 2019
- Subjects: Mobile commerce Finance
- Language: English
- Type: Thesis , Masters , MCom (Economics)
- Identifier: http://hdl.handle.net/10353/13281 , vital:39630
- Description: The study investigated risk and adoption of mobile financial services among some users in selected municipalities within the Eastern Cape Province, using the theory of reason action, technology acceptance model and the theory of expected utility and risk aversion to explain the variables. Moreover, the explanatory research design and quantitative data collection approach formed the methodology adopted in the study. In addition, a validated semistructured interview questionnaire was used as a research instrument in the study. The multistage, stratify, purposive and convenience sampling techniques were applied to select 6 research sites and 386 research participants for the study. Three research objectives were stated and tested using descriptive, Principal Component Analysis (PCA) to profile the risk and logit regression statistics. The results of statistical analysis show different level of cross tabulation between MFS and education level, all the 6 different locations, individual age range, job type, and average income of individual. Analysis revealed that age and income level of individuals have the highest relationship with the use of MFS. The statistical analysis used was the logistic regression. Pool of effort of all the stake holders in financial services sector should focus on including the low income earners and the technology should be simple enough for the use of the older generation.
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- Date Issued: 2019
A study of the role of nature conservation law enforcement officers as facilitators of environmental education
- Authors: Barrett, Janice Anne
- Date: 1992
- Subjects: Environmental education Nature conservation
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1783 , http://hdl.handle.net/10962/d1003668
- Description: This study explores the potential roles of a sample of 18 nature conservation law enforcement officers, as facilitators of environmental education. More specifically it examines their attitudes towards their dual duties of enforcing laws and providing extension services. Attitudes were examined by means of qualitative data analysis from semi-structured interviews. Officers' environmental attitudes, as well the relative emphasis placed on law enforcement and extension, and their own perspectives of working with communities, are explored. The historical and cultural context of officers' work, as well as worldviews and personality traits are also discussed. Certain recommendations regarding officers' roles as facilitors of environmental education are made.
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- Date Issued: 1992
The relationship between conscientiousness, extraversion and leadership effectiveness among local government managers in Bisho and East London
- Authors: Bell, Clement
- Date: 2012
- Subjects: Extraversion -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Big Five model , Public officers , Role conflict , Conscience -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom (Industrial Psychology)
- Identifier: vital:11556 , http://hdl.handle.net/10353/d1007116 , Extraversion -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Local government -- South Africa -- Eastern Cape , Big Five model , Public officers , Role conflict , Conscience -- South Africa -- Eastern Cape
- Description: This study investigated the relationship between conscientiousness, extraversion, and leadership effectiveness among the local government managers in Bisho and East London. Conscientiousness and extraversion were used as independent variables in the study while leadership effectiveness was used as the dependent variable. The data was collected from a sample of 222 local government managers using a self-designed biographical and occupational questionnaire. To measure conscientiousness and extraversion, a 24-item 5-point rating scale adopted from Finchan & Rhodes (2005) was used. To measure leadership effectiveness, a 6-item 5-point derailment rating scale adopted from Lombardo & McCauley (1994) was used. Data analysis was done using various statistical techniques, including t-tests, Pearson Product Moment Correlation Technique and Multiple Regression Analysis. The results indicated that both conscientiousness and extraversion are strongly associated with leadership effectiveness. Conscientiousness was also strongly associated with the individual components of leadership effectiveness, interpersonal relationships; molding a staff; making strategic transitions; follow-through and ability to work independently. Extraversion was also strongly associated with the individual components of leadership effectiveness, molding a staff; making strategic transitions; strategic similarities with management; follow-through and ability to work independently. Although conscientiousness and extraversion combined were found to have an additive effect on leadership effectiveness, conscientiousness accounts for a higher proportion of variance in leadership effectiveness than extraversion. Finally, the results also indicated that age was strongly associated with leadership effectiveness. The study therefore recommends that organisations should use conscientiousness and extraversion when selecting individuals for leadership positions.
