A critical analysis of the in-service education courses offered at Trinset, with particular reference to Geography
- Authors: Mniki, Felicia Nobesuthu Vuyiswa
- Date: 2000
- Subjects: Teachers -- In-service training -- South Africa Geography teachers -- In-service training -- South Africa Transkei Teachers' In-service College
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1475 , http://hdl.handle.net/10962/d1003356
- Description: The aim of establishing the Transkei Teachers’ In- Service College (Trinset) in 1986 by the former Transkei Department of Education, was to alleviate the problem of inappropriately qualified teachers. This problem was seen as impacting negatively on the performance of matriculation candidates in the final examinations. In the twelve years since the college’s inception there has been no formal evaluation, this despite the perception of the importance of evaluation as an integral part of planning and implementation for any educational endeavour (Mc Naught, Taylor & O’Donoghue, 1990). This study analyses the courses offered at Trinset with particular reference to the subject of Geography. The aim is to explore how best these courses can support educators in the light of the current changes in South African education. The analysis of the in-service courses used a multifaceted approach guided by the participatory principle underlying Fourth Generation Evaluation. The analysis of the in-service courses offered by Trinset, in particular by the Geography Department, has served to raise questions and to highlight issues that are seen as particularly valuable in the reconfiguration of Trinset that is part of the current educational transformation process in South Africa in terms of the provision of in-service education.
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- Date Issued: 2000
A history of the German settlers in the Eastern Cape, 1857-1919
- Authors: Zipp, Gisela Lesley
- Date: 2013
- Subjects: Colonists -- Eastern Cape -- 19th Century Immigrants -- Germany -- History Immigrants -- Germany -- Social life and customs
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3609 , http://hdl.handle.net/10962/d1004215
- Description: This thesis came into being as the result of a question innocently posed to me three years ago: Why do some towns in the Eastern Cape have German names? This thesis is not so much an answer to that question (which is answered in the following paragraphs) as an attempt to answer the questions that followed: Were the Germans really as benevolent and hard-working as much of the most readily available literature implies? Why did the military settlers leave and the peasant farmer settlers remain? What was the nature of relationships between the German settlers and other groups in the area? How did the German settlers see themselves? The existing literature provides the historic details, more or less, but not the context and explanations I sought. As such, I set out to find them and document them myself, addressing three main questions: 1. What was the (changing) nature of the German settlers' day-to-day lives between 1857 and 1919? 2. How was a German identity maintained/constructed within the German communities of the Eastern Cape between 1857 and 1919? 3. How did the Germans interact with other groups in the area? In answering these questions, I have also provided the necessary background as to why these settlers chose to come to South Africa, and why some of them left. I have limited this study to the period between 1857 and 1919 so as to include the First World War and its immediate aftermath, a time when enmity between Great Britain and Germany would have made life difficult for German descendants in the Union of South Africa. Introduction, p. 7.
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- Date Issued: 2013
A multivariate model of the offence behaviours of South African serial killers
- Authors: Hodgskiss, Brin Allan
- Date: 2013-05-14
- Subjects: Serial murderers -- South Africa -- Psychology Criminal behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3169 , http://hdl.handle.net/10962/d1007793
- Description: It was hypothesised that there would be behavioural consistencies in the offences of South African serial killers. The themes underlying these observable differences can help us understand the nature of these offences. Crime scene data was ohtained from police records, and structured, in-depth offender interviews. 73 offences, committed by 13 offenders, were analysed. The analysis used Smallest Space Analysis (SSA), a Multidimensional scaling (MDS) procedure. This analysis revealed systematic patterns of behaviour in the offences. It was found that the focus of these offences is an impersonal, hostile, and act-focused murder were the victim is treated as a depersonalised object. Empirical support for an underlying thematic structure to these offences was also provided. The offence themes identified relate to the nature of the actions committed during the offence, and the function these actions had for the offender. These fmdings thus support the hypothesis that these offences will display meaningful behavioural variation. These findings have direct utility in the investigation and study of serial killing in South Aflica. They also provide the basis for comparison with previously suggested typologies of serial killing, and indicate directions for future research into this phenomenon in the South African setting. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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A strategic analysis on the meaning of work: a focus on the fashion retail industry
- Authors: Van Heerden, Lisle
- Date: 2016
- Subjects: Retail trade -- South Africa Job satisfaction -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/13936 , vital:27360
- Description: The primary objective of this research study was to strategically analyse the meaning of work for fashion retail industry employees with the aim of developing a calling orientation to work.A sample of 84 fashion retail industry employees from Port Elizabeth, South Africa indicated their perception of callings in work; the pathways to callings in work and job satisfaction. Furthermore, fashion retail industry employees also indicated their use of job crafting techniques as a tool to foster meaningful work. This is one of the first studies conducted on callings in work in the fashion retail industry.Findings of the study indicated that although on average fashion retail industry employees are neutral about having a calling orientation to work, 24-27% indicated to having a calling orientation to work. Furthermore the study showed that there is a positive correlation between 1) transcendent guiding force; 2) value-driven behaviour and sense and meaning; 3) identification with one’s work and person-environment fit and a calling orientation to work. The study also indicated that the presence of a transcendent guiding force and job satisfaction are the two independent variables that are influential in achieving calling orientation to work for fashion retail industry employees of Port Elizabeth. Implications and recommendations from this study are outlined.
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- Date Issued: 2016
A survey of the writing approaches followed by ESL teachers in Port Elizabeth secondary schools where Afrikaans is the first language
- Authors: Harran, Marcelle
- Date: 1994
- Subjects: English language -- Study and teaching -- South Africa -- Foreign speakers Written communication -- Study and teaching -- South Africa English language -- Writing
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1789 , http://hdl.handle.net/10962/d1003674
- Description: In this study an attempt is made to describe and illuminate the current approaches to ESL writing in secondary schools in the Port Elizabeth-Despatch areas where Afrikaans is the first language of the pupils. Teacher and pupil Questionnaires were used as a means of data collection through which the approaches, practices and attitudes to the teaching of ESL writing in the secondary schools in the survey area could be reviewed and assessed. The teacher Questionnaire revealed that most respondents appeared to have a limited awareness or understanding of basic composing processes, especially the role of multiple drafting and teacher intervention in the form of interactive feedback. There is also evidence that there is a limited understanding of how these activities can be effectively implemented in a classroom situation. The pupil Questionnaire was used as a means to extend the understanding of teacher approaches to ESL writing as revealed in the teacher Questionnaire, to enable comparisons to be made and to evaluate the writing approaches currently practised in the ESL classroom. Many of the observations revealed in the teacher Questionnaire were echoed in the analysis of the pupil Questionnaire, especially the limited roles of planning and feedback, treatment of error, attitude to writing and the limited improvement in writing as pupils progress through the secondary school. The analysis also revealed that pupils were reluctant to expose, or share their work with audiences, were pre-occupied with error and viewed the teacher as grade-giver, grammarian and topic-provider. Topic selection was also revealed as a factor which influenced the pupils' negative or indifferent attitudes to writing. Although the process approach was considered a traditional approach to writing by 1986, the analysis and review of the Questionnaire data has revealed that a fair assessment of the state of ESL writing in the survey schools would place the current writing approaches in the traditional product- centred, form-dominated, teacher-centred mould. For this position to change, research pedagogy will need to become part of teacher training and the classroom so that there can be greater teacher awareness and understanding of composing processes and their implementation in the classroom. This is necessary, because research findings have revealed that a genuine orientation to a process approach and the application of composing stategies followed by good writers will result in improved writing progress and pupils having a more positive attitude to writing.
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- Date Issued: 1994
Access to social grants information by the Balfour Village elderly population in Eastern Cape Province, South Africa
- Authors: Faku, Andile
- Date: 2020
- Subjects: Information services Information resources
- Language: English
- Type: Thesis , Masters , MSoc. Sci (Library and Information Science)
- Identifier: http://hdl.handle.net/10353/18096 , vital:42231
- Description: This study sought to investigate the access to information about social grants by the elderly population of Balfour village in Raymond Mhlaba Local Municipality in SA’s Eastern Cape Province. A study on access to information is quite relevant in the knowledge-based economies. People act when they have information and similarly elderly people require information in order to access their grants. This study is quite relevant in the Library and Information Science field. The targeted population for the study were the elderly people of the Balfour village. The qualitative research approach was used in this study. The researcher selected a sample for the study using snowballsampling procedure. Both in-depth interviews and questionnaires were employed as methods of gathering data and thematic analysis of data was used. Results showed that there is a lack of information dissemination and access to information about social grants for elderly people living in Balfour. The study found out that elderly people in Balfour complained that, in most cases, they were not sure about the documents they were supposed to bring with them when they visited the South African Social Security Agency offices. This indicates the need for SASSA to train their staff members to be customer orientated and encourage staff to empower themselves with formal educational qualifications. In addition, the distance to and from SASSA offices is of great concern because elderly people spend significant amounts of money for travelling these distances. Therefore, there must be an office that is situated in a favourable distance to the elderly so that they do not struggle when they want to reach SASSA offices. Another option would be to avail a mobile office that may serve the area two or three times a week.
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- Date Issued: 2020
An analysis of neural networks and time series techniques for demand forecasting
- Authors: Winn, David
- Date: 2007
- Subjects: Time-series analysis , Neural networks (Computer science) , Artificial intelligence , Marketing -- Management , Marketing -- Data processing , Marketing -- Statistical methods , Consumer behaviour
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:5572 , http://hdl.handle.net/10962/d1004362 , Time-series analysis , Neural networks (Computer science) , Artificial intelligence , Marketing -- Management , Marketing -- Data processing , Marketing -- Statistical methods , Consumer behaviour
- Description: This research examines the plausibility of developing demand forecasting techniques which are consistently and accurately able to predict demand. Time Series Techniques and Artificial Neural Networks are both investigated. Deodorant sales in South Africa are specifically studied in this thesis. Marketing techniques which are used to influence consumer buyer behaviour are considered, and these factors are integrated into the forecasting models wherever possible. The results of this research suggest that Artificial Neural Networks can be developed which consistently outperform industry forecasting targets as well as Time Series forecasts, suggesting that producers could reduce costs by adopting this more effective method.