- Full Text:
- Date Issued: 2012
Decent work and informal employment: the case of Bulawayo Metropolitan Province (Central Business District) Zimbabwe
- Authors: Bob, Shaka Keny
- Date: 2020
- Subjects: Labor -- Zimbabwe , Informal sector (Economics) -- Zimbabwe , Job creation -- Zimbabwe , Poor -- Zimbabwe -- Employment , Labor policy -- Zimbabwe , Football coaches -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/115241 , vital:34104
- Description: Zimbabwe, similar to other developing countries experiences a high level of informal employment. However, most informal jobs are situated in very poor working conditions and are characterised by decent work deficits. Despite the fact that various studies have shown the importance of the informal economy in that it provides livelihood earning opportunities for the majority of people in the Global South, it has remained a largely forgotten sector in policy making in most countries. It is, therefore, important that informal work be taken seriously and efforts must be made to improve working conditions for the urban working poor in the developing world. The purpose of this study is to investigate on the self-reported experiences of informal workers to understand their perspectives surrounding the concept of decent work in the Zimbabwean context. The case study is the Bulawayo metropolitan province, and this study targeted informal workers who trade within the central business district. The study also aimed to measure the decent work deficit scores between two economic sectors (food and clothing traders). This was done by testing the suitability of the Edward Webster Decent Work Deficit Index as a methodology of measuring decent work at a micro level. The analysis is based on a mixed methods study which was carried out through the use of a semi-structured survey. The study revealed that decent work for the sampled informal workers meant work related improvements, insurances and risk management, right of expression and business advancement skills which closely resembles the International Labour Organisation's conceptualisation of decent work. The study also highlighted that childcare assistance and disability insurance are concepts which remained excluded in the current conceptualisation of decent work. The thesis offers a new policy angle which shows that to promote decent work the concept of heterogeneity must be adopted because inequalities persist within the informal economy. The study also suggested that the Edward Webster Decent Work Deficit Index can be used as an appropriate methodology of monitoring the progress towards achieving decent work at the micro level i.e. industry or individual level. This is because since the formation of the decent work concept; the International Labour Organisation has only provided a methodology of how to measure the progress of decent work at the county level. The survey findings revealed that food vendors scored more poorly on the decent work deficit index compared to the clothing traders. The study also identified that food vendors and clothing traders are faced with different challenges which suggests that policy makers must take that into consideration when attempting to design policies or programmes which are aimed at assisting informal workers.
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- Date Issued: 2020
Development of a degreasing and anti-fogging formulation for wet wipe application for automotive glass surfaces
- Authors: Bosch, Tanya
- Date: 2012
- Subjects: Porous materials -- Transport properties , Hydrophobic surfaces , Vapor degreasing , Cleaning compounds , Water-soluble polymers
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10418 , http://hdl.handle.net/10948/d1013177
- Description: It was the objective of this project to provide a glass cleaner formulation for a wet wipe application with cleaning and anti-fogging properties. This glass cleaner formulation was developed for automotive glass i.e. interior of windscreens. This formulation relates to a glass cleaner with a composition comprising of: (a) a blend of amphoteric surfactants; (b) a solvent system with a combination of glycol ethers; and (c) an aqueous solvent system. This glass formulation must provide good cleaning properties while also providing good wetting and sheeting properties to assist with anti-fogging properties. The objectives were obtained using 2 specific approaches: The first was by using a blend of 2 amphoteric surfactants in an alkaline medium, allowing the glass surface to become more hydrophilic which will also assist with reduction of surface tension on the glass surface. The second was by using the glycol ethers that have good coupling properties and surface tension reducing properties. The formulation was evaluated using commercial standard test methods as per the industry. A predictive model was successfully obtained for each of the five criteria that were evaluated using the 25 formulations derived from the statistical design. There were variables and variable interactions that were antagonistic for some of the criteria which were found to be synergistic for others. To achieve satisfactory cleaning, the fogging rating had to be compromised.
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- Date Issued: 2012
Fatty acid composition, colour stability and lipid oxidation of mince produced from fresh and frozen/thawed fallow deer meat
- Authors: Chido, Chakanya
- Date: 2016
- Subjects: Lipids -- Oxidation Meat -- Preservation Mincemeat
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2479 , vital:27874
- Description: The aim of the study was to determine the fatty acid composition, colour stability and lipid oxidation of fresh mince produced from fallow deer and to evaluate the effect of frozen storage duration on the retail display shelf life of the mince. A total of 31 fallow deer carcasses were used in the study. After cooling for 24hrs, the carcasses were deboned, external fat from the fore and hindquarter muscles removed and individually vacuum packed. For the first trial, seven fallow deer carcasses were used. Meat from the hind and fore-quarters of each carcass was divided into two equal batches per animal. One batch was minced (through a 5 mm die) and packed into oxygen permeable overwraps and refrigerated at 4°C for a period of eight days under retail display conditions. The second batch was vacuum packed and frozen at -20°C for 2 months at the end of which mince was also produced and monitored over an eight-day period under the same conditions that were used for the fresh mince. Colour, pH, lipid and myoglobin stability was determined. Proximate and fatty acid composition was also determined. No differences (P>0.05) were noted between proximate composition of fresh and frozen/thawed minced meat. The lipid content of fallow deer was 2.4 percent (±0.04). Total n3 fatty acids differed (P<0.05) between treatments and decreased with increased storage and display day. There were significant (P<0.05) treatment and time interactions on all measured colour parameters, TBARS and myoglobin forms. Fresh mince was lighter and had higher redness (a*) and yellowness (b*) values than mince from two months frozen stored