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- Date Issued: 2007
An evaluation of industrial action in selected agro-based infant industries in the Msasa Industrial Area of Harare (Zimbabwe)
- Authors: Kapunura, Gift
- Date: 2018
- Subjects: Strikes and lockouts--Zimbabwe Zimbabwe--Economic conditions
- Language: English
- Type: Thesis , Masters , Sociology
- Identifier: http://hdl.handle.net/10353/15452 , vital:40409
- Description: Agro based-infant industries played a greater role in the development of Zimbabwe since 1980 when the country gained its independence. However, its success has been hindered by industrial action in the country. The continuous increase in the number of industrial action is the major motives of this study. Conversely, with the increasing levels of industrial action in the country, it was noted that the main causes of industrial action were low wages, poor communication between employers and employees, disparities in pay structures, lack of consultation in the process of decision-making and poor working conditions. The study adopted a qualitative approach in data collection and analysis. Thirty in-depth interviews were undertaken with selected participants who are the workers and managers of agro-based infant industries using purposive sampling technique in Msasa industrial area. Findings of the study show that main forms of industrial action were industrial strike, sit in, absenteeism, go slow, work to rule and overtime ban. Major findings of the study point to the fact that industrial action affects the solidarity of workers negatively since some of the workers will not stand for others when they are dismissed after industrial action. In general, industrial action therefore weakens worker solidarity. Secondly, industrial action affects the economic welfare of workers and their families negatively. This is because during the period of industrial action there could be pay cut and the families will not be able to afford basic commodities, thereby affecting their general welfare as well as bringing tension and conflicts within the families. Thirdly, it is also acknowledged in the study that industrial action affects employer-employee relations.
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- Date Issued: 2018
An evaluation of the use of testamentary and Inter vivos trusts as estate-planning vehicles and the development of holistic estate-planning models involving the use of these trusts
- Authors: Naidoo, Loganathan
- Date: 2013
- Subjects: Commission of Inquiry into Certain Aspects of the Tax Structure of South Africa Income tax -- Law and legislation -- South Africa Taxation -- Law and legislation -- South Africa Trusts and trustees -- South Africa Trusts and trustees -- Taxations -- South Africa Estate planning -- South Africa Estates (Law) -- South Africa Administration of estates -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:904 , http://hdl.handle.net/10962/d1008100
- Description: Trusts are subject to multiple forms of legislative regulation dealing with taxation and governance. Trusts were widely used by planners as tax avoidance shelters. Tax legislation was amended to subject trusts, other than special trusts as defined, to the highest income tax rate of forty percent, in terms of section 5(2) of the Income Tax Act, 58 of 1962. The inter vivos trust is also subject to a wide range of anti-avoidance measures, including those contained in sub-sections (3) to (8) of section 7 of the Income Tax Act and Part X of the Eighth Schedule to the Act, as well as the general anti -avoidance measures in section 103. These measures impact negatively on the use of trusts for estate-planning purposes. The research objective was to evaluate the use of testamentary and inter vivos trusts for estate-planning purposes and to develop a holistic estate-planning model incorporating these planning instruments. Both the testamentary trust and the inter vivos trust were evaluated against broad principles of effective estate planning and the taxes and duties applicable to them. The research also reviewed the writings of financial planners on various techniques and models used for estate planning, as wells as case studies documented in the literature. The research developed and evaluated holistic estate-planning models incorporating testamentary trusts and inter vivos trusts, respectively. By neutralizing the effects of various taxes and duties, it was demonstrated that it is possible to develop an estate plan that satisfies most of the requirements of effective estate planning.
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- Date Issued: 2013
An exploration of the use of the transformational leadership style in enhancing public service delivery : the case of Buffalo City Metropolitan Municipality
- Authors: Dlamkile, Phumlani
- Date: 2016
- Subjects: Leadership Organizational change Organizational effectiveness
- Language: English
- Type: Thesis , Masters , MAdmin
- Identifier: http://hdl.handle.net/10353/8245 , vital:32095
- Description: A clear vision and understanding of the leadership roles by the leaders of the municipality under study are questionable, the low rate of the public service delivery and the lack of accountability by municipality officials also rises some concerns. The aim of this research is therefore to establish a level of understanding of the transformational leadership style in enhancing public service delivery. The study used a qualitative research design that involves a desktop research. Data was collected through the review of available published or existing documents. Data analysis included using documents analysis which consist of the existing information reviewed from literature or document containing information about various municipalities issues, journals and books as well as reviewed of various data analysis done in relation to an exploration of the use of transformational leadership style in enhancing public service delivery with the aim of analysing the organisation structure of the municipality. The findings from previous literature revealed that there are constraints faced in delivering services. The study confirmed some of the municipal leaders’ lack skills, competencies and a lack of clear understand of transformational leadership style as well as training. The findings also identified the search for solutions to the hurdles or challenges faced by the municipal leadership both political and administrative in Buffalo City Metropolitan Municipality by providing an insight for further research regarding the institutional weakness and policy issues in this part of the world. The implications of the findings are that unless the challenges are resolved, municipalities will continue to experience poor service delivery, poor economic growth and development. Recommendations to overcome these are suggested.
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- Date Issued: 2016
An investigation into understanding the experiences of the level 5-7 student teachers when teaching fractions in primary schools in Namibia: a case study
- Authors: Vatilifa, Ndamononghenda
- Date: 2013
- Subjects: Mathematics -- Study and teaching (Elementary) -- Research -- Namibia -- Case studies Fractions -- Study and teaching (Elementary) -- Research -- Namibia -- Case studies Mathematics teachers -- Training of -- Namibia -- Case studies Education, Elementary -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1398 , http://hdl.handle.net/10962/d1001792
- Description: The Namibian government through the Ministry of Education seeks for teachers to meet the demands and rise to the challenges of the post-independence basic education system. Therefore the University of Namibia Education Faculty must ensure through the training of student teachers for both lower, upper primary and secondary school level that these demands are met. Research shows that one of the major challenges in teacher training programs, specifically in the mathematics education programmes, lies with the student teachers’ difficulties in dealing with various topics in mathematics, particularly fractions. The teaching of fractions is a challenging area at primary level and lays the foundation for understanding different topics in upper grades such as algebra, ratio and proportion, statistics and probability, to mention just a few. This study focused on an exploration of teaching fractions by five student teachers during their teaching practice.The main purpose was to gain an understanding of the experiences of the level 5-7 student teachers with regard to their practice of fraction teaching; their experience of the mathematics education course with respect to the teaching of fractions; and their prior experience related to fractions and fraction teaching at Grade 6 level. The findings from this research showed that student teachers viewed mathematics, specifically fractions, as just about doing calculations, doing drill and practice as in this way learners’ understanding of fractions is enhanced. The importance of using rules and procedures was emphasized as paving the way to mastering fractions. The data analysis also revealed that student teachers employed different teaching approaches when they considered learners’ prior knowledge. However, they misinterpreted the learner-centred approach in terms of group work and class discussion in their teaching of fractions. The data also revealed that some student teachers had an understanding of fractions as they managed to redirect their learners from applying some fraction misconceptions. The findings further showed that due to lack of understanding most of the participants experienced fear and anxiety in their fraction teaching; attempted an approach then reverted to old practices used in schools; taught fractions as symbolic representations where no meaning was involved; used incorrect terminologies such as ‘1 over 4’ or ‘1 out of 4’ instead of a ‘quarter’ or ‘one-fourth’. It is further revealed that the some student teachers viewed a fraction as a pair of two different whole numbers and can be broken apart. The findings of this study yielded one main implication for the teaching of mathematics: that the teacher training programs, specifically for mathematics teachers, must take into consideration the weaknesses and strengths of the student teachers shown in this study to properly train and prepare them to become effective mathematics teachers.
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- Date Issued: 2013
Evaluation of some Eastern beach bacteria for high activity laccase production
- Authors: Ntlatywa, Nonkolisi
- Date: 2019
- Subjects: Laccase
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/${Handle} , vital:40025
- Description: Laccases are multi-copper oxidases endowed with huge applicability and versatility. They are found in nature, fungi, insects, archaea and bacteria; however, there is a dearth of information regarding bacterial laccases. Thus, the search for novel bacterial laccases becomes crucial. Therefore, the broad aim of the study was the assessment of some bacteria on marine water isolated from Eastern beach for the production of high activity laccases. In this study, marine water samples obtained from the Eastern beach in East London were investigated for bacterial laccase-producing isolates. The samples were analysed using different microbiological media and varied substrates via qualitative methods. The isolates were tested for laccase activity using ABTS (2, 2’- azinobis 3-ethyl-benzothiazoline-6-sulphonate), as a substrate. The present study also dealt with the optimization of culture conditions for laccase production and characterization of laccase. A total of forty-eight (48) bacterial isolates were obtained, which were identified based on their morphological and cultural characteristics. Many of the isolates (42) were categorized as Gram positive and a few (6) as Gram negative upon subjecting to microscopic examination. Result showed that on average, laccase activity ranged from 5.33 – 6.5 U/L as demonstrated by three bacterial isolates (Bacillus sp. NFN1, Bacillus sp. NLN and Escherichia coli LO). Laccase production was highly enhanced by the supplementation with vanillic acid by Bacillus sp. strain NLN with yield of 15.83 ± 0.7 U/L, Bacillus sp. strain NFN1, 12.72 ± 0.21 U/L. However, Escherichia coli LO demonstrated enhanced laccase production with guaiacol (12.84 ± 1.12 U/L) followed by ferrulic acid (12.8 ± 0.36 U/L). While optimization results revealed that the laccase yield was enhanced under the following conditions: 72 h of incubation, pH 5, 0.5mg/L lactose as a carbon source, 1. 5 mg/L yeast extract as a nitrogen source as well as in the presence of corn stover and mandarin peels as lignocellulosic substrates depending on the bacteria.The time course and stability of laccase against temperature, pH, metal ions and organic solvents were investigated using previously described methods. In the findings obtained for the time course, the laccase activity ranged from 22.2- 23.98 U/L. In general, the optimum parameters for the optimum laccase activities depended on the bacterial isolates and the time of incubation and included 80 °C and 70 °C, pH 3 and 9 while, the thermal stability was over 100%. Overall, NaCl, ZnSO4, NiCl and 20% acetone demonstrated positive effect on the residual activity of the laccases of all the bacterial isolates (Bacillus sp. NFN1, Bacillus v sp. NLN and Escherichia coli LO). In conclusion the findings of the study, suggest that marine water of the Eastern beach is a rich source for laccase producing bacteria with potential of high activity.