meat. Hue angle for fresh mince remained stable throughout display whereas it increased for frozen/thawed mince. Fresh mince had lower TBARS values than frozen/thawed mince. Minced meat produced from frozen/thawed deer meat had higher surface met-myoglobin and total met-myoglobin percentages. Surface and total oxy-myoglobin percentage was higher in fresh mince. The first trial clearly showed colour and lipid stability differences between fresh mince and mince from frozen/thawed meat. It also showed that fresh mince has a longer retail display life than mince produced from frozen/thawed meat (six days and four days, respectively). In the second trial, the effects of frozen storage duration on colour and lipid stability were investigated. Twenty-four fallow deer were used. Twelve were harvested in June (6male 6female) and the other twelve in August (6 male 6female) of the same year.Twenty four hours after harvesting, the fore and hindquarter muscles of the carcasses were deboned, vacuum packed and kept at -20°C until October (i.e. 2months and 4months frozen storage period). Upon thawing, the meat was processed into mince following the same procedure used for the first trialand displayed for a fiveday period under retail display conditions. Frozen duration and gender had no effect (P>0.05) on the proximate composition of fallow deer meat. The total amount of saturated fatty acids (SFA) increased and total amount of poly unsaturated fatty acids (PUFA) decreased as frozen duration and display day increased (P<0.05). Frozen duration affected (P<0.01) lipid oxidation and percentage oxy-myoglobin. Mince pH and all colour parameters (L*, a*, b*,hue and chroma) differed (P<0.05) between treatments on day zero and three. Display day was a significant factor (P<0.05) on all measured parameters. By day three all parameters except pH showed signs of extended oxidation and discolouration as evidenced by reduced redness, decreased colour intensity and high TBARS values. This study showed that prolonged frozen storage negatively affects the colour and lipid stability of meat and increases oxidation of PUFAs during frozen storage. However, the study also suggests that although frozen/thawed meat has a shorter retail display shelf life; the proximate composition of the meat remains unchanged.
- Full Text:
- Date Issued: 2016
The design of a research centre for the study of indigenous medical plants, Walter Sisulu University, Mthatha
- Authors: Dabula, Xola
- Date: 2016
- Subjects: College buildings , Research institutes -- South Africa -- Eastern Cape -- Designs and plans , Architecture -- Technological innovations -- South Africa -- Eastern Cape , Architecture, Modern
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/18718 , vital:28710
- Description: This treatise is preoccupied with the design of an Indigenous Medicine Research Institute within the region of (the former) underdeveloped Transkei. The interest in the matter developed out of a concern for a medical system which finds itself in jeopardy of depletion due to over-harvesting which is endangering the ecosystem and its dependents. This is as a resultant lack of development due to its informal nature, and loss of impact of traditional knowledge. Indigenous medicine forms part of the cultural, religious, medical and socio-economical back bone of the region, research will create opportunities for the discovery of new medicinal plants and exploring the applications of age-old remedies in contemporary times. Thus developing and promoting indigenous medicine of the region to a wider user group, in a sustainable method which will protect the environment. Architecturally, the design seeks to respond to an in-depth quest to identify the appropriate nurturing of the relationship between learning and the natural environment, while accommodating the necessary programmatic components which will satisfy the needs of the Institute; namely education, conservation and research. Central to the design is the development of an architecture that addresses the fundamental challenges of education, conservation and the research of plants, in a manner that provides opportunities for collaborative learning practices and an interchange between the user-groups and the plants to be studied, resulting in a building that is at harmony with nature. Through this collaboration of the diverse components, an effective scheme has evolved which offers a singular co-operative environment for the indigenous medical system, in a particular effort to transform the learning environment and extend of the knowledge, as a catalyst for further development and reconciliation with nature. Set in the academic context of the Walter Sisulu University Campus, a once major university in Transkei renowned for its medical department, the Research Institute facility re-establishes the University's medical status in a manner that truly represents its region. The built form will integrate itself into the existing campus conditions in a contemporary way that sets up a response which is conducive to the discovery, preservation and sharing of knowledge pertaining to indigenous medicine.
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- Date Issued: 2016
The nature and origin of gold mineralization in the Tugela valley, Natal Structural and Metamorphic Province
- Authors: De Klerk, Ian Duncan
- Date: 1991
- Subjects: Gold ores -- Geology -- South Africa , Gold mines and mining -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4979 , http://hdl.handle.net/10962/d1005591 , Gold ores -- Geology -- South Africa , Gold mines and mining -- South Africa
- Description: The project area is situated within the Tugela Valley, located in the Northern Marginal Zone of the Natal Structural and Metamorphic Province, and this work outlines the different styles of gold mineralization found in the Tugela Valley. Two different styles have been recognized and both have economic significance:- 1) Epigenetic shear zone-hosted gold occurs in late-stage relatively undeformed thin quartz veins confined to shear zones, and is present in both the greenschist facies Natal Thrust Belt and the amphibolite facies Natal Nappe Complex. However the vast majority of these occurrences are concentrated within the thrust front (i.e. the Natal Thrust Belt). The gold grades (up to 7 g/t) and the hydrothermal alteration assemblages associated with the epigenetic deposits have been documented. 2) An as yet unrecognized occurrence of syngenetic gold mineralization is found associated with the sediment-hosted exhalative massive, to semi-massive, sulphides of the iThuma prospect, located within the amphibolite facies Natal Nappe Complex. Here gold (up to 3 g/t) is concentrated together with the main sulphide are, as well as some gold enrichment (230ppb) in the hydrothermally altered footwall feeder pipe. It is proposed that the epigenetic mineralization was formed as a consequence of the northward directed abduction of the major thrust slices of the Natal Nappe Complex. This increased the permeability of the rocks and provided channelways for the focussing of fluids. Deposition took place at the thrust front where metamorphic hydrothermal fluids interacted with meteoric water.