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- Date Issued: 2019
Ill at ease in our translated world ecocriticism, language, and the natural environment in the fiction of Michael Ondaatje, Amitav Ghosh, David Malouf and Wilma Stockenström
- Authors: Johnson, Eleanore
- Date: 2011
- Subjects: Ondaatje, Michael, 1943- The English patient Ghosh, Amitav. The hungry tide Malouf, David, 1934- An imaginary life Stockenström, Wilma. The expedition to the Baobab tree Ecocriticism Human ecology in literature Nature in literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2234 , http://hdl.handle.net/10962/d1002277
- Description: This thesis explores the thematic desire to establish an ecological human bond with nature in four contemporary novels: The English Patient by Michael Ondaatje, The Hungry Tide by Amitav Ghosh, An Imaginary Life by David Malouf, and The Expedition to The Baobab Tree by Wilma Stockenström. These authors share a concern with the influence that language has on human perception, and one of the most significant ways they attempt to connect with the natural world is through somehow escaping, or transcending, what they perceive to be the divisive tendencies of language. They all suggest that human perception is not steered entirely by a disembodied mind, which constructs reality through linguistic and cultural lenses, but is equally influenced by physical circumstances and embodied experiences. They explore the potential of corporeal reciprocity and empathy as that which enables understanding across cultural barriers, and a sense of ecologically intertwined kinship with nature. They all struggle to reconcile their awareness of the potential danger of relating to nature exclusively through language, with a desire to speak for the natural world in literature. I have examined whether they succeed in doing so, or whether they contradict their thematic suspicion of language with their literary medium. I have prioritised a close ecocritical reading of the novels and loosely situated the authors’ approach to nature and language within the broad theoretical frameworks of radical ecology, structuralism and poststructuralism. I suggest that these novels are best analysed in the context of an ecocritical mediation between poststructuralist conceptions of nature as inaccessible cultural construct, and the naïve conception of unmediated, pre-reflective interaction with the natural world. I draw especially on the phenomenological theories of Maurice Merleau-Ponty, whose insistence that perception is always both embodied and culturally mediated truly renders culture and nature irreducible, intertwined categories. By challenging historical dualisms like mind/body and culture/nature, the selected novels suggest a more fluid and discursive understanding of the perceived conflict between language and nature, whilst problematizing the perception of language as merely a cultural artefact. Moreover, they are examples of the kind of literature that has the potential to positively influence our human conception of nature, and adapt us better to our ecological context on a planet struggling for survival.
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- Date Issued: 2011
Improved singlet oxygen generation by a novel bodipy dye and a study of upconverison nanoparticles mixed with a functionalized bodipy compound
- Authors: Wildervanck, Martijn Johannes
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3718 , vital:20538
- Description: This research explores the use of the versatile 4,4-difluoro-4-boro-3a,4a-diaza-s-indacene (BODIPY) dyes and the modification of their spectroscopic properties. The synthesis of a tetramethyl-BODIPY bearing a sterically hindered meso-phenyl ring with an ethynyl functional group at the para-position was compared to that of its freely rotating counterpart with no methyl substituents on the BODIPY core, with the fluorescence properties in particular proving to be markedly different. These phenyl-ethynyl-substituted BODIPYs were used as the starting materials for the synthesis of novel BODIPY dyes for sensor applications via Sonogashira coupling reactions at the ethynyl position, but this resulted instead in the serendipitous synthesis of a novel BODIPY dimer in which the para-positions of the meso-phenyl rings are linked by a diethynyl bridge. Following iodination at the 2, 6-positions, the dimer was found to have a singlet oxygen quantum yield of 0.88, compared to the value of 0.86 that was obtained for the analogous monomer. Since the εmax values for the main spectral bands of the dimers are significantly higher, the compounds may be of interest for singlet oxygen generation applications. A second study was carried out on the interaction between methyl ester functionalized BODIPY dyes and upconversion nanoparticles (UCNPs) to explore the possible use of BODIPY-UCNP conjugates in biomedical applications. The singlet oxygen generation properties of the BODIPY were tested following iodination at the 2, 6-positions, a singlet oxygen quantum yield value of 0.86 was obtained. Three sets of oleate capped UCNPs were synthesized with different diameters and were rendered water dispersible with the addition of a silica shell. The necessary scaffolding for conjugation to the BODIPY was provided by amine groups following functionalization of this shell. All of the sets of oleate capped and silica coated UCNPs were characterized by transmission electron microscopy (TEM) and X-ray diffractometry (XRD) and their emission properties were studied upon excitation at 978 nm with a diode laser with a Picoquant Fluotime 300 spectrophotometer that enables the measurement of anti-Stokes emission. The potential utility of UCNP-BODIPY conjugates for singlet oxygen applications, such as PDT, was then assessed.