- Full Text:
- Date Issued: 1991
The effect of grain and soya bean-based diets on chicken production, some egg quality traits, and the potential for allergen carryover to eggs and meat
- Authors: Dokora, Adia-En-Michelle
- Date: 2015
- Subjects: Chickens -- Nutrition Chickens --Feeding and feeds Meat -- Quality
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2946 , vital:28192
- Description: This study determined the effect of maize-, whole wheat-, soya bean-based-diets on the growth performance, egg quality and dressing percentage of chickens, as well as the potential for soy and gluten allergen carryover to eggs and meat from chickens. Twenty 36-week-old Lorham White (LW) hens were divided into two groups and kept in individual cages until they reached 39-weeks of age, with water and feed supplied ad libitum. Ten LW hens were fed a maize/soya bean-based diet (T1) and the other ten birds were fed a maize/soya bean-based diet with a 15 percent whole wheat inclusion (T2) for a period of four weeks, with weekly individual hen weights and group feed consumption figures being recorded. After a two-week diet adaptation period, six eggs per treatment group were collected every second day from the LW hens’ to measure egg quality traits. Every third day, over a 29-day period, six eggs per treatment were collected and analysed for the presence of soy, gluten and gluten-derived peptides using allergen specific enzyme linked immunosorbent assays (ELISA) kits. For the broiler trial, a total of 160 Ross 308 mixed sex day old chicks were used in a completely randomized design. Two dietary treatments were assigned to eight cages (replicate) per treatment, with ten birds per cage. The Ross 308 broiler feeding programme consisted of three phases, starter (day 1 to day 10), grower (day 11 to day 20) and finisher (day 21 to day 28). At the beginning of the trial all chicks were fed T1 which contained a maize/soya bean-based diet for a period of 10 days and then eight cages with 10 birds per cage were randomly selected and fed the T2 diet, which contained a maize/soya bean-based diet with a 15 percent whole wheat inclusion, until they reached 28 days of age. Weekly live weights, feed intake, average daily gain and the average daily feed intake were recorded and calculated. At the end of the grower (day 21) and finisher phase (day 28), one broiler bird was selected per cage to have eight (8) birds per treatment and 16 birds per phase that were slaughtered and breast meat samples were analysed in duplicate for the presence of soy and gluten allergens using ELISA kits. The dressing percentage of hot carcasses was also determined at the end of the finisher phase on eight birds per treatment. For LW hens, live weight (LW) at 39 weeks of age, the average daily feed intake (ADFI) and weekly feed intakes (FI) were significantly different (P < 0.05) between treatments with birds on T2 recording higher gains. As birds age in weeks increased, significant differences (P < 0.05) in live weight values were recorded. Egg quality traits measured (shell weight, yolk weight, albumen weight, albumen height and Haugh units) were significantly different (P < 0.05) between treatments, with eggs from hens receiving T1 recording higher mean values. As hens got older, the colour of egg yolk improved, producing eggs with higher b* (yellowness) values and lower L* (lightness) and a* (redness) mean values. The Haugh unit, significantly improved (P < 0.05) as the hens got older, signifying better quality of eggs. For the broiler birds, growth traits measured indicated that there were no significant differences (P > 0.05) in live weight (LW), average daily feed intake (ADFI), weekly feed intake (FI), feed conversion ratio (FCR), cumulative feed intake (CFI) and cumulative gain (CG) between treatments. No significant differences (P > 0.05) between dressing percentage of broilers from the two treatments were observed. As birds grew, significant differences (P < 0.05) in LW, FI, AFI, FCR, and CFI, over a four-week period were recorded. Results of the allergen analyses indicated that soy and gluten allergens were not carried over from feed into eggs and meat of chickens fed a maize/soya bean-based diet and a maize/soya bean-based with a 15 percent whole wheat inclusion, respectively. In conclusion, a maize/soya bean-based diet and maize/soya bean-based diet with a 15 percent whole wheat inclusion that contained soy and gluten allergens, are feed sources that promote and stimulate 36-week-old LW hen and Ross 308 chicken growth.
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- Date Issued: 2015
Crossing the border : constructions of borderline personality disorder within the South African context: a discourse analytic study
- Authors: Elphick, Marie-Clair
- Date: 2013-07-12
- Subjects: Borderline personality disorder -- South Africa Borderline personality disorder -- Diagnosis
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3184 , http://hdl.handle.net/10962/d1008307
- Description: This research aims to open up for critical discussion the effects of the discourses employed by mental health professionals in relation to the diagnosis of BPO, with a view of questioning the discursive practices available within a South African context. This discussion will situate identified discourses in relation to the subjects and objects to which it refers in an attempt to identify and interrogate dominant discourses which circulate to oppress and discriminate against female 'others' within the mental health setting. This discussion will serve to challenge mainstream, traditional psychology by questioning the utility of deploying these concepts within a South African context as well as the effects this deployment may have. A discourse analytic methodology is employed to identify the constructions of BPO by five mental health professionals working within a government setting. The analysis aims at interrogating the broader role of the identified discourses in supporting institutions, preserving power relations and transmitting ideological practices. Ultimately the aim of the research is to open up for critical debate, through the example of psychology and psychiatry's treatment of BPO; constituted as 'other', the possibility that there may be deleterious consequences for the wholesale acceptance of traditional psychological understandings by mental health professionals working within a South African context. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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Study into the synthesis, characterisation and applications of Vanadium-based metal organic frameworks, using 1, 2, 4, 5-benzenetetracarboxylic acid
- Authors: Feldmann, Wesley
- Date: 2016
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/55245 , vital:26680
- Description: This study focussed on the synthesis, characterisation and catalytic application of synthesised vanadium-based Metal-Organic Frameworks using 1,2,4,5-benzenetetracarboxylic acid as a ligand. A number of synthetic methods were tested in multiple attempts to synthesise a V-MOF, these included; ambient, gel, reflux and solvothermal methods of synthesis. Two products of interest were identified, an ambient synthesis produced a vanadium-based complex with the empirical formula: V2O2(Na2H2B4C).6H2O (RU-V2) and a solvothermal synthesis produced a MOF with the empirical formula: V2O2(H2O)2(B4C) (RU-V1). Both products were characterised using elemental analysis, infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry and X-ray powder diffraction. The catalytic activity of these products was tested, alongside the activity of the solid decavanadate ion, for the conversion of cyclohexene to cyclohexene oxide. The decavanadate ion was included to determine if the ion was catalytically active in the solid state, to potentially be used in the construction of a future MOF or V-complex. The reaction for the conversion of cyclohexene to cyclohexene oxide was chosen, as it has been previously conducted using a V-MOF and was found to be successful. The product of the reaction, the epoxide: cyclohexene oxide, is a very useful precursor for a number of reactions involved in the pharmaceutical industry, so developing catalysts which are able to convert cyclohexene to the epoxide with high yields and selectivities are well sought after in industry. The results of the catalytic reactions were varied, as the materials exhibited high yields and selectivities to the epoxide, but these results were only obtained when water was present in the reaction mixture. Water was able to bring about the cleavage of the bonds between the metal and ligand in a highly coordinated framework, at a faster rate than other solvents, such as decane. This ultimately leads to the structural decomposition of the entire complex or framework, depending upon the reaction time. The use of water was a double edged sword in that it was required to initiate the catalytic reaction, but was also the reason that the catalytic materials were noted to decompose over time. The solid decavanadate ion was only noted to exhibit homogeneous activity by dissolving into the small volume of water present in the reaction mixture. The study proved that using a multidentate ligand such as 1,2,4,5-benzenetetracarboxylic acid yielded products which were highly coordinated in nature and would therefore not have large open spaces associated with them, which is commonly observed with other MOFs. Instead the closed nature of the synthesised complexes and frameworks offered a different environment for catalytic reactions, where the small pores/channels had a controlling and inhibiting effect on the reaction. The conversion of cyclohexene to the epoxide is accompanied with a number of undesired side products, so when using the synthesised closed-natured MOF, it was found that there was a greater selectivity for the epoxide over other potential products. This indicates that close natured MOFs may find application in catalytic reactions which require high selectivities for a particular product.
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- Date Issued: 2016
Selfhood, identity and madness in the works of Milan Kundera and Peter Carey
- Authors: Graven, Ashley Holm
- Date: 2016
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/3904 , vital:20554
- Description: Despite all the critical attention Milan Kundera’s and Peter Carey’s fiction has received, relatively little has been said about the way in which these authors problematise selfhood. In this study, I argue that these two writers share a preoccupation with the strictures placed on the individual by his/her location in language and discourse. I show that they deconstruct subjectivity with a view to intimating the possibility of momentarily transcending discursive control, and thereby inhabiting authentic selfhood. In addition, I demonstrate that both authors draw attention to the nature of language through their thematisation of madness, and I then trace the implications of this nexus between language and madness for the reader, who of course is a subject in language. My contention in this regard is that Carey and Kundera seek to instil in the reader a self-reflexive awareness of the ways in which his/her location in language shapes his/her perception of others. In turn, this awareness charges the reader with the responsibility of questioning his/her judgements, and thereby enables him/her to negotiate a measure of authenticity from his/her position in language.