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- Date Issued: 2016
Invariant control systems and sub-Riemannian structures on lie groups: equivalence and isometries
- Authors: Biggs, Rory
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64815 , vital:28607
- Description: In this thesis we consider invariant optimal control problems and invariant sub-Riemannian structures on Lie groups. Primarily, we are concerned with the equivalence and classification of problems (resp. structures). In the first chapter, both the class of invariant optimal control problems and the class of invariant sub-Riemannian structures are organised as categories. The latter category is shown to be functorially equivalent to a subcategory of the former category. Via the Pontryagin Maximum Principle, we associate to each invariant optimal control problem (resp. invariant sub-Riemannian structure) a quadratic Hamilton-Poisson system on the associated Lie-Poisson space. These Hamiltonian systems are also organised as a category and hence the Pontryagin lift is realised as a contravariant functor. Basic properties of these categories are investigated. The rest of this thesis is concerned with the classification (and investigation) of certain subclasses of structures and systems. In the second chapter, the homogeneous positive semidefinite quadratic Hamilton-Poisson systems on three-dimensional Lie-Poisson spaces are classified up to compatibility with a linear isomorphism; a list of 23 normal forms is exhibited. In the third chapter, we classify the invariant sub-Riemannian structures in three dimensions and calculate the isometry group for each normal form. By comparing our results with known results, we show that most isometries (in three dimensions) are in fact the composition of a left translation and a Lie group isomorphism. In the fourth and last chapter of this thesis, we classify the sub-Riemannian and Riemannian structures on the (2n + 1)-dimensional Heisenberg groups. Furthermore, we find the isometry group and geodesics of each normal form.
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- Date Issued: 2015
Investigating soil microbial interactions of Portulacaria afra
- Authors: Fulmaka, Aviwe
- Date: 2016
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54598 , vital:26592
- Description: Portulacaria afra commonly known as Spekboom contributes significantly to carbon sequestration and has been widely planted in degraded areas of the Eastern Cape. Approximately 50% of planted cuttings do not survive although the cause of this decline is unknown. Like many indigenous plants, Spekboom forms a symbiotic relationship with mycorrhizal fungi and the interaction with rhizobacteria may enhance and improve plant growth and establishment. This study aims to investigate these relationships which will include a survey of the arbuscular mycorrhizal (AM) fungal populations associated with Spekboom, determination of the causal agent of Spekboom decline, isolation and identification of the associated rhizobacteria and investigation of their plant growth promotion properties and assessing the ability of arbuscular mycorrhizal fungi and selected rhizobacteria to enhance establishment and growth of Spekboom. Soil and root samples from selected trial sites were used to assess AM fungal spore abundance and colonisation; isolation, characterization, and identification of rhizobacteria and determine the interaction of the microbes on Spekboom growth and tolerance to Fusarium. AM spore abundance and percentage root colonisation did not differ between the three Spekboom plots. Molecular analyses of the SSU region from the plots showed 4 families of AM fungi and were identified as Ambisporaceae, Glomeraceae, Claroideoglomeraceae and Paraglomeraceae. A suspected Fusarium pathogen was isolated and molecularly identified. Pathogenicity tests indicated reduced Spekboom growth with poor root development. Thirty four rhizobacterial isolates were tested for various plant growth promoting abilities. Of these, 6 were able to produce IAA which may promote plant root growth, 27 siderophores and 23 were phosphate solubilisers. Bacterial isolates were molecularly identified to be from various species of Bacillus, with some Arthrobacter, Enterobacter, Pseudomonas and Microbacterium. Inoculation of Spekboom cuttings with mycorrhizal fungi and selected rhizobacterial isolates significantly improved shoot height. Spekboom cuttings challenged with Fusarium and inoculated with mycorrhizal fungi and two rhizobacterial isolates significantly improved growth. The inoculation of cuttings in the nursery with mycorrhizal fungi and selected rhizobacteria is recommended prior to establishing Spekboom in the field.