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- Date Issued: 2016
Distribution of iron-titanium oxides in the vanadiferous main magnetite seam of the upper zone : Northern limb, Bushveld complex
- Authors: Gwatinetsa, Demand
- Date: 2014
- Subjects: Igneous rocks -- South Africa -- Bushveld Complex , Sulfide minerals -- South Africa -- Bushveld Complex , Vanadium -- South Africa -- Bushveld Complex , Titanium dioxide -- South Africa -- Bushveld Complex , Ferric oxide -- South Africa -- Bushveld Complex , Geology -- South Africa -- Bushveld Complex , Mineralogy -- South Africa -- Bushveld Complex , Mines and mineral resources -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5063 , http://hdl.handle.net/10962/d1013281
- Description: The main magnetite seam of the Upper Zone of the Rustenburg Layered Suite (SACS, 1980) on the Bushveld Complex is known to host the world‘s largest vanadium bearing titaniferous iron ores. The vanadiferous titanomagnetites, contain vanadium in sufficient concentrations (1.2 - 2.2 per cent V₂O₅) to be considered as resources and vanadium has been mined historically by a number of companies among them Anglo-American, Highveld Steel and Vanadium and VanMag Resources as well as currently by Evraz Highveld Steel and Vanadium Limited of South Africa. The titanomagnetites contain iron ore in the form of magnetite and titanium with concentrations averaging 50-75 per cent FeO and 12-21 per cent TiO₂. The titaniferous iron ores have been historically dismissed as a source of iron and titanium, due to the known difficulties of using iron ore with high titania content in blast furnaces. The economic potential for the extractability of the titaniferous magnetites lies in the capacity of the ores to be separated into iron rich and titanium rich concentrates usually through, crushing, grinding and magnetic separation. The separatability of iron oxides and titanium oxides, is dependent on the nature in which the titanium oxide occurs, with granular ilmenite being the most favourable since it can be separated from magnetite via magnetic separation. Titanium that occurs as finely exsolved lamellae or as iron-titanium oxides with low titania content such as ulvospinel render the potential recoverability of titanium poor. The Upper Zone vanadiferous titanomagnetites contain titanium in various forms varying from discrete granular ilmenite to finely exsolved lamellae as well as occurring as part of the minerals ulvospinel (Fe₂TiO₄) and titanomagnetite (a solid solution series between ulvospinel and magnetite) . Discrete ilmenite constitutes between 3-5 per cent by volume of the massive titanomagnetite ores, and between 5-10 per cent by volume of the magnetite-plagioclase cumulates with more than 50 per cent opaque oxide minerals. The purpose of this research was to investigate the mineralogical setting and distribution of the iron and titanium oxides within the magnetitite layers from top to bottom as well as spatially along a strike length of 2 000m to determine the potential for the titanium to be extracted from the titanomagnetite ores. The titanomagnetites of the Upper Zone of the Bushveld Complex with particular reference to the Northern Limb where this research was conducted contains titanium oxides as discrete ilmenite grains but in low concentrations whose potential for separate economic extraction will be challenging. The highest concentration of titanium in the magnetite ores is not contained in the granular ilmenite, but rather in ulvospinel and titanomagnetite as illustrated by the marked higher concentration of TiO₂ in the massive ores which contain less granular ilmenite in comparison to the disseminated ores which contain 3 to 8 percentage points higher granular ilmenite than the massive ores. On the scale of the main magnetite seam, the TiO₂ content increases with increasing stratigraphic height from being completely absent in the footwall anorthosite. The V₂2O₅ content also increases with stratigraphic height except for in one of the 3 boreholes where it drops with increasing height. The decrease or increase patterns are repeated in every seam. The titanomagnetites of the main magnetite seam display a variety of textures from coarse granular magnetite and ilmenite, to trellis ilmenite lamellae, intergranular ilmenite and magnesian spinels and fine exsolution lamellae of ulvospinel and ferro-magnesian spinels parallel to the magnetite cleavage. The bottom contact of the main magnetite seam is very sharp and there is no titanium or vanadium in the footwall barely 10cm below the contact. Chromium is present in the bottom of the 4 layers that constitute the main magnetite seam and it upwards decreases rapidly. In boreholes P21 and P55, there are slight reversals in the TiO₂ and V₂O₅ content towards the top of the magnetite seams.