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- Date Issued: 2016
Isolation, characterization and biomimetic oxidation of selected marine natural products and their analogues
- Authors: Mutsvairo, Tafadzwa
- Date: 2016
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/64685 , vital:28592
- Description: Marine brown algae produce a variety of terpenes with a wide range of biological activities. However, very few phytochemical studies of brown algae have been conducted in South Africa. Therefore, in our continued search for biologically active natural products, we examined the South African brown alga Brassicophycus brassicaeformis. The dichloromethane-methanol extract of B.brassicaeformis was fractionated by silica gel column chromatography followed by normal phase HPLC to give pure four pure compounds which were identified by spectroscopic methods as; fucosterol, fucoxanthin and two monogalactosyldiacylglycerol lipids. Many potential drug molecules such as natural products have failed to reach the market due to poor pharmacokinetic and metabolic profiles despite having potent biological activity. Therefore the importance of early drug metabolism studies in the drug development process is clear. A biomimetic oxidation model was used for in vitro drug metabolism studies to predict any possible metabolites that could be produced by these natural products. Two biomimetic oxidation models catalyzed by two water soluble metalloporphyrins as biomimics of cytochrome P450, in the presence of two terminal oxidants either hydrogen peroxide or iodobenzene diacetete were successfully developed. The models were applied to a range of natural products. The oxidation of the quinone natural products, sargahydroquinoic acid, and lapachol was most easily achieved by metalloporphyrins employed in this study.
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- Date Issued: 2016
Laypersons’ perceptions and livelihood uses of invasive alien species (Opuntia ficus-indica) in the Eastern Cape Province, South Africa
- Authors: Mdweshu, Luleka
- Date: 2020
- Subjects: Opuntia ficus-indica
- Language: English
- Type: Thesis , Masters , MSc (Botany)
- Identifier: http://hdl.handle.net/10353/18720 , vital:42727
- Description: Opuntia ficus-indica is a succulent plant species that originated from Mexico and parts of neighbouring middle-America and introduced in South Africa by white settlers in the eighteenth century. The species is now categorized as invasive in South Africa but has both commercial and non-market uses. This study evaluated the livelihood uses and local perceptions of O. ficus-indica of rural residents in Makana, Ngqushwa and Raymond Mhlaba Local Municipalities in the Eastern Cape province in South Africa. Data on the livelihood uses and local perceptions on the species in the study area were gathered through community focus group discussions and household surveys using semi-structured questionnaires between June 2018 and August 2019. A sample of 150 participants selected via snowball-sampling technique provided detailed accounts on utilization of O. ficus-indica in the study area. The importance of O. ficus-indica as a useful plant species was ubiquitously perceived, with all respondents reporting its contribution towards their livelihood needs and more than three quarters (88.0%) using the species on a regular basis. Majority of the respondents (41.0%) regarded O. ficus-indica as an important source of cash income while about a third (33.0%) regarded the species as an important source of food products and nutrition. Interviews with respondents revealed that O. ficusindica is currently being harvested from the wild with 73.3% of the respondents reporting that the abundance of the species was decreasing. The positive socioeconomic contributions of O. ficus-indica need to be taken into account when assessing the costs resulting from invasions caused by alien plant species. This study is a crucial starting point in trying to understand and initiate the management of alien invasive species such as O. ficus-indica. Results of this study are also important for understanding local peoples’ perceptions of new introductions and management of existing alien plants in the province.
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- Date Issued: 2020
Linking institutional and ecological provisions for wastewater treatment discharge in a rural municipality, Eastern Cape, South Africa
- Authors: Muller, Matthew Justin
- Date: 2013
- Subjects: Sewage disposal plants -- South Africa -- Sundays Estuary (Eastern Cape) , Sewage disposal -- Law and legislation -- South Africa , Sewage -- Environmental aspects -- South Africa , Water-supply -- South Africa -- Management , Sewage disposal in rivers, lakes, etc. -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Environmental aspects -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Regulation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6044 , http://hdl.handle.net/10962/d1013048
- Description: The Green Drop Certification Programme, launched in 2008 alongside the Blue Drop Certification Programme, aims to provide the Department of Water Affairs with a national overview of how municipalities and their individual wastewater treatment works (WWTW) are complying with licence conditions set by the National Water Act (NWA) (No. 36 of 1998; DWAF 1998) and the Water Services Act (No. 108 of 1997; DWAF 1998). By publishing the results of each municipality’s performance, the programme aims to ensure continuous improvement in the wastewater treatment sector through public pressure. The programme has been identified by this project as a necessary linking tool between the NWA and the Water Services Act to ensure protection and sustainable use of South Africa’s natural water resources. It does this through assisting municipalities to improve their wastewater treatment operations which in theory will lead to discharged effluent that is compliant with discharge licence conditions. These discharge licences form part of the NWA’s enforcement tool of Source Directed Controls (SDC) which help a water resource meet the ecological goals set for it as part of Resource Directed Measures (RDM). The link between meeting the required SDC and achieving the RDM goals has never been empirically tested. This project aimed to determine the present ecological condition of the Uie River, a tributary of the Sundays River which the Sundays River Valley Municipality (SRVM) discharges its domestic effluent into. It then determined whether the SRVM’s WWTW was complying with the General Standard licence conditions and what the impact of the effluent on the river was through the analysis of monthly biomonitoring, water chemistry and habitat data. Lastly, the project examined the effectiveness of the Green Drop Certification Programme in bringing about change in the SRVM’s wastewater treatment sector, which previously achieved a Green Drop score of 5.6 percent. It wanted to examine the underlying assumption that a WWTW which improves its Green Drop score will be discharging a better quality effluent that will help a water resource meets the RDM goals set for it. The Kirkwood WWTW did not have a discharge licence at the time of assessment and was thus assessed under the General Standard licence conditions. It was found that the Kirkwood WWTW was not complying with the General Standard discharge licence conditions in the Uie River. This was having a negative impact on the river health, mainly through high concentrations of Total Inorganic Nitrogen (TIN-N), orthophosphate and turbidity. The SRVM should see an improvement in its Green Drop score for the Kirkwood WWTW. However, the municipality showed no implementation of necessary programmes. Implementation of these programmes would help the SRVM meet the General Standard licence conditions (part of SDC) which would help the Uie River meet the RDM goals set for it.
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- Date Issued: 2013
Moringa oleifera leaf powder as a functional antioxidant additive in pork droewors
- Authors: Mukumbo, Felicitas Esnart
- Date: 2016
- Subjects: Antioxidants Moringa oleifera Pork -- Quality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/15354 , vital:40400
- Description: The study investigated the effect of Moringa oleifera leaf powder (MLP) on physico-chemical characteristics, antioxidant activity, antioxidant compound content and lipid oxidation in pork droëwors. Firstly, the physico-chemical properties (proximate composition, salt content, water activity (aw), pH) of commercially produced droëwors from different types of meat (beef, game, ostrich) were determined. In the second experiment beef and pork droëwors with similar fat content were produced. Physico-chemical properties and lipid oxidation (thiobarbituric reactive substances (TBARS)) during processing and 26 days of storage at 25 °C and 50percent relative humidity (RH) were measured. In the third experiment, antioxidant compounds (Total Phenolic Compounds (TPC), α-tocopherol, β-carotene) in MLP were quantified. Thereafter, 4 treatments of pork droëwors were produced, with MLP included at 0, 0.5, 1 and 2 g/ 100 g. Physico-chemical properties and TBARS were measured at intervals during drying (0, 1.5, 5.75, 27.25, 72 h) and after 7 days of storage under ambient conditions. Antioxidant activity (ferric reducing antioxidant power (FRAP)), TBARS, α- and γ-tocopherol, and β-carotene contents were measured. In the fourth experiment, three batches of droëwors were produced (C: no antioxidant, M0.75: 0.75 g/ 100 g MLP, VE: 15 mg/ kg α-tocopherol oil) and stored at 25 °C and 50percent relative humidity for 112 days. Drying kinetics and α-tocopherol contents of pork droëwors after drying were measured and the physico-chemical properties and TBARS were followed during storage. Results showed no differences (P > 0.05) in the physico-chemical characteristics of beef, game meat and ostrich droëwors; containing on average 25.8 ± 1.25 g/100 g moisture, 42.0 ± 0.10 g/100 g protein, 32.0 ± 1.68 g/100 g fat, 6.2 ± 0.13 g/100 g ash and 4.2 ± 0.10 g/100 g salt; with aw and pH of 0.79 ± 0.015 and 5.3 ± 0.05, respectively. During processing and storage, TBARS were higher (P < 0.05) in pork droëwors (maximum 3.83 mg MDA/kg DM) than in beef (maximum 0.99 mg MDA/kg DM). Moringa oleifera leaf powder contained high levels of TPC (7.5 ± 0.2 mg gallic acid eq/g) and substantial levels of α-tocopherol (76.7 ± 1.9 mg/100 g) and β-carotene (23.2 ± 2.8 mg/100 g). The FRAP, α-tocopherol and β-carotene content of pork droëwors increased (P < 0.05) proportionally with increasing levels of MLP inclusion. Lipid oxidation occurred more rapidly (P < 0.05) when MLP was not added and was similar (P > 0.05) for all MLP treatments. There was no significant effect of the inclusion of 0.75 g/100 g MLP on the drying curves and physico-chemical characteristics of the droëwors. The α-tocopherol content was higher (P < 0.05) and TBARS during storage were lower (P > 0.05) with MLP addition. The results of the current study give an overview of the composition of commercial droëwors and showed higher susceptibility to lipid oxidation in pork droëwors. Moringa oleifera leaf powder exhibited antioxidant activity in pork droëwors, inhibited lipid oxidation and increased the content of α-tocopherol in the product. It can be concluded that MLP could be used as a functional antioxidant additive in pork droëwors.
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- Date Issued: 2016