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- Date Issued: 2014
Synthesis, characterization and anticancer studies of Oxovanadium(iv) Dithiocarbamate complexes
- Authors: Hlobo, Priscilla Vuyiswa
- Date: 2019
- Subjects: Inorganic compounds -- Synthesis Chemistry, Inorganic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/19131 , vital:39880
- Description: Eight new oxovanadium(IV) dithiocarbamate complexes, formed by the interaction of vanadyl sulfate pentahydrate and as-synthesized dithiocarbamate ligands, potassium N-morpholine-4- dithiocarbamate ligand (L1), potassium N-piperidinedithiocarbamate (L2), potassium N-(4- methoxyphenyl)dithiocarbamate ligand (L3), potassium N-diallyldithiocarbamate ligand (L4), potassium N-phenyldithiocarbamate ligand (L5), potassium N-dibenzylminedithiocarbamate ligand (L6), potassium N-(4-methylphenyl)dithiocarbamate ligand (L7), N-(1Himidazoledithiocarbamate) fluoride ligand (L8) in aqueous ethanol are described. The resulting complexes were elemental analyses, molar conductance, infrared, electronic, and nuclear magnetic resonance spectral studies. The spectral studies confirmed the formation of the ligands and complexes. Four complexes [VO(L1)2], [VO(L3)2], [VO(L6)2], and [VO(L8)2] derived from potassium N-morpholine-4-dithiocarbamate ligand (L1), potassium N-(4- methoxyphenyl)dithiocarbamate ligand (L3), potassium N-dibenzylminedithiocarbamate ligand (L6), and N-(1H-imidazoledithiocarbamate) fluoride ligand (L8) were characterized using cyclic voltammetry, to study their electrochemical behavior. Square pyramid oxovanadium(IV) complexes were proposed with the metal ion coordinated to two bidentate dithiocarbamate ligands through sulphur to complete its square pyramidal geometry. The anticancer screening of four oxovanadium(IV) dithiocarbamate complexes [VO(L1)2], [VO(L3)2], [VO(L6)2], and [VO(L8)2] are described.
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- Date Issued: 2019
Analysis of selected choral works by John Tavener with particular reference to the post-1977 works
- Authors: Imrie, Sally
- Date: 1998
- Subjects: Tavener, John Choral music
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:2642 , http://hdl.handle.net/10962/d1002307
- Description: This thesis deals with sacred choral music written by John Tavener, a British composer born in 1944. It touches briefly on the background of Tavener and his early works (i.e. from about 1960-1976) - two works from that period have been selected for analysis, Celtic Requiem and Nomine Jesu. The main body of the thesis is concerned with those works composed,.after 1977, which show the influence of the Orthodox Church and Byzantine hymnography on Tavener's stylistic development. The selected works from this period to be analysed are: Ode of St Andrew of Crete, Two Hymns to the Mother of God, Magnificat, Nunc Dimittis, The Uncreated Eros, Eonia and We Shall See Him As Heis.
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- Date Issued: 1998
An investigation into whether a leadership and management development project changed the perceptions of the educators in a black, disadvantaged school
- Authors: Jaftha, A P
- Date: 2003
- Subjects: University of Port Elizabeth -- Institute for Development Planning and Research Delta Foundation -- Centres of Learning School management and organization -- South Africa Educational leadership -- South Africa Educational change -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1620 , http://hdl.handle.net/10962/d1003502
- Description: This study investigates whether a leadership and management development programme changed the management perceptions of the teachers of one of the schools that participated in the programme. The programme seeks to change the organisational culture of schools and develop effective management. The development philosophy of the programme is informed by literature on school effectiveness, organisation development, whole school development and systemic change. My research is conducted in the interpretive paradigm. Interpretive researchers view reality a construct of the human mind, and therefore the way people perceive the world is not necessarily the same since there can be different understandings of what is real. I employ convenience sampling to select the school and purposive sampling to identify my research participants. Whilst overall impression that the data conveys is that much of the programme does not seem to have had a lasting effect on the culture of the school, it nonetheless made an impression on the teachers’ perceptions of management. There clearly seems to be a greater appreciation of participative management processes. The reintroduction of proper prior planning played a decisive role in re-establishing sound work ethics at the school and contributes to a more structured approach to events at the school. Some sort of organisational learning has also been introduced at the school. The realisation on the part of the staff that they now have their destiny in their own hands is an especially critical development. And whilst the vision is not a compelling force in the organisation, it has nevertheless produced some strategic focus at the school. The insights and skills they acquired concerning resource management will also stand them in good stead.
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- Date Issued: 2003
Christo-centric reconciliation : being a dissertation considering reconciliation with particular reference to; the baptism of Jesus, the temptations of Jesus, the title of Son of Man as used by Jesus, and the Pauline texts which refer to reconciliation
- Authors: Jeannot, Hugues Donald
- Date: 1973
- Subjects: Reconciliation -- Biblical teaching , Jesus Christ -- Temptation , Baptism -- Biblical teaching , Son of Man -- Biblical teaching
- Language: English
- Type: Thesis , Bachelor , BDiv
- Identifier: vital:1278 , http://hdl.handle.net/10962/d1013397
- Description: [From Introduction]. "God, ... through Christ reconciled us to himself and gave us the ministry of reconciliation." "Among all churches throughout the world there is a growing conviction that God's great reconciliation in Jesus Christ is still the answer desperately needed by modern man." The United Presbyterian Church U.S.A.'s Confession of 1967 made "reconciliation the all-embracing category for describing God's work and man's response, including especially his response in social and political action".
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- Date Issued: 1973
An investigation into how Zimbabwe's Bulawayo viewers negotiate the gay storyline in Generations
- Authors: Khumalo, Senziwani
- Date: 2015
- Subjects: Generations (Television program) , Homosexuality on television , Homosexuality -- Social aspects -- Zimbabwe -- Bulawayo , Homosexuality -- Law and legislation -- Zimbabwe , Homophobia -- Zimbabwe -- Bulawayo , Social psychology -- Zimbabwe -- Bulawayo
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3543 , http://hdl.handle.net/10962/d1017784
- Description: This study seeks to evaluate how aspects of religion, culture, political context, education and class, amongst others, impact on the manner with which Zimbabwe’s Bulawayo residents make sense of media messages which explore issues of homosexuality, as encountered in the soap opera Generations. This is against the backdrop of Zimbabwean legislation, such as the Sexual Deviancy Act, which criminalises homosexuality and the state victimisation of gays and lesbians in this country. The inclusion of homosexual liberties was rejected by all political parties and both public and private media in the recent drafting of a new rule of law. The legislation, including gay rights exclusion in the new constitution, and state action has perpetuated an impression that Zimbabwe is a deeply homophobic society. As a starting point the study examines the claims of the media imperialism thesis which supposes an all-consuming power of western media and next examines Straubhaar’s thesis of ‘cultural proximity’ which argues that there is often a preference for regional media, which is proximate to viewers’ local culture, language and identity. The study explores the prominence of South Africa as a regional media player and that proximate identities with some cultures in that country have played a role in drawing some Bulawayo viewers to South African television, as they feel slighted by Zimbabwean media. Utilising qualitative research methods, the study explores whether or not the representation of gay images on this South African soap opera provides viewers with opportunities for ‘symbolic distancing’. The concept highlights that when people have insight into lifestyles that are different from their own, they use that as a resource to critically analyse their own lives and cultural understandings. The study evaluates if Bulawayo viewers’ sentiments towards homosexuality has been challenged and changed through their interface with the soap opera, Generations.
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- Date Issued: 2015
Characterization and application of phthalocyanine-magnetic nanoparticle conjugates anchored to electrospun polyamide nanofibers
- Authors: Ledwaba, Mpho
- Date: 2014
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54610 , vital:26593
- Description: This work presents the syntheses, photophysical and photochemical characterization of zinc tetracarboxyphenoxy phthalocyanine (ZnTCPPc, 3) and its gadolinium oxide nanoparticle conjugate (4). By means of spectroscopic and microscopic characterization, the conjugation of the ZnTCPPc to the silica coated gadolinium oxide nanoparticles (Si-Gd2O3 NPs, 2) through an amide bond was confirmed. The thermal stability, morphology, nanoparticle sizes and their conjugates with the Pc were studied using ThermoGravimetric Analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM) and powder X-ray diffractometry (XRD). Conjugation of ZnTCPPc to the magnetic nanoparticles, proved to have a negligible effect on the photophysical parameters of the phthalocyanine, where a slight decrease in fluorescence and triplet quantum yields and lifetimes was observed. The singlet oxygen quantum yield, however, increased slightly upon conjugation, suggesting that the overall efficiency of the ZnTCPPc as a photosensitizer had improved. Physical mixing of the ZnTCPPc and the silica-coated gadolinium nanoparticles also showed an improvement in the singlet oxygen quantum yield and triplet lifetime, also showing an enhanced efficiency for the photosensitizer and therefore photocatalysis. ZnTCPPc (3) alone and the Pc-gadolinium oxide nanoparticle conjugate (4) were therefore electrospun into nanofibers to create a solid support. The fibers were characterized and their diameter sizes and composition was studied confirming the incorporation of the phthalocyanine and gadolinium oxide nanoparticle. Increased singlet oxygen generation resulted in increased Photodegradation of the environmental pollutant Orange G and the fibers were found to be more efficient as photocatalysts compared to the photosensitizer in solution. The nanomaterial may therefore be applied to the photodegradation of Orange G.
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- Date Issued: 2014
Kedibone
- Authors: Mokae, Sabata Paul
- Date: 2014
- Subjects: Creative writing (Higher education) -- Research -- South Africa , Creative writing -- Fiction , South African fiction (English) -- Study and teaching (Higher) , South African fiction (English) -- 21st century
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:6000 , http://hdl.handle.net/10962/d1020883
- Description: A young woman from a rural village near Kimberley is killed by her husband in a fit of jealousy. Her illiterate mother is summoned to the hospital to authorize the removal of vital organs – eyes, liver, kidney and heart – for organ donation. But some members of the family feel that their child should not be buried with parts of her body missing. Thus begins a story that changes the lives of many people, both black and white, over the following twenty years.
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- Date Issued: 